EPA Jan. 2020 Summerville Water Results

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 4 Laboratory Services and Applied Science Division


980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

January 30, 2020


4LSASD-LSB

MEMORANDUM

SUBJECT: FINAL Analytical Report


Project: 20-0169, GAEPD Summerville PFAS Screening

FROM: Diana Burdette


OCS Analyst

THRU: Jason Collum, Chief


LSB Organic Chemistry Section

TO: Nathan Barlet

Attached are the final results for the analytical groups listed below. This report shall not be reproduced except in
full without approval of the Region 4 laboratory. These analyses were performed in accordance with the
Laboratory Services Branch's Laboratory Operations and Quality Assurance Manual (LSB LOQAM) found at
www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives specified in writing by the data
requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry
data have been verified based on the LSB LOQAM specifications and have been qualified by this laboratory if
the applicable quality control criteria were not met. Verification is defined in Chapter 5 of the LSB LOQAM. For
a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in
this report. The reported results are accurate within the limits of the method(s) and are representative only of the
samples as received by the laboratory.
Analyses Included in this report: Method Used: Accreditations:

Semi Volatile Organics (SVOA)


PFAS ASBPROC-800PFAS (Water)

Page 1 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Sample Disposal Policy

Due to limited space for long term sample storage, LSB’s policy is to dispose of samples on a periodic schedule.
Air samples collected in summa canisters will be disposed of 30 days following the issuance of this report. All
other sample media including original samples, sample extracts and or digestates will be disposed of, in
accordance with applicable regulations, 60 days from the date of this report.

This sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by
the criminal investigators that case development and litigation are complete.

These samples may be held in the laboratory's custody for a longer period of time. If samples require storage
beyond the 60-day period, please contact the Sample Control Coordinator by e-mail at
R4SampleCustody@epa.gov.

Page 2 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

SAMPLES INCLUDED IN THIS REPORT

Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID Laboratory ID Matrix Date Collected Date Received

Goodwin Hill Field Blank E200403-01 Field Blank 1/23/20 13:10 1/24/20 7:15
Lowe Springs Field Blank E200403-02 Field Blank 1/23/20 12:20 1/24/20 7:15
Summerville WTP Field Blank E200403-03 Field Blank 1/23/20 11:30 1/24/20 7:15
Trip Blank E200403-04 Trip Blank - Water 1/23/20 10:50 1/24/20 7:15
Goodwin Hill Tank E200403-05 Potable Water 1/23/20 13:05 1/24/20 7:15
Lowe Spring Raw E200403-06 Municipal Water Supply 1/23/20 12:00 1/24/20 7:15
Lowe Springs Finished E200403-07 Potable Water 1/23/20 12:10 1/24/20 7:15
Raccoon Creek E200403-08 Municipal Water Supply 1/23/20 11:00 1/24/20 7:15
Raccoon Creek Dup E200403-09 Municipal Water Supply 1/23/20 11:05 1/24/20 7:15
Raccoon Creek Finished E200403-10 Potable Water 1/23/20 11:25 1/24/20 7:15

Page 3 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

DATA QUALIFIER DEFINITIONS

U The analyte was not detected at or above the reporting limit.


J The identification of the analyte is acceptable; the reported value is an estimate.
QM-1 Matrix Spike Recovery less than method control limits

ACRONYMS AND ABBREVIATIONS

CAS Chemical Abstracts Service


Note: Analytes with no known CAS identifiers have been assigned codes beginning with "E", the EPA ID as assigned by
the EPA Substance Registry System (www.epa.gov/srs), or beginning with "R4-", a unique identifier assigned by the EPA
Region 4 laboratory.

MDL Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and
reported with a 99% confidence that the analyte concentration is greater than zero.

MRL Minimum Reporting Limit - Analyte concentration that corresponds to the lowest demonstrated level of acceptable
quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and
moisture content of soil/sediments.

TIC Tentatively Identified Compound - An analyte identified based on a match with the instrument software's mass
spectral library. A calibration standard has not been analyzed to confirm the compound's identification or the
estimated concentration reported.

ACCREDITATIONS:
ISO ASB is accredited by ISO/IEC 17025, including an amplification for forensic accreditation through ANSI-ASQ
National Accreditation Board.
Refer to the certificate and scope of accreditation AT-1644 at:
http://www.epa.gov/aboutepa/about-region-4s-science-and-ecosystem-support-division-sesd

NR The EPA Region 4 Laboratory has not requested accreditation for this test.

Page 4 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Goodwin Hill Field Blank Lab ID: E200403-01


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 13:10


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS

Page 5 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Goodwin Hill Field Blank Lab ID: E200403-01


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 13:10


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 0:04 ASBPROC-800PF
AS

Page 6 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Springs Field Blank Lab ID: E200403-02


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 12:20


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS

Page 7 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Springs Field Blank Lab ID: E200403-02


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 12:20


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 0:26 ASBPROC-800PF
AS

Page 8 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Summerville WTP Field Blank Lab ID: E200403-03


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 11:30


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS

Page 9 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Summerville WTP Field Blank Lab ID: E200403-03


Station ID: Matrix: Field Blank

Date Collected: 1/23/20 11:30


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 0:48 ASBPROC-800PF
AS

Page 10 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Trip Blank Lab ID: E200403-04


Station ID: Matrix: Trip Blank - Water

Date Collected: 1/23/20 10:50


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS

Page 11 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Trip Blank Lab ID: E200403-04


Station ID: Matrix: Trip Blank - Water

Date Collected: 1/23/20 10:50


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 1:10 ASBPROC-800PF
AS

Page 12 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Goodwin Hill Tank Lab ID: E200403-05


Station ID: GWHT Matrix: Potable Water

Date Collected: 1/23/20 13:05


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 89 ng/L 40 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 ng/L 18 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 32 ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 320 ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 47 ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 45 ng/L 18 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 640 ng/L 20 11:39 1:32 ASBPROC-800PF
AS

Page 13 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Goodwin Hill Tank Lab ID: E200403-05


Station ID: GWHT Matrix: Potable Water

Date Collected: 1/23/20 13:05


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 1:32 ASBPROC-800PF
AS

Page 14 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Spring Raw Lab ID: E200403-06


Station ID: LSWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 12:00


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 18 U ng/L 18 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 17 U ng/L 17 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS

Page 15 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Spring Raw Lab ID: E200403-06


Station ID: LSWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 12:00


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 1:54 ASBPROC-800PF
AS

Page 16 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Springs Finished Lab ID: E200403-07


Station ID: LSWTP Matrix: Potable Water

Date Collected: 1/23/20 12:10


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U, J, QM-1 ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 40 U ng/L 40 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 18 U ng/L 18 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS

Page 17 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Lowe Springs Finished Lab ID: E200403-07


Station ID: LSWTP Matrix: Potable Water

Date Collected: 1/23/20 12:10


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 2:16 ASBPROC-800PF
AS

Page 18 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Lab ID: E200403-08


Station ID: SWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 11:00


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 80 ng/L 40 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 32 ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 350 ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 48 ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 47 ng/L 18 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 670 ng/L 20 11:39 2:38 ASBPROC-800PF
AS

Page 19 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Lab ID: E200403-08


Station ID: SWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 11:00


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 2:38 ASBPROC-800PF
AS

Page 20 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Dup Lab ID: E200403-09


Station ID: SWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 11:05


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 89 ng/L 40 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 33 ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 340 ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 47 ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 41 ng/L 18 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 660 ng/L 20 11:39 3:00 ASBPROC-800PF
AS

Page 21 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Dup Lab ID: E200403-09


Station ID: SWTP Matrix: Municipal Water Supply

Date Collected: 1/23/20 11:05


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 3:00 ASBPROC-800PF
AS

Page 22 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Finished Lab ID: E200403-10


Station ID: SWTP Matrix: Potable Water

Date Collected: 1/23/20 11:25


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
757124-72-4 4:2FTS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
27619-97-2 6:2FTS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
39108-34-4 8:2FTS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
754-91-6 FOSA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
13252-13-6 HFPO-DA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
2355-31-9 N-MeFOSAA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
375-22-4 PFBA 86 ng/L 40 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
375-73-5 PFBS 18 U ng/L 18 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
335-76-2 PFDA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
307-55-1 PFDoA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
335-77-3 PFDS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
375-85-9 PFHpA 32 ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
375-92-8 PFHpS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
307-24-4 PFHxA 340 ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
355-46-4 PFHxS 18 U ng/L 18 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
375-95-1 PFNA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
68259-12-1 PFNS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
335-67-1 PFOA 49 ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
1763-23-1 PFOS 49 ng/L 18 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
2706-90-3 PFPeA 660 ng/L 20 11:39 3:22 ASBPROC-800PF
AS

Page 23 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics


Project: 20-0169, GAEPD Summerville PFAS Screening

Sample ID: Raccoon Creek Finished Lab ID: E200403-10


Station ID: SWTP Matrix: Potable Water

Date Collected: 1/23/20 11:25


CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method

1/29/20 1/30/20
2706-91-4 PFPeS 19 U ng/L 19 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
72629-94-8 PFTrDA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS
1/29/20 1/30/20
2058-94-8 PFUdA 20 U ng/L 20 11:39 3:22 ASBPROC-800PF
AS

Page 24 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics (SVOA) - Quality Control


US-EPA, Region 4, LSASD
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch 2001044 - S PFC


Blank (2001044-BLK1) Prepared & Analyzed: 01/29/20
ASBPROC-800PFAS
4:2FTS U 19 ng/L U
6:2FTS U 19 " U
8:2FTS U 19 " U
FOSA U 20 " U
HFPO-DA U 20 " U
N-MeFOSAA U 20 " U
PFBA U 40 " U
PFBS U 18 " U
PFDA U 20 " U
PFDoA U 20 " U
PFDS U 19 " U
PFHpA U 20 " U
PFHpS U 19 " U
PFHxA U 20 " U
PFHxS U 18 " U
PFNA U 20 " U
PFNS U 19 " U
PFOA U 20 " U
PFOS U 18 " U
PFPeA U 20 " U
PFPeS U 19 " U
PFTrDA U 20 " U
PFUdA U 20 " U

LCS (2001044-BS1) Prepared & Analyzed: 01/29/20


ASBPROC-800PFAS
4:2FTS 297 19 ng/L 374.00 79.3 67.1-125
6:2FTS 306 19 " 380.00 80.6 49.2-134
8:2FTS 331 19 " 384.00 86.1 56.4-136
FOSA 322 20 " 400.00 80.5 57.7-148
HFPO-DA 396 20 " 400.00 98.9 51.1-127
N-MeFOSAA 321 20 " 400.00 80.3 43.2-178
PFBA 311 40 " 400.00 77.8 67.9-118
PFBS 279 18 " 354.00 78.7 68.2-118
PFDA 324 20 " 400.00 81.1 47.4-162
PFDoA 301 20 " 400.00 75.3 56.5-155
PFDS 311 19 " 386.00 80.6 35.1-168
PFHpA 326 20 " 400.00 81.4 72.8-116
PFHpS 307 19 " 380.00 80.7 59.7-130

Page 25 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics (SVOA) - Quality Control


US-EPA, Region 4, LSASD
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch 2001044 - S PFC


LCS (2001044-BS1) Prepared & Analyzed: 01/29/20
PFHxA 328 20 ng/L 400.00 81.9 62.6-127
PFHxS 299 18 " 364.80 81.9 69.5-117
PFNA 327 20 " 400.00 81.7 64.1-128.4
PFNS 287 19 " 384.00 74.7 63.3-126
PFOA 323 20 " 400.00 80.8 66.7-122
PFOS 298 18 " 370.20 80.5 70.4-122
PFPeA 324 20 " 400.00 80.9 72-115
PFPeS 309 19 " 376.00 82.3 69-117
PFTrDA 276 20 " 400.00 69.0 32.2-215
PFUdA 329 20 " 400.00 82.3 65.8-142

Matrix Spike (2001044-MS1) Source: E200403-07 Prepared: 01/29/20 Analyzed: 01/30/20


ASBPROC-800PFAS
4:2FTS 247 18 ng/L 302.10 U 81.8 70-133
6:2FTS 238 19 " 306.95 U 77.7 58-143
8:2FTS 246 19 " 310.18 U 79.2 66-126
FOSA 166 20 " 323.10 U 51.4 61-138 QM-1
HFPO-DA 333 20 " 323.10 U 103 45-129
N-MeFOSAA 266 20 " 323.10 U 82.2 47-169
PFBA 241 39 " 323.10 U 74.7 60-141
PFBS 212 17 " 285.95 U 74.1 62-135
PFDA 267 20 " 323.10 U 82.6 53-156
PFDoA 226 20 " 323.10 U 70.0 30-172
PFDS 206 19 " 311.79 U 66.1 44-151
PFHpA 272 20 " 323.10 U 84.1 75-122
PFHpS 257 19 " 306.95 U 83.7 66-132
PFHxA 271 20 " 323.10 U 83.9 64-138
PFHxS 254 18 " 294.67 U 86.3 72-124
PFNA 265 20 " 323.10 U 82.1 72-129
PFNS 219 19 " 310.18 U 70.6 61-126
PFOA 268 20 " 323.10 U 83.1 74-127
PFOS 252 18 " 299.03 U 84.1 68-132
PFPeA 264 20 " 323.10 U 81.6 75-122
PFPeS 255 19 " 303.72 U 83.9 72-122
PFTrDA 201 20 " 323.10 U 62.2 10-193
PFUdA 252 20 " 323.10 U 78.1 44-164

Page 26 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics (SVOA) - Quality Control


US-EPA, Region 4, LSASD
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch 2001044 - S PFC


Matrix Spike Dup (2001044-MSD1) Source: E200403-07 Prepared: 01/29/20 Analyzed: 01/30/20
ASBPROC-800PFAS
4:2FTS 240 19 ng/L 285.50 U 84.1 70-133 2.87 34
6:2FTS 268 19 " 290.08 U 92.3 58-143 11.6 45
8:2FTS 291 19 " 293.13 U 99.2 66-126 16.8 56
FOSA 194 20 " 305.34 U 63.5 61-138 15.5 39
HFPO-DA 328 20 " 305.34 U 107 45-129 1.37 57
N-MeFOSAA 265 20 " 305.34 U 86.7 47-169 0.384 65
PFBA 230 40 " 305.34 U 75.3 60-141 4.84 37
PFBS 204 18 " 270.23 U 75.7 62-135 3.51 32
PFDA 278 20 " 305.34 U 91.2 53-156 4.21 57
PFDoA 245 20 " 305.34 U 80.4 30-172 8.09 56
PFDS 231 19 " 294.66 U 78.5 44-151 11.6 66
PFHpA 273 20 " 305.34 U 89.6 75-122 0.650 26
PFHpS 260 19 " 290.08 U 89.6 66-132 1.17 28
PFHxA 265 20 " 305.34 U 86.7 64-138 2.37 42
PFHxS 250 18 " 278.47 U 89.6 72-124 1.90 32
PFNA 279 20 " 305.34 U 91.3 72-129 5.05 31
PFNS 230 19 " 293.13 U 78.6 61-126 5.02 35
PFOA 268 20 " 305.34 U 87.7 74-127 0.220 32
PFOS 259 18 " 282.60 U 91.7 68-132 2.99 37
PFPeA 265 20 " 305.34 U 86.8 75-122 0.454 27
PFPeS 258 19 " 287.02 U 89.7 72-122 1.12 29
PFTrDA 244 20 " 305.34 U 79.9 10-193 19.3 106
PFUdA 269 20 " 305.34 U 88.2 44-164 6.49 48

MRL Verification (2001044-PS1) Prepared & Analyzed: 01/29/20


ASBPROC-800PFAS
4:2FTS 17.0 19 ng/L 18.700 91.0 47.1-145 MRL-2,
Q-2, J
6:2FTS 22.5 19 " 19.000 119 29.2-154 MRL-2
8:2FTS 20.3 19 " 19.200 106 36.4-156 MRL-2
FOSA 13.8 20 " 20.000 68.9 37.7-168 MRL-2,
Q-2, J
HFPO-DA 14.6 20 " 20.000 73.2 31.3-147 MRL-2,
Q-2, J
N-MeFOSAA 11.7 20 " 20.000 58.4 23.2-198 MRL-2,
Q-2, J
PFBS 16.6 18 " 17.700 93.5 48.2-138 MRL-2,
Q-2, J
PFDA 19.7 20 " 20.000 98.3 27.4-182 MRL-2,
Q-2, J

Page 27 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Semi Volatile Organics (SVOA) - Quality Control


US-EPA, Region 4, LSASD
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch 2001044 - S PFC


MRL Verification (2001044-PS1) Prepared & Analyzed: 01/29/20
PFDoA 18.9 20 ng/L 20.000 94.6 36.5-175 MRL-2,
Q-2, J
PFDS 20.4 19 " 19.300 105 15.1-188 MRL-2
PFHpA 19.5 20 " 20.000 97.6 52.8-136 MRL-2,
Q-2, J
PFHpS 18.5 19 " 19.000 97.4 39.7-150 MRL-2,
Q-2, J
PFHxA 16.8 20 " 20.000 83.9 42.6-147 MRL-2,
Q-2, J
PFHxS 15.7 18 " 18.240 86.1 49.5-138 MRL-2,
Q-2, J
PFNA 18.0 20 " 20.000 89.8 44.1-148 MRL-2,
Q-2, J
PFNS 15.1 19 " 19.200 78.8 43.3-146 MRL-2,
Q-2, J
PFOA 18.9 20 " 20.000 94.7 46.7-142 MRL-2,
Q-2, J
PFOS 20.6 18 " 18.510 111 50.4-142 MRL-2
PFPeA 19.3 20 " 20.000 96.5 52-135 MRL-2,
Q-2, J
PFPeS 18.2 19 " 18.800 97.0 49-137 MRL-2,
Q-2, J
PFTrDA 19.3 20 " 20.000 96.7 12.2-235 MRL-2,
Q-2, J
PFUdA 21.2 20 " 20.000 106 45.8-162 MRL-2

MRL Verification (2001044-PS2) Prepared & Analyzed: 01/29/20


ASBPROC-800PFAS
PFBA 34.3 40 ng/L 40.000 85.7 47.9-138 MRL-2,
Q-2, J

Page 28 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48


UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Laboratory Services and Applied Science Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 20-0169
Project: 20-0169, GAEPD Summerville PFAS Screening - Reported by Diana Burdette

Notes and Definitions for QC Samples


U The analyte was not detected at or above the reporting limit.
J The identification of the analyte is acceptable; the reported value is an estimate.
MRL-2 MRL verification for Non-Potable Water matrix
Q-2 Result greater than MDL but less than MRL.
QM-1 Matrix Spike Recovery less than method control limits

Page 29 of 29 E200403 SVOA FINAL 01 30 20 1448 1/30/20 14:48

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