Lukoil Atf Synth HD: Safety Data Sheet

SAFETY DATA SHEET
Complying with Regulation (EU) 1907/2006, amended by Regulation (EU) No. 453/2010 and
Regulation (EU)1272/2008
LUKOIL ATF SYNTH HD

Issue date: April 7, 2012 Version 1 Page 1 of 23
1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY /

UNDERTAKING
1.1 Product identification element
Product name: LUKOIL ATF SYNTH HD
1.2. Relevant uses of the substance or mixture and uses advised against
Use: LUKOIL ATF SYNTH HD is a high performance lubricating oil used for the automatic
transmissions of passenger cars and heavy transport vehicles.
It was created for high power (heavy duty) latest generation equipment for both
conventional and modern transmissions. It can be used both in vehicles from
Northern America and in those from Europe.
LUKOIL ATF SYNTH HD is a lubricating oil with a high viscosity index and it
provides excellent resistance to corrosion, anti-wear protection and good antifoaming
properties.
Uses advised against: Not identified.
1.3 Details regarding the supplier of the safety data sheet
Identification of the
Manufacturer: LUKOIL LUBRICANTS EAST EUROPE S.R.L.
11-15 Tipografilor St, Building A2, ground floor, Bucharest,
Sector 1, Romania,
Emergency tel.: +40 244 504 651 from 900 to 1700
E-mail: www.lukoil-lubricants.ro
2. HAZARD IDENTIFICATION
2.1 Substance / mixture classification
Classification according to Directive EC 67/548 or Directive 1999/45/EC, Government Decision 1408/2008

or Government Decision 937/2010
The product is not classified as hazardous to health or environment.
Classification according to Regulation CLP, Annex VI, Harmonized classification list (Regulation EC
790/2009)
Product classification according to Regulation (EC) 1272/2008 and Regulation (EC) 790/2009 is not available.
Hazards to health:
This product is not classified as hazardous to health.
Prolonged and/or repeated contact with this product may cause skin degreasing, especially at high temperatures.
This may cause irritation and possibly dermatitis, especially under insufficient personal hygiene conditions.
Contact with skin must be minimized.
Hazards for the environment:

This product is not classified as hazardous for the environment.
Avoid product release in the environment.
Accidental releases form a film on water surface, obstructing oxygen transfer.
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Safety hazards:
The product contains a substance with exposure occupational limit (see section 8).
2.2 Labelling elements
Labelling complying with Directive EC 67/548/EEC or Directive EC 1999/45/EC, Government Decision

1408/2008 or Government Decision 937/2010:
Symbol: Not necessary
Risk phrases (R): Not necessary
Safety phrases (S):

S2 Keep out of the reach of children
S24/25 Avoid contact with skin and eyes.
S29 Do not empty into drains
S36 Wear suitable protective clothing.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions / safety data sheets.
Labelling complying with Regulation (EC) No. 1272/2008 on classification, labelling and packaging of
substances and mixtures, and its amendments.
Labelling according to Regulation (EC) No. 1272/2008 and Regulation EC No. 790/2009 is not available.
2.3 Other hazards:

Waste oils may contain hazardous impurities, accumulated during the use. The concentration of these impurities
depends on the relevant use, and they may pose risks for health and environment when exhausted. All waste oils
must be handled with great care and contact with skin must be avoided as much as possible. Prolonged or
repeated exposure to waste oils must be made cautiously, as they may cause skin cancer.
3. COMPOSITION/INFORMATION ON COMPONENTS
3.1 Substances: Not applicable
3.2 Mixtures
Product description/characterisation: mixture of synthetic base oils and additives
Hazardous components:
IITEM CHEMICAL CONC. IDENTIFICATION NO. CLASSIFICATION

NO. DENOMINATION [%]
Directive Regulation
67/548/EEC and (EC)1272/2008
Gov. Dec. (CLP)
1408/2008
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

1. Distillates 43.0 – REACH registration No.: Self-classification

(petroleum), 46.0 01-2119484627-25-0035 - GHS 08
hydrotreated heavy EC No.: 265-157-1 H, L* notes are
paraffinic CAS No.: 64742-54-7 applied Aspiration hazard,
Base oil – INDEX No.: 649-467-00-8 Cat. 1, H304
unspecified H, L* notes are applied
(YUBASE 6)
2 Distillates 35.0- REACH registration No.:
(petroleum), 38.0 01-2119487077-29-0000 - Self-classification
hydrotreated light EC No.: 265-158-7 H, L* notes are GHS 08
paraffinic; CAS No.: 64742-55-8 applied
Base oil – INDEX No.: Aspiration hazard,
unspecified 649-468-00-3 Cat. 1, H304
(YUBASE 3) H, L* notes are applied
3. Dibutyl phosphite 1.1 – 1.2 REACH registration No.: Xn, R21, It is not listed in
Not available R36/37/38 Annex VI of
EC No.: - Reg.1272/2008
CAS No.: 1809-19-4
INDEX No.: -
4. Diphenylamine 0.08 – REACH registration No.: T; R23/24/25 GHS06, GHS08, GHS09

0.12 Not available R33
CAS No.: 122-39-4 N; R50/53
EC No.: 204-539-4 Acute Tox. 3, H331
INDEX No.: Acute Tox. 3, H311
612-026-00-5 Acute Tox. 3, H301
STOT RE 2, H373
Aquatic Chronic2, H411
5. Solvent naphtha REACH registration No.: Self-
(petroleum), heavy 01-2119463588-24-xxxx classification It is not listed in
aromatic EC No.: 919-284-0 Carc. Cat 3; R40, Annex VI of
CAS No.: 64742-94-5 Xn, R65, R66, Reg.1272/2008
Index No.: - R67,
} 0.0135 N;R51/53
Naphthalene REACH registration No.: Self-
01-2119451151-53-xxxx classification It is not listed in
EC No.: 926-273-4 Carc. Cat 3; R40, Annex VI of
CAS No.: 91-20-3 Xn; R65, R66, Reg.1272/2008
Index No.: - R67, N;R51/53
6. Solvent red dye REACH registration No.: Carc. Cat. 3, R40 It is not listed in
(comparable to C.I. Pre-registration Annex VI of
19 Solvent red) EC No.: 260-124-8 Reg.1272/2008
CAS No.: 56358-09-9
Index No.: -
0.0165}
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

REACH registration No.: Carc. Cat. 3, R40 It is not listed in

Pre-registration Annex VI of
EC No.: 260-913-7 Reg.1272/2008
CAS No.: 57712-94-4
Index No.: -
*The substance is not classified as carcinogenic T, R45 according to Directive EC 67/548/EEC and the
Government Decision 1408/2008 or GHS08, Carc. 1B, H350 according to Regulation (EC) No. 1272/2008
(CLP) as it complies with Note L having polynuclear aromatic hydrocarbon content < 3% determined in
accordance with IP 346 (dimethyl sulfoxide extraction) (Annex VI – Regulation EC 1272/2008.
See section 16 for the full text of R phrases

See section 16 for the full text of H phrases
4. FIRST AID MEASURES

4.1 Description of first aid measures
Inhalation: Inhalation at ambient temperature is unlikely, due to the low vapour pressure
of the substance.
Symptoms: irritation of the respiratory ways due to the exposure to the excess
of smoke, mist or vapours.
In case of symptoms caused by the inhalation of smoke, mist or vapours: take
the person from the dangerous area and transport it to a safe, quiet and well-
ventilated area.
In case the victim is no longer conscious and:
- does not breathe – make sure that breathing is not obstructed and perform
artificial respiration (by qualified personnel only). If necessary, perform external
cardiac massage and immediately get medical assistance.
- breathes: place the person in a recovery positions. If necessary, give
oxygen. Get medical assistance if breathing is difficult.
Skin contact: Symptoms: skin drying. Irritation may occur in case of repeated or prolonged
exposure. May cause burns in case of contact with the product at high
temperatures. Remove the contaminated clothes and footwear, and safely
dispose them. Wash the affected area with water and soap.
Get medical assistance if skin, irritation, swelling or reddening occur and persist
.
When using equipment operating at high temperatures, product
subcutaneous injection may occur (if applied). If lesions caused by product
subcutaneous injection occur, immediately get specialized medical assistance.
Do not wait for the symptoms to be developed.
For minor burns: cool the skin area. Keep it under cold water for several
minutes, until pain diminishes. However, avoid body hypothermia.
Do not put ice on the burned skin. Carefully remove the clothes which did
not adhere to the burn. DO NOT try to remove the parts of clothes stuck to the
burn, but cut around it.
Get specialized medical assistance whenever serious burns occur.
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Eye contact: Symptoms: light irritations (non-specific). May cause burns in case the contact
with the product occurs at high temperatures.
Rinse the eyes with plenty of water, for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Get specialized medical assistance (ophthalmologist), if irritation, sight blurring
or eye swelling develop and persist..
If hot product is splashed into the eyes, rinse and cool immediately with cold
water to dissipate heat. Immediately get specialized medical assistance
(ophthalmologist), for evaluation and treatment in case of accident.
Ingestion: Symptoms: some symptoms may occur or not. Nausea and diarrhoea may occur
if it is assumed that product was aspirated.
Immediately get specialized medical assistance and transport the victim to
the hospital. Do not wait for the symptoms to be developed.
Do not induce vomiting, as there is the risk of aspiration.
Never give anything by mouth to an unconscious person.
4.2 The most important symptoms

and effects, both acute and
delayed: Not known.
4.3 Indications regarding any kind

of immediate medical attention
and special necessary treatment: In case of involuntary vomiting, the substance should not be aspirated into
the lungs, as it may cause severe pulmonary problems.
Give symptomatic treatment.
5. FIRE-FIGHTING MEASURES
5.1 Fire-fighting means
Recommended extinguishing media:

- foam (used by qualified personnel only),
- sprayed water (used by qualified personnel only),
- dry chemical powders,
- carbon dioxide,
- other inert gases,
- sand or earth.
Not recommended extinguishing media:

Do not use a direct water jet on the hot product, as it may cause foaming and fire
propagation.
Simultaneously use foam and water on the same surface, to avoid foam
destruction.
5.2 Special hazards

caused by the burning substances
or products generated during
a fire: Incomplete combustion may produce a complex mixture of solid particles, liquids
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

and gases, carbon monoxide, carbon dioxide and non-identified organic and
inorganic combustion products.
Avoid spraying hot surfaces or electric circuits with the product. Product losses
from pipes under pressure generate product mist.
5.3 Recommendations for fire-fighters

Information for fire-fighters and protection equipment:
In case of a big fire, or of a fire which occurred in closed or poorly ventilated
spaces, firemen should wear a special, fire resisting equipment and positive
pressure self contained breathing apparatus (SCBA) with full-face mask.
Protective equipment should comply with Government Decision 160/2007.

Fires from closed areas shall be extinguished by specialised personnel only.
Note: Take precautionary measures collecting the residues and the water resulted from
fire extinguishing, in order to avoid spillage in waters, sewage or drinkable water
supply system.
6. ACCIDENTAL RELEASE MEASURES
General information: Stop or contain the spillage directly at the source, if this operation can be safely
performed. Avoid direct contact with the spread material.
Stay on the same side with wind direction.
Keep the non-involved personnel away from the area where the release
occurred. Immediately alert the emergency teams.
As an exception, in case of smaller releases, any action should be evaluated and
advised, if possible, by qualified and competent personnel for emergency
situations.
It is recommended to eliminate all of the ignition sources (e.g.: electrical
conduits, sparks, fires, flames).
If necessary, notify the competent authorities, according to applicable national
regulations.
6.1 Precautionary measures for the personnel,

protective equipment and emergency procedures:
Small releases: usually, the antistatic individual protective equipment is
sufficient. Big releases: full individual protective equipment, made of an
antistatic material resisting to chemicals.
Wear adequate protective gloves, resisting to chemicals, specific for aromatic
hydrocarbons. Note: PVA gloves are not waterproof and they are not adequate
for emergency situations.
Wear a protective helmet and boots or another antistatic footwear.
Wear protective goggles or mask for the whole face, if product splashing or
contact occur or are anticipated.
Respiratory protection may be necessary in special cases only (for example, mist
forming). Complete or semi-complete respiratory protection with combined filters
for dust/organic vapours or full self contained breathing apparatus (SCBA) may
be used depending on the release size or the expected exposure. In case risks
cannot be fully evaluated or oxygen deficit may occur, the only device that
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

should be used is the self contained breathing apparatus (SCBA).
6.2 Precautionary measures regarding the environment:

Prevent spillage entering waters, sewage or water supply system; prevent soil
infiltration.
6.3 Methods and materials for fire isolation and cleaning:

Liquid spilled on the ground: If necessary, contain the liquid spillage with sand, earth or another adequate
non-combustible material.
Big releases may be covered with foam, as a precaution measure, and if
available, to limit the fire risk.
Do not use a direct water jet.
If the release occurred inside a building or in closed spaces, provide an
adequate ventilation.
Absorb the released product with adequate non-combustible materials.
Carefully collect the released product.
Store the collected product and other contaminated materials in drums or
adequate containers, to be recycled, recovered or for disposal, in compliance
with the national legislation mentioned in section 13.
Release in water:
In case of small releases in closed waters (e.g.: ports), contain the product
with floating barriers or other devices.
Collect the released product by absorbing it with specific floating absorbers.
If possible, big releases in open waters should be contained with floating
barriers or other adequate mechanical devices.
If this is not possible, control release dispersion and collect the product with
adequate mechanical equipment.
Before using dispersive agents, you should ask the opinion of a specialist
and, if necessary, the approval of the local authorities.
Store the collected product and other contaminated materials in drums or
adequate containers, to be recycled, recovered or for disposal, in compliance
with the national legislation mentioned in section 13.
Additional information: Recommendations regarding product release in water and soil are based
on the most probable release scenario for this product; however,
geographical conditions, wind, temperature and (in case of release in water)
waves, current direction and speed may influence a lot the selection of the
most adequate methods to be taken. This is the reason why the opinion of the
local specialists should be requested. Note: Local regulations recommend or
forbid the measures to be taken.
6.4 References to other sections: For safe handling information, see section 7.
For personal protective equipment, see section 8.
For waste disposal information, see section 13.
7. HANDLING AND STORAGE

SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

General information: Make sure that all of the regulations regarding the handling and storage of
combustible products are complied with.
It is advisable to keep the product away from sparks / open flames / hot surfaces.
Do not smoke.
Use and store the product only outside the buildings or in well ventilated spaces.
Avoid contact with the product.
Avoid product dispersion in the environment.
7.1 Instructions for safe
handling:
Take precaution measures against static electricity.
Avoid splashing with the hot product when you handle in product in bulk to fill
the containers.
Avoid contact with skin. Avoid smoke/mist inhalation.
Prevent slipping risk.
Use personal protective equipment, if necessary.
For more information regarding the protective equipment and the operating
conditions for the substances which are not classified by applying the notes, see
the exposure scenario. Risk management represents the worst case possible.
For the substances which are not classified, the information can be found in the
Safety Data Sheet.
It is recommended to use electrical systems and steam pipes with self-limitation

at the temperature of maximum 120 0C (for example, a low vapour pressure of 2
bar, when the product cannot be stirred, to avoid an incontrollable temperature
increase). When product is heated, temperature must be constantly monitored.
7.2 Safe storage conditions, any

incompatibilities included:
The aspects regarding storage area, model of road tanker or tank, operating
equipment and procedures must comply with the local, national or European
legislation.
Depots must be adequate and they must have gutters, as a precaution
measure, to prevent soil and water pollution in case of release or spreading.
The cleaning, inspection and maintenance of storage tank internal structure
must be performed by adequate teams only and the operations should be
performed by qualified personnel only, in accordance with the internal, local or
national regulations.
Store separately from strong oxidizing agents.
Adequate container materials: Recommended materials: for containers or container gaskets, use soft steel or
stainless steel.
Non-recommended materials for containers: some synthetic materials may

not be adequate for containers or container gaskets, depending on material
specification and intended use.
Container material compatibility must be checked with the container
manufacturer.
Container information: If the product is supplied by the manufacturer in containers:

- Keep it only in its original container or in containers adequate for this
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

product.
- Keep containers tightly closed and properly labelled.
- Emptied containers may contain combustible product residue. Do not perform
welding, cutting, soldering, drilling or other similar operations if the container
was not adequately cleaned.
Hygiene measures: Make sure that the cleaning and hygiene measures are complied with.
Precaution measures: Contaminated materials must not be kept and stored at the work place
and they must never be kept inside pockets.
Keep the product away from human and animal food.
Do not eat, drink or smoke when using the product.
Always wash your hands after product handling.
Change contaminated clothes at the end of the work hours.
Loading/
discharging temperature, °C: Ambient.
Storage temperature, °C: Ambient.
7.3 Specific final use: Transmission oil.
8. EXPOSURE CONTROL / PERSONAL PROTECTION

8.1 Control parameters:
Exposure control measures: Provide ventilation with exhausting system, so that not to exceed the
limit values of occupational exposure.
Limit values of occupational exposure according to Law 319/2006 on Safety and health at work and Government
Decision 1218/2006 on establishing minimum requirements for safety and health at work in order to ensure
workers’ protection against the risks related to the presence of the chemical agents – Annex 1:
3
No. Limit value, mg/m
COMPONENT Long term exposure Short term exposure
8 hours 15 minutes
1. Oil (mist) 5 mg/m3 10 mg/m3
8.2 Exposure controls
Personal protective equipment
Respiratory protection: No respiratory protection is necessary in case proper ventilation exists at the
work place and in open spaces. When, by accumulation, the concentration
exceeds the occupational exposure limit (insufficient ventilation) or in closed
spaces, a respiratory protection device shall be used.
If the product is overheated, exposure to harmful substances or flammable gases
(e.g. sulphuretted hydrogen) may occur, and in this case respiratory protection is
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

necessary.
Hand protection: Use gloves resistant to lubricating oils (complying with SR EN 374).
Eye protection: Under normal use conditions, eye protection is not necessary. If there is a
splashing risk, wear safety goggles.
Body protection: Protective equipment, including footwear resistant to mineral oil.
General protection and

hygiene measures: Avoid the contact with eyes, skin and clothes.
Remove the clothes and footwear that were contaminated or stained with
product. Wash contaminated clothes with water and soap before reuse.
Wash the hands with water and soap (do not use solvents or other irritating
products that have a skin degreasing effect) before the lunch, drinking and
smoking breaks, before going to the toilet or at the end of the work hours.
Do not eat, drink and smoke at the work place.
Provide eye showers and shower cabins near working places.
Environment exposure control: Check the emissions generated during work to ensure that they comply with
environmental protection legislation. If necessary, make technological changes
of the production equipment in order to reduce the emissions at acceptable
levels.
9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information regarding the main physical and chemical properties
Physical-chemical characteristics Values Test methods
State of aggregation liquid -

Smell specific -
Colour red ASTM 1500
9.2 Important information for health, safety and environment

2
Kinematic viscosity at 100 ºC, mm / sec (cSt) 7.0-8.5 ASTM D 664
Kinematic viscosity at 40 ºC, mm 2/ sec (cSt) 40 ASTM D 664
Viscosity index, min. 160 ASTM D 2270
Brookfield viscosity, cP (mPa.s), max. 15000 ASTM D 2983

- at the temperature of -40°C
Pour point, °C, max. -45 ASTM D 97
Flash point, open cup, ºC , min. 180 ASTM D 92

Water content , v/m % nil ASTM D 95
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Copper strip corrosion at 150°C, 3h , max. 1b ASTM D 130
Foaming properties, ml /ml, max. (S I)

- at 24 ° C 50-0 ASTM D 892
Foaming properties, ml /ml, max. (S II)
- at 93.5 ° C 50-0 ASTM D 892
Foaming properties, ml /ml, max. (S III) 50-0

- la 24°C, after determination at 93.5 oC ASTM D 892
Density at 20°C, Kg/m3 To be determined ASTM D 4052
9.2 Other information: Not available.

10. STABILITY AND REACTIVITY
10.1 Reactivity: No information is available.
10.2 Chemical stability: The product is stable under normal use and storage conditions.
10.3 Risk of hazardous

reactions: Hazardous polymerization: it does not occur.
10.4 Conditions to be avoided: Extreme heat.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition

products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, and
flammable vapours may be formed in case of heating or fire.
11. TOXICOLOGICAL INFORMATION
11.1 Information regarding toxicological effects:
No toxicological studies on the product as such were performed.
Toxicity data regarding the components:
Acute toxicity synthetic oils:
Acute oral toxicity: LD50, oral > 5000 mg/kg (Practically, it is not toxic).
Acute dermal toxicity: LD50, dermal > 2000 mg/kg (Practically, it is not toxic).
Acute inhalation toxicity: LC50, inhalation > 5.0 mg/ litre (Practically, it is not toxic).
Irritating effects
Skin corrosion/irritation: Either a slight irritation or no skin irritation, according to the data of the
experiments made on rabbits and human subjects.
It is not expected that the substance might have a corrosive action.
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Eye severe lesions/irritation: Practically, it is not irritating to the eyes.
Sensitization of skin or
respiratory ways: It is not expected that the substance cause the sensitization of the respiratory
ways or of the skin.
Chronic effects
Carcinogenic effect: As the DMSO extract determined in accordance with IP 346 is < 3% w/w
(typically 0.2%, maximum 0.5%), the substance is not carcinogenic. Therefore,
the substance is not classified as being carcinogenic.
Mutagenicity of
germinative cells: This substance was not found to be mutagenic.
Reproduction toxicity: Dermal toxicity NOAEL reproduction (development): > 2000 mg/kg.
This substance does have effects on reproduction.
STOT (toxicity on specific

target organs) – single exposure: No data are available.
STOT (toxicity on specific

target organs) – repeated exposure: Sub-chronic repeated dose, dermal: NOAEL: 1000 mg/kg
Sub-chronic repeated dose, inhalation: NOAEL (local effects):> 220 mg/m3
and NOAEL (systemic effects): > 980 mg/m3
This substance is not classified for toxicity at repeated dose.
Hazard by aspiration: No data are available.
Toxicological information on the package of additives:
Acute toxicity, oral: LD50 oral, rat > 10.000 mg/kg

Based on components or similar materials.
Acute toxicity, dermal: LD50 dermal, rabbit > 2.000 mg/kg

Acute toxicity, inhalation: LC50 inhalation (1 hour), rat, as product powder or mist
> 200 mg/l
Irritating effects:
Skin corrosion/irritation: Not expected to be irritating to skin. Based on components or similar
materials.
Prolonged or repeated contact with skin or the contact caused by wearing
product contaminated clothes may cause dermatitis
.
Symptoms may include skin reddening, oedema, drying and cracking.
Eye severe lesion/irritation: May cause a slight irritation of the eyes. Classification with R36 is not
necessary. Based on data obtained on similar materials.
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Respiratory irritation: May cause nose, throat and lung irritation.

Based on data obtained on similar materials.
Skin sensitization: There are no available data attesting that the product or its components may
be sensitizing to skin.
Sensitization of
respiratory ways: There are no available data attesting that the product or its components may
be sensitizing to respiratory system.
Chronic effects:
Chronic toxicity: There are no available data attesting that the product or its components
present in concentrations higher than 1% may pose a chronic danger to
health.
.
Carcinogenicity: This product contains mineral oils which are highly refined and they are not
carcinogenic according to IARC. All the oils from this product have a content
of polycyclic aromatic substances lower than 3%, determined in accordance
with IP 346.
Mutagenicity of
germinative cells: There are no available data attesting that the product or its components
present in concentrations higher than 0.1% are mutagenic or genotoxic.
Reproduction toxicity: There are no available data attesting that the product or its components
present in concentrations higher than 0.1% are toxic to reproduction.
Teratogenicity: There are divergences between literature data on teratogenicity of diphenylamine.

However, due to the prevailing exposure way, the oral one (administration in
food) and to the relatively high administration dose, positive effects were
recorded in the studied animals, but without a danger for the work place.
Other information: No other dangers for health are known.

12. ECOLOGICAL INFORMATION
12.1 Toxicity:
No eco-toxicological studies on the product as such were performed.
Data regarding the components:
Acute ecotoxicity synthetic oils:

Acute toxicity, fish: LL50 > 100 mg/l
Long term toxicity, fish: NOEL: > 10 mg/l
Acute toxicity algae: NOEL: > 100 mg/l
Acute toxicity aquatic

invertebrates: EL50: > 10.000 mg/l
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Long term toxicity,

aquatic invertebrates: NOEL: > 10 mg/l
12.2 Persistence and

degradability: No data are available.
12.3 Bioaccumulation
potential: No data are available.
12.4 Mobility: No data are available.
12.5 Results of PBT and vPvB

evaluation: No data are available.
12.6 Other adverse effects: It is not expected that this product may pose risks to the environment, other
than those related to oil release.
* NOEL = Concentration limit at which no (toxicological) effect was noticed.
Toxicological information regarding the package of additives:
Acute toxicity freshwater fish: LC50 = 10 -100 mg/L (based on components)
Acute toxicity freshwater

invertebrates: EC50 = 10 -100 mg/L (based on components)
Inhibition algae: Not determined
Acute toxicity sea fish: LC50 = 10 -100 mg/L (based on components)
Acute toxicity sea

invertebrates: Not determined.
Toxicity bacteria: Not determined.
12.7 Persistence and degradability:

Biodegradation: At least 25% of the components of this product indicate a moderate
biodegradation according to the data obtained by means of the OECD
method, test 301.
At least 25% of the components of this product indicate a limited
biodegradation according to the data obtained by means of the OECD
method, test 302.
12.8 Bioaccumulation potential: 1 – 10 % of the components may be bioaccumulable in aquatic organisms.
12.9 Mobility in soil: Not determined
12.10 Results of PBT and vPvB

evaluation: No data are available.
12.11 Other adverse effects: Not known.

SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

13. DISPOSAL CONSIDERATIONS

Product waste treatment
methods: Product waste must be controlled. Product waste (the waste oil) must be treated
as a hazardous waste and handed over to the authorized collecting points,
complying with the national regulations and norms in force.
Waste disposal legislation: Law 211/2011 on the regime of waste.

Order 1032/2011 amending the Order of the Minister of Environment and Water
Management No. 578/2006 on approving the calculation methodology for the
contributions and taxes owed to the Environmental Fund.
Government Decision 427/2010 amending and supplementing Government
Decision No. 128/2002 on waste incineration.
Government Decision 1061/2008 on the transport of dangerous and non-
dangerous waste on the territory of Romania;
Government Decision 235/2007 on waste lubricating oil management;
decision No. 128/2002 on waste incineration
Government Decision 349/2005 on waste storage.
Order of the Ministry of Waters and Environment Protection No. 756/2004
for approving the Technical norms on waste incineration;
Government Decision 856/2002 on waste record-keeping and management
and for approving the list which includes the wastes, hazardous ones included.
Government Decision 128/2002 on waste incineration, amended and
supplemented by Government Decision 268/2005.
Product waste code: 13 02 06* synthetic engine, gear and lubricating oils.
The waste code is set according to the use. When the product is used for other
purposes, the user is obliged to assign another code to the product.
Waste container disposal: Containers that contain substance residues should be treated as a hazardous
waste and handed over to the authorized collecting points, according to the laws
in force.
Legislation on
packaging waste:
Order 794/2012 regarding the procedure of reporting the data concerning the
packaging and the packaging waste.
Decision 621 /2005 regarding the management of packaging and packaging
waste.
Decision 621/2005 regarding the management of packaging and packaging
waste.
Packaging waste code: 15 01 10* packaging containing residues of or contaminated by dangerous

substances.
14. TRANSPORT INFORMATION
Road / railway transport (ADR/RID):
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

14.1 UN No.: -
14.2 Correct UN name for shipment: -
14.3 Hazard class (classes) for transport: -
14.4 Packaging group: -
14.5 Hazards for environment: no
14.6 Special precautions for users: -
14.7 Bulk transport, according to Annex II
to MARPOL 73/78 and IBC code: -
Transport by sea (IMDG):

14.1 UN No.: -
Air transport (IATA):

14.1 UN No.: -
Additional information: Not classified as dangerous goods for transport.

15. REGULATORY INFORMATION
15.1 Regulations / laws in the field of safety, health and environment specific for the relevant substance
or mixture:
SDS Regulation:
This Safety Data Sheet was prepared complying with Regulation (EC) No. 1907/2006, amended by Regulation
(EU) 453/2010 and Regulation (EU) No. 1272/2008.
Regulation (EC) No. 1907/2006 – REACH

Restrictions for placing on the market and use, Regulation 552/2009: It does not contain restricted
substances.
National regulations:
Law 249/2011 amending art. 4 of Law No. 349/2007 on the reorganizing of the institutional framework in the field
of chemical substance management.
Law 254/2011 amending art. 26 of Law No. 260/2003 on the regime of dangerous chemical substances and
preparations
Commission Regulation (EU) No. 286/2011 amending, for the purposes of its adaptation to technical and
scientific progress, Regulation (EC) No. 1272/2008 of the European Parliament and of the Council on
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

classification, labelling and packaging of substances and mixtures

Government Decision 1408/2008 on classification, packaging and labelling of dangerous substances.
Government Decision 937/2010 on classification, packaging and labelling of dangerous mixtures when placed
on the market.
Regulation (EC) No. 1272/2008 on classification, labelling and packaging of substances and mixtures, amending
and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Rectification of Regulation (EC) No. 1272/2008 of the European Parliament and of the Council on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. (Official Journal of the European
Union L 535 of 31 December 2008).
Regulation (EC) No. 790/2009 amending in view of adapting of Regulation EC 1272/2008 on classification,
packaging and labelling of substances and mixtures to the scientific and technical progress.
Commission Regulation (EU) No. 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the
European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH)
Regulation 552/2009 amending Annex XVII of Regulation (EC) No. 1907/2006 - REACH "Restrictions on the
production, marketing and use of certain dangerous substances, mixtures and articles”.
Government Decision 735/2006 on limiting the emissions of volatile organic compounds.
Government Decision 371/2010 amending and supplementing Government Decision 699/2003 on establishing
measures for reduction of volatile organic compounds emissions due to the use of organic solvents in certain
activities and equipment.
Law 360/2003 on the regime of hazardous chemical substances and preparations.
Law 263/2005 on amending and supplementing Law No. 360/2003 regarding the regime of hazardous chemical
substances and preparations;
Government Decision 1093/2006 setting minimum safety and health requirements for workers’ protection
against the risks related to the exposure to carcinogenous or mutagenous agents at the work place.
Regulation EC 1336/2008 on amending Regulation 648/2004 in view of adapting it to Regulation 1272/2008 on
the classification, packaging and labelling of substances and mixtures.
Government Decision 477/2009 on establishing penalties for violation of Regulation (EC) No. 1907/2006 of the
European Parliament and the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH), establishing of the European Chemicals Agency, amending Directive 1999/45/EC and
repealing Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 of the Commission and
also of Council Directive 76/769/EEC, as well as Directives 91/155/EEC, 93/67/EEC, 93/105/EEC and
2000/21/EC of the Commission.
Government Decision 398/2010 on establishing measures for application of Regulation 1272/2008 of the
European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EEC and amending
Regulation 1907/2006.
Government Emergency Ordinance 122/2010 on setting sanctions applicable for the infringement of the
Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No. 1907/2006.
15.2 Chemical safety evaluation
No information is available.
Tactile symbol, if distributed to the population: If the product is distributed to the population, the tactile symbol
is not necessary.
16. OTHER INFORMATION

SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Full text of the risk phrases R mentioned in sections 2 and 3 (classification according to Government
Decision 1408/2008 and Government Decision 937/2010):
R21 Harmful in contact with skin
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R33 Danger of cumulative effects
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
R50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment
R51/53 Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
Full text of the hazard statements H mentioned in sections 2 and 3 (classification according to Regulation
(EC) No. 1272/2008 (CLP)):
H301 Toxic if swallowed.

H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H331 Toxic if inhaled
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Other information:
This Safety Data Sheet is based on the national legislation in force and on our current knowledge regarding this
product when the sheet was prepared. The purpose of this sheet is to describe the product from the points of
view of safety in use, handling and transport.
The physical-chemical data describe the product from the point of view of the safety requirements and they do not
represent a guarantee regarding the specific properties of the product, which can be found in the product
specification or in the contract.
The manufacturer and the distributor are not responsible for other uses of this product than the recommended
ones. The user will be always responsible for taking all the precaution measures for each section of this Safety
Data Sheet, so that to ensure the safe use of the product.
Safety data sheet, complying with Regulation (EC) No. 453/2010.

See Sections: 2, 3 and 15.
Label complying with Directive 1999/45/EC and Government Decision 937/2010:
LUKOIL ATF SYNTH HD
S2 Keep out of the reach of children

S24/25 Avoid contact with skin and eyes.
SAFETY DATA SHEET
LUKOIL ATF SYNTH HD

Label complying with Regulation (EC) 1272/2010: Not available

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SAFETY DATA SHEET

LUKOIL ATF SYNTH HD

1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY /

1.1 Product identification element

Product name: LUKOIL ATF SYNTH HD

Uses advised against: Not identified.

1.3 Details regarding the supplier of the safety data sheet

Classification according to Directive EC 67/548 or Directive 1999/45/EC, Government Decision 1408/2008

Hazards for the environment:

LUKOIL ATF SYNTH HD

2.2 Labelling elements

Labelling complying with Directive EC 67/548/EEC or Directive EC 1999/45/EC, Government Decision

Symbol: Not necessary

Risk phrases (R): Not necessary

Safety phrases (S):

2.3 Other hazards:

3.1 Substances: Not applicable

Product description/characterisation: mixture of synthetic base oils and additives

IITEM CHEMICAL CONC. IDENTIFICATION NO. CLASSIFICATION

LUKOIL ATF SYNTH HD

1. Distillates 43.0 – REACH registration No.: Self-classification

4. Diphenylamine 0.08 – REACH registration No.: T; R23/24/25 GHS06, GHS08, GHS09

LUKOIL ATF SYNTH HD

REACH registration No.: Carc. Cat. 3, R40 It is not listed in

See section 16 for the full text of R phrases

4. FIRST AID MEASURES

LUKOIL ATF SYNTH HD

4.2 The most important symptoms

4.3 Indications regarding any kind

Recommended extinguishing media:

Not recommended extinguishing media:

5.2 Special hazards

LUKOIL ATF SYNTH HD

5.3 Recommendations for fire-fighters

Protective equipment should comply with Government Decision 160/2007.

6. ACCIDENTAL RELEASE MEASURES

6.1 Precautionary measures for the personnel,

LUKOIL ATF SYNTH HD

should be used is the self contained breathing apparatus (SCBA).

6.2 Precautionary measures regarding the environment:

6.3 Methods and materials for fire isolation and cleaning:

7. HANDLING AND STORAGE

LUKOIL ATF SYNTH HD

It is recommended to use electrical systems and steam pipes with self-limitation

7.2 Safe storage conditions, any

Non-recommended materials for containers: some synthetic materials may

Container information: If the product is supplied by the manufacturer in containers:

LUKOIL ATF SYNTH HD

Storage temperature, °C: Ambient.

7.3 Specific final use: Transmission oil.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

8.2 Exposure controls

Personal protective equipment

LUKOIL ATF SYNTH HD

Body protection: Protective equipment, including footwear resistant to mineral oil.

General protection and

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical-chemical characteristics Values Test methods

State of aggregation liquid -