10/1/2017

General Chemistry
CHEM 101
(3+1+0)

Dr. Mohamed El-Newehy

http://fac.ksu.edu.sa/melnewehy

Chapter 2
Chemistry: Atoms, Molecules and Ions

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The Structure of the Atom

Dalton’s Atomic Theory (1808)

o Compounds are composed of atoms of more than one

element.

o Elements are composed of extremely small particles called

atoms.

o A chemical reaction involves only the separation,

combination, or rearrangement of atoms; it does not result
in their creation or destruction.

The Structure of the Atom

Dalton’s Atomic Theory (1808)
o Atom is the basic unit of an element that can enter into
chemical combination.

o Dalton imagined an atom that was both extremely small and

indivisible.

o The 1850s and extended into the twentieth century: atoms

actually possess internal structure; they are made up of
even smaller particles, which are called subatomic particles.

o This research led to the discovery of three such particles -

electrons, protons, and neutrons.

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The Structure of the Atom

The Electron
o Radiation - the emission and transmission of energy through space in the
form of waves.
o One device used to investigate this phenomenon was a cathode ray tube
(It is a glass tube from which most of the air has been evacuated).

The Structure of the Atom

The Electron
When the two metal plates are connected to a high-voltage source;
o The negatively charged plate, called the cathode, emits an invisible ray.
o The cathode ray is drawn to the positively charged plate, called the
anode, where it passes through a hole and continues traveling to the other
end of the tube.
o When the ray strikes the specially coated surface, it produces a strong
fluorescence, or bright light.

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The Structure of the Atom

The Electron
In some experiments, two electrically charged plates and a magnet
were added to the outside of the cathode ray tube.
o When the magnetic field is on and the electric field is off, the
cathode ray strikes point A.
o When only the electric field is on, the ray strikes point C.
o When both the magnetic and the electric fields are off or when they
are both on but balanced so that they cancel each other’s influence, the
ray strikes point B.

According to electromagnetic theory, a moving charged body behaves

like a magnet and can interact with electric and magnetic fields through
which it passes.

The Structure of the Atom

The Electron
o Because the cathode ray is attracted by the plate bearing
positive charges and repelled by the plate bearing negative
charges, it must consist of negatively charged particles.
o We know these negatively charged particles as electrons.

J.J. Thomson, measured mass/charge of e-

(1906 Nobel Prize in Physics)

Thomson’s charge/mass of e- = -1.76 x 108 C/g

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The Structure of the Atom

Millikan’s Experiment Measured mass of e-
(1923 Nobel Prize in Physics)

o Millikan examined the motion of single

tiny drops of oil that picked up static
charge from ions in the air.
o He suspended the charged drops in air
by applying an electric field and followed
their motions through a microscope.

e- charge = -1.60 x 10-19 C

Thomson’s charge/mass of e- = -1.76 x 108 C/g
e- mass = 9.10 x 10-28 g

The Structure of the Atom

Radioactivity
o It was suggested by Marie Curie.
o Radioactivity - spontaneous emission of particles and/or radiation.
o Radioactive - any element that spontaneously emits radiation.

o Röntgen noticed that cathode rays caused glass and metals to emit
very unusual rays.

• Highly energetic radiation penetrated matter, darkened covered

photographic plates, and caused a variety of substances to fluoresce.
• These rays could not be deflected by a magnet, they could not
contain charged particles as cathode rays do.
• Röntgen called them X rays because their nature was not known.

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The Structure of the Atom

Radioactivity
Three types of rays are produced by the decay, or breakdown, of
radioactive substances such as uranium.

1.Two of the three are deflected by

oppositely charged metal plates.
o Alpha () rays or  particles;
positively charged particles, and are
deflected by the positively charged plate.
o Beta () rays or  particles; are
electrons and are deflected by the
negatively charged plate.
2. Gamma () rays; high-energy rays.
Like X rays,  rays have no charge and are
not affected by an external field.

The Structure of the Atom

The Proton and the Nucleus
o By the early 1900s, two features of atoms had become clear:
they contain electrons, and they are electrically neutral.
o To maintain electric neutrality, an atom must contain an
equal number of positive and negative charges.
Thomson’s Model
 a uniform, positive sphere of matter
in which electrons are embedded
like raisins in a cake.
 This so-called “plum-pudding”
model was the accepted theory for a
number of years.

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The Structure of the Atom

The Proton and the Nucleus
Rutherford’s Experiment
(1908 Nobel Prize in Chemistry)

 particle velocity ~ 1.4 x 107 m/s
(~5% speed of light)

1. atoms positive charge is concentrated in the nucleus

2. proton (p) has opposite (+) charge of electron (-)
3. mass of p is 1840 x mass of e- (1.67 x 10-24 g)

The Structure of the Atom

The Proton and the Nucleus
Rutherford’s Model of the Atom
o Most of the atom must be empty space.
This explains why the majority of a particles passed through the gold
foil with little or no deflection.
o The atom’s positive charges, are all concentrated in the nucleus, which is
a dense central core within the atom.
o Whenever an  particle came close to a nucleus in the scattering
experiment, a large repulsive force and therefore a large deflection.
o The positively charged particles in the nucleus are called protons .

atomic radius ~ 100 pm = 1 x 10‐10 m
nuclear radius ~ 5 x 10‐3 pm = 5 x 10‐15 m

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The Structure of the Atom

The Neutron
Chadwick’s Experiment (1932)
(1935 Noble Prize in Physics)
o When a thin sheet of beryllium was bombarded with a particles, a
very high-energy radiation similar to  rays was emitted by the metal.
o Later experiments showed that the rays actually consisted of a third
type of subatomic particles, which Chadwick named neutrons,
electrically neutral particles having a mass slightly greater than that
of protons.

H atoms - 1 p; He atoms - 2 p
mass He/mass H should = 2
measured mass He/mass H = 4
neutron (n) is neutral (charge = 0)
n mass ~ p mass = 1.67 x 10-24 g

The Structure of the Atom

The Neutron

mass p ≈ mass n ≈ 1840 x mass e-

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Atomic Number, Mass Number and Isotopes

Atomic number (Z) = number of protons in nucleus
Mass number (A) = number of protons + number of neutrons
= atomic number (Z) + number of neutrons
Isotopes are atoms of the same element (X) with different
numbers of neutrons in their nuclei

Mass Number A
ZX
Element Symbol
Atomic Number

1 2 3
1H 1H (D) 1H (T)
hydrogen deuterium tritium

235 238
92 U 92 U

Atomic Number, Mass Number and Isotopes

The Isotopes of Hydrogen

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Atomic Number, Mass Number and Isotopes

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How many protons, neutrons, and electrons are in 6 C ?

6 protons, 8 (14 - 6) neutrons, 6 electrons

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How many protons, neutrons, and electrons are in 6 C ?

6 protons, 5 (11 - 6) neutrons, 6 electrons

Atomic Number, Mass Number and Isotopes

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The Periodic Table

Alkali Earth Metal
Alkali Metal

Noble Gas
Group

Halogen
Period

The Periodic Table

Chemistry In Action
Natural abundance of elements in Earth’s crust

Natural abundance of elements in human body

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Molécules and Ions

o A molecule is an aggregate of two or more atoms in a definite
arrangement held together by chemical forces.

H2 H2O NH3 CH4

o A diatomic molecule contains only two atoms

H2, N2, O2, Br2, HCl, CO

diatomic elements

o A polyatomic molecule contains more than two atoms

O3, H2O, NH3, CH4

Molécules and Ions

o An ion is an atom, or group of atoms, that has a net positive
or negative charge.
cation – ion with a positive charge
If a neutral atom loses one or more electrons
it becomes a cation.

11 protons 11 protons
Na 11 electrons Na+ 10 electrons

anion – ion with a negative charge

If a neutral atom gains one or more electrons
it becomes an anion.

17 protons 17 protons
Cl 17 electrons Cl- 18 electrons

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Molécules and Ions

o A monatomic ion contains only one atom
Na+, Cl-, Ca2+, O2-, Al3+, N3-

o A polyatomic ion contains more than one atom

OH-, CN-, NH4+, NO3-

Molécules and Ions

Common Ions Shown on the Periodic Table

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Molécules and Ions

27 3+
How many protons and electrons are in 13 Al ?

13 protons, 10 (13 – 3) electrons

78 2-
How many protons and electrons are in 34 Se ?

34 protons, 36 (34 + 2) electrons

Chemical Formulas

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Chemical Formulas
o A molecular formula shows the exact number of atoms of each
element in the smallest unit of a substance

o An empirical formula shows the simplest whole-number ratio of

the atoms in a substance

molecular empirical
H2O H2O
C6H12O6 CH2O
O3 O
N2H4 NH2

o An allotrope is one of two or more distinct forms of an element.

Oxygen (O2) and ozone (O3) are allotropes of oxygen.
diamond and graphite are allotropes of carbon.

Chemical Formulas
o Ionic compounds consist of a combination of cations and
an anions
• The formula is usually the same as the empirical formula
• The sum of the charges on the cation(s) and anion(s) in each formula
unit must equal zero

The ionic compound NaCl

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Chemical Formulas

The most reactive metals (green) and the most reactive

nonmetals (blue) combine to form ionic compounds.

Chemical Formulas
o If the charges on the cation and anion are numerically
different, we apply the following rule to make the formula
electrically neutral:
The subscript of the cation is numerically equal to the charge on the
anion, and the subscript of the anion is numerically equal to the
charge on the cation.

Aluminum Oxide. The cation is Al3+ and the oxygen anion is O2-.

The sum of the charges is 2(+3) + 3(-2) = 0.

Thus, the formula for aluminum oxide is Al2O3.

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Chemical Formulas
Formula of Ionic Compounds
2 x +3 = +6 3 x -2 = -6

Al2O3
Al3+ O2-

1 x +2 = +2 2 x -1 = -2

CaBr2
Ca2+ Br-

1 x +2 = +2 1 x -2 = -2

Na2CO3
Na+ CO32-

Chemical Formulas

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Naming Compounds

o Ionic Compounds
– Often a metal + nonmetal
– Anion (nonmetal), add “ide” to element name

BaCl2 barium chloride

K2O potassium oxide
Mg(OH)2 magnesium hydroxide

KNO3 potassium nitrate

Naming Compounds
o Transition metal ionic compounds
– indicate charge on metal with Roman numerals

FeCl2 2 Cl- -2 so Fe is +2 iron(II) chloride

FeCl3 3 Cl- -3 so Fe is +3 iron(III) chloride

Cr2S3 3 S-2 -6 so Cr is +3 (6/2) chromium(III) sulfide

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Naming Compounds

Naming Compounds

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Naming Compounds

Naming Compounds

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Naming Compounds
Molecular compounds
− They are usually composed of nonmetallic elements.

− Many molecular compounds are binary compounds.

− Naming binary molecular compounds is similar to naming binary ionic

compounds.

− We place the name of the fi rst element in the formula first, and the
second element is named by adding -ide to the root of the element
name.

HCl hydrogen chloride

HBr hydrogen bromide
SiC silicon carbide

Naming Compounds
Molecular compounds
− If more than one compound can be formed from the same elements,
use prefixes to indicate number of each kind of atom

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Naming Compounds
Molecular compounds

HI hydrogen iodide

NF3 nitrogen trifluoride

SO2 sulfur dioxide

N2Cl4 dinitrogen tetrachloride

NO2 nitrogen dioxide

N2O dinitrogen monoxide

Naming Compounds
Molecular compounds
Notes in naming compounds with prefixes:
o The prefix “mono-” may be omitted for the first element.
For example, PCl3 is named phosphorus trichloride, not
monophosphorus trichloride.
o For oxides, the ending “a” in the prefix is sometimes
omitted.
For example, N2O4 may be called dinitrogen tetroxide
rather than dinitrogen tetraoxide.

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Naming Compounds

Naming Compounds

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Naming Compounds
Acids and Bases
Naming Acids
o An acid can be defined as a substance that yields
hydrogen ions (H+) when dissolved in water.
For example: HCl gas and HCl in water

o Pure substance, hydrogen chloride

o Dissolved in water (H3O+ and Cl−),

hydrochloric acid

o Anions whose names end in “-ide” form acids with a “hydro-

” prefix and an “-ic” ending.

HCl hydrogen chloride

HCl hydrochloric acid

Naming Compounds
Acids and Bases
Naming Acids

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Naming Compounds
Acids and Bases
Naming Oxoacids and Oxoanions
o An oxoacid is an acid that contains hydrogen, oxygen, and
another element.

HNO3 nitric acid

H2CO3 carbonic acid

H3PO4 phosphoric acid

Naming Compounds
Acids and Bases
Naming Oxoacids and Oxoanions

o The formulas of oxoacids are usually written with the H first,

followed by the central element and then O.

H2CO3 carbonic acid

HClO3 chloric acid
HNO3 nitric acid
H3PO4 phosphoric acid
H2SO4 sulfuric acid

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Naming Compounds
Acids and Bases
Naming Oxoacids and Oxoanions
Two or more oxoacids have the same central atom but a different
number of O atoms; the following rules to name these compounds.

1. Addition of one O atom to the “-ic” acid: The acid is called “per . . -ic”
acid.
HClO3 chloric acid
HClO4 perchloric acid
2. Removal of one O atom from the “-ic” acid: The acid is called “-ous”
acid.
HNO3 nitric acid
HNO2 nitrous acid
3. Removal of two O atoms from the “-ic” acid: The acid is called “hypo
. . . -ous” acid.
HBrO3 Bromic acid
HBrO hypobromous acid.

Naming Compounds
Naming Oxoacids and Oxoanions
o The rules for naming oxoanions, anions of oxoacids, are as
follows:

1. When all the H ions are removed from the “-ic” acid, the anion’s
name ends with “-ate.”

2. When all the H ions are removed from the “-ous” acid, the anion’s
name ends with “-ite.”

3. The names of anions in which one or more but not all the hydrogen
ions have been removed must indicate the number of H ions present.

For example:
– H3PO4 phosphoric acid
– H2PO4- dihydrogen phosphate
– HPO4 2- hydrogen phosphate
– PO43- phosphate

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Naming Compounds
Naming Oxoacids and Oxoanions

Naming Compounds
Naming Oxoacids and Oxoanions

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Naming Compounds

Naming Compounds
Acids and Bases
Naming Bases
o A base can be defined as a substance that yields hydroxide
ions (OH-) when dissolved in water.

NaOH sodium hydroxide

KOH potassium hydroxide

Ba(OH)2 barium hydroxide

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Naming Compounds
o Hydrates are compounds that have a specific number of
water molecules attached to them.

BaCl2•2H2O barium chloride dihydrate

LiCl•H2O lithium chloride monohydrate

MgSO4•7H2O magnesium sulfate heptahydrate

Sr(NO3)2 •4H2O strontium nitrate tetrahydrate

CuSO4•5H2O CuSO4

Naming Compounds
Familiar Inorganic Compounds

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