Awful Chemistry
Awful Chemistry
Awful Chemistry
CHEMISTRY
Straight Objective Type
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
1. For standardizing NaOH solution, which of the following is used as a primary standard ?
(1) Sodium tetraborate (2) Ferrous Ammonium Sulfate
(3) Oxalic acid (4) dil. HCl
NH3CH3COO
C6H5NH2
+ HNO2 A B
SO3H
O
N=N–O–CCH3 N=N NH2
(1) and
SO3H SO3H
O
H
N=N–OCCH3 N=N–N
(2) and
SO3H SO3H
N=NCOCH3 N=N
(3) and
SO3H SO3H
N=NCOCH3
3. When XO2 is fused with an alkali metal hydroxide in presence of an oxidizing agent such as KNO3 ; a
dark green product is formed which disproportioates in acidic solution to afford a dark purple solution. X
is :
(1) Mn (2) Cr (3) V (4) Ti
(1) (2)
Cl
Cl MeO
Cl
(3) (4)
MeO MeO
A A A A
(1) (2) (3) (4)
HBr
Br
8. In the extraction of copper from its sulphide ore, metal is finally obtained by the oxidation of cuprous
sulphide with :
(1) SO2 (2) Fe2O3 (3) Cu2O (4) CO
10. Which of the following conversions involves change in both shape and hybridisation ?
+
(1) H2O H3O (2) BF3 BF4– (3) CH4 C2H6 (4) NH3 NH4
12. In Wilkinson’s catalyst, the hybridization of central metal ion and its shape are respectively :
3 2 3
(1) sp d, trigonal bipyramidal (2) d sp , octahedral
2 3
(3) dsp , square planar (4) sp , tetrahedral
13. At 320 K, a gas A2 is 20 % dissociated to A(g). The standard free energy change at 320 K and 1 atm in
–1 –1 –1
J mol is approximately : (R = 8.314 JK mol ; ln 2 = 0.693 ; ln 3 = 1.098)
(1) 1844 (2) 2068 (3) 4281 (4) 4763
16. When 9.65 ampere current was passed for 1.0 hour into nitrobenzene in acidic medium, the amount of
p-aminophenol produced is :
(1) 109.0 g (2) 98.1 g (3) 9.81 g (4) 10.9 g
18. An unknown chlorohydrocarbon has 3.55 % of chlorine. If each molecule of the hydrocarbon has one
chlorine atom only ; chlorine atoms present in 1 g of chlorohydrocarbon are :
23 –1
(Atomic wt. of Cl = 35.5 u ; Avogadro constant = 6.023 × 10 mol )
9 23 21 20
(1) 6.023 × 10 (2) 6.023 × 10 (3) 6.023 × 10 (4) 6.023 × 10
–1
20. The mass of a non-volatile, non-electrolyte solute (molar mass = 50 g mol ) needed to be dissolved in
114 g octane to reduce its vapour pressure to 75 %, is :
(1) 37.5 g (2) 75 g (3) 150 g (4) 50 g
22. Assuming ideal gas behaviour, the ratio of density of ammonia to that of hydrogen chlroide at same
temperature and pressure is : (Atomic wt. of Cl 35.5 u)
(1) 1.46 (2) 1.64 (3) 0.46 (4) 0.64
24. The gas phase reaction 2NO2(g) N2O4(g) is an exothermic reaction. The decomposition of N2O4, in
26. A group 13 element ’X’ reacts with chlorine gas to produce a compound XCl3. XCl3 is electron deficient
and easily reacts with NH3 to form Cl3X NH3 adduct; however, XCl3 does not dimerize. X is :
Br
KOH
SN 2
NH2
OH OH OH OH
28. If 50 % of a reaction occurs in 100 second and 75 % of the reaction occurs in 200 second, the order of
this reaction is :
(i) OHCCH2COCl
(ii) H2SO4 , heat
MeO OH
OMe O
(1) (2)
O MeO O O
O OMe
(3) (4)
MeO O O O
30. Which of the following compounds will most readily be dehydrated to give alkene under acidic
condition?