Awful Chemistry

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| PAPER-1 (B.E. / B.TECH.

) JEE (MAIN) | ONLINE | 16-04-2018

CHEMISTRY
Straight Objective Type
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.

1. For standardizing NaOH solution, which of the following is used as a primary standard ?
(1) Sodium tetraborate (2) Ferrous Ammonium Sulfate
(3) Oxalic acid (4) dil. HCl

2. Products A and B formed in the following reactions are respectively :

NH3CH3COO

C6H5NH2
+ HNO2 A B

SO3H
O
N=N–O–CCH3 N=N NH2

(1) and

SO3H SO3H
O
H
N=N–OCCH3 N=N–N

(2) and

SO3H SO3H

N=NCOCH3 N=N

(3) and

SO3H SO3H
N=NCOCH3

(4) and HO3S N NH2


H
SO3H

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| PAPER-1 (B.E. / B.TECH.) JEE (MAIN) | ONLINE | 16-04-2018

3. When XO2 is fused with an alkali metal hydroxide in presence of an oxidizing agent such as KNO3 ; a
dark green product is formed which disproportioates in acidic solution to afford a dark purple solution. X
is :
(1) Mn (2) Cr (3) V (4) Ti

4. The major product B formed in the following reaction sequence is :


CHO
(i) C2H5MgBr HCl
A B
(ii) H2O
MeO

(1) (2)
Cl
Cl MeO
Cl

(3) (4)
MeO MeO

5. In a complexometric titration of metal ion with ligand


M (Metal ion) + L (Ligand) C (Complex) end point is estimated spectrophotometrically (through light
absorption). If ’M’ and ’C’ do not absorb light and only ’L’ absorbs, then the titration plot between
absorbed light (A) versus volume of ligand ’L’ (V) would look like :

A A A A
(1) (2) (3) (4)

V (Ligand) V (Ligand) V (Ligand) V (Ligand)

6. The major product of the following reaction is :


CH=CHCH3

HBr

CH2CH2CH2Br BrCHCH2CH3 CH2CHCH3 CH=CHCH3


Br
(1) (2) (3) (4)

Br

7. Among the following, the incorrect statement is :


(1) Cellulose and amylase has 1,4-glycosidic linkage.
(2) Lactose contains -D-galactose and -D-glucose.
(3) Maltose and lactose has 1,4-glycosidic linkage.
(4) Sucrose and amylose has 1,2-glycosidic linkage.

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8. In the extraction of copper from its sulphide ore, metal is finally obtained by the oxidation of cuprous
sulphide with :
(1) SO2 (2) Fe2O3 (3) Cu2O (4) CO

9. Among the oxides of nitrogen :


N2O3, N2O4 and N2O5 ; the molecule(s) having nitrogen-nitrogen bond is/are :
(1) N2O3 and N2O4 (2) N2O4 and N2O5 (3) N2O3 and N2O5 (4) Only N2O5

10. Which of the following conversions involves change in both shape and hybridisation ?
+
(1) H2O H3O (2) BF3 BF4– (3) CH4 C2H6 (4) NH3 NH4

11. The most polar compound among the following is :


F F F

(1) (2) (3) (4)


F
F F

12. In Wilkinson’s catalyst, the hybridization of central metal ion and its shape are respectively :
3 2 3
(1) sp d, trigonal bipyramidal (2) d sp , octahedral
2 3
(3) dsp , square planar (4) sp , tetrahedral

13. At 320 K, a gas A2 is 20 % dissociated to A(g). The standard free energy change at 320 K and 1 atm in
–1 –1 –1
J mol is approximately : (R = 8.314 JK mol ; ln 2 = 0.693 ; ln 3 = 1.098)
(1) 1844 (2) 2068 (3) 4281 (4) 4763

14. Which of the following complexes will show geometrical isomerism ?


(1) Potassium tris(oxalato)chromate(III)
(2) Pentaaquachlorochromium(III)chloride
(3) Aquachlorobis(ethylenediamine)cobalt(II) chloride
(4) Potassium amminetrichloroplatinate(II)

15. Which of the following statements is false ?


(1) Splitting of spectral lines in electrical field is called Stark effect.
(2) Frequency of emitted radiation from a black body goes from a lower wavelength of higher
wavelength as the temperature increases.
(3) Photon has momentum as well as wavelength.
(4) Rydberg constant has unit of energy.

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16. When 9.65 ampere current was passed for 1.0 hour into nitrobenzene in acidic medium, the amount of
p-aminophenol produced is :
(1) 109.0 g (2) 98.1 g (3) 9.81 g (4) 10.9 g

17. For which of the following processes, S is negative ?


(1) C(diamond) C(graphite) (2) N2(g, 1 atm) N2(g, 5 atm)
(3) N2(g, 273 K) N2(g, 300 K) (4) H2(g) 2H(g)

18. An unknown chlorohydrocarbon has 3.55 % of chlorine. If each molecule of the hydrocarbon has one
chlorine atom only ; chlorine atoms present in 1 g of chlorohydrocarbon are :
23 –1
(Atomic wt. of Cl = 35.5 u ; Avogadro constant = 6.023 × 10 mol )
9 23 21 20
(1) 6.023 × 10 (2) 6.023 × 10 (3) 6.023 × 10 (4) 6.023 × 10

19. The incorrect statement is :


2+
(1) Cu ion gives chocolate coloured precipitate with potassium ferrocyanide solution.
2+ 2+
(2) Cu and Ni ions give black precipitate with H2S in presence of HCl solution.
(3) Ferric ion gives blood red colour with potassium thiocyanate.
2+
(4) Cu salts give red coloured borax bead test in reducing flame.

–1
20. The mass of a non-volatile, non-electrolyte solute (molar mass = 50 g mol ) needed to be dissolved in
114 g octane to reduce its vapour pressure to 75 %, is :
(1) 37.5 g (2) 75 g (3) 150 g (4) 50 g

21. The incorrect geometry is represented by :


(1) NF3 – trigonal planar (2) BF3 – trigonal planar
(3) AsF5 – trigonal bipyramidal (4) H2O – bent

22. Assuming ideal gas behaviour, the ratio of density of ammonia to that of hydrogen chlroide at same
temperature and pressure is : (Atomic wt. of Cl 35.5 u)
(1) 1.46 (2) 1.64 (3) 0.46 (4) 0.64

23. The correct match between items of List-I and List-II is :


List-I List-II
(A) Phenelzine (P) Pyrimidine
(B) Chloroxylenol (Q) Furan
(C) Uracil (R) Hydrazine
(D) Ranitidine (S) Phenol
(1) (A)-(S), (B)-(R), (C)-(Q), (D)-(P) (2) (A)-(R), (B)-(S), (C)-(P), (D)-(Q)
(3) (A)-(R), (B)-(S), (C)-(Q), (D)-(P) (4) (A)-(S), (B)-(R), (C)-(P), (D)-(Q)

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| PAPER-1 (B.E. / B.TECH.) JEE (MAIN) | ONLINE | 16-04-2018

24. The gas phase reaction 2NO2(g) N2O4(g) is an exothermic reaction. The decomposition of N2O4, in

equilibrium mixture of NO2(g) and N2O4(g), can be increased by :

(1) addition of an inert gas at constant pressure.

(2) lowering the temperature

(3) increasing the pressure

(4) addition of an inert gas at constant volume.

25. Which one of the following is not a property of physical adsorption ?

(1) Higher the pressure, more the adsorption

(2) Greater the surface area, more the adsorption

(3) Lower the temperature, more the adsorption

(4) Unilayer adsorption occurs

26. A group 13 element ’X’ reacts with chlorine gas to produce a compound XCl3. XCl3 is electron deficient

and easily reacts with NH3 to form Cl3X NH3 adduct; however, XCl3 does not dimerize. X is :

(1) B (2) Al (3) In (4) Ga

27. The major product of the following reaction is :

Br

KOH
SN 2
NH2

OH OH OH OH

(1) (2) (3) (4)


NH2 NH2 H2N H2N

28. If 50 % of a reaction occurs in 100 second and 75 % of the reaction occurs in 200 second, the order of

this reaction is :

(1) 2 (2) 3 (3) Zero (4) 1

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| PAPER-1 (B.E. / B.TECH.) JEE (MAIN) | ONLINE | 16-04-2018

29. The major product of the following reaction is :

(i) OHCCH2COCl
(ii) H2SO4 , heat
MeO OH

OMe O

(1) (2)
O MeO O O

O OMe

(3) (4)
MeO O O O

30. Which of the following compounds will most readily be dehydrated to give alkene under acidic

condition?

(1) 4-Hydroxypentan-2-one (2) 3-Hydroxypentan-2-one

(3) 1-Pentanol (4) 2-Hydroxycyclopentanone

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