Shell Rimula R4 X 15W-40: Safety Data Sheet
Shell Rimula R4 X 15W-40: Safety Data Sheet
Shell Rimula R4 X 15W-40: Safety Data Sheet
2. HAZARDS IDENTIFICATION
GHS Classification
Based on available data this substance / mixture does not meet the classification criteria.
Precautionary statements :
Prevention:
No precautionary phrases.
Response:
No precautionary phrases.
Storage:
No precautionary phrases.
Disposal:
No precautionary phrases.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
4. FIRST-AID MEASURES
In case of skin contact : Remove contaminated clothing. Flush exposed area with
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Most important symptoms : Oil acne/folliculitis signs and symptoms may include formation
and effects, both acute and of black pustules and spots on the skin of exposed areas.
delayed Ingestion may result in nausea, vomiting and/or diarrhoea.
Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
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Methods and materials for : Slippery when spilt. Avoid accidents, clean up immediately.
containment and cleaning up Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
Soak up residue with an absorbent such as clay, sand or other
suitable material and dispose of properly.
Storage
Other data : Keep container tightly closed and in a cool, well-ventilated
place.
Use properly labeled and closable containers.
Packaging material : Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.
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Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil
Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.
General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
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Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be
replaced. Personal hygiene is a key element of effective hand
care. Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
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Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.
Colour : amber
Odour Threshold : Data not available
pH : Not applicable
pour point : -36 °C / -33 °FMethod: ASTM D97
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Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available
Viscosity
Viscosity, dynamic : Data not available
Viscosity, kinematic : 109 mm2/s (40.0 °C / 104.0 °F)
Method: ASTM D445
Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.
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Basis for assessment : Information given is based on data on the components and
the toxicology of similar products.Unless indicated otherwise,
the data presented is representative of the product as a
whole, rather than for individual component(s).
Exposure routes : Skin and eye contact are the primary routes of exposure
although exposure may occur following accidental ingestion.
Acute toxicity
Product:
Acute oral toxicity : LD50 rat: > 5,000 mg/kg
Remarks: Low toxicity:
Based on available data, the classification criteria are not met.
Acute inhalation toxicity : Remarks: Based on available data, the classification criteria
are not met.
Skin corrosion/irritation
Product:
Remarks: Slightly irritating to skin., Prolonged or repeated skin contact without proper cleaning
can clog the pores of the skin resulting in disorders such as oil acne/folliculitis., Based on
available data, the classification criteria are not met.
Components:
Zinc dialkyl dithiophosphate:
Remarks: Based on available data, the classification criteria are not met.
Zinc dialkyldithiophosphate:
Remarks: Based on available data, the classification criteria are not met.
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Zinc dialkyldithiophosphate:
Remarks: Based on available data, the classification criteria are not met.
Components:
Calcium sulphonate:
Remarks: May cause an allergic skin reaction in sensitive individuals.
Remarks: Not a carcinogen., Based on available data, the classification criteria are not met.
Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-
painting studies., Highly refined mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC).
Reproductive toxicity
Product:
:
Remarks: Not a developmental toxicant., Does not impair
fertility., Based on available data, the classification criteria are
not met.
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Aspiration toxicity
Product:
Not an aspiration hazard.
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The
concentration of such impurities will depend on use and they may present risks to health and the
environment on disposal., ALL used oil should be handled with caution and skin contact avoided
as far as possible.
Remarks: Continuous contact with used engine oils has caused skin cancer in animal tests.
Basis for assessment : Ecotoxicological data have not been determined specifically
for this product.
Information given is based on a knowledge of the components
and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).(LL/EL/IL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).
Ecotoxicity
Product:
Toxicity to fish (Acute :
toxicity) Remarks: LL/EL/IL50 > 100 mg/l
Practically non toxic:
Based on available data, the classification criteria are not met.
Toxicity to algae/aquatic :
plants (Acute toxicity) Remarks: LL/EL/IL50 > 100 mg/l
Practically non toxic:
Based on available data, the classification criteria are not met.
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Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains components with the potential to
bioaccumulate.
Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal
methods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses
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Local legislation
Remarks : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
International Regulations
ADR
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea.
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Further information
Training advice : Provide adequate information, instruction and training for
operators.
Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
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