Methane MSDS

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Methane/LNG SYNONYMS

Carburetted hydrogen
Appearance Colourless Firedamp
Hydrogen bicarbide
Odour Very faint, nearly odourless Liquefied natural gas
LNG
UN Number 1972/1971 Marsh-gas
Methyl hydride
MFAG Table 620 MTH

The Main Hazard


FLAMMABLE

STOP GAS SUPPLY. Do not extinguish flame until gas or liquid supply has been shut off, to avoid
possibility of explosive re-ignition. Extinguish with dry powder, halon or carbon dioxide. Cool tanks and
surrounding areas with water spray.

DO NOT DELAY. Flood eye gently with clean fresh water. Force eye open if necessary Do not rub
affected area. Continue washing for at least 15 minutes. Obtain medical advice or assistance as soon as
possible.

DO NOT DELAY. Remove contaminated clothing Flood affected area with water. Handle patient gently.
Do not rub affected area. lmmerse frost-bitten area in warm water until thawed. Obtain medical advice
or assistance as soon as possible.

REMOVE VICTIM TO FRESH AlR. Remove contaminated clothing. lf breathing has_stopped or is weak or
irregular, give mouth to mouth/nose resuscitation or oxygen, as necessary. Obtaih medical advice or
assistance as soon as possible.

STOP THE FLOW. Avoid contact with liquid or vapour. Extinguish sources of ignition. Flood with large
amounts of water to disperse the spill, and to prevent brittle fracture. lnform port authorities or
coastguard of spill.

ON EYES Tissue damage due to frost-bite. PerSOnal prOteCtiOn


Protectiveclothingcoveringallpartsofthebody,
BY SKIN ABSORPTION Not absorbed through skin. Jgainsi cold te-mfeirature attack.
*
industrial use.
-qloves,boats,gogglesorfaceshield,allinsulated
ON EYES No hazard in normal industrial use. May
be tissue damage due.to frost-bite.

ON SKIN No hazard in normal industrial use. May


be tissue damage due to frost-bite.

WHEN INHALED
Acute effect
Vapour has narcotic effect. Because of very rapid
evaporation rate, there is possibility of total air
replacement and danger of asphyxiation.
Chronic effect
No chronic effect known.

ICS TANKER SAFETY GUIDE (LIQUEFIED GAS) DATA SHEEl'


Methane/LNG

Flashpoint -175'C approx. Explosion Hazards


Vapour can form a flammable
Auto-ignition Temperature mixture with air which, if ignited,
may release explosive force causing
structural damage.
Flammable Limits
5-160/0 by volume.

Chemical Family Hydrocarbon.

Water, fresh or salt No dangerous Other liquids or gases


reaction; may freeze to form ice or Dangerous reaction possible with
hydrates. chlorine.

Air No reaction.

Boiling Point at Coefficient of Cubic Expansion Enthalpy (KllKg)


Atmospheric Pressure -161"C. 0.0026 per t at -165'C Liquid 29.3 al-165"C 285.5 at -100"C
Vapour 545.1 at -165'C 588.3 at -100"C.
Vapour Pressure Bar (A) Freezing Point -182"C.
See graph in Figure A1.2. Latent Heat of Vaporisation
Relative Vapour Density (KrlKg)
Specific Gravity See graph in 0.55. See graph in Figure A1.2
Figure A1.2.
Molecular Weight Electrostatic Generation
16.04K9/Kmole.

Normal Carriage Condition Control of Vapour within Vapour Detection


Fully refrigerated. Cargo Tank Flammable.
Fully inerted with zero oxygen
Ship Type 2G. content. Gauging Closed or indirect.

lndependent Tank required No.

Unsuitable Mild steel. Suitable Stainless steel, aluminium, copper, 9o/o or 36


nickel steel.

Notes and special requirements


1 Liquefied natural gas is a hydrocarbon
mixture, mainlV of methane but with
small quantitiei of ethane, propane,
butane and nitroqen. Always obtain
shipper's advice, and refer to relevant
data sheet for hazards of a specific
mixture.

126 ICS TANKER SAFETY CUIDE (LIQUEFIED GAS) DATA SHEET

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