Safety Data Sheet

Revision Number: 005.0 Issue date: 10/12/2017

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE EA 3473 A known as Fix Fast IDH number: 702087
Set Steel Putty RESIN
Product type: Epoxy resin Item number: 39917_10345000
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or
rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off
contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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Hazardous Component(s) CAS Number Percentage*
Diiron trioxide 1309-37-1 60 - 70
Epichlorohydrin-4,4'-isopropylidene
25068-38-6 20 - 30
diphenol resin
Neopentyl glycol diglycidyl ether 17557-23-2 1-5
Calcium carbonate 471-34-1 1-5

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Get medical attention. Wash clothing
before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.

Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray. Closed containers may
rupture (due to build up of pressure) when exposed to extreme heat.

Hazardous combustion products: Oxides of carbon. Irritating organic fragments. Aldehydes.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up as much material as possible. Clean
residue with soap and water. Store in a closed container until ready for
disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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 7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling.
Keep container closed. Refer to Section 8.

Storage: Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Store away from heat, sparks, flames, or other
sources of ignition.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

10 mg/m3 PEL Fume.
50 MPPCF TWA
Total dust.
5 mg/m3 TWA
5 mg/m3 TWA
Diiron trioxide Respirable fraction. None None
Respirable fraction.
15 mg/m3 TWA Total
dust.
15 MPPCF TWA
Respirable fraction.
Epichlorohydrin-4,4'-isopropylidene
None None None None
diphenol resin
Neopentyl glycol diglycidyl ether None None None None
5 mg/m3 PEL
10 mg/m3 TWA Total Respirable fraction.
Calcium carbonate None None
dust. 15 mg/m3 PEL Total
dust.

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid, paste
Color: Gray, White
Odor: Slight, musty
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 2.6
Vapor density: Not available.
Flash point: > 93 °C (> 199.4 °F) Closed cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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 Solubility in water: Insoluble
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available.
VOC content: < 1.0 %; < 10 g/l (value for resin and hardener together) (estimated)
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Aldehydes. Irritating organic vapours.

products:

Incompatible materials: Strong acids and strong bases. Strong oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Heat, flames, sparks and other sources of ignition. Excessive heat. Store away from
incompatible materials.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: May cause dizziness, incoordination, headache, nausea, and vomiting. May cause lung
damage. Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye irritation.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Allergen, Cardiac, Central nervous system,
Diiron trioxide None
Irritant, Kidney, Liver, Lung
Epichlorohydrin-4,4'-isopropylidene
None Allergen, Irritant
diphenol resin
Allergen, Blood, Bone Marrow, Immune
Neopentyl glycol diglycidyl ether None
system, Irritant, Reproductive
Oral LD50 (Rat) = 6,450 mg/kg
Calcium carbonate Nuisance dust
Oral LD50 (Mouse) = 6,450 mg/kg

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Diiron trioxide No No No
Epichlorohydrin-4,4'-isopropylidene
No No No
diphenol resin
Neopentyl glycol diglycidyl ether No No No
Calcium carbonate No No No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrin
resin)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A
Epichlorhydrin resin)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Marine pollutant: Bisphenol-A Epichlorhydrin resin

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: 2

Prepared by: Product Safety and Regulatory Affairs

Issue date: 10/12/2017

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 702087 Product name: LOCTITE EA 3473 A known as Fix Fast Set Steel Putty RESIN
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