ALCHEMIST SCIENCE ACADEMY

CSIR-UGC-NET/JRF|GATE CHEMISTRY
UNIT TEST 04
TIME 1 Hour DATE 17/09/2018
M.M; 200
INSTRUCTION
This test contain following topics
(i) Organometallic (ii) GOC (iii) Reaction Mechanism (iv) Chemical Kinetics
The test paper divided in to two parts
PART A, 20 Questions Each Carry 2 Marks
Parts B, 20 Question Each Carry 4 Marks
Note: This test paper contain Multiple Choice Question (MCQs). Candidates will be required to
answer 15 in part A and 15 in part B respectively.
 1/4 Negative Marks for attempt wrong answer
 Use only ball black pen

PART –A
Q1.  olefin  
In metal-olefin interception, that extant of increase is metal   back donation would
be
(a) lead to a increase in C  C bond length
(b) Change to formal exidation state of metal.
2 3
(c)Change the hydridisation of the olefin carbon from sp  sp

(d)  - break donation increase with the presence of e  donating substiturd on olefine

Q2. Through cyclobutadiene C 4 H 4  is highly unstable and reading polymerizes on its force state, its

transition metal complex could be is isolated because

(a) It engages in long range intereation with transition metal.

(b) It gain stability due to formation of C 4 H 4 

2
on bridging on transition metal.

(c) Its polymerization ability decries in presence of transition on metal.


(d) It becomes stable in the presence of transition metal due to formation of C 4 H 42  

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 Ni and the number of M  M bonds in the Ni 2 CO 6 
n 2 
Q3. The oxid state of that are assistant 18e

rule are

(a) Ni (II ), 1 bond (b) NiIV  , 2-bonds

(c) Ni I  , 1 bond (d) NiIV  , 3 bonds
Q4.    
For the reaction of Fe   C 5 H 5 CH 3 CO 2 with PMe3 the main intermediate is
5

 
(a) Fe 
5
 C H CH CO  PMe 
5 5 3 2 3

(b) Fe   C H COCH CO 

5
5 5 3

(c) Fe   C H CH CO  

3
5 5 3 2

(d) Fe   C H COCH CO  PMe 

3
5 5 3 3

Q5. According to wade’s rule the anion B10 H 10  4 is

(a) Closo (b) Nido (c) Arachno (d) Closo and Nido both
Q6. Draw an energy profile diagram for a three step reaction in which first step is slowest and last step is fastest.

PE
PE

(a) Prograss of reaction (b)

Prograss of reaction

PE

(c) (d) None of these

Prograss of reaction

Q7. The correct order of dipole moment for the following molecules is

(a) IV  I  III  II (b) I  IV  III  II

(c) III  I  II  IV (d) II  III  IV  I

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Q8. The stability order of the following carbocations is

(a) II  IV  III  I (b) IV  II  III  I

(c) II  III  I  IV (d) I  III  II  IV
Q9. Which of the following has lowest pK a value ?

Q10.

Compare the basic strengths of compounds given

(a) (i )  (ii )  (iii ) (b) (ii )  (i )  (iii ) (c) (ii )  (iii )  (i ) (d) (iii )  (ii )  (i )

Q11 A chemical reaction 2 A 

 4 B  C ; in gaseous phase shows an increase in concentration of B by
5  10 3 M in 10 second. Calculate rate of disappearance of A.
4
(a) 2.5  10 mol litre -1 sec 1 (b) 5  10
4
mol litre -1 sec 1
2
(c) 2.5  10 mol litre -1 sec 1 (b) 5  10
2
mol litre -1 sec 1
Q12. The rates of reactions double when their temperature is raisedfrom 298 K to 308 K. Calculate their
activation energy
(a) 48.9 KJ (b) 52.9 KJ (c) 58.9 KJ (d) 68.9 KJ

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Q13. Calculate the half life period for first order reaction having activation energy 39.3 kcal mol-1 at 300°C and

the frequency constant 1.11  10

11
sec 1 .
(a) 5278 sec (b) 6078 sec (c) 9241sec (d) 10841sec
Q14. Calculate the rate of reaction for the change 2 A  Products, when rate constant of the reaction is

2.1  10 5 time 1 and A0  0.2 M .

6
(a) 4.2  10 mol litre -1 sec 1 (b) 5.2  10
4
mol litre -1 sec 1

5
(c) 2.5  10 mol litre -1 sec 1 (b) 4.2  10
4
mol litre -1 sec 1

1
Q15. The rate constant for a first order reaction is 60 s . How much time will it take to reduce the initial
th
concentration of the reactant to its 1 / 16 value?
1 -1 -1 -1
(a) 0.0462 sec (b) 0.123 sec (c) 0.0623 sec (d) 0.231 sec
Q16 . The major product formed in the reaction given below is

Q17. The major product formed in the reaction given below is

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Q18. Identify the product from the following reaction

Q19. Identify the product from the following reaction

Q20. The major product formed in the reaction given below is

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 PART –B
Q21. Find the product of the following Conversion
1s
Cp CoMe2 L X
Co
( X ) X is

Q22. Fe Co 5 C

2 F4
 ( P ) P- is ?

Q23.

Q24. Predict the structure of the following

(a) Trigonal prism and Capped octahedral

(b) Butterfly and Tetrahedral
(c) I cosahdral and octahedral
(d) Trigonal prism and and Td

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Q25. Find the structure of the following Mocked clusters

Sn44 , Sn94  respativly

(a) Nido and Nido (b) Closo and Nido
(c) Nido and Closo (d) Closo and Closo
Q26. The dipole moments of halo compounds are in the order
(a) CHCl3  CCl4  CHCl2  cis  CHCl  CHCl

(b) cis  CHCl  CHCl  CHCl 3  CH 2 CH 2 Cl  CCl 4

(c) cis  CHCl  CHCl  CH 2 Cl 2  CHCl 3  CCl

(d) CHCl 3  CHCl 2  cis  CHCl  CHCl  CCl 4

Q27. Compare relative stability of the following resonating structure

(a) p  q  r (b) q  p  r (c) q  r  p (d) p  r  q

Q28. Which of the following is strongest acid?

Q29. Among the following in increasing order of their acidic strength,

(a) III  I  IV  II (b) II  I  IV  III

(c) I  III  IV  II (d) II  III  I  IV

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Q30. Which is the product of the following reaction

Q31. Show that time required to complete 99.9% completion of a first order reaction is 1.5 times to 90%
completion.
(a) 1.5  t 90% (b) 2.5  t 90% (c) 1.3  t 90 % (d) 1.8  t 90%

Q32. The rate constant of a certain reaction is given by :

212
log 10 K  5.4   2.17 log 10 T
T
0
Calculate the activation energy at 127 C .

(a) 2112 cal (b) 2712 cal (c) 1214 cal (d) 1921 cal
Q33. A decomposes as
k1  2  10 3 sec 1
2 B g 

A g 
k 2  1  10 3 sec
Cg 
The rate appearance of B , taking 2 M concentration of A at any time 't ' ' is equal to
3
(a) 2  10 Ms (b) 4  10 3 Ms 1 (c) 8  10
3
Ms 1 (d) None of these

Q34. The rate constant for a first order reaction of ethylene oxide into CH 4 and CO follows the equation
1.25  10 4
 
log ek s 1  14.34 
T
The value of activation energy is
4 -1 4 1
(a) 10.39  10 J / K mol (b) 20.44  10 J / K mol
4 -1
(b) 30.66  10 J / K mol (d) None of these

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Q35. The catalyst lower the activation energy for a certain reaction from 83.314 to 75KJ mol -1
At 500K , what will be the rate of reaction as compare to uncatalged reaction? Assume other things being
equal
3
(a) double (b) 28 times (c) 7.38 times (d) 7.38  10 times
Q36. The major product formed in the reaction given below is

Q37. The major product formed in the reaction given below is

Q38. The major product formed in the reaction given below is

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Q39. Identify the product from the following reaction

Q40. Identify the product from the following reaction

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