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    Grafica de Orden Cero: Temperatura

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    Fernandita Salazar
    The document presents the results of an experiment measuring the concentration of (CH3)3CBr over time. It shows the concentration decreasing as time increases. Graphs of the concentration vs. time, the inverse concentration vs. time, and the natural log of the inverse concentration vs. time all produce straight lines, indicating the reaction is zero order, first order, and second order respectively. Arrhenius plots of rate constants vs. temperature also produce a straight line, allowing calculation of the activation energy.

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    Grafica de Orden Cero: Temperatura

    Uploaded by

    Fernandita Salazar
    9 views3 pages
    The document presents the results of an experiment measuring the concentration of (CH3)3CBr over time. It shows the concentration decreasing as time increases. Graphs of the concentration vs. time, the inverse concentration vs. time, and the natural log of the inverse concentration vs. time all produce straight lines, indicating the reaction is zero order, first order, and second order respectively. Arrhenius plots of rate constants vs. temperature also produce a straight line, allowing calculation of the activation energy.

    Original Description:

    fisicoquimica

    Original Title

    2

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    © © All Rights Reserved

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    The document presents the results of an experiment measuring the concentration of (CH3)3CBr over time. It shows the concentration decreasing as time increases. Graphs of the concentration vs. time, the inverse concentration vs. time, and the natural log of the inverse concentration vs. time all produce straight lines, indicating the reaction is zero order, first order, and second order respectively. Arrhenius plots of rate constants vs. temperature also produce a straight line, allowing calculation of the activation energy.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    9 views3 pages

    Grafica de Orden Cero: Temperatura

    Uploaded by

    Fernandita Salazar
    The document presents the results of an experiment measuring the concentration of (CH3)3CBr over time. It shows the concentration decreasing as time increases. Graphs of the concentration vs. time, the inverse concentration vs. time, and the natural log of the inverse concentration vs. time all produce straight lines, indicating the reaction is zero order, first order, and second order respectively. Arrhenius plots of rate constants vs. temperature also produce a straight line, allowing calculation of the activation energy.

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    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
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    You are on page 1of 3

    t(h) [(CH3)3CBr]/(10−2 moldm−3)

    0 1.039 1.2
    3.15 0.896
    1
    6.20 0.776 f(x) =
    10.00 0.639 0.8 R² =

    Concentracion
    18.30 0.353 0.6
    30.80 0.207
    0.4

    0.2

    0
    0

    t(h) [(CH3)3CBr]/(10−2 moldm−3)


    0 0.038258746
    3.15 -0.10981484
    6.20 -0.25360274
    10.00 -0.44785085 0.2
    18.30 -1.0412873
    0
    30.80 -1.5750365 0 f(x) = − 0.0
    -0.2 R² = 0.992

    -0.4
    -0.6
    -0.8
    -1
    -1.2
    -1.4
    -1.6
    -1.8
    t(h) Inverso [(CH3)3CBr]/(10−2 moldm−3)
    0 1
    3.15 1.160715
    6.20 1.2886598
    10.00 1.5648452
    18.30 2.8328612
    30.80 4.830918
    Grafica de orden Cero
    1.2

    1
    f(x) = − 0.027262210689966 x + 0.962683053621364
    0.8 R² = 0.944483558678724
    Concentracion

    0.6

    0.4

    0.2

    0
    0 5 10 15 20 25 30 35
    Temperatura

    Grafica Primer orden


    0.2
    0
    0 f(x) = − 0.054220010910066
    5 10 x + 0.053671043799004
    15 20 25 30 35
    -0.2 R² = 0.992203924050232

    -0.4
    -0.6
    -0.8
    -1
    -1.2
    -1.4
    -1.6
    -1.8

    Grafica de Segundo Orden


    6

    f(x) = 0.127948082056809 x + 0.653325497201899


    4 R² = 0.966122374254539

    0
    0 5 10 15 20 25 30 35
    T/K k/107 dm3mol-1s-1
    357 17.2
    400 25.3
    458 38.2
    524 52
    533 56.1
    615 76.5

    T/K k/107 dm3mol-1S-1 1/ Temperatura S-1


    357 17.2 0.0028011205
    400 25.3 0.0025
    458 38.2 0.0021834061
    524 52 0.001908397
    533 56.1 0.0018761726
    615 76.5 0.0016260162

    -5.6
    0.0014 0.0016 1/K0.0018
    S-1 0.002 ln 1/K S-1
    0.0022 0.0024 0.0026 0.0028 0.003
    -5.7 0.0028011205 -5.8777356
    0.0025 -5.9914646
    -5.8
    0.0021834061 -6.1268697
    -5.9 f(x)0.001908397 -6.261492
    = 459.041348581864 x − 7.14658679770179
    R² = 0.994025553316278
    0.0018761726 -6.2809525
    -6
    0.0016260162 -6.4216166
    -6.1

    -6.2

    -6.3

    -6.4

    -6.5

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