CHRA Form - For Distillation Methanol

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Methanol is highly flammable and toxic if swallowed, inhaled or absorbed through the skin. It can cause damage to organs and has sensitizing, irritating and corrosive properties.

Methanol is rated as HR2 (can be carried out on open bench with caution) and is flammable, irritating, sensitizing and harmful. Exposure can be toxic, corrosive or cause cumulative effects.

Personal protective equipment recommended includes a lab coat, eye protection, nitrile gloves and a respirator when there is a risk of inhalation or skin contact.

Faculty of Engineering

Chemical Health Risk Assessment (CHRA)

Substance name: Methanol

SYNONYMS:
CAS Number: Storage location: - Used location: -
Suppliers name, address, telephone, and catalogue CHRA Reg. No By FSO*:
number: Leave this section empty. Leave this section empty.

Cat. NO.:
Hazard and risk information – retrieved from MSDS/CSDS
Hazard description: H225 Highly flammable liquid and vapor
H301 Toxic if Swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H370 Causes damage to organs
Risk phrase description:
Safety phrase description:
Permissible exposure
limit (PEL):
Degree of hazard guidelines
Hazard
Safety
rating Hazard Risk Phrase
phrase
(HR)
Green Relatively No classified No known adverse health affect
HR1 safe as
hazardous
Blue Can be Skin R36 Irritating to eyes
HR2 carried out sensitizing R38 Irritating to skin
on open Skin R42 May cause sensitization by inhalation
bench with irritants R43 May cause sensitization by skin contact
caution
Orange Can be Harmful R20 Harmful by inhalation
HR3 carried out Corrosive R21 Harmful in contact with skin
on open Irritant R22 Harmful if swallowed
bench with Sensitising R30 Can become highly flammable in use
caution R34 Causes burns
R37 Irritating to respiratory system
R40 Possible risk of irreversible effect/
Limited evidence of a carcinogenic effect
R41 Risk of serious damage to eyes
Red Great care Very R23 Toxic by inhalation
HR4 necessary corrosive R24 Toxic in contact with skin
Toxic R25 Toxic if swallowed
Carcinogeni R31 Contact with acids liberates toxic gas
c (category R33 Danger of cumulative effects
2) R35 Causes severe burns
Mutagenic R39 Danger of very serious irreversible
(category 2) effects
Teratogenic R48 Danger of serious damage to health by

CHRA/rev.02/Jul13
(category 2) prolonged exposure
Gold Dangerous Very toxic R26 Very toxic by inhalation
HR5 Avoid Carcinogeni R27 Very toxic in contact with skin
exposure c (category R28 Very toxic if swallowed
1) R32 Contact with acids liberates very toxic
Mutagenic gas
(category 1) R45(1)May cause cancer
Teratogenic R46(1)May cause heritable genetic damage
(category 1) R47(1)May Cause birth defects
R49 May cause cancer by inhalation
Safety Analysis Checklist
Hazards to health
HR2 Sensitising HR2 Irritant HR3/4 Corrosive
HR3 Harmful HR4 Toxic HR5 Very Toxic
HR4/5 Teratogen HR4/5 Mutagen HR4/5 Carcinogen
Physicochemical properties
HR3 Highly
Biohazard HR2 Flammable
Flammable
HR4 Extremely
HR4 Oxidizing HR5 Explosive
Flammable
Exposure route
Inhalation Eye Skin
Ingestion Other NO YES
If YES please stated:
Factor increase the risk
Fine powder Fume
Containment classification
Local exhaust ventilation system (LEV) Fume hood
Others NO YES
If YES please stated:
Personal protective equipment (PPE)
Lab coat Eye protection Nitrile gloves
Face mask Chemical resistant glove Respirator
Other NO YES If YES please stated:
Storage method:
Disposal method:
Accidental release measure –
spills/leaks:
Fire fighting measure:
First aid measures
Eyes - Immediately flush eyes with plenty of water for 15 minutes, get medical aid
Skin - Immediately flush skin with plenty of water for 15 minutes, get medical aid
Ingestion - Get medical aid by medical personnel
Inhalation - Remove from exposure and move to fresh air immediately, get medical
aid
Assesses by : Leave this section empty. Signature:
Hp : Leave this section empty. Date:
Reviewed by project’s supervisor: Leave this section
Signature:
empty.
Reviewed by FSO*: Leave this section empty. Signature:

CHRA/rev.02/Jul13
*FSO – Faculty Safety Office

CHRA/rev.02/Jul13

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