Last Year Paper Mains (2019)

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JEE Mains 2018
Physics
1. The density of a material in the shape of a cube is determines by measuring three sides of
the cube and its mass. If the relative errors in measuring the mass and length are respectively
1.5% and 1%, the maximum error in determining the density is :
(1) 2.5%
(2) 3.5%
(3) 4.5%
(4) 6%
Solution:
M

L3
 M 3L
 
  L
 1.5  31
 4.5%
Hence the Solution is Option (3)
2. All the graphs below are intended to represent the same motion. One of them does it
incorrectly. Pick it up.
(1)
(2)
(3)
(4)
Solution:
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JEE Mains 2018
(1),(3),(4) uniform retardation & then uniform acceleration.

(2) Normal uniform acceleration & retardation.
3. Two masses m1 = 5 kg and m2 = 10 kg, connected by an inextensible string over a

frictionless pulley, are moving as shown in the figure. The coefficient of friction of horizontal
surface is 0.15. The minimum weight m that should be put on top of m2 to stop the motion is :
(1) 18.3 g
(2) 27.3 kg
(3) 43.3 kg
(4) 10.3 kg
Solution:
To stop the motion,

m1 g  T    m1  m2  g
m1
  m2  m

5
  10  m
0.15
 m  23.3kg
Hence the nearest Solution is Option (2)
4. A particle is moving in a circular path of radius a under the action of an attractive potential
k
U   2 . Its total energy is :
2r
k
(1)  2
4a
k
(2)
2a2
(3) Zero
3 k
(4)
2 a2
JEE Mains 2018
Solution:
K
u
2r 2
du  K
But F   3
dr r
‘ – ‘ sign of force implies attractive force
So,
K mv 2

r3 r
2
mv K
  2  EK
2 2r
K K
UT  2  2
2r 2r
0
5. In a collinear collision, a particle with an initial speed  0 strikes a stationary particle of the
same mass. If the final total kinetic energy is 50% greater than the original kinetic energy, the
magnitude of the relative velocity between the two particles, after collision, is :
0
(1)
4
(2) 20

(3) 0
2
0
(4)
2
Solution:
By cons of linear momentum,
mv0  mv1  mv2
v0  v1  v2 .....  i 
1 2 1 2 1 2
 mv1  mv2    mv0 
Also,   2  100
2 2
1 2
mv
2 0
 50
1
 v12  v22  v02  v02
2
3
 v12  v22  v02
2
Using (i)
JEE Mains 2018
3
 v0  v2   v22  v02
2
2
1
v22  2v0v2  v12  v02
2
 1 
2v22   2v0  v2   v02   0
 2 
2v0  4v02  4v02
v2 
4
v  2v0
 0
2
v  2v0
If v2  0
2
v  2v0
 v1  0
2
So relative velocity :
 v2  v1  2v0
6. Seven identical circular planar disks, each of mass M and radius R are welded
symmetrically as shown. The moment of inertia of the arrangement about the axis normal to
the plane and passing through the point P is :
19
(1) MR2
2
55
(2) MR2
2
73
(3) MR2
2
181
(4) MR2
2
Solution:
Moment of inertia of each disc about the given axis is,
JEE Mains 2018
1 3
I1  MR 2  MR 2  MR 2
2 2
1 19
I 4  MR 2  M  3R   MR 2
2
2 2
1 51
I 7  MR 2  M  3R   MR 2
2
2 2
I net  I1  I 2  I 3  I 4  I 5  I 6  I 7
I net  I1  I 4  I 7
73
I net  MR 2
2
R
7. From a uniform circular disc of radius R and mass 9 M, a small disc of radius is
3
removed as shown in the figure. The moment of inertia of the remaining disc about an axis
perpendicular to the plane of the disc and passing through centre of disc is :
(1) 4MR2
40
(2) MR2
9
(3) 10MR2
37
(4) MR2
9
Solution:
Mass of disc = Volume x Density
9M = A  T   (Area x thickness x density)
9M =  R2  t  ......... i 
For the disc which is cut off.
2
R
M '      t  ......  ii 
3
JEE Mains 2018
(i)Divided by (ii)
9M
9M ' M
M
Moment of inertia of complete disc about an axis passes through O.
1
I1   9M   R2
2
Moment of inertia of cut off disc about an axis passes through O

2 2
1 R  2R 
I2  M     M   
2 3  3 
1 MR2 4MR2
 
2 9 9
So, moment of inertia of remaining disc = I1  I 2
9MR 2 MR 2 4MR 2
  
2 18 9
 81  1  8 
  MR
2
 18 
 4MR 2
8. A particle is moving with a uniform speed in a circular orbit of radius R in a central force
inversely proportional to the nth power of R. If the period of rotation of the particle is T, then :
(1) T R3/2 for any n.
n
1
(2) T R 2
(3) T R n1/2
(4) T Rn/2
Solution:
F  KR n 1
mv 2 K
So,  n
R R
K 1
v   n 1 /2
M R
2 R 2 R n 1
Now, T   R 2
v K
M
 T  R n 1 /2
9. A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a

liquid in a cylindrical container. A massless piston of area a floats on the surface of the
JEE Mains 2018
liquid, covering entire cross section of cylindrical container. When a mass m is placed on the
surface of the piston to compress the liquid, the fractional decrement in the radius of the
 dr 
sphere,   is :
 r 
Ka
(1)
mg
Ka
(2)
3mg
mg
(3)
3Ka
mg
(4)
Ka
Solution: Bulk Modulus,
P
K
 V / V 
4
For sphere, V   r 3
3
V 3r
 
V r
r P Mg
  
r 3K 3Ka
10. Two moles of an ideal monoatomic gas occupies a volume V at 270 C. The gas expands
adiabatically to a volume 2 V. Calculate (a) the final temperature of the gas and (b) change in
its internal energy.
(1) (a) 189 K (b) 2.7 kJ
(2) (a) 195 K (b) -2.7 kJ
(3) (a) 189 K (b) -2.7 kJ
(4) (a) 195 K (b) 2.7 kJ
Solution:
Initially n = 2, v, T= 300k
Finally Vd = 2v
Gas is monoatomic, So, r = 5/3
So,
JEE Mains 2018
nR Ti  T f 
dw 
r 1
r 1
TV
i i  T f V fr 1
2/3
1
Ti     Tf
2
300 300
 Tf    189k
41/3 1.6
Since gas undergoes expensed.
So, d w  0
& d q  du  d w
 du  0.
11. The mass of a hydrogen molecule is 3.32 1027 kg. If 1023 hydrogen molecules strike, per
second, a fixed wall of area 2 cm2 at an angle of 450 to the normal, and rebound elastically
with a speed of 103 m/s, then the pressure on the wall is nearly :
(1) 2.35 103 N / m2
(2) 4.70 103 N / m2
(3) 2.35 102 N / m2
(4) 4.70 102 N / m2
Solution:
Change in momentum normal to the wall
 2mv cos 45o
So, Force 
 2mv cos 45   N o
t
1
2  3.32 1027 103  1023
Pr essure  2
2 104 1
P  2.35 103 N / m2
12. A silver atom in a solid oscillates in simple harmonic motion in some direction with a
frequency of 1012/sec. What is the force constant of the bonds connecting one atom with the
other ? (Mole wt. of silver = 108 and Avagadro number = 6.02 x 10 23 gm mole-1)
(1) 6.44 N/m
JEE Mains 2018
(2) 7.1 N/m

(3) 2.2 N/m
(4) 5.5 N/m
Solution:
M
T  2
K
4  M
2
K
T2
108 103
 4 
2
6.023 1023
 10 
12 2
10.8
 4 2  102
6.023
 7.1N / m
13. A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal
vibrations. The density of granite is 2.7 103 kg/m3 and its young’s modulus is 9.27 1010 Pa.
What will be the fundamental frequency of the longitudinal vibrations ?
(1) 5 kHz
(2) 2.5 kHz
(3) 10 kHz
(4) 7.5 kHz
Solution:
Since rod is clamped at centre. So centre it behaves as node & end it behave as antinode.
So,

 30cm
4
   1.2m
9.27 1010
y
 
 2.7 103
 5.85 103 m / s
5.85 103
So, 
1.2
 5kHz
14. Three concentric metal shells A, B and C of respective radii a, b and c (a < b < c) have
surface charge densities  ,  and  respectively. The potential of shell B is :
  a 2  b2 
(1)   c
0  a 
JEE Mains 2018
  a 2  b2 
(2)   c
0  b 
  b2  c 2 
(3)   a
0  b 
  b2  c 2 
(4)   a
0  c 
Solution:
Charge in sphere
A  qA    4 a 2
B  qB    4 b2
C  qc    4 c 2
Potential of B:
qA qb qc
  
4 0 b 4 0 b 4 0 c
 a2 b 2  c 2
  
0 b 0 b 0 c
  a2 
  b  c
0  b 
  a b
2 2

   c
0  b 
15. A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a

5
dielectric material constant K = is inserted between the plates, the magnitude of the
3
induced charge will be :
(1) 1.2 n C
(2) 0.3 n C
(3) 2.4 n C
(4) 0.9 n C
Solution:
JEE Mains 2018
qi  C0V
 90 1012  20
 1800 1012
 1.8nC
5
q f  1.8nC
3
 3nC
So, qind  3nC  1.8nC
 1.2nC
16. In an a.c. circuit, the instantaneous e.m.f. and current are given by e = 100 sin 30 t
 
i  20sin  30t   . In one cycle of a.c., the average power consumed by the circuit and the
 4
wattless current are, respectively :
(1) 50, 10
1000
(2) ,10
2
50
(3) ,0
2
(4) 50, 0
Solution:
Pqv  rms  I rms  cos 
100 20  
   cos  
2 2 4
2000
 watt
2 2
1000
 w
2
I w  I rms  cos 
20 1
 
2 2
 10 A
17. Two batteries with e.m.f. 12 V and 13 V are connected in parallel across a load resistor of
10𝛺. The internal resistances of the two batteries are 1𝛺 and 2𝛺 respectively. The voltage
across the load lies between :
(1) 11.6 V and 11.7 V
(2) 11.5 V and 11.6 V
(3) 11.4 V and 11.5 V
JEE Mains 2018
(4) 11.7 V and 11.8 V
Solution:
Total
 1  2 
  
emf   1
r r2 
1 1
  
 r1 r2 
 12 13 
  

1 2
1 1 
  
1 2 
37
 Volt
3
So, V    Ir
r

Rr
 11.53V
18. An electron, a proton and an alpha particle having the same kinetic energy are moving in
circular orbits of radii re, rp, r𝛼 respectively in a uniform magnetic field B. The relation
between re, rp, r𝛼 is :
(1) re > rp = r𝛼
(2) re < rp = r𝛼
(3) re < rp < r𝛼
(4) re < r𝛼 < rp
Solution:
For change moving in circular orbit is a uniform magnetic field,
mv 2mEK
r 
Bq Bq
B2q2r 2
 EK 
2m
Since all particles came same EK & B,
So,
JEE Mains 2018
q2r 2
 Cons tan t
2m
qe  q p & me  m p
 re  rp
For proton &  -particle
12  rp2 22  r2

2 1 2 4
 rp  r
19. The dipole moment of a circular loop carrying a current I, is m and the magnetic field at
the centre of the loop is B1. When the dipole moment is doubled by keeping the current
B
constant, the magnetic field at the centre of the loop is B2. The ratio 1 is :
B2
(1) 2
(2) 3
(3) 2
1
(4)
2
Solution:
Magnetic moment, M  IA  I   r and magnetic field at the centre of circle
2
I
B 0
2R
M f  I   rf2  2M
M i  I   ri 2  M
rf
  2
ri
B1 rf
So,   2
B2 ri
1
20. For an RLC circuit driven with voltage of amplitude  m and frequency 0  the
LC
current exhibits resonance. The quality factor, Q is given by :
0 L
(1)
R
JEE Mains 2018
0 R
(2)
L
R
(3)
0C 
CR
(4)
0
Solution:
Qfactor = (voltage across L or C at Resonance)/(voltage across R)
I  X L 0 L
= 
I R R
  z 
21. An EM wave from air enters a medium. The electric fields are E1  E01xˆ cos 2 v   t 
  c 
in air and E2  E02 xˆ cos k  2z  ct  in medium, where the wave number k and frequency 𝜐
refer to their values in air. The medium is non-magnetic. If r1 and r2 refer to relative
permitivities of air and medium respectively, which of the following options is correct ?

(1) r1  4
r2
r1
(2) 2
r2
r1 1
(3) 
r2 4
r1 1
(4) 
r2 2
Solution:
  z 
E1  E01xˆ cos 2 v   t 
  c 
E2  E02 xˆ cos k  2z  ct 
Where
2  1
k & 
 c 
So volume in medium 1 = C
Volume in medium 2 = C/2
1
C
 0r1
JEE Mains 2018
C 1

2  0r2
r2
2
r1
r1 1
 
r2 4
22. Unpolarized light of intensity I passes through an ideal polarizer A. Another identical
1
polarizer B is placed behind A. The intensity of light beyond B is found to be .Now
2
another identical polarizer C is placed between A and B. The intensity beyond B is now
1
found to be . The angle between polarizer A and C is :
8
0
(1) 0
(2) 300
(3) 450
(4) 600
Solution:
I
Unpolarized light of intensity I, when passed through a polarizer A, its intensity becomes
2
I
Since intensity of light emerging from polarizer B =
2
So, A & B are parallel placed.
Let, C makes angle  with A.
So,
I I
cos 4  
2 8
1
 cos 2  
2
1
 cos  
2
  45 
23. The angular width of the central maximum in a single slit diffraction pattern is 60 0. The
width of the slit is 1 𝜇m. The slit is illuminated by monochromatic plane waves. If another
slit of same width is made near it, Young’s fringes can be observed on a screen placed at a
JEE Mains 2018
distance of 50 cm from the slits. If the observed fringe width is 1 cm, what is slit separation
distance ?
(i.e. distance between the centres of each slit.)
(1) 25𝜇m
(2) 50𝜇m
(3) 75𝜇m
(4) 100 𝜇m
Solution:
2 
 600 
d 180
 1
     m
 3 2
In Ydse,
D
B'  106
d'
 1 1
  
 10  
2 2 2 2
106
d'

d' 2
106
10 12
 26.16  25 m
24. An electron from various excited states of hydrogen atom emit radiation to come to the
ground state. Let n,g be the de Broglie wavelength of the electron in the nth state and the
ground state respectively. Let  n be the wavelength of the emitted photon in the transition
from the nth state to the ground state. For large n, (A, B are constants)
B
(1)  n  A  2
n
(2) n  A  Bn
(3) 2n  A  Bn2
(4) 2n  
Solution:
JEE Mains 2018
h h
 
mv 2MEk
h2
Ek 
2m 2
For emitted photon,
En  E1
hc

n
h2 h2 hc
  
2mn 2mg  n
2 2
hc h2  h 2 
  K K  
 n 2mn2  2mg2 
  2 n  A  Bn2
25. If the series limit frequency of the Lyman series is 𝜐L , then the series limit frequency of
the Pfund series is :
(1) 25vL
(2) 16vL
v
(3) L
16
v
(4) L
25
Solution:
1  1 1
 R 2  2   v
  n1 n2 
1 1
R  2   vl & R  2   v p
1  5 
v 1
 l 
v p 25
vl
 vp 
25
26. It is found that if a neutron suffers an elastic collinear collision with deuterium at rest,
fractional loss of its energy is pd; while for its similar collision with carbon nucleus at rest,
fractional loss of energy is pc. The values of pd and pc are respectively :
(1) (.89, .28)
(2) (.28, .89)
JEE Mains 2018
(3) (0, 0)
(4) (0, 1)
Solution: U1 , U2=0
Since collision is elastic,
u  M  M 2   2 M 1M 2
1  1 1
M1  M 2
But , u2  0
1 M1  M 2
  .............  i 
u1 M1  M 2
Fractional loss in kinetic energy of neutron,
1 1
M 1u12  M 112
2 2
1
M 1u12
2
2
 
 1  1 
 u1 
So, A.TQ;
 1 2  8
2
Pd  1      0.89
 1 2  9
 1  12 
2
Pc  1     0.28
 1  12 
27. The reading of the ammeter for a silicon diode in the given circuit is :
(1) 0
(2) 15 mA
(3) 11.5 mA
(4) 13.5 mA
Solution:
The given diode is a forward bias & hence behaves as a perfect conductor i.e., it offers zero
resistance.
So,
V 3
I   1102 A
R 200
 15mA
JEE Mains 2018
28. A telephonic communication service is working at carrier frequency of 10 GHz. Only

10% of it is utilized for transmission. How many telephonic channels can be transmitted
simultaneously if each channel requires a bandwidth of 5 kHz ?
(1) 2 103
(2) 2 104
(3) 2 105
(4) 2 106
Solution:
Required number of channels
10
10 109
 100
5 103
 2 105
29. In a potentiometer experiment, it is found that no current passes through the galvanometer
when the terminals of the cell are connected across 52 cm of the potentiometer wire. If the
cell is shunted by a resistance of 5𝛺, a balance is found when the cell is connected across 40
cm of the wire. Find the internal resistance of the cell.
(1) 1𝛺
(2) 1.5𝛺
(3) 2𝛺
(4) 2.5𝛺
Solution:
l 
r   1  1 R
 l2 
 52 
   1  5
 40 
12  5

40
 1.5
JEE Mains 2018
30. On interchanging the resistances, the balane point of a meter bridge shifts to the left by 10
cm. The resistance of their series combinations is 1 k𝛺. How much was the resistance on the
left slot before interchanging the resistances ?
(1) 990𝛺
(2) 505𝛺
(3) 550𝛺
(4) 910𝛺
Solution:
P l

Q 100  l
Q l  10
& 
P 110  l
l 110  l
 
100  l l  10
 l 2  10l  11000  100l  100l  l 2
 200l  11000
 l  55cm
l  100  l 
  1000
A A

  10
A
l
So,  10  55
A
 550
Chemistry
31. The ratio of mass present of C and H of an organic compound (CXHYOZ) is 6 : 1. If one
molecule of the above compound (CXHYOZ) contains half as much oxygen as required to burn
one molecule of compound CXHY completely to CO2 and H2O. The empirical formula of
compound CXHYOZ is :
(1) C3H6O3
(2) C2H4O
(3) C3H4O2
(4) C2H4O3
JEE Mains 2018
Solution:
CxHyOz – Organic compound
mass of C
 6 :1
mass of H
mass of C / 12 6 1
 :
mass of H / 1 12 2
No.of moles of C 1
  :1
No.of moles of H 2
moles of C
Cx H yOz 
Moles of H
 y y
Cx H y   x   o2  xco2  H 2o
 x 2
 y x y
cx hy oz  x    o2  x co 2  H 2O
 4 2 x
1 y y z
x  x 
2 4 4 2
x y y
 2x   Z
4 2
y
Z  x
4
4
c2 h4o3 Z  2   3
4
Hence the answer is option (4).
32. Which type of ‘defect’ has the presence of cations in the interstitial sites ?
(1) Schottky defect
(2) Vacancy defect
(3) Frenkel defect
(4) Metal deficiency defect
Solution:
Frankel defect has the presence of cation in interstitial site.
33. According to molecular orbital theory, which of the following will not be a viable
molecule ?
(1) H22
(2) He2
JEE Mains 2018
(3) H 2
(4) H22
Solution :
*
H22 electronic configuration  1S 2 ,  1S 2
1 1
Number of electrons = 4 ; Bo   Nb  Na    2  2  0
2 2
Molecule does not exist.
34. Which of the following lines correctly show the temperature dependence of equilibrium
constant K, for an exothermic reaction?
(1) A and B
(2) B and C
(3) C and D
(4) A and D
Solution:
H o S o
ln K    Re lationbetween Rate cons tan t 
RT R
For exothermic reaction H = -ve.
H o
Slope  0
R
35. The combustion of benzene (1) gives CO2(g) and H2O(I). Given that heat of combustion
of benzene at constant volume is -3263.9 kJ mol-1 at 250 C; heat of combustion (in kJ mol-1)
of benzene at constant pressure will be :
(1) 4152.6
(2) -452.46
(3) 3260
(4) -3267.6
Solution:
JEE Mains 2018
15
C6 H 6  l  O2  g   6CO2  3H 2O  l 
2
ng  6  7.5  1.5
H  U  ngRT
 3263.9  1.5  8.134 103  298
 3267.6
36. For 1 molal aqueous solution of the following compounds, which one will show the
highest freezing point?
(1) Co  H 2O 6  Cl3
(2) Co  H2O5 Cl  Cl2 .H2O
(3) Co  H2O 4 Cl2  Cl.2H 2O

(4) Co  H2O3 Cl3  .3H2O
Solution:
Tf  i  kf  m
Tf  i
1
Tf 
i
Co  H2O3 Cl3  .3H2O ; i = 1
Co  H 2O 6  Cl3 ; i = 2
Co  H2O5 Cl  Cl2 .H2O ; i = 4
Co  H2O 4 Cl2  Cl.2H 2O ; i = 3
37. An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants
for the formation of HS- from H2S is 1.0 x 10-7 and that of S2- from HS- ions is 1.2 x 10-13 then
the concentration of S2- ions in aqueous solution is :
(1) 5 x 10-8
(2) 3 x 10-20
(3) 6 x 10-21
(4) 5 x 10-19
Solution:
JEE Mains 2018

H 2 S  2 H   S 2
ka1 .ka2
0.1  x 0.2 x
 0.2 
 52
2
ka1.ka2 
0.1
2
1.2 10  0.1
  S 2 
0.04
 S 2   3 1020
38. An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1M

solution of Na2SO4 is added, BaSO4 just begins to precipitate. The final volume is 500 mL.
The solubility product of BaSO4 is 1 x 10-10. What is the original concentration of Ba2+ ?
(1) 5 x 10-9 M
(2) 2 x 10-9 M
(3) 1.1 x 10-9 M
(4) 1.0 x 10-10 M
Solution:
KS p  BaSO4   1010
QS p  KS p
 Ba  SO   10
2 2
4
10
50
Ba 2  1010
500
  Ba 2   109
m1v1  m2 v2
m  450  109  500
500
m   109
450
m  1.1109
39. At 5180 C, the rate of decomposition of a sample of gaseous acetaldehyde, initially ar a

pressure of 363 Torr, was 1.00 Torr s-1 when 5% had reacted and 0.5 Torr s-1 when 33% had
reacted. The order of the reaction is :
(1) 2
(2) 3
(3) 1
(4) 0
Solution:
JEE Mains 2018
r  k  p  m = order of reaction
m
m
 95 
1  k 363  ............1
 100 
 67 
0.5  k  362   ........... 2 
 100 
equation  1 / Equation  2
m
1  95 

0.5  67 
m
 95 
2 
 67 
2   0.4 
m
log 2  m log1.4
0.3010
m
log1.4
0.3010
m
0.15
m2
40. How long (approximate) should water be electrolysed by passing through 100 amperes
current so that the oxygen released can completely burn 27.66 g of diborane?
(Atomic weight of B = 10.8 u)
(1) 6.4 hours
(2) 0.8 hours
(3) 3.2 hours
(4) 1.6 hours
Solution:

Cathode: H2O  2e  H 2  2OH

 Re duction
Anode:
2 H 2O  4 H   O2  4e  oxidation 
B2 H 6  3O2  B2O3  3H 2O
27.66 g
27.66
n 1
276
Moles of O2 required = 3
JEE Mains 2018
Gram equivalent of O2 = 3  4  12
Gram equivalent
it
w
96500
100  t
12 
96500
12  965
t sec
60  60
t  3.2hr
41. The recommended concentration of fluoride ion in drinking water is up to 1 ppm as

fluoride ion is required to make teeth enamel harder by converting 3Ca3  PO4 2 .Ca OH 2 
:
(1) CaF2 
(2) 3  CaF2  .Ca  OH 2 
(3) 3Ca3  PO4 2 .CaF2 
 
(4) 3 Ca  OH 2 .CaF2 
 
Solution:
3Ca3  PO4 2 .CaF2 
42. Which of the following compounds contain(s) no covalent bond(s) ?

KCl, PH3, O2, B2H6, H2SO4
(1) KCl, B2H6, PH3
(2) KCl, H2SO4
(3) KCl,
(4) KCl, B2H6
Solution:
KCl is an ionic compound. It cannot from covalent bond. Elements of s – block & p – block
combine to form ionic compounds.
43. Which of the following are Lewis acids ?

(1) PH3 and BCl3
(2) AlCl3 and SiCl4
(3) PH3 and SiCl4
JEE Mains 2018
(4) BCl3 and AlCl3
Solution:
BCl3 and AlCl3 are electron deficient compounds. Boron and aluminium has 6 electrons in
their valence shell in BCl3 & AlCl3,. PH3, SiCl4 have 8 electrons in their valence shell. They
are not Lewis acids.
44. Total number of lone pair of electrons in I 3 ion is :

(1) 3
(2) 6
(3) 9
(4) 12
Solution:
The total number of lone pair of electrons is I3 is 9
45. Which of the following salts is the most basic in aqueous solution?
(1) Al(CN)3
(2) CH3COOK
(3) FeCl3
(4) Pb(CH3COO)2
Solution: CH3COOK is a salt of weak acid and strong base

Hydrolysis of potassium acetate gives strong base KOH
4 3
46. Hydrogen peroxide oxides  Fe  CN 6  to  Fe CN 6  in acidic medium but reduces
3 4
 Fe CN 6  to  Fe  CN 6  in alkaline medium. The other products formed are,
respectively:
(1)  H 2O  O2  and H2O

(2)  H 2O  O2  and H2O  OH  
(3) H2O and  H 2O  O2 

(4) H2O and H2O  OH  
JEE Mains 2018
Solution:
4 3
 Fe 2  CN   H 2O2
  Fe   CN 6   H 2O
3
 6 Oxidizing agent
reducing agent
 oxidi sin g agent  H 2O21  H 2O2  Re duction 
 Re ducing agent  H2O21  O2  oxidation 
3 4
 Fe 3  CN   H 2O2
  Fe 2  CN    O2
 6  Oxidizing agent  6
 oxiding agent 
47. The oxidation states of Cr in Cr  H2O6  Cl3 , Cr C6 H6 2  , and
K2 Cr  CN 2  O 2  O2  NH3  respectively are :
(1) +3, +4, and +6
(2) +3, +2, and +4
(3) +3, 0, and +6
(4) +3, 0, and +4
Solution:
The Oxidation state of Cr in
Cr  H 2O 6  Cl3
x  6  0  3  0 .
x  3
Cr  C6 H 6 2 
x  2  0  0
x0
K 2 Cr  CN 2  O 2  O2  NH 3 
2  x  2  1  2  2   1  2   0
6
 x  6
48. The compound that does not produce nitrogen gas by the thermal decomposition is :
(1) Ba(N3)2
(2) (NH4)2Cr2O7
JEE Mains 2018
(3) NH4NO2
(4) (NH4)2SO4
Solution:

NH 4 NO2   N 2  H 2O
 NH 4 2 Cr2O7 
 N 2  H 2O  Cr2O3
Ba  N 3 2 

 Ba  N 2
49. When metal ‘M’ is treated with NaOH, a white gelatinous precipitate ‘X’ is obtained,
which is soluble in excess of NaOH. Compound ‘X’ when heated strongly gives an oxide
which is used in chromatography as an adsorbent. The metal ‘M’ is :
(1) Zn
(2) Ca
(3) Al
(4) Fe
Solution:
The Gelatinous precipitate formed in Al(OH)3 ; Al(OH)3 on strong heating gives Al2O3 which
is used in chromatography as an adsorbent. So the metal is Al.
50. Consider the following reaction and statements:


Co  NH3 4 Br2   Br   Co  NH3 3 Br3   NH3
(I) Two isomers are produced if the reactant complex ion is a cis-isomer.
(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(III)Only one isomer is produced if the reactant complex ion is a trans-isomer.
(IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.
The correct statements are :
(1) (I) and (II)
(2) (I) and (III)
(3) (III) and (IV)
(4) (II) and (IV)
Solution:
JEE Mains 2018
As all the NH3 positions are identical

only one product can be formed.
51. Glucose on prolonged heating with HI gives :

(1) n-Hexane
(2) 1-Hexane
(3) Hexanoic acid
(4) 6-iodohexanal
Solution:
C6 H12O6 
HI
CH3   CH 2 4  CH3
Glu cos e n  hexane
52. The trans-alkenes are formed by the reduction of alkynes with :

(1) H2 – pd/C, BaSO4
(2) NaBH4
(3) Na/liq. NH3
(4) Sn-HCl
Solution:
Trans alkenes are formed by the reaction of alkynes with Na/liq. NH3
(birch Reduction)
JEE Mains 2018
53. Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen
estimation?
Solution:
Kjeldahl’s method:-
Organic compounds nitrogen +

Conc.H 2 SO4   NH 4 2 SO4
 alkali
NH3
Nitro compounds, A2O compounds & Nitrogen part of the aromatic ring will not give
positive result for Kjeldahl’s method.
Aniline is the best suitable to estimate nitrogen using Kjeldahl’s method.
54. Phenol on treatment with CO2 in the presence of NaOH followed by acidification
produces compound X as the major product. X on treatment with (CH3CO)2O in the presence
of catalytic amount of H2SO4 produces :
(1)
(2)
JEE Mains 2018
(3)
(4)
Solution:
55. An alkali is titrated against an acid with methyl orange as indicator, which of the
following is a correct combination?
Solution:
When a weak base is titrated with string acid with methyl orange as an indicator then at end
point
The colour change will be yellow to pinkish red.
JEE Mains 2018
56. The predominant form of histamine present in human blood is (pk a , Histidine = 6.0)
(1)
(2)
(3)
(4)
Solution:
57. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A.
A reacts with Br2 to form product B. A and B are respectively :
(1)
(2)
(3)
(4)
JEE Mains 2018
Solution:
58. The increasing order of basicity of the following compounds is :

(a)
(b)
(c)
(d)
(1) (a) < (b) < (c) < (d)

(2) (b) < (a) < (c) < (d)
(3) (b) < (a) < (d) < (c)
(4) (d) < (b) < (a) < (c)
Solution:
The lone pair on the nitrogen atom is in conjugation with the  bond hence it can involve in
resonance.
during resonance the other nitrogen attains a negative charge.
Hence ‘c’ is a strong base.
JEE Mains 2018
The +I group of CH3 and C2H5 makes ‘d’ more basic but less basic than ‘c’
Due to -I of  bond, basic character decreases.
The nitrogen involves sp2 hybridization which is highly electro negative have least basic.
59. The major product formed in the following reaction is :
(1)
(2)
(3)
(4)
Solution:
JEE Mains 2018
60. The major product of the following reaction is :
(1)
(2)
(3)
(4)
Solution:

NaOMe
MeOH

E2 reaction
JEE Mains 2018
Mathematics
61. Two sets A and B are as under :

A={(a, b)  R  R : a  5  1 and b  5  1};
B={(a, b)  R  R : 4(a  6)2  9(b  5)2  36 }. Then :
(1) B A
(2) A B
(3) A  B   (an empty set)
(4) neither A  B nor B  A
62. Let S= {x  R : x  0 and 2 x  3  x ( x  6)  6  0} . Then S :

(1) is an empty set.
(2) contains exactly one element.
(3) contains exactly two element.
(4) contains exactly four elements.
Solution:
2 | x  3|  x  
x 6 6 0
Case-I x 3
2  
x  3  x  6 x  6  0  x  4 x  0  x  0,6
As x  9  x  16
Case  II x 3 2 x 6 x6 x 6  0
 x 6  
x  2  0  x  36,4
As, x  3  x  4
There are exactly two elements in the given set.
63. If  ,   c are the distinct roots, of the equation x2  x 1  0 , then  101   107 is equal
to :
(1) -1
(2) 0
(3) 1
(4) 2
Solution:
x2 – x+ 1 = 0
JEE Mains 2018
1  3
x   ,  2
2
    and    2
       2   101   214     2     1
101 107
x  4 2x 2x
64. If 2 x x  4 2 x = ( A  Bx)( x  A)2 , then the ordered pair (A, B) is equal to :
2x 2x x  4
(1) (-4, -5)
(2) (-4, 3)
(3) (-4, 5)
(4) (4, 5)
65. If the system of linear equations

x  ky  3z  0
3x  ky  2 z  0
2 x  4 y  3z  0
xz
has a non-zero solution (x, y, z), then is equal to:
y2
(1) -10
(2) 10
(3) -30
(4) 30
66. From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to
be selected and arranged in a row on a shelf so that the dictionary is always in the
middle. The number of such arrangements is :
(1) at least 1000
(2) less than 500
(3) at least 500 but less than 750
(4) at least 750 but less than 1000
67. The sum of the co-efficients of all odd degree terms in the expansion of
x    
5 5
x3  1  x  x3  1 ,( x  1) is:
(1) -1
(2) 0
(3) 1
(4) 2
JEE Mains 2018
12
68. Let a1 , a2 , a3 ,......, a49 be in A.P. such that a
k 0
4 k 1  416 and a9  a43  66 .
If a12  a22  .....  a172  140m , then m is equal to:

(1) 66
(2) 68
(3) 34
(4) 33
Solution:
a1  a5  a9  416 a  24d  32 ..............i 
a9  a43  66  a  25d  33 ...............ii 
From (i) and (ii) d = 1 and a = 8
Now, a12  a22  .......  a172  140m
17 17
 8   r  1   7  r   140m  m  34
2
r 1 r 1
69. Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of
the series
12  2 22  32  2 42  52  2 62  .....
If B-2A=100  , then  is equal to:
(1) 232
(2) 248
(3) 464
(4) 496
Solution:
A = 12 + 2.22 + 32 + 2.42+ ………+ A2+2.202
= (12 + 2.22 + 32 + 42+ ………+202)+ (22+ 42+ ………+ 202)
20  21 41 10 11 21
  4  2870  1540  4410  2870  1540  4410
6 6
40  41 81 4  20  21 41
B   540  41  41 280  41 820  33620
6 6
33620  8820  100
100  24800
  248
70. For each t  R, let [t] be the greatest integer less than or equal to t. Than
 1 2 15  
lim x        ......    
x0
 x  x  x 
(1) is equal to 0
JEE Mains 2018
(2) is equal to 50
(3) is equal to 120
(4) does not exist (in R)
71. Let S={t  R:f(x)= x   • (e  1)sin x is not differentiable at t}. Then the set S is
x
equal to:
(1)  (an empty set)
(2) {0}
(3) {}
(4) {0, }
72. If the curve y2 = 6x, 9x2 + by2 = 16 intersect each other at right angles, then the
value of b is:
(1) 6
7
(2)
2
(3) 4
9
(4)
2
Solution:
2yy’= 6
6 3
y'  
2 y y1
18 x1 9 x1 27 x 27 x
18 x1     21  1  b  2 1
2by1 by1 by1 y1
9
y12  6 x1  b 
2
1 1 f ( x)
73. Let f ( x)  x2 
2
and g ( x)  x  , x  R  1,0,1 . If h( x)  , then the local
x x g ( x)
minimum value of value of h( x) is :
(1) 3
(2) -3
(3) 2 2
2
(4) 2
JEE Mains 2018
sin 2 x cos2 x
 dx
sin x  cos3 x sin 2 x  sin 3 x cos2 x  cos5 x 
2
74. The integral 5 is equal to :
1
(1) c
3 1  tan 3 x 
1
(2) c
3 1  tan 3 x 
1
(3) c
1  cot 3 x
1
(4) c
1  cot 3 x
Solution:
sin 2 x cos2 x
 dx
sin  cos x sin 2 x  sin3 x cos2 x  cos2 x  cos5 x 
5 3 2
tan 2 x sec6 x
  tan5 x  tan2 x  tan3 x  1 dx
dt
Put tanx = t  sec2 x 
dx
t 2 1  t 2 
2
 dt
t 3  1 t 2  1
2 2
T3 +1=y
dy
3t 2 
dt
1 dy 1 1

3 y 2

3 y 
C  
3  tan 3 x  1
C

2
sin 2 x
75. The value of 
 1+2x
dx is:
2

(1)
8

(2)
2
(3) 4

(4)
4
JEE Mains 2018
76. Let g ( x)  cos x2 , f ( x)  x , and  ,      be the roots of the quadratic

equation 18x2  9 x   2  0 . Then the area (in sq. units) bounded by the curve
y  ( gof )( x) and the lines x   , x   and y  0 , is :
(1)
1
2
 3 1 
(2)
1
2
 3 1 
(3)
1
2
 3 2 
(4)
1
2
 2 1 
Solution:
g  x   cos x 2
f  x  x
g  f  x    cos x
given, 18 x 2  9 x   2  0   6 x    3x     0
 
x ,
6 3
 /3
3 1
Area 

 cos x dx 
/6 2
77. Let y=y(x) be the solution of the differential equation

dy  
sin x  y cos x =4 x , x  (0, ) . If y    0 , then y   is equal to :
dx 2 6
4
(1) 2
9 3
8 2
(2) 
9 3
8
(3)  2
9
4
(4)  2
9
Solution:
dy
 y cot x  4x cos ec x  d  y sin x   4xdx
dt
Integrating both sides we get y sin x  2x2  C
   2
Also, y    0  c  
2 2
JEE Mains 2018
2   8 2
 y sin x  2x2   y   
2 6 9
78. A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct
points P and Q. If O is the origin and the rectangle OPRQ is completed, then the locus of
R is:
(1) 3x  2 y  6
(2) 2x  3y  xy
(3) 3x  2 y  xy
(4) 3x  2 y  6xy
Solution:
Let R = (h,k)
P = (0, k)
Q = (h,0)
Equation of line would be,
x y
  1 ........ i 
h k
2 3
  1
h k
2k + 3h = hk
Locus of (h, k) is 2y + 3x = xy
79. Let the orthocenter and centroid of a triangle be A(-3, 5) and B(3, 3) respectively. If
C is the circumcentre of this triangle, than the radius of the circle having line segment
AC as diameter, is :
(1) 10
2
(2) 10
5
(3) 3
2
3 5
(4)
2
JEE Mains 2018
80. If the tangent at (1,7) to the curve x2  y  6 touches the circle

x2  y2  16x  12 y  c  0 than the value of c is :
(1) 195
(2) 185
(3) 85
(4) 95
81. Tangent and normal are drawn at P(16, 16) on the parabola y 2  16 x , which intersect
the axis of the parabola at A and B, respectively. If C is the centre of the circle through
the points P, A and B and CPB   , then a value of tan  is :
1
(1)
2
(2) 2
(3) 3
4
(4)
3
Solution:
The equation of tangent at P
1
y  16   x  16  A   16, 0
2
The normal is y = y – 16 = -2(x – 16)
B = (24, 0)

Since APB 
2
AB is the diameter
Centre of the circle C = (4, 0)
Slope of PB = -2 = m1
4 m  m1
Slope of CP =  m2  tan  2 2
3 1  m2m1
82. Tangents are drawn to the hyperbola 4x2  y2  36 at the points P and Q. If these
tangents intersects at the point T(0, 3) then the area (in sq. units) of  PTQ is :
(1) 45 5
(2) 54 3
(3) 60 3
(4) 36 5
JEE Mains 2018
Solution:
Equation of PQ,
4x.(0) -3y = 36
Y = -12
1
Area of TPQ   15  6 5  45 5
2
83. If L1 is the line of intersection of the planes 2x  2 y  3z  0, x  y  z  0 and L2 is

the line of intersection of the planes x  2 y  z  3  0,3x  y  2z  0 then the distance of
the origin from the plane, containing the lane L1 and L2 , is :
1
(1) 4 2
1
(2) 3 2
1
(3) 2 2
1
(4) 2
84. The length of the projection of the line segment joining the points (5, -1, 4) and (4, -
1, 3) on the plane, x + y + z = 7 is :
2
(1)
3
2
(2)
3
1
(3)
3
2
(4)
3
85. Let u be a vector coplanar with the vectors a  2i  3 j  k and b  j  k . If u is

perpendicular to a and u . b = 24, than equal to :
(1) 336
(2) 315
(3) 256
(4) 84
JEE Mains 2018
Solution:
 
u a  b  0; u.a  0 and u.b  24
   
Let b  b.a a.  b.u u
  b.a    b. u 
2 2 2
b
2
  b. u
2 2
b  b.a  2
u
2  24 
2
2
2  2
 u  336
7 u
86. A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its
colour is observed and this ball along with two additional balls of the same colour is
returned to the bag. If now a ball is drawn at random from the bag, then probability that
this drawn ball is red, is:
3
(1)
10
2
(2)
5
1
(3)
5
3
(4)
4
9 9
87. If  (x  5)  9 and  (x  5)
i 1
i
i 1
i
2
 45 , then the standard deviation of the 9 items
x1, x2, …., x9 is:

(1) 9
(2) 4
(3) 2
(4) 3
     1
88. If sum of all the solution of equation 8cos x.  cos   x  .cos   x     1 in
 6  6  2
[0,  ] is k ,then k is equal to :
2
(1)
3
13
(2)
9
JEE Mains 2018
8
(3)
9
20
(4)
9
89. PQR is a triangular park with PQ=PR=200 m. AT.V. tower stands at the mid-point
of QR. If the angle of elevation of the top of the tower at P,Q and R are respectively 450 ,
300 and 300 then the height of tower (in m) is :
(1) 100
(2) 50
(3) 100 3
(4) 50 2
Solution:
h 1

x 3
x  3h
200  3h2  h2
4h2   200 
2
4h2  40000
h  100
90. The Boolean expression ( p  q)  ( p  q) is equivalent to:

(1) p
(2) p
(3) q
(4) q
Solution:
( p  q)  ( p  q)
P q ( p  q) pq
T F F F
T F F F
F T F T
F F T F
JEE (Main) 2018
BOOKLET CODE : A
Q.No. Answer Q.No. Answer Q.No. Answer
1. (3) 31. (4) 61. (2)
2. (2) 32. (3) 62. (3)
3. (2) 33. (4) 63. (3)
4. (3) 34. (1) 64. (3)
5. (2) 35. (4) 65. (2)
6. (4) 36. (4) 66. (1)
7. (1) 37. (2) 67. (4)
8. (3) 38. (3) 68. (3)
9. (3) 39. (1) 69. (2)
10. (3) 40. (3) 70. (3)
11. (1) 41. (3) 71. (1)
12. (2) 42. (3) 72. (4)
13. (1) 43. (4)* 73. (4)
14. (2) 44. (3) 74. (2)
15. (1) 45. (2) 75. (4)
16. (2) 46. (3) 76. (1)
17. (2) 47. (3) 77. (3)
18. (2) 48. (4) 78. (3)
19. (3) 49. (3) 79. (3)
20. (1) 50. (2) 80. (4)
21. (3) 51. (1) 81. (2)
22. (3) 52. (3) 82. (1)
23. (1) 53. (2) 83. (2)
24. (1) 54. (1) 84. (4)
25. (4) 55. (3) 85. (1)
26. (1) 56. (4) 86. (2)
27. (3) 57. (3) 87. (3)
28. (3) 58. (3) 88. (2)
29. (2) 59. (4) 89. (1)
30. (3) 60. (2) 90. (1)
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(1),(3),(4) uniform retardation & then uniform acceleration.

3. Two masses m1 = 5 kg and m2 = 10 kg, connected by an inextensible string over a

To stop the motion,

Moment of inertia of cut off disc about an axis passes through O

9. A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a

Solution: Bulk Modulus,

 2mv cos 45o

(2) 7.1 N/m

15. A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a

(4) 11.7 V and 11.8 V

Hence the Solution is Option (3)

Hence the Solution is Option (2)

28. A telephonic communication service is working at carrier frequency of 10 GHz. Only

Hence the answer is option (4).

(3) Co  H2O 4 Cl2  Cl.2H 2O

38. An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1M

39. At 5180 C, the rate of decomposition of a sample of gaseous acetaldehyde, initially ar a

41. The recommended concentration of fluoride ion in drinking water is up to 1 ppm as

42. Which of the following compounds contain(s) no covalent bond(s) ?

43. Which of the following are Lewis acids ?

(4) BCl3 and AlCl3

44. Total number of lone pair of electrons in I 3 ion is :

Hence the answer is option (1).

Solution: CH3COOK is a salt of weak acid and strong base

50. Consider the following reaction and statements:

As all the NH3 positions are identical

Hence the answer is option (2).

51. Glucose on prolonged heating with HI gives :

52. The trans-alkenes are formed by the reduction of alkynes with :

Hence the answer is option (3).

Organic compounds nitrogen +

Hence the answer is option (1).

Hence the answer is option (4).

Hence the answer is option (3).

58. The increasing order of basicity of the following compounds is :

(1) (a) < (b) < (c) < (d)

Due to -I of  bond, basic character decreases.

59. The major product formed in the following reaction is :

Hence the answer is option (4).

60. The major product of the following reaction is :

Hence the answer is option (2).

61. Two sets A and B are as under :

62. Let S= {x  R : x  0 and 2 x  3  x ( x  6)  6  0} . Then S :

65. If the system of linear equations

If a12  a22  .....  a172  140m , then m is equal to:

76. Let g ( x)  cos x2 , f ( x)  x , and  ,      be the roots of the quadratic

77. Let y=y(x) be the solution of the differential equation

80. If the tangent at (1,7) to the curve x2  y  6 touches the circle