SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH)

Date 25.01.18
Version 1 Issue date: 25.01.18 Page 1 / 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name 4601A64155A10

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Coating agent

1.3 Details of the supplier of the safety data sheet

IGP Pulvertechnik AG
Ringstrasse 30
CH-9500 Wil
+41 71 929 81 11
+41 71 929 81 81

Only Representative IGP Pulvertechnik GesmbH

Alois Lutter-Strasse 33
A - 2514 Traiskirchen
Tel. +43 (0)2252 508046

Regional representative IGP Pulvertechnik Deutschland GmbH IGP Benelux BV

Alte Regensburger Str. 14 Rietveldstraat 18
D - 84030 Ergolding NL - 8013 RW Zwolle
Tel. +49 (0)871 966 77 0 Tel. +31 38 4600695

IGP Pulvertechnik SAS IGP Hungary Kft.

362 avenue Marie Curie Berscényi M.u.14
F - 74166 St Julien en Genevois H - 6000 Kecskemét
Cedex Tel. +36 76 507 974
Tel. +33 (0)4 50 95 35 10

IGP Pulvertechnik Polska Sp. z o.o. IGP Scandinavia AB

ul. Zelechowska 2 b Drottensgatan 2
PL - 96-321 Siestrzen S - 222 23 Lund
Tel. +48 (0)22 724 94 49 Tel. +46 46 120 220

IGP Pulvertechnik GesmbH IGP UK

Alois Lutter-Strasse 33 10 North Rd, Yate
A - 2514 Traiskirchen GB - BS37 7PA Bristol
Tel. +43 (0)2252 508046 Tel. +44 (0)1454 800 020

IGP North America LLC

615 South DuPont Highway
USA - DE 19901 Dover
Tel. +1 502.939.5606

Dept. responsible for msds@igp.ch

information

1.4 Emergency telephone number

Emergency information Tox Info Suisse
Switzerland
145; 24h - Notfallnummer oder
Tel. +41 44 251 51 51

Emergency information Emergency Contact

 SAFETY DATA SHEET
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International GBK GmbH

(24-Hour-Number)
Tel. +49 (0) 6132-84463

SECTION 2: Hazards identification

Classification according to EC regulation 1272/2008 (CLP)

2.1 Classification of the substance or mixture

Nature of Hazard GHS07 Exclamation mark
GHS09 Environment

Signal word Warning

Classification Aquatic Chronic 2; H411 Toxic to aquatic life with long lasting effects.
Eye Irrit. 2; H319 Causes serious eye irritation.
Skin Sens. 1; H317 May cause an allergic skin reaction.

2.2 Label elements

Nature of Hazard GHS07 Exclamation mark
GHS09 Environment

Signal word Warning

Hazard statements H319 Causes serious eye irritation.

H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Safety precautions P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P302+P352 IF ON SKIN: Wash with plenty of water/soap.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/container to appropriate disposal of waste.

Special provisions concerning not applicable

the labelling of certain
mixtures

2.3 Other hazards

Information pertaining to Dust can form an explosive mixture with air. The substances in the mixture do
special dangers for human and not meet the PBT/vPvB criteria according to REACH, annex XIII.
environment

SECTION 3: Composition / information on ingredients

3.2 Mixtures

Hazardous ingredients
 SAFETY DATA SHEET
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Date 25.01.18
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Substance 1 Substance 2
Reaction mass of bis(2,3-epoxypropyl) terephthalate and Tetradecyl-trimethylammoniumbromide: <= 0.09 %
tris(oxiranylmethyl) benzene-1,2,4-tricarboxylate: 1 % - CAS-Number: 1119-97-7
2.49 % EINECS / ELINCS / NLP: 214-291-9
EINECS / ELINCS / NLP: 940-592-6
REACH registration No.: 01-2120065788-39-xxxx Classification according to EC regulation 1272/2008 (CLP):
Acute Tox. 4; H302 / Acute Tox. 4; H332 / Aquatic Acute
Classification according to EC regulation 1272/2008 (CLP): 1; H400 / Aquatic Chronic 1; H410 / Eye Dam. 1; H318 /
Acute Tox. 4; H302 / Aquatic Chronic 2; H411 / Eye Dam. STOT SE 3; H335 / Skin Irrit. 2; H315
1; H318 / STOT RE 2; H373 / Skin Irrit. 2; H315 / Skin
Sens. 1; H317

Additional information not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
General information First aider: Pay attention to self-protection! Move victim out of danger zone.
Put victim at rest, cover with a blanket and keep warm. Do not leave affected
person unattended.

In case of inhalation In case of accident by inhalation: remove casualty to fresh air and keep at
rest. If you feel unwell, seek medical advice.

In case of skin contact Thoroughly wash skin with soap and water. Do not use solvents or thinners.
Remove contaminated clothing.

After eye contact If product gets into the eye, keep eyelid open and rinse immediately with large
quantities of water, for at least 10 minutes. Remove contact lenses, if any. In
case of troubles or persistent symptoms, consult an opthalmologist.

After swallowing Have victim repeatedly drink large amounts of water with activated charcoal. Do
not induce vomiting. No administration in cases of unconsiousness or cramps.
Rinse mouth immediately and drink plenty of water. Observe risk of aspiration if
vomiting occurs. Get medical advice/attention.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms No known symptoms to date.

4.3 Indication of any immediate medical attention and special treatment needed
Information to physician No known symptoms to date.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media In case of fire: Use water spray, dry powder, foam or carbon dioxide for
extinction.

Extinguishing media which must Strong water jet and carbon dioxide gases under presussure
not be used for safety
reasons
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5.2 Special hazards arising from the substance or mixture

Special protective equipment Exposure to fire produces thick, black smoke that is hazardous to health. Do not
for firefighters breathe smoke.

5.3 Advice for firefighters

Special exposure hazards Wear self-contained breathing apparatus.
arising from the substance
itself, combustion products,
resulting gases

Additional information Do not allow fire water to penetrate into surface or ground water.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions Wear appropriate protective equipment.

6.2 environmental precautions

Environmental measures Do not empty into drains.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Remove leaked material dry using explosion-proof vacuum cleaner or moistened
with a broom and collect it for disposal in appropriate containers in accordance
with the local regulations (see section 13). Dispose of waste according to
applicable legislation.

6.4 Reference to other sections

Additional information refer to section 13

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advices on safe handling When using do not eat, drink or smoke. Wear personal protection equipment (refer
to section 8). Avoid dust formation. Provide adequate ventilation, and local
exhaust as needed.

Precautions against fire and Take care of general rules for industrial preventive fire protection. Dust can
explosion form an explosive mixture with air.

Dust explosion risk During plant operation, a value of 15 g/m3 must not be exceeded.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storerooms Store at room temperature in a dry and well ventilated area. Protect from heat
and containers and direct sunlight. Always close containers tightly after the removal of
product.

7.3 Specific end use(s)

Specific end use(s) not available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

8.2 Exposure controls

 SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)

Date 25.01.18
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Exposure controls Provide good ventilation and/or an exhaust system in the work area. Occupational
exposure limit values: A: respirable fraction <= 1.25 mg/m3 and <= 10 mg/m3 E:
inhalable fraction

Respiratory protection Wear a dust mask, in case of excessive dust. Respiratory protection must be worn
whenever the WEL levels have been exceeded.

Hand protection Wear suitable gloves. Suitable gloves type: Disposable gloves natural latex or
Nitrile rubber Category 3 according to DIN EN 374 and DIN EN 420. Observe glove
manufacturer's instructions concerning penetrability and breakthrough time. In
case of prolonged or frequently repeated skin contact: Protect skin by using
skin protective cream.

Eye protection In case of dust formation: tightly sealed goggles according to EN 166.

Body protection Wear suitable protective clothing. Avoid contact of neck and wrists with the
powder because of possible skin irritations and dermatitis. Wash thouroughly
after contact with skin areas.

General protection and hygiene When using do not eat, drink or smoke.
measures

SECTION 9: Physical and chemical properties

9.1 information on basic physical and chemical properties
Form solid
Colour substance group relevant properties
Odour odourless
Initial boiling point and not determined
boiling range
Melting point/freezing point > 50 °C
Flash point/flash point range not determined
Ignition temperature 450 °C - 600 +°C
Oxidizing characteristics not determined
Auto-ignition temperature not determined
Lower explosion limit 20 - 90 g/m3
Density 1.2 g/cm3 - 1.9 g/cm3
Density: Temperatures 20 °C
Density: Text calculated
Bulk density 400 Kg/m3 - 1000 Kg/m3
Water solubility Text insoluble
Partition coefficient not determined
n-octanol/water
Solvent content not applicable

9.2 Other information

Other information none

SECTION 10: Stability and reactivity

10.1 Reactivity
Reactivity refer to section 10.3

10.2 Chemical stability

Chemical stability Product is stable under normal storage conditions.
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10.3 Possibility of hazardous reactions

Polymerisation none

10.4 Conditions to avoid

Conditions to avoid none

10.5 Incompatible materials

Materials to avoid none

10.6 Hazardous decomposition products

Hazardous decomposition Hazardous decomposition products such as carbon dioxide, carbon monoxide, fumes,
products nitrogen oxides may develop with exposure to high temperatures.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

General remarks There are no data available on the preparation/mixture itself.

CAS-Number Reaction mass of bis(2,3-epoxypropyl) terephthalate and tris(oxiranylmethyl) benzene-1,2,4-tricarboxylate

Applic. Path Method Species Unit Dosis Text
oral LD50 Rat mg/kg 2000.00000 -
sensitization: OECD 406 guinea pig sensitising 0.00000 -
Skin irritation: OECD 404 Rabbit Not an irritant 0.00000 -
Eye irritation: OECD 405 Rabbit irritant 0.00000 -
Mutagenicity: OECD 471 (Ames test) not required positive 0.00000 -
Mutagenicity: OECD 483 not required negative 0.00000 -
Mutagenicity: OECD 473 not required positive 0.00000 -
dermal LD50 Rat mg/kg > 2000.00000 -
NOEL(C): OECD 407 not required mg/kg bw/day 75.00000 28d
NOAEL(C): OECD 407 not required mg/kg bw/day 75.00000 28d

SECTION 12: Ecological information

12.1 Toxicity

Ecotoxicological effects: There are no data available on the preparation/mixture itself.

components

CAS-Number Reaction mass of bis(2,3-epoxypropyl) terephthalate and tris(oxiranylmethyl) benzene-1,2,4-tricarboxylate

Applic. Path Method Species Unit Dosis Text
Fish toxicity: LC50 fish mg/l 8.80000 OECD 203, 96h
Daphnia toxicity: EC50 Daphnia magna (Big water flea) mg/l 81.00000 OECD 433, 48h
Algae toxicity: EC50 Algae mg/l > 2.72000 OECD 201, 72h
log Koc: not required not required not re 0.65000 -
NOEC not required Algae mg/l 0.36800 OECD 201, 72h

CAS-Number 1119-97-7 Tetradecyl-trimethylammoniumbromide

Applic. Path Method Species Unit Dosis Text
Fish toxicity: LC50 fish mg/l 1.81000 96 h
Daphnia toxicity: EC50 Daphnia magna (Big water flea) mg/l 0.02200 48 h
Algae toxicity: EC50 Algae mg/l 0.00540 72 h

12.2 Persistence and degradability

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Further details refer to section 12.1 or No data available

12.3 Bioaccumulative potential

Bioaccumulative potential refer to section 12.1 or No data available

12.4 Mobility in soil

Mobility refer to section 12.1 or No data available

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB The components in this formulation do not meet the criteria for classification
assessment as PBT or vPvB.

12.6 Other adverse effects

General information There are no data available on the preparation/mixture itself.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Recommendation Avoid release to the environment. Dispose of waste according to applicable
legislation. Handle contaminated packages in the same way as the substance
itself. Waste codes/waste designations according to EWC/AVV

Waste key number 080201

150101
150102
150110*

SECTION 14: Transport information

14.1 UN number
Land transport UN 3077
Sea transport UN 3077
Air transport UN 3077

14.2 UN proper shipping name

Land transport ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ,
Tetradecyl-trimethylammoniumbromide
Sea transport ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ,
Tetradecyl-trimethylammoniumbromide
Air transport ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ,
Tetradecyl-trimethylammoniumbromide

14.3 Transport hazard class(es)

Land transport 9
Sea transport 9
Air transport 9

14.4 Packing group

Land transport III
Sea transport III
Air transport III

14.5 Environmental hazards

Marine Pollutant - IMDG Yes.

14.6 Special precautions for user

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Date 25.01.18
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Land transport
Code: ADR/RID 3
Kemmler-number 90
Hazard label ADR 9
Special provisions for packing MP10
together

Sea transport
EmS F-A,S-F

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Transport in bulk according to not applicable
Annex II of MARPOL 73/78 and
the IBC Code

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Europe
Further regulations, Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Labelling
limitations and legal according to Regulation (EC) No. 1272/2008 [CLP] Classification according to
requirements Regulation (EC) No 1272/2008 [CLP]

Germany
Water Hazard Class 2

Denmark
Further regulations, MAL-Code: 1-5
limitations and legal
requirements

Switzerland
Further regulations, Observe employment restrictions concerning young persons. according to ArGV5, SR
limitations and legal 822.115
requirements

USA
Federal Regulations All ingredients of this product are on the TSCA inventory, or are not required
to be listed on the TSCA inventory.

Canada
Further regulations, All ingredients of this product are listed on the DSL Domestic Substances List,
limitations and legal or are not required to be listed on the DSL Domestic Substances List.
requirements

15.2 Chemical Safety Assessment

Chemical Safety Assessment Chemical safety assessments for substances in this preparation were not carried
out.

SECTION 16: Other information

Hazard statements (CLP) H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
H302 Harmful if swallowed.
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H315 Causes skin irritation.

H318 Causes serious eye damage.
H373 May cause damage to organs (or state all organs affected, if known)
through prolonged or repeated exposure (state route of exposure if it is
conclusively proven that no other routes of exposure cause the hazard).
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Further information The information in this data sheet has been established to our best knowledge
and was up-to-date at time of revision.

Literature For abbreviations and acronyms, see: ECHA Guidance on information requirements
and chemical safety assessment, chapter R.20 (Table of terms and
abbreviations).

Reason of change Data changed compared with the previous version.