MATERIAL SAFETY DATA SHEET

Demulsifier 334
CL-334-L/2017 - Effective Date: 21/5/17

1. Identification Of The Substance And The Company/Undertaking

Product name : Demulsifier 334
Use of the product : Emulsion Break oil-water
Supplier/Manufacturer : PT. Liquitech Indonesia
Gd Arva Lt 5, Jl RP Soeroso No 40 Jakarta Indonesia 10350
E-mail: admin@liquitech-indonesia.com
Emergency telephone number : +62 21 315 6119

2. Hazards Identification
Classified as Dangerous Goods according to Indonesian Government Regulation PP No 4 2001
and its amendments,

Classification : Hazardous
See section 11 for more detailed information on health effects and symptoms.

3. Composition/Information on Ingredients
Product definition : Mixture
Proprietary compound with carbonate and chloride
See section 11 for more detailed information on health effects and symptoms.

4. First Aid Measure

Inhalation : Remove victim from area of exposure - avoid becoming a
casualty. Remove contaminated clothing and loosen remaining
clothing. Allow patient to assume most comfortable position and
keep warm. Keep at rest until fully recovered. For all but the most
minor symptoms arrange for patient to be seen by a doctor as
soon as possible, either on site or at the nearest hospital.
Skin Contact : If spilt on large areas of skin or hair, immediately drench with
running water and remove clothing. Continue to wash skin and
hair with plenty of water (and soap if material is insoluble) until
advised to stop by the Poisons Information Centre or a doctor.
Eye Contact : If in eyes, hold eyelids apart and flush the eye continuously with
running water. Continue flushing until advised to stop by a
Poisons Information Centre or a doctor, or for at least 15
minutes.

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 Ingestion : Immediately rinse mouth with water. If swallowed, do NOT induce
vomiting. Give a glass of water. Seek immediate medical
assistance.

Indication of immediate medical attention and special treatment needed:

Treat symptomatically. Can cause corneal burns.

5. Fire Fighting Measures

Suitable Extinguishing Media:Not combustible, however, if material is involved in a fire use:
Fine water spray, normal foam, dry agent (carbon dioxide, dry
chemical powder).

Specific hazards arising from the substance or mixture:

Non-combustible material.

Special protective equipment and precautions for fire-fighters:

Not combustible, however following evaporation of aqueous component residual material can
decompose if involved in a fire, emitting toxic fumes. Contact with metals may liberate hydrogen
gas which is extremely flammable. Fire fighters to wear self-contained breathing apparatus and
suitable protective clothing if risk of exposure to products of decomposition.

6. Accidental Release Measures

Emergency procedures/Environmental precautions:
Clear area of all unprotected personnel. If contamination of sewers or waterways has occurred
advise local emergency services.

Personal precautions/Protective equipment/Methods and materials for containment and

cleaning up:
Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent
skin and eye contact and breathing in vapours. Work up wind or increase ventilation. Contain -
prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material).
Collect and seal in properly labelled containers or drums for disposal. Caution - heat may be
evolved on contact with water.

7. Handling and Storage

This material is must be stored, maintained and used in accordance with the relevant regulations.

Precautions for safe handling:

Avoid skin and eye contact and breathing in vapor, mists and aerosols.

Conditions for safe storage, including any incompatibilities:

Store in cool place and out of direct sunlight. Store away from incompatible materials described in
Section 10. Store away from foodstuffs. Do not store in aluminium or galvanised containers nor
use die-cast zinc or aluminium bungs; plastic bungs should be used. At temperatures greater
than 40°C, tanks must be stress relieved. Keep containers closed when not in use - check
regularly for leaks.

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 8. Exposure Controls/Personal Protection
Control Parameters: No value assigned for this specific material. However, Workplace
Exposure Standard(s) for constituent(s):

Peak Limitation = 2 mg/m3

Peak Limitation - a maximum or peak airborne concentration of a particular substance

determined over the shortest analytically practicable period of time which does not exceed 15
minutes.

These Workplace Exposure Standards are guides to be used in the control of occupational health
hazards. All atmospheric contamination should be kept to as low a level as is workable. These
workplace exposure standards should not be used as fine dividing lines between safe and
dangerous concentrations of chemicals. They are not a measure of relative toxicity.

Appropriate engineering controls:

Ensure ventilation is adequate to maintain air concentrations below Workplace Exposure
Standards. Keep containers closed when not in use.

If in the handling and application of this material, safe exposure levels could be exceeded, the
use of engineering controls such as local exhaust ventilation must be considered and the results
documented. If achieving safe exposure levels does not require engineering controls, then a
detailed and documented risk assessment using the relevant Personal Protective Equipment
(PPE) (refer to PPE section below) as a basis must be carried out to determine the minimum PPE
requirements.

Individual protection measures, such as Personal Protective Equipment (PPE):

The selection of PPE is dependent on a detailed risk assessment. The risk assessment should
consider the work situation, the physical form of the chemical, the handling methods, and
environmental factors.
COVERALLS, CHEMICAL GOGGLES, FACE SHIELD, GLOVES (Long), APRON, RUBBER
BOOTS.

Wear overalls, chemical goggles, face shield, elbow-length impervious gloves, splash apron or
equivalent chemical impervious outer garment, and rubber boots. Always wash hands before
smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storage or re-use. If determined by a risk assessment an inhalation risk exists,
wear a suitable mist respirator meeting the standard requirements.

9. Physical And Chemical Properties

Physical state : Liquid
Colour : Colourless to Slightly Coloured
Solubility : Miscible with water.
Specific Gravity : 1.48-1.52 @20°C
Relative Vapour Density (air=1) : Not available
Vapour Pressure (20 °C) : 1.34 mm Hg (literature)

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 Flash Point (°C) : Not applicable
Flammability Limits (%) : Not applicable
Autoignition Temperature (°C) : Not applicable
Boiling Point/Range (°C) : 145 (literature)
pH : 14 (literature)
Freezing Point/Range (°C) : 12 (literature)

10. Stability and Reactivity

Reactivity : Reacts violently with acids. Reacts exothermically on
dilution with water.
Chemical stability : Stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure. Absorbs
carbon dioxide from the air.
Possibility of hazardous reactions : Reacts with ammonium salts, evolving ammonia gas.
Reacts readily with various reducing sugars (i.e. fructose,
galactose, maltose, dry whey solids) to produce carbon
monoxide. Take precautions including monitoring the tank
atmosphere for carbon monoxide to ensure safety of
personnel before vessel entry.
Conditions to avoid : Avoid exposure to moisture.
Incompatible materials : Incompatible with ammonium salts, tin, and zinc.
Hazardous decomposition products: None known.

11. Toxicological Information

No adverse health effects expected if the product is handled in accordance with this Safety Data
Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and
overexposure occurs are:
Ingestion : Swallowing can result in nausea, vomiting, diarrhoea,
abdominal pain and chemical burns to the gastrointestinal
tract.
Eye contact : A severe eye irritant. Corrosive to eyes; contact can cause
corneal burns. Contamination of eyes can result in
permanent injury.
Skin contact : Contact with skin will result in severe irritation. Corrosive to
skin - may cause skin burns.
Inhalation : Breathing in mists or aerosols may produce respiratory
irritation.
Acute toxicity : No LD50 data available for the product.
Skin corrosion/irritation : Severe irritant (rabbit).
Chronic effects : No information available for the product

12. Ecological Information

Avoid contaminating waterways.

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 13. Disposal Considerations
Disposal methods: Should be neutralized before disposal.
Refer to Waste Management Authority for standard quality of disposal. Dispose of
contents/container in accordance with local/regional/national/international regulations.

14. Transport Information

Classified as Dangerous Goods.

Transport Hazard Class: 8 Corrosive

Packing Group: II

15. Regulatory Information

Classification:
This material is hazardous according to to Indonesian Government Regulation PP No 4 2001;
HAZARDOUS SUBSTANCE.

Classification of the substance or mixture:

Corrosive to Metals
Skin Corrosion
Eye Damage

16. Other Information

Used and restriction : This product is intended for use only in produced water treatment plant. See
product/Technical report for recommended use.

Disclaimer:
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PT. Liquitech Indonesia provides the information contained herein in good faith but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a
guide to the appropriate precautionary handling of the material by a properly trained person using
this product. Individuals receiving the information must exercise their independent judgment in
determining its appropriateness for a particular purpose.
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