Flixborough Disaster

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Risk and Safety Management in Process

Industries

Assignment 1
Error Analysis of the Flixborough Disaster

Submitted by:
Harshal Sawant
08CH14
3 yr-6th sem
rd

B.Tech Chemical Engineering


Date: 24/01/2010
Flixborough Disaster

Facility: Flixborough (near Scunthorpe), Humberside (now North


Lincolnshire), England, UK

Date: 1 June 1974

Consequences: 28 fatalities and 36 injured. Offsite consequences resulted in 53


reported injuries.

Background: The chemical plant, owned by Nypro UK (a joint venture between Dutch
State Mines and the British National Coal Board) and in operation since
1967, produced caprolactam, a precursor chemical used in the
manufacture of nylon. Residents of the village of Flixborough were not
happy to have such a large industrial development so close to their
homes and had expressed concern when the plant was first proposed.

Description of The cyclohexane plant consisted of a train of six reactors in series


Modification: connected througn short 28-in.-diameter connecting pipes. To allow for
expansion, each 28-in. pipe contained a bellows (expansion joint). The
plant was used to produce a mixture
of cyclohexanol and cyclohexanone. On 27 March 1974, it was
discovered that a vertical crack in reactor No.5 was leaking cyclohexane.
The plant was subsequently shut down for an investigation which
identified a serious problem with the reactor. The decision was taken to
remove it and install a bypass assembly to connect reactors No.4 and
No.6 so that the plant could continue production.
The bypass was a temporary 20-in. pipe, which had two bends
in it, to allow for the difference in height. The existing bellows were
left in position at both ends of the temporary pipe .

The bypass had been designed by engineers who were not experienced
in high-pressure pipework, no plans or calculations had been produced,
the pipe was not pressure-tested, and was mounted on
temporary scaffolding poles that allowed the pipe to twist under
pressure. The by-pass pipe was a smaller diameter (20") than the
reactor flanges (24") and in order to align the flanges, short sections of
steel bellows were added at each end of the by-pass - under pressure
such bellows tend to squirm or twist. The pipe was not properly
supported; it merely rested on scaffolding. Because there was a bellows
at each end, it was free to rotate or "squirm" and did so when the
pressure rose a little above the normal level. This caused the bellows to
fail. No professionally qualified engineer was in the plant at the time the
temporary pipe was built. But in addition, the engineers at Flixborough
did not know that design by experts was necessary.

Description At 16:53 on Saturday 1 June 1974, the temporary bypass pipe


of Accident: (containing cyclohexane at 150°C (302°F) and1 MPa (10 bar)) ruptured,
possibly as a result of a fire on a nearby 8 inch (20 cm) pipe which had
been burning for nearly an hour. Within a minute, about 40 tonnes of
the plant's 400 tonne store of cyclohexane leaked from the pipe and
formed a vapour cloud 100–200 metres (320–650 feet) in diameter. The
cloud, on coming in contact with an ignition source (probably a furnace
at a nearby hydrogen production plant) exploded, completely destroying
the plant. Around 1,800 buildings within a mile radius of the site were
damaged.
The fuel-air explosion was estimated to be equivalent to 15 tonnes
of TNT (60 gigajoules) and it killed all 18 employees in the
nearby control room. Nine other site workers were killed, and a delivery
driver died of a heart attack in his cab. Resulting fires raged in the area
for over 10 days.

Key Lessons Plant modification


Learnt:
A plant modification occurred without a full assessment of the potential
consequences. Only limited calculations were undertaken on the
integrity of the bypass line. No calculations were undertaken for the
dog-legged shaped line or for the bellows. No drawing of the proposed
modification was produced. No HAZOP(A hazard and operability study)
was carried out.

Maintenance procedures

No pressure testing was carried out on the installed pipework


modification. Could make use of flexible pipes

Plant layout

Those concerned with the design, construction and layout of the plant
did not consider the potential for a major disaster happening
instantaneously.
Control room design

Control rooms should be designed to withstand major hazards events.


18 fatalities occurred in the control room.

Operating procedures

The incident happened during start up when critical decisions were


made under operational stress. In particular, the shortage of nitrogen
for inerting would tend to inhibit the venting of off-gas as a method of
pressure control/reduction.

Limit inventory in plant

The large inventory of flammable material in the plant contributed to the


scale of the disaster. Limiting inventory is part of the inherently safer
design principle.

References: What went wrong: Case history of process plant disasters–Trevor Kletz

The Flixborough Disaster: Report of the Court of Inquiry

Frank P Lees: vol3. Loss Prevention in Industries

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