Safety Data Sheet: Section 1. Identification
Safety Data Sheet: Section 1. Identification
Safety Data Sheet: Section 1. Identification
Benzene
Section 1. Identification
GHS product identifier : Benzene
Chemical name : benzene
Other means of : benzene, purebenzol; cyclohexatriene; phenyl hydride; phene; coal naphtha; pyrobenzol
identification
Product use : Synthetic/Analytical chemistry.
Synonym : benzene, purebenzol; cyclohexatriene; phenyl hydride; phene; coal naphtha;
pyrobenzol
SDS # : 001062
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 1/14
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Benzene
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 2/14
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Benzene
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Benzene
Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 4/14
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Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 5/14
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Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 6/14
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Benzene
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Incompatibility with various : Highly reactive or incompatible with the following materials: oxidizing materials.
substances
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 7/14
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Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 8/14
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Benzene
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Causes damage to organs through prolonged or repeated exposure.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : May cause genetic defects.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Bioaccumulative potential
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 9/14
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Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Packing group II II II II II
Environment No. No. No. No. No.
Additional Reportable quantity Explosive Limit and - - Passenger and Cargo
10 lbs / 4.54 kg [1.3675 Limited Quantity Index AircraftQuantity
information
gal / 5.1767 L] 1 limitation: 5 L
Package sizes shipped Cargo Aircraft Only
in quantities less than Passenger Carrying Quantity limitation: 60 L
the product reportable Road or Rail Index Limited Quantities -
quantity are not subject 5 Passenger Aircraft
to the RQ (reportable Quantity limitation: 1 L
quantity) transportation
requirements.
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 10/14
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Packaging instruction
Passenger aircraft
Quantity limitation: 5 L
Cargo aircraft
Quantity limitation: 60 L
Special provisions
IB2, T4, TP1
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 11/14
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Benzene
SARA 313
Product name CAS number %
Form R - Reporting benzene 71-43-2 100
requirements
Supplier notification benzene 71-43-2 100
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : This material is listed.
New York : This material is listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
benzene Yes. Yes. 6.4 µg/day 24 µg/day (ingestion)
(ingestion) 49 µg/day
13 µg/day (inhalation)
(inhalation)
Canada inventory : This material is listed or exempted.
International regulations
International lists : Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: This material is listed or exempted.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): Not determined.
Chemical Weapons : Not listed
Convention List Schedule
I Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals
Canada
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 12/14
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Benzene
Flammability 3
Physical hazards 0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
3 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
History
Date of printing : 4/26/2015.
Date of issue/Date of : 4/26/2015.
revision
Date of previous issue : 10/16/2014.
Version : 0.03
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 13/14
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Benzene
Date of issue/Date of revision : 4/26/2015. Date of previous issue : 10/16/2014. Version : 0.03 14/14
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