Unit 3 Basics of Superconductivity: Soren Prestemon Paolo Ferracin and Ezio Todesco
Unit 3 Basics of Superconductivity: Soren Prestemon Paolo Ferracin and Ezio Todesco
Unit 3 Basics of Superconductivity: Soren Prestemon Paolo Ferracin and Ezio Todesco
Basics of superconductivity
Soren Prestemon
Lawrence Berkeley National Laboratory (LBNL)
Paolo Ferracin and Ezio Todesco
European Organization for Nuclear Research (CERN)
Basics of superconductivity
1. History
2. General principles
3. Diamagnetism
4. Type I and II superconductors
5. Flux pinning and flux creep
6. Critical surfaces for superconducting materials
USPAS
USPAS,June
June 2009, Superconducting
2015, Rutgers Universityaccelerator magnets
Superconducting accelerator magnets Basic Cryogenics 12.
History
Abrikosov with
Princess Madeleine
Discovery of
superconductors
RRR=ρ(273K)/ ρ(4K))
USPAS, June 2015, Rutgers University Superconducting accelerator magnets 10
Aside: Maxwell’s equations
~ ⇢
r·E = Gauss’ law
✏
~
r·B = 0
@B ~
~
r⇥E = Faraday’s law
@t
@ ~ Ampere’s law
E
~
r⇥B = µ0 J~ + µ0 ✏0
@t (corrected by Maxwell)
Permeability of free space
Permittivity of free space
∇ ⋅ (∇ × F )= 0 ∀F ∇ × (∇ × F )= ∇(∇ ⋅ F )− ∇ 2 F ∀F
∇ × (∇u ) = 0 ∀u or ∇× F = 0 ⇔ F = ∇u
(F is conservative if curl F is zero)
Volume Integral
∫ F ⋅ n dS = ∫ ∇ ⋅ F dV Divergence Theorem
S V
∫ F ⋅ dl = ∫ (∇ × F )⋅ n dS
l S
Curl Theorem (Stoke’s Theorem)
∇ × B = µ0 J Amperes law
~meV~10-22J!!
Derive starting from the classical Drude model, but adapt to account for
the Meissner effect:
o The Drude model of solid state physics applies classical kinetics to electron
motion
✓ Assumes static positively charged nucleus, electron gas of density n.
✓ Electron motion damped by collisions
“Frictional drag” on “normal” conduction electrons
d~v ~
m = eE ~v
dt
J~s = ens~v
✓ ◆
~ = 1 B
2
@ m ~s + B
~ = 0 =) r B
2 ~ = µ0 n s e ~
) 2
r ⇥ J B 2
@t ns e m L
µ0
φ0 % 1&
H c1 ≈ Ln ( κ + ) ; κ >> 1
4 2πµ0 λ 2
* 2+
-M
Hc: Thermodynamic critical field
Hc=Hc1 for type I superconductors
φ0
Hc = 2
Hc1 Hc Hc2
2 2 µ0κπξ
! # T $2 "
H c (T ) ! H c (0) %1 − ( ) &
%, * Tc + &-
USPAS, June 2015, Rutgers University Superconducting accelerator magnets 30
Scaling of critical current:
field dependence
The Kramer formulation provides excellent fits in the region 0.2<h<0.6 for Nb3Sn; it is
appropriate for regimes where the number of fluxoids exceeds the number of pinning sites
Outside this region, a variety of effects (e.g. inhomogeneity averaging) can alter the pinning
strength behavior, so the pinning strength is often fitted with the generalization
q
f p (h) ∝ h p (1 − h ) ; h = H / H c 2
J c1/ 2 B1/ 4 !
1.1×105
µ 0 (H c 2 − H )
κ
H c (T )
= 1− t2
H c (0)
#
$1 − 0.31t 2 (1 − 1.77 ln(t ) ) Summers
κ (T ) $$
=% 1 − 0.33t Summers (reduced)
κ (0) $ 1.52
$ 1 − t Godeke / De Gennes
2
$& 1− t
USPAS, June 2015, Rutgers University Superconducting accelerator magnets 32
Scaling of critical current, Nb3Sn
Empirical Strain dependence
The critical current of Nb3Sn is strain dependent, particularly at high
field
The strain dependence is typically modeled in terms of the normalized
critical temperature:
3
H c 2 (4.2, ε ) " Tc (ε ) #
!$ % = s (ε )
H c 2 m (0) T
& cm '
The term Tcm and Hc2m refer to the peaks of the strain-dependent
curves
A “simple” strain model proposed by Ekin yields
1.7
s (ε ) = 1 − a ε axial
# 900 ε axial < 0
a=$
%1250 ε axial > 0
USPAS, June 2015, Rutgers University Superconducting accelerator magnets 33
Strain dependence of Jc in Nb3Sn:
physics-based model
A physics-based model of strain dependence has been developed using the
frequency-dependent electron-phonon coupling interactions (Eliashberg;
Godeke , Markiewitz)
Phonon density of states
α 2 (ω ) F (ω )
λep (ε ) = 2 ∫ dω
ω
From the interaction parameter the strain dependence of Tc can be derived
Experimentally, the strain dependence of Hc2 behaves as
H c 2 (4.2, ε ) Tc (ε )
≅
H c 2 m (4.2) Tcm
The theory predicts strain dependence of Jc for all LTS materials, but the
amplitude of the strain effects varies (e.g. very small for NbTi)
The resulting model describes quite well the asymmetry in the strain
dependence of Bc2, and the experimentally observed strong dependence on the
deviatoric strain
NbTi parameterization
Temperature dependence of BC2 is provided by Lubell’s formulae:
& , T )1.7 #
BC 2 (T ) = BC 20 $1 − ** '' !
$% + TC 0 ( !"
where BC20 is the upper critical flux density at zero temperature
(~14.5 T)
Temperature and field dependence of Jc can be modeled, for example,
by Bottura’s formula
γ NbTi
J C (B, T ) CNbTi $ B %
α NbTi
$ B %
β NbTi
$ & T '1.7 %
= ( ) (1 − ) (1 − + , )
J C ,ref B - BC 2 (T ) . - BC 2 (T ) . T
(- / C 0 0 ).
1.0
0.8
0.6
Fits for NbTi
fHtL
0.4
0.2
0.0
0.0 0.2 0.4 0.6 0.8 1.0
t=TêTc0
"
(ε axial − ε shift ) + (ε 0,a ) #& − Ca2ε axial
2 2 2 2
Ca1 % (ε shift ) + (ε 0,a ) −
s (ε axial ) = ' ( + 1,
1 − Ca1ε 0,a
Ca2ε 0,a
ε shift =
2 2
(Ca1 ) − (Ca2 )
C1 2
J c (H , T , ε ) ≅
µ0 H
( )( )
s (ε ) 1 − t1.52 1 − t 2 h 0.5 (1 − h )
H c2* (T , ε ) ≅ H c2m
*
(
(0 )s (ε ) 1 − t1.52 )
, T - ,1- , 1 D µ0 H c2 (T ) -
ln . / = ψ . / − ψ .. + //
. Tc (0 ) / 0 2 1 2 2 φ k T
0 1 0 0 B 1
USPAS, June 2015, Rutgers University Superconducting accelerator magnets 38
Using magnetization data
We have seen that the Meissner state corresponds to perfect diamagnetic behavior
We have seen that beyond Hc1, flux begins to penetrate and can be pinned at defects =>
hysteretic behavior
⇒ Much can be understood by measuring the effective magnetization of superconducting material
The measured magnetization provides insight into flux pinning and flux motion,
key concepts governing the performance of superconducting materials.
ΔM
M · B / Fp (T, B)
Often used to evaluate Jc(B,T)!
BSCCO2223