WB Urethane: Safety Data Sheet
WB Urethane: Safety Data Sheet
WB Urethane: Safety Data Sheet
wb urethane PART A
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED): LEGGARI WB URETHANE
2. HAZARD(S) IDENTIFICATION
GHS RATINGS
Skin Corrosive 3 Reversible adverse effects in dermal tissue, Draize score: >=
1.5 < 2.3
Skin Sensitizer 1 Skin Sensitizer
GHS HAZARDS
H227 Combustible liquid
H302 Harmful if swallowed
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
GHS PRECAUTIONS
P210 Obtain special instructions before use
P235 Do not handle until all safety precautions have been read and understood
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P264 Wash … thoroughly after handling
P270 Contaminated work clothing should not be allowed out of the workplace
P272 Wear protective gloves/protective clothing/eye protection/face protection
P280 Use personal protective equipment as required
P321 Specific treatment (see … on this label)
P330 Take off contaminated clothing and wash before reuse
P363 Wash contaminated clothing before reuse
P301+P312 IF ON SKIN: Wash with soap and water
P302+P352 IF exposed or concerned: Get medical advice/attention
P333+P313 If skin irritation occurs: Get medical advice/attention
P370+P378 In case of fire: Use … for extinction
P403+P235 Store in a well ventilated place. Keep cool
P501 Dispose of contents/container to …
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS number Weight Concentration %
1-Butoxy-2-propanol 5131-66-8 1.00% - 5.00%
Triethanolamine 102-71-6 1.00% - 5.00%
Dipropylene glycol monomethyl ether 34590-94-8 1.00% - 5.00%
INHALATION: Remove to fresh air. If not breathing, give INGESTION: If swallowed, do not induce vomiting.
artificial respiration. If breathing is difficult, give oxygen. If victim is conscious and alert, give 2 to 4 cups full
Get immediate medical attention. Do NOT use mouth- of water or milk. Call a physician or poison control
to-mouth resuscitation. center immediately. Never give anything by mouth
to an unconscious person. Treat symptomatically and
ASPIRATION HAZARD: Do not induce vomiting or give supportively.
anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate SKIN CONTACT: Remove contaminated clothing.
medical attention. Wash skin with soap and water. Get medical attention if
irritation develops or persists.
EYE CONTACT: Immediately flush eyes with plenty of
water for least 15 minutes holding eyelids open. Get
medical attention. Do NOT allow rubbing of eyes or
keeping eyes closed.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, and Water Fog.
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly
closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam.
If water is used, fog nozzles are preferred.
FOR NON-EMERGENCY PERSONNEL: No action shall be taken involving any personal risk or without suitable
training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
FOR EMERGENCY RESPONDERS: If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the information in “For non-emergency
personnel”.
Dipropylene glycol 100 ppm TWA; 600 mg/m3 150 ppm STEL NIOSH: 100 ppm TWA;
monomethyl ether TWA 100 ppm TWA 600 mg/m3 TWA
34590-94-8 150 ppm STEL; 900
mg/m3 STEL
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to
decomposition, it emits acrid smoke and irritating fumes.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalis.
COMPONENT TOXICITY
5131-66-8 1-Butoxy-2-propanol
Oral LD50: 1,900 mg/kg (Rat)
102-71-6 Triethanolamine
Oral LD50: 4,190 mg/kg (Rat)
EYE CONTACT: Causes eye irritation. Irritating, and may INHALATION: Low hazard for usual industrial handling
injure eye tissue if not removed promptly. or commercial handling by trained personnel . High gas,
vapor, mist or dust concentrations may be harmful if
SKIN CONTACT: Substance may cause slight skin inhaled. Avoid breathing fumes, spray, vapors, or mist.
irritation. Low hazard for usual industrial handling or
commercial handling by trained personnel. INGESTION: Substance may be harmful if swallowed.
CERCLA-SARA Hazard Category: This product has been reviewed according to the EPA ‘Hazard Categories’
promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA
Title III) and is considered, under applicable definitions, to meet the following categories:
- None
Sara Section 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
- None
Leggari Products, LLC believes, to the best of its knowledge, the information contained herein to be accurate and reliable as of the date of
this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume
no responsibility or liability for personal injury or property damage incurred by the use of these materials. Leggari Products, LLC makes no
warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present
unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for
the users’ consideration and examination . It is the responsibility of the user to determine the final suitability of this information and to comply
with all applicable international, federal, state, and local laws and regulations.
SAFETY DATA SHEET
wb URETHANE PART B
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED): LEGGARI WB PRIMER
2. HAZARD(S) IDENTIFICATION
GHS RATINGS
Organ toxin single 3 Transient target organ effects- Narcotic effects- Respiratory
exposure tract irritation
GHS HAZARDS
H317 May cause an allergic skin reaction
H332 Harmful if inhaled
H335 May cause respiratory irritation
GHS PRECAUTIONS
P261 Avoid breathing dust/fumes/gas/mist/vapours/spray
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P363 Wash contaminated clothing before reuse
P302+P352 IF ON SKIN: Wash with soap and water
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing
P333+P313 If skin irritation or a rash occurs: Get medical advice/attention
P405 Store locked up
P403+P233 Store in a well ventilated place. Keep container tightly closed
P501 Dispose of contents/container to …
SIGNAL WORD: WARNING
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS number Weight Concentration %
Hexamethylene diisocyanate homopolymer 28182-81-2 70.00% - 80.00%
Cyclohexanamine, N,N-dimethyl-, compounds with 3- 666723-27-9 10.00% - 20.00%
(cyclohexylamino)-1-propanesulfonic acid-blocked 1,6-
diisocyanatohexane homopolymer
INHALATION: Remove to fresh air. If not breathing, give EYE CONTACT: Immediately flush eyes with plenty of
artificial respiration. If breathing is difficult, give oxygen. water for at least 15 minutes holding eyelids open. Get
Get immediate medical attention. Do NOT use mouth- medical attention. Do NOT allow rubbing of eyes or
to-mouth resuscitation. If you experience difficulty in keeping eyes closed.
breathing, leave the area to obtain fresh air. If continued
difficulty is experienced, get medical assistance SKIN CONTACT: Remove contaminated clothing.
immediately . Wash skin with soap and water. Get medical attention if
irritation develops or persists.
INGESTION: If swallowed, do not induce vomiting.
If victim is conscious and alert, give 2 to 4 cups full Aspiration hazard: Do not induce vomiting or give
of water or milk. Call a physician or poison control anything by mouth because this material can enter the
center immediately. Never give anything by mouth lungs and cause severe lung damage. Get immediate
to an unconscious person. Treat symptomatically and medical attention.
supportively.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Use dry chemical, CO2, Water spray (fog) or foam.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: Decomposition products may include the following
materials: carbon dioxide, carbon monoxide, nitrogen oxides.
SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS: Promptly isolate the scene by removing all persons from
the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed
containers cool.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Fire-fighters should wear appropriate protective
equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
SMALL SPILL: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
LARGE SPILL: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-
proof equipment. Approach release from upwind. Prevent entry into sewers, watercourses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows . Contain and collect spillage with
noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container
for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
ENVIRONMENTAL PRECAUTIONS
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers . Inform the
relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
PROTECTIVE MEASURES: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed
waste disposal contractor. Approach release from upwind. Prevent entry into sewers, watercourses, basements
or confined areas. Wash spillages into an effluent treatment plant or proceed as follows . Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place
in container for disposal according to local regulations (see Section 13). Contaminated absorbent material may
pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section
13 for waste disposal. Put on appropriate personal protective equipment (see Section 8). Persons with a history of
skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions
have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not
ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate . Do not
enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.
Do not reuse container.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY ADVICE ON GENERAL OCCUPATONAL HYGIENE:
INCOMPATIBILITIES: Store in accordance with local Eating, drinking and smoking should be prohibited
regulations. Store in a segregated and approved in areas where this material is handled, stored and
area. Store in original container protected from direct processed. Workers should wash hands and face before
sunlight in a dry, cool and well-ventilated area, away eating, drinking and smoking. Remove contaminated
from incompatible materials (see Section 10) and food clothing and protective equipment before entering
and drink. Store locked up. Eliminate all ignition sources. eating areas. See also Section 8 for additional information
Separate from oxidizing materials. Keep container tightly on hygiene measures.
closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid
environmental contamination.
Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits
Hexamethylene Not Established Not Established Not Established
diisocyanate homopolymer
28182-81-2
Cyclohexanamine, N,Ndi- Not Established Not Established Not Established
methyl-, compounds with
3-(cyclohexylamino)-1-
propanesulfonic acidblocked
1,6- diisocyanatohexane
homopolymer
666723-27-9
APPROPRIATE ENGINEERING CONTROLS: Use only with adequate ventilation. Use process enclosures, local
exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
ENVIRONMENTAL EXPOSURE CONTROLS: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.
BODY PROTECTION: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling this product. When there
is a risk of ignition from static electricity, wear anti- static protective clothing . For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
REACTIVITY: No specific test data related to reactivity available for this product or its ingredients.
POSSIBILITY OF HAZARDOUS REACTIONS: Under normal conditions of storage and use, hazardous reactions
will not occur.
INCOMPATIBLE MATERIALS: Reactive or incompatible with the following materials: oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
COMPONENT TOXICITY
Exposure to this material may affect the following organs:
Effects of Overexposure
INHALATION: Harmful if inhaled. May cause respiratory SKIN CONTACT: Causes skin irritation. May cause an
irritation. May cause allergy or asthma symptoms allergic skin reaction.
or breathing difficulties if inhaled. Exposure to
INGESTION: Irritating to mouth, throat and stomach.
decomposition products may cause a health hazard.
Serious effects may be delayed following exposure. EYE CONTACT: Causes serious eye irritation.
INHALATION: Adverse symptoms may include the following: respiratory tract irritation, coughing, wheezing and
breathing difficulties asthma.
SKIN CONTACT: Adverse symptoms may include the following: irritation, redness.
CERCLA-SARA Hazard Category: This product has been reviewed according to the EPA ‘Hazard Categories’
promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA
Title III) and is considered, under applicable definitions, to meet the following categories:
- None
Sara Section 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
- None