This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous

Chemicals - Code of Practice” (Feb 2016).

SAFETY DATA SHEET

1. Identification of the material and supplier
Product name : Dettol Anti-bacterial Laundry Sanitizer
Fresh Cotton
SDS # : D8293334 v1.1
Formulation # : 8291101 v1.0
Supplier : AUSTRALIA
Reckitt Benckiser (Australia) Pty Limited
ABN: 17 003 274 655
680 George St , Sydney, NSW 2000
Tel: +61 (0)2 9857 2000

NEW ZEALAND
Reckitt Benckiser (New Zealand) Limited
2 Fred Thomas Drive, Takapuna
Auckland , New Zealand
Tel: +64 9 484 1400
Poison Information contact: : Australia - 13 11 26
New Zealand - 0800 764 766 or 0800 POISON

Material uses : Fabric Treatment

Section 2. Hazard(s) identification

Classification of the : SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
substance or mixture SKIN SENSITIZATION - Category 1
HSNO Classification :6.5B, 8.3A, 9.1C
GHS label elements
Hazard pictograms :

Signal word : DANGER

Hazard statements : Causes serious eye damage.
Precautionary statements May cause an allergic skin reaction.
General : Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention : Wear protective gloves. Wear eye or face protection. Avoid breathing vapor.
Contaminated work clothing should not be allowed out of the workplace.
Response : IF IN EYES: Rinse cautiously with water for several minutes.Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local regulations.

Supplemental label :Ingredient Declaration:

elements 0.96% w/w Benzalkonium chloride
0.72% w/w Octyl decyl dimethyl ammonium chloride
0.42% w/w Didecyl dimethyl ammonium chloride

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Section 2. Hazard(s) identification

Additional information : No known significant effects or critical hazards.
Recommendations : No known significant effects or critical hazards.
Recommendations : No known significant effects or critical hazards.
Other hazards which do not : None known.
result in classification

Section 3. Composition and ingredient information

Substance/mixture : Mixture

Ingredient name % (w/w) CAS number

Quaternary ammonium <3 68424-95-3
compounds, di-
C8-10-alkyldimethyl, chlorides
<1 68391-01-5
quaternary ammonium
compounds, benzyl-
C8-18-alkyldimethyl, chlorides
Other Non-hazardous ingredients to 100%
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.

Most important symptoms/effects, acute and delayed

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Section 4. First aid measures

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : No specific fire or explosion hazard.

from the chemical
Hazardous thermal : No specific data.
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Hazchem code

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to
local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.

See Section 1 for emergency contact information.

See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. If during normal use the material presents a
respiratory hazard, use only with adequate ventilation or wear appropriate respirator.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container
tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.

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Section 8. Exposure controls and personal protection

Control parameters
Australia
Occupational exposure limits
None.

New Zealand
Occupational exposure limits : No exposure standard allocated.

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection : Considering the parameters specified by the glove manufacturer, check during use
that the gloves are still retaining their protective properties. It should be noted that
the time to breakthrough for any glove material may be different for different glove
manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid. [Clear.]
Color : Blue.
Odor : Not available.
Odor threshold : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: >93.3°C (>199.9°F)

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Section 9. Physical and chemical properties

Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.992 to 1.002
Solubility : Easily soluble in the following materials: cold water and hot water.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Flow time (ISO 2431) : Not available.
Aerosol product

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Dettol Laundry Skin - Erythema/Eschar Human 0 - 48 hours
Cleanser_FF8291101
(D8293334)ANZ
Eyes - Cornea opacity In vitro >5 - -
Conclusion/Summary
Skin : Non-irritant to skin. * Information is based on toxicity test result of a similar product.
Eyes : Causes serious eye damage. * Information is based on toxicity test result of a
similar product.
Respiratory : Based on available data, the classification criteria are not met.
Sensitization

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Section 11. Toxicological information

Product/ingredient name Route of Species Result
exposure
Dettol Laundry skin Mouse Sensitizing
Cleanser_FF8291101
(D8293334)ANZ
Conclusion/Summary
Skin : Skin sensitizer *Information is based on toxicity test result of a similar product.
Respiratory : Based on available data, the classification criteria are not met.
Mutagenicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Carcinogenicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Reproductive toxicity
Not available.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Teratogenicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.

Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure

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Section 11. Toxicological information

Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

Conclusion/Summary : Based on available data, the classification criteria are not met.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral >5000 mg/kg

Section 12. Ecological information

Toxicity
Not available.
Conclusion/Summary : Based on Calculation method: Harmful to aquatic life with long lasting effects.

Persistence and degradability

Conclusion/Summary : The surfactant(s) contained in this preparation complies (comply) with the
biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
Data to support this assertion are held at the disposal of the competent authorities
of the Member States and will be made available to them, at their direct request or
at the request of a detergent manufacturer.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information

ADG ADR/RID IMDG IATA
UN number Not regulated. Not regulated. Not regulated. Not regulated.

UN proper - - - -
shipping name
Transport hazard - - - -
class(es)

Packing group - - - -
Environmental No. No. No. No.
hazards

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
Transport in bulk according : Not available.
to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

Standard Uniform Schedule of Medicine and Poisons
Not Scheduled
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
Australia inventory (AICS) : All components are listed or exempted.
New Zealand Inventory of : All components are listed or exempted.
Chemicals (NZIoC)
+612*URXS6WDQGDUG Cleaning Products Subsidiary Hazard
HSNO $SSURYDO1XPEHU : AHSR002530

Section 16. Any other relevant information

Key to abbreviations : ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods

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Section 16. Any other relevant information

LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
Date of issue / Date of : 20/05/2019
revision
Version : 1.1
Procedure used to derive the classification
Classification Justification
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 On basis of test data
SKIN SENSITIZATION - Category 1 On basis of test data
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Please read all labels carefully before using product.

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