Subatomic Physics: Nuclear Physics Part: Profe. Carolina Pinilla
Subatomic Physics: Nuclear Physics Part: Profe. Carolina Pinilla
Subatomic Physics: Nuclear Physics Part: Profe. Carolina Pinilla
Ψ $ = 1sin5$ + 6cos5$.
6 = 0,
ℏ# : # ; #
Ψ . = 1sin5. = 0 → 5' . = :; → ' =
2>. #
Some quantum mechanics tools: One-dimensional
Stationary Bound states
infinite well
*=4 ) = 16))
" !$%
• Solid line: Ψ! ! = #
sin #
• Dashed line: Ψ! ! "
' '
" ℏ $
• )! = * "(#' = )) *"
*=3 ) = 9))
*=2 ) = 4))
*=1 ) = ))
!=0 !=$
Some quantum mechanics tools: One-dimensional
stationary bound states
Simple harmonic oscillator*
In this case we have to solve
ℏ! %! 1 !
− + )& Ψ & = ,Ψ & ,
2$ %& ! 2
#
" $%
Ψ& = . ! / & ,
&' !')
with 0! = ℏ%
and 1 ! = ℏ%
, we have
. = $";
1! 1 3 1 1 $ℏ
0= − = − ; 5= = .
2$ 2 ℏ5 2 6 6
Some quantum mechanics tools: One-dimensional
stationary bound states
Simple harmonic oscillator
We end up with the differential equation for the Hermite polynomials
!" !
!
!# " $
" − 2" !# !$ " + 2&!$ " = 0; * " ≡ !$ " ,
% '
With -$ = & +& ℏ/ and !$ " = −1 $ 1 # " ! 1 (# " .
!# '
Therefore
%
15 ) *
( +"
Ψ$ 3 = 1 & !$ 53 .
2$ &! 6
Some quantum mechanics tools: One-dimensional
stationary bound states
Simple harmonic oscillator Wave functions “confined in the
potential”
Ψ$ " # = 7#!
Ψ# " # = 5#!
Ψ! " ℏ&
# = #! =
"=0 2
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom
"#
!
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom
We have to solve
34
#Ψ %% , %& = EΨ %' , %& , E<0,
r
re Rcm +(& +(%
#= + + / |%% − %& |
2 2-& 2-%
rp
Changing %% , %& → 3)* , % and +& , +% → +)* , 4 .
O The Hamiltonian becomes
,.0.1,-0-
% = %% −%& ; 3)* = ;
,.1,- +()* 4(
# = #)* + #+ = + + / |%| ,
26 27
-& +& − -% +%
4= , +)* = +& + +% ,-,.
-% + -& with 7 = , 6 = -& + -%
/
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom
Therefore
' ,-./⋅1./
As Φ 3$% = &( )/+ 7 and observables involve the square of this quantity, we ignore it for
practical purposes.
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom
Thus we need to solve
!! %!
− * + = -* + ; # ≈ 0#
2# 4'(" )
ℏ! ! %!
→ − ∇ − − - * + = 0.
20# 4'(" )
Using
1 7 7 8!
∇! = ! )! − ! !,
) 7) 7) ℏ )
! !
7 cos : 7 1 7
8! = −ℏ! + + ,
7: ! sin : 7: sin! : 7A!
* + = B$ ) C$% :, A and 8! C$% :, A = ℏ! D D + 1 C$% :, A ,
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom
we end up with
ℏ! %! 2 % ( ( + 1 *!
− + − − − . /$ & = 0.
2$" %& ! & %& &! 4,-# &
%& '
The radial differential equation is obtained by changing /$ & = '
, 4. *.
ℏ! %! $
− ! + 5()) (&) − . 8$ & = 0,
2$" %&
$ *! ℏ! ( ( + 1
5()) & =− + .
4,-# & 2$" & !
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Effective potential
• Rydberg energy
&'
1 Ryd = = 13.6 eV
8)*+ ,+
• Bohr Radius
4)*+ ℏ'
,+ = '
≈ 0.529 A°
45 &
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
ℏ! %! ℏ! ( ( + 1 *!
− + − − . /$ & = 0,
2$" %& ! 2$" & ! 4,-# &
'
& !
2 5−(−1 ! (
)*
$ $+' !$+'
2
/%$ & = * 8 & 9%($(' 8& ; 8 =
! .
56# 25 5 + ( ! 56#
* Arfken & Weber, Mathematical methods for physics, Elsevier Academic Press (2005).
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
The !"! " are the associated Laguerre polynomials. They fulfill the Rodrigues representation
# $" !
$ " '
!"! = $ $# " !%" .
%! '" !
Ryd
.! = − ' .
%
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
(
- *
2 %−(−1 ! .
/0
!"# " = , * - # " #1( .*#1(
".#.( -"
%&' 2% % + ( !
(/*
23
.
• The factor , assures that !"# " → ∞ → 0
&'
1
$ [&' ]
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
"#$
• !! = −
!%
• $& = $ − % − 1 → 0 ≤ % ≤ $ − 1.
• +! = ∑!*+
'() 2% + 1 = $
,
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
1 1
Δ" = "+, − "+- = − Ryd
&." &/"
Δl = ±1
Some quantum mechanics tools: Three-dimensional
stationary bound states
Hydrogen atom: Radial wave functions and energy
Some quantum mechanics tools: Resonances
#!
No resonant continuum #!
potential
Veff $>0
"
!
0 0
r
!, #, $ → −!, −#, −$
', (, ) → ', * − (, + + *
or '⃗ → −⃗'
1
)→+ Π = Π#Π$ −1 ' .
) → Relative coordinate
+ → Relative angular momentum
+, ./0 ⟩ = ℏ$. . + 1 ./0 ⟩.