Final 100 Question by SY Sir
Final 100 Question by SY Sir
Final 100 Question by SY Sir
www.etoosindia.com
Plot No. 46, In front of Skyline Apartments, Corner Building,
Rajeev Gandhi Nagar, Kota, (Rajasthan) Pin code : 324005.
Help Desk : 09214233303 | 09214233343 |
2 Physics
Chemistry
GOC
1. Compound which is unstable at roo temperature
O
(A) + (B) (C) O (D)
N N
H H
2. Molecule among the following can not show resonance :
(A) CO2 (B) H2C = C = CH2 (C) N3H (D) CH2N2
3. The correct order of C–N bond length order is
NH2 NH2 NH
NH2 + 2
+ + +
(C) > > > (Resonance energy order)
+
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 3
Detol + (B)
8. aq NaOH
(A)
solution
salt
Compound (A) is :
(A) (A) is Salt of Chloroxylenol (B) (B) is Salt of Chloroxylenol
(C) (A) is Salt of Terpineol (D) (B) is Salt of Terpineol
OH
(B) O2N NO2 (Q) React with NaOH
NO2
OH
HO O
HO O
Passage for Q. 11 and 12
The concept of resonance explain various properties of compounds. The molecules with conjugated systems of
bonds are stabilised by resonance and have low heat of hydrogenation. Hyper conjugative stabilisation also decreases
heat of hydrogenation. In aromatic rings a functional group with a lone pair exerts +M effect.
11. The correct order of heat of hydrogenation -
(p) 1,3-pentadiene (q) 1,3-butadiene
(r) 2, 3-dimethyl-1,3-butadiene (s) propadiene
(A) p > q > r > s (B) s > q > p > r (C) q > s > p > r (D) s > p > q > r
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
4 Physics
Chemistry
12. In which option among following I canonical structure is more stable than II-
(A)
N
..
N
I II
O O
(B)
N N
H H
I II
(C)
CH2
CH2
I II
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 5
ISOMERISM
13. Identify ‘R’ and ‘S’ configurations of chiral centres in the following compound and select correct option.
(1) (1R) , (2S) (2) (1R) , (2R) (3) (1S) , (2R) (4) (1S) , (2S)
14. Identify compound having highest heat of combustion :
17.
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
6 Physics
Chemistry
18. Which of the following order is incorrectly matched with given properties.
20. Select the pair among following not representing position isomerism:
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 7
21. The compound among following can not show geometrical isomerism:
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
8 Physics
Chemistry
HALOGEN DERIVATIVES
25. Degree of unsaturation of compound ‘C’ and F is/are ‘P’ and ‘Q’ then what would be value of Q–P ?
H2SO4 NBS AgF/DMSO
CH2 – OH
A B C
HBr
Mg/ether B
D E (SN 2 reaction)
F
26. Which one of the following compounds will give enantiomeric pair on treatment with HOH?
C2 H 5 CH 3 H C2 H5
| | | |
(A) C 6 H 5 C I (B) CH C Br (C) C H C Br (D) C 2 H 5 C Br
3 6 5
| | | |
C 2H5 C2 H5 D CH 3
27. In the given reaction
CH 3 CH CH 2 CH 2 CH CH 3
| |
OTs OTs
[X]
[X] will be:
OTs S
| | S S
(A) CH 3 CH CH 2 CH 2 CH CH 3 (B)
CH3 CH CH2 CH2 CH CH3
(C) (D)
Me SOCl2
Et2O P
28. HO D
SOCl2
Q
H
N
P and Q are respectively
Me Me Me Me
(A) D Cl Cl D (B)
Cl D D Cl
H H H H
Me Me Me Me
H H
(C) Cl D Cl (D) D Cl Cl
H D H D
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 9
CH3
18 PCl3 aq.Na O Me
29. H R
OH
D
R is
CH3 CH3
18
(A) H O–CH3 (B) H3CO D
D H
CH3 CH3
18
(C) H3CO H (D) H O–CH3
D D
30. Select the incorrect statement about the product mixture in the following reaction :
Br
2 Products
CCl 4
(A) it is optically active (B) it is racemic mixture
(C) it is a resolvable mixture (D) it is a mixture of erythro compounds
31.
OH– Major product.
NMe3
CH3
Cl
32. alc I
.KOH
Br
H
Major products of above reaction are
I I Cl Cl
Cl Cl I I
CH3 CH3
(C) Cl + en (D) I + en
I Cl
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
10 Physics
Chemistry
33. In which of the following case configuration about chiral (C) is retained:
Na CH Br SOCl CH ONa
(A) 3 (B) 2 3
1.TsCl
(C) PCl3
CH 3ONa
(D) H 2
.MeONa
D
34. Which of following reaction products are diastereomer to each other ?
Me
Br2
(A) CH3
(B) D H HBr
CCl 4
Ph
(C) HBr
(D) CH 3 CH CH CH Ph
HCl
CCl4 peroxide
|
35.
Et
Total number of achiral dibromo product possible when S-2-bromobutane is treated with Br /h in 1: 1 ratio.
2
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 11
ALCOHOL & ETHER
H OHBr HCHO
B Mg
/
ether
36. CH3MgBr + 3
A C D
HI E
H O 3
E is
I II
38. P
O OH
P can be
(A) (i) LAH (ii) H2O (B) NaBH4/ EtOH
(C) (i) BH3.THF (ii) CH3COOH (D) All of these
39. In the following reaction, final product is
14
ClCH 2CH C H 2 NaOC H
25
\ /
O
14 14
(A) ClCH 2 CH C H 2 OC 2 H 5 (B) ClCH 2CH C H 2 ONa
| |
OH OC 2 H 5
14 14
(C) C H 2 CHCH 2 OC 2 H 5 (D) C H 2 CHCH 2 OC 2 H 5
O O
18
( i ) H 3C C O OH
||
O
40.
Product(s)
( ii ) OH ¯/ H 2O
18
OH OH OH
41. dil
.alk
.KMnO
4 Product(s)
Product(s) is / are
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
12 Physics
Chemistry
CH3 CH3
(A) OH (B) OH + en
OH H
H OH
CH3
CH3
OH
(C) H (D) H + en
OH
H
H
H / H O
2
42. J (Major)
J is
OH
OH OH OH
(A) (B) (C) (D)
Et Et O
|| 18
( i ) CH3 C O O H
43.
( ii ) H / H 2 O
D D
Major product(s) of the above reaction is :
Et 18 Et
D OH D OH
(A) + en (B)
18
+ en
HO D D OH
Et Et
Et Et
D OH D OH
+ en
(C) D OH (D)
HO D
Et Et
Cerric ammonium nitrate
Red colour
I2/OH¯
44. P Yellow ppt.
C3H8O
NaHCO 3
CO2
What is structure of P.
O OH
(A) OH (B) O (C) (D)
(A) NaBH
4 (B) NaBH
4
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 13
(C) LiAlH
4 (D) LiAlH
4
18
46. Ph O Et HI
(excess
) Products.
Products are
18
(A) Ph – I + EtI (B) Ph – OH + EtI (C) Ph O H EtI (D) None of these
H / H O
2
(A) (P) OH
(i) Hg (OAc) 2 / H 2 O
(B) (Q) OH
(ii) NaBH 4 / OH
OH
( i ) BH / THF
(C) 3 (R)
( ii ) H 2O 2 / OH
OH
(S)
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
14 Physics
Chemistry
CARBONYL COMPOUND AND CARBOXYLIC ACID
– –
OH OH H
48. PhCOCHBr2 A B
C
The compound 'C' is
(A) PhCH(OH)CHO (B) PhCH(OH)COOH
(C) PhCOC Br2 (D) None of these
|
H
49. What will be the product of the following reaction
RCO H
Ph(Me)CHCOMe 3 ?
CH2OH
O H
CH OH HIO
50. OH 3
X
4
Y+Z
dry HCl
OH OH
OH
The product Y is :
CH2OH
O H O OH
OH H3 O
51. CH3 COCHO P Q
H SO
2Q 2
4
R
The product R is :
O
C O
O C
O
O
O OH
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 15
o
OH CH3MgBr Zn– Hg
52. A B C
heat Conc.HCl
Br
(C) PhCH2 CH(Br) COOH (D) PhCH = CH – COBr
54. Among the following which one will show significant hydration ?
(I) CCl3CHO (II) (CH3)3CCO(CH3)3
(A) I and III (B) II and III (C) III and IV (D) I and II
CHO
HCHO (excess),
NaOH (aqueous)
C
O CH3
CH2OH CH2OH
CHO
COONa
C
C
O C(CH2OH)3
O C(CH2OH)3
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
16 Physics
Chemistry
56. The possible number of stereoisomers of the product of following reaction would be :
NH2OH
CH3 – CH = CH – CH – CHO
|
CH3
(A) 2 (B) 4 (C) 6 (D) 8
57. The final product (C) of the following reactions would be
NH OH HCl . Br / Fe PCl
2 (A) (B) 2 (C)
5
C 6 H 5 C C 6H 5
|| (1) ( 2) (3 )
O
(A) Br C Cl (B) C NH
|| ||
N O
OH Br
(C) C NH Br (D)
||
O
O
|| O
O COOH HO CH2OH
(B) C–OC2H5
O
O
O
|| O O CH2OH
(C) O CH2OH
C–OC2H5
O O
O HO CH2OH HO COOH
(D) CH2OH
O
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 17
60. The correct sequence of reagents for the following conversion is
CH N
2 2 2 SOCl
(i) / Ag Ag 2O SOCl2 CH2N2
(C)
HO
(D)
H 2O
(ii) 2 /H
O
O
AlCl3
61. X+Y
X, Y both responds to FeCl3 test and 2, 4 DNP test. One is thermodynamically controlled product
(TCP) and another is kinetically controlled product (KCP). KCP is
OH OH OH
COR
(A) (B) (C) (D) All of these
COR
COR
62. The following conversion is possible by
Ph – CH2 – CH = O Ph – CH 2 – CH – COOH
|
NH2
(Phenyl alanine)
KCN / H O 3 NH , H O ,
2 3
(A)
KCN / NH Cl H O ,
(B) 4
3
HCN / NaOH 2 NH3 SOCl H O ,
(C) 3
Br / CH COOH 3 NH CrO / H
(D) 2
3 3
63. Match the column
Column I Column II
OH
(A) MeCO(CH2)4COMe
(p)
OEt
(B) (CH2)4 (q)
(C) PhCHO + 3
CH COO –
(r) (Ph)2 C — COO –
|
OH
OH
(D) PhCOCOPh (s)
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
18 Physics
Chemistry
AMINES
64. Hydrolysis of alkyl isocyanide yields:
(A) Primary amine (B) Tert. amine (C) Alcohol (D) Aldehyde
65. The compound obtained by the reaction between primary amine and aldehyde is:
(A) An amide (B) Imine (C) Nitrite (D) Nitro
Me2 NH
66. Major product is:
NO2
NMe2 Me F NHMe
NMe2
(A) (B) (C) (D)
CH 3
| HNO
67. CH 3 CH — C — CH 2 NH 2 2 (X) (major)
| |
CH 3 CH 3
Major product of above reaction is
CH3
CH3
(A) CH C CH2 OH (B)
CH3
CH3 OH
(C) (D)
OH OH
68. Identify X in the reaction
NH2
Cl COOH Cl Cl
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 19
69. In given reaction sequence.
O
HCl
HCN
(X) LiAlH
4 (Y) NaNO
2 (Z) then
Me
Compound (Z) is:
O O
Correct statement is :
(A) Compound (D) will give phenyl hydrazone with carbonyl compound.
(B) Compound (E) formed is benzoylchloride
(C) Compound (C) formed will give carbylamine test.
(D) Compound (A) & Compound (E) are identical
71. In the reaction shown below, the major product(s) formed is/are
acetic
anhydride
CH Cl
Product
2 2
H
N CH3
O + CH3COOH
(A) (B)
NH2
O
H
N CH3 NH3CH3COO
O + H2O
(C)
H (D)
H
N CH3 N CH3
O O O O
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
20 Physics
Chemistry
72. In the given reaction sequence:
( i ) KMnO / O H / ( i ) SOCl Br / KOH
(A) 2 (B) 2 (C)
CH3–CH2–OH 4
(ii ) H ( ii ) NH 3 /
(C) will be :
(A) Methylamine (B) Ethylamine (C) Propylamine (D) Acetamide
Me
(i) H /HN
3
Et COOH + (A)
(ii) H3O
(P)
73. H
NH/3 Br/NaOH
2
(B) (C)
Choose the correct statements :-
(A) Products (A) and (C) are identical
(B) Products (A) and (C) have different configuration
(C) Product (A) and (C) are enantiomers
(D) (C) can give compound having unpleasant smell on reaction with CHCl3/OH¯
PARAGRAPH (74-76)
NO2
Sn / HCl
(X) NaNO
2
0 C
/ HCl
(Z) H
(Y) CuCN / HCN / H 2O
(W)
–
Cl N2Cl NH2 CN
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 21
77. Number of reactions which can produce 1° amine are :
(I) R – C – NH2 OH / Br
2
O
O
(i) OH–
(II) N – H (ii) R–I
–
(iii) OH/H2O
O
NH
(III) CH3 2 H / H O
O
(IV) N+ C +
H /H2O
NH–Et H/ H2O
+
(V)
O
N3H/conc. H2SO4
(VI)
COOH
(VII) C N +
H/ H2O
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
22 Physics
Chemistry
O
O OH
(A) C–CH3 (B)
C–CH3
O
O OH
CH3 H3C
(C) (D)
CH2OH O
Br KMnO
79. A 2 4 B
OH O
||
CH 3 C Cl
82. (
i ) OH
P
(ii ) CO 2
(iii ) H
P is a drug, it is
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 23
O
OH O – C – CH3
O
C – CH3 OH
(A) (B)
COOCH3 COOH
(i ) O
83. Na
/NH3
3 NaOH /
CaO
J
( ii ) H O / H O
EtOH 2 2 2
J is
F
Cl NO2
NaOMe /
84. X , X is
NO2
F OMe Cl OMe
MeO NO2 F NO2 MeO NO2 Cl NO2
85. The correct order of electrophilic aromatic substitution among the following:
O
CH3 O–C–CH3 OH NH2
86. CH2 NO
2BF
4¯
O2N
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
24 Physics
Chemistry
What is / are the product(s) in the reaction?
NO2
NO2
CH2 CH2
(A) (B)
O2N O2N
CH2 NO2
(C) (D) Both (B) and (C)
O 2N
87. Which of the following reaction(s) can produce aromatic hydrocarbon?
OH
SO3H MgBr
(C) H/
H 2O
(D) H
2O
CH3
NH2
88. conc
.H N O
3 Product
H 2S O 4
AlCl (i) O /
89.
Cl CH 2CH 2 CH 3 3 P
2
Q Phenol
( ii ) H 3O
The major products P and Q are
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 25
Paragraph for Question Nos. 90 to 92
Riemer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl
group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of
substituted salicylaldeydes as depicted below.
90. Which one of the following reagents is used in the above reaction?
(A) aq. NaOH + CH3Cl (B) aq. NaOH + CH2Cl2
(C) aq. NaOH + CHCl3 (D) aq.NaOH + CCl4
91. The electrophile in this reaction is
CH Cl
3
AlCl 3 ,
(A) (B)
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
26 Physics
Chemistry
Biomolecules, Polymer and Chemistry in Every Day Life
95. Which amino acid among following can not synthesised by Gabriel's pnthalimide synthesis method ?
(A) Glycine (B) Alanine (C) Proline (D) Phenylalaline
96. The non-essential amino acid among following is :
(A) Valine (B) Histidine (C) Proline (D) Leucine
98.
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 27
HC N NH Ph
C N NH Ph
HO H
104. H OH The given osazone can be obtained by :
H OH
CH2OH
Cl Cl
Cl
(C) Cl C – CH2 Cl (D) H3C CH Cl
Cl CCl3
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
28 Physics
Chemistry
117. The correct strutcure of Aspirin is :
OCOCH3 COCH3
(A) (B)
COOH COOH
OCOCH3
COCH3
(C) (D)
HOOC
OH
118. Peptide linkage is -
O O O O
(A) –C – O – (B) –C – NH2 (C) –C – NH– (D) –C – NH–NH2
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005
MSSir
SY Sir 29
ANSWER KEY
1. D 2. B 3. B 4. D 5. A 6. CD 7. ABD
8. A 9. BD 10. (A)P,Q,R,S ; (B)P,Q,R,S ; (C)P,Q,S ; (D)P,Q,R,S 11. B
12. C 13. C 14. B 15. A 16. B 17. A 18. BCD
19. ACD 20. ACD 21. BCD 22. 9 23. 24
24. AP ; BR ; CS ; DQ 25. 1 26. C 27. C 28. B
29. A 30. A 31. A 32. C 33. AC 34. ABD 35. 2
36. D 37. C 38. D 39. D 40. D 41. A 42. B
43. B 44. D 45. AC 46. C 47. (A) Q (B) R (C) S 48. B
49. A 50. C 51. B 52. C 53. B 54. A 55. B
56. D 57. C 58. C 59. D 60. B 61. B
62. ABC 63. (A - q; B - p; C - s; D - r) 64. A 65. B 66. A 67. C
68. D 69. B 70. D 71. A 72. A 73. AD 74. B
75. A 76. B 77. 6 78. B 79. D 80. B 81. B
82. D 83. B 84. D 85. B 86. D 87. ABCD 88. AC
89. C 90. C 91. C 92. B 93. D 94. A 95. C
96. C 97. C 98. C 99. A 100. C 101. B 102. D
103. A 104. D 105. C 106. C 107. B 108. C 109. A
110. B 111. A 112. A 113. A 114. D 115. A 116. A
117. A 118. C
Head Office :- Plot No. 46, In front of Skyline Apartments, Corner Building, Rajeev Gandhi nagar, Kota (Raj.) Pin code : 324005