AITS-2021-OPEN TEST-JEEA-PAPER-1-Sol
AITS-2021-OPEN TEST-JEEA-PAPER-1-Sol
AITS-2021-OPEN TEST-JEEA-PAPER-1-Sol
OPEN TEST
JEE (Advanced)-2021
PAPER –1
SECTION – A
1. B
Sol. In a rotational equilibrium net torque about the CM must be zero i.e. F must pass through CM.
2. A
Sol. Coefficient of friction is small so there will be slipping between the blocks.
3. C
f
Sol. U nR T2 T1
2
3
Pf Vf PV
i i
2
3
105 4 105 6 3 105 J
2
4. B
Sol. Motion of Q with respect to P
v Q,P v Q v P
vQ,P
d d
sin 60 60°
30 P
30 km 60° O
d 15 3 km 60°
60°
V
Q
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 2
5. B
Sol. E A EB
20D
6. A
Sol. d r.dqE
d = r.(2r.dr) E
r dB dr
E r
2 dt
QR2 dB
4 dt
MR2
dt 0
2
Q
B0
2M
7. C, D
dT
Sol. H K 0 x4x 2
dx
2R0 T0
H dx
4K 0
R0
x3 2T
dT , it will give H
0
x T
H dx
and
4K 0 R0
x3 2T
dT , it will give T = f(x).
0
8. B, C, D
D
Sol. Optical path length = dy 2 D
0
0
20D
t
c
9. B, D
1
Sol. When the distance increases, intensity gets reduced as I
r2
Kmax depends on the frequency of light.
10. A, D
Sol.
mdv
dt
qE0 ˆI q v x ˆi v y ˆj v zkˆ XB0 ˆj
Solving we get vy = 0
E02
and vx(max) = v 02
B02
11. A, C
Sol. Conceptual
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3 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
12. B, C, D
mv 02 v0
Sol. T , decreases.
2 R R
d v 0 d v0
d
dt dt 2R R
2 t
2R R d v dt 0
0 0
R
SECTION – C
13. 00007.70
2
1 R H
Sol. mg w g
3 3 3
2
1 R H 1
mg g R2Hw g
3 2 2 3
Solving these equation, 7.70
w
14. 00000.15
Sol. mg = R2P R
1 1
Where P = S r
r R
Since R >> r
1
P = S
r
S
mg R 2
r
Mg mg R 2 P
1 1
P S ,
r R
r
r , R r
2
2
P S
r
R .2r R2 .2r
2
R R 2
2
Mg mg 2R2 S
r
S
4R2
r
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 4
= 4 mg
M = 3m
= 3 × 0.050
= 0.15 Kg
15. 00002.49
Sol. Conservation of momentum
1
2 4K 1 2 12K 3 cos K2 0n
16. 00001.23
hc
Sol. K e max
12400
10 90 eV
124
Ke of fastest electron falling in collector is 10090 eV
hc
C
eV
12400
1.23
10090
17. 00000.25
Sol. Power, P = mgv0
= 2 10 2.5
= 50W
dT
P 2H
dt
dT 50
0.25 C/s
dt 200
18. 00019.60
Sol. If E = 0
Let particle strikes at point B. v0
z
AB2 = OB2 OA2
3a2 3a2 a2
= r2 = a2
4 4 4
a B
AB a
2 r
a
O A
AB 2 1 x
sin (0, 0, 0)
OB a 2
2 r
m
3
Time taken to reach at B, t =
q0B (0, 0, a) v0
E 0, this time displacement along y-axis during
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5 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
2 2
1 qE 2 m 2 Em 2 a
y 0
2 m 3 q20B 2 2q0B2 3 2
Co-ordinate of point of impact
3a a a
= , ,
2 2 2
Velocity at point of impact
E 2 ˆ 3v 0 ˆ a ˆ ˆ
v v 0 cos 60iˆ j ˆ
k ( i j 3k)
B 3 2 2
Angular momentum of particle before collision about O,
a
L 1 ( 3iˆ ˆj k)ˆ a (ˆi ˆj 3k)
ˆ
2 2
= 4 ( 3 1)iˆ 4jˆ ( 3 1)kˆ
| L | 8 6 kg-m2/sec
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 6
Chemistry PART – II
SECTION – A
19. D
Sol. Possible isomers are
K 3 Fe CN6 K 3 Fe NC 6
K 3 Fe CN5 NC K 3 Fe NC 5 CN
K 3 Fe CN4 NC 2 K 3 Fe NC 4 CN2
cis and trans cis and trans
K 3 Fe CN3 NC 3
fac and mer
20. A
Sol.
Ph
N N N N Ph N N
Here phenyl group preferentially migrates due to its high migratory aptitude.
21. B
Sol. Ph Ph OH Ph
NH2OH
C O
pH 5 C N C N
Me Me Me OH
Ph OH O
H2SO4 /
C N Ph C N CH3
Beckman's rearrangement
H3C H
N methyl benzamide
22. B
Sol.
H2 g I2 g
2HI g
Initial mol 1 1 0
mol at eqbm 1 x 1 x 2x
1 x 1 x
2x
eqbm conc
V V V
Now, equivalents of hypo used = equivalents of I2 present at equilibrium
0.110 1 1 x 2
x = 0.5
1
2
So, K c 4
1 1
2 2
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7 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
1 1 1 2 1
HI g
H2 g I2 g will be 0.5
2 2 4 2
Hence, (B)
23. D
Sol. qp 806 100 80600 J
80600
So, Hvap 40300 J mol1 40.3 kJmol1
2
n Hvap 80600
S vap 216.08 J K 1
boiling point 373
Uvap Hvap ngRT
80.6 2 8.314 373 103
74.3 kJ
Since, the system is at equilibrium so G 0.
Hence, (D) is incorrect.
24. D
Sol. Correct reaction is
1.B H THF
CH2 CH2
2 6
2. CH COOH
CH3 CH3
3
25. B
Sol. (A) Highly pure dilute solution of sodium in liquid ammonia is blue and not red.
4NaNO3 s 2Na2 O 2N2 g 5O2 g
o
800 C
(B)
Na O2
Na2 O2 NaO2
(C)
excess traces
(D)
B OH 4 H
(i) H3BO3 H2 O
…(i)
O OH
OH HO OH
ii B
B
OH OH
OH HO O
So, in accordance with Le Chatlier’s principle, Eq. (i) shifts in forward direction due to reaction (ii)
and hence pH decreases.
26. A, C, D
q
Sol. (A) S X Z 0 reversible adiabatic change
T
100
(B) SXZ Y S XY 2.303 5 8.314log10 95.7 JK 1
10
(because ‘S’ is a state function).
(C) S X Y 95.7 JK 1 Reversible isothermal expansion
(D) Since ‘S’ is a state function, so S X Y S X Z SZ Y 95.7 JK 1
0 S z Y 95.7
So, A, C and D are correct.
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 8
27. A, B, C
Sol. (A) H
Me H
Me Et
Et Me
Me Et
Me Et H Me (S)
H Me Me2HC Et
Me
H Me H
H H
CHMe2
Me
Me
(B) H
H H
H Me
Et CHMe2
Me Me
Me2HC Me H H (S)
Me2HC H Et Me
CHMe2
H Me2HC H
H
Me H
Me
Me
(C) H
Et H
Et CHMe2
CHMe2 Et
H CHMe2
H CHMe2 H Et (S)
H Et Me CHMe2
H
H H H H
Me H
H
H
(D) Et
Et Et
Et Me
H Me
H Me Et Et
H
H H H
H
H
H
Me
Et Et
Me
(achiral)
28. A, C, D
Sol. Resonance effect of ester is less dominant than aldehydes and ketones.
29. A, B, C
Sol. O O O O
Si Si Cr Cr
O O O O O O
O O O O
(A) (B)
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9 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
O O
S S
. .
O O O
O .
O
(C) (D)
(Cyclic silicate)
30. A, B, D
Sol. (A) 1st excitation
Cl :
3s 3p 3d
So, x 5
(B) nd
2 excitation
1st excitation
He :
1s 2s y 3
(C) nd
2 excitation
1st excitation
H:
1s 2s 2p 3s 3p 3d
degenarate
So, z = 9
SECTION – C
31. 00002.80
Sol. CH3 NO2
Si C
H3C CH3 Cl Cl
CH3 Cl
tetra methyl silane tear gas
(x = 6) (y = 14)
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 10
32. 00001.50
Sol. O O
N NH2
4e
Highly acidic condition
Electric current
OH
O O
N NH2
6e
Mild acidic condition
Electric current
So, n = 4 F, m = 6 F
33. 00001.80
Sol. Blue coloured compound Red coloured
compound
O2 , O3 g , Cu NH3 4 SO 4 , HgI2 ,Pb3 O 4 CuO Black
III II II III
Ag2CrO 4 ,KO3 ,Cu2O C2H5 3 BO3 colourless
K Fe Fe CN6 , K Fe Fe CN6 , y=5 CaC2O 4 white
z=3
N2 O3
x=6
34. 00009.90
n2
Sol. t1/ 2
k f kb
35. 00005.60
1.4 meqvts of acid used
Sol. % of N
w
1.4 20
5.60
5
36. 00002.50
Pb
Sol. Z 1
RT
b
So, slope
RT 492.6
4
b RT 4 r 3 NA
492.6 3
So, r 2.50A o
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11 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
SECTION – A
37. C
Sol. x 2 x 2 x 2 4 3 tan x 16 0
x 2 4 3 tan x 16 0 must have at least one positive root
2
4 3 tan 0 tan > 0 and 4 3 tan 16 0 3 tan2 1
1
tan
3
n , n ; n z
6 2
38. B
Sol. Required circles C1 and C2 are given by C1
(x – 1)2 + (y – 1)2 + k(3x + 4y – 7) = 0
It touches x axis A(4, 5)
x2 + (3k – 2)x + (2 – 7k) = 0 has equal roots
k = –2, 2/9
C1 = x2 + y2 – 8x – 10y + 16 = 0
4 10 4 C2
C2 = x 2 + y 2 – x y 0
3 8 9 6 5
B ,
4 6 5 3 5 5 4 1 1 9 9
Slope of AB , Q , i.e. , Q
3 9 9 5 9 9 5 3 9
39. C
Sol.
dy
2x3 1
y
3x
dx x 1 x 3 1 x3
2
1
2x
x 2 dx
2x3 1
x1 x3 dx 1 2
x x
If = e e x
1 x3
x 3x2 yx 1 1
Solution is y 1 x dx , c y
3 3 3 2
1 x 3 1 x 2 1 x3 2x 1 x 3
40. C
Sol. Equation of auxiliary circle (x – 1)2 + (y – 4)2 = a2
a = 5 ae 5 2 e 2
S(6, 9)
7 13
Point on directrix LL ,
2 2 Q
Equation of directrix is x + y – 10 = 0 (5, 7) P(h, k)
(1, 4)
Equation of tangent through (5, 7) is x + 2y – 19 = 0
Point Q(1, 9) PSQ = 90 S(–4, –1)
13
P(h, k) is 6,
2
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 12
41. C
Sol. Use graph
42. C
Sol. r xa yb z a b ..... (1)
r a b r b a r a b
r b 2, r a 3
3
Moreover x , y 1
2
15 1
Also, r z
2 2
r a b 2
43. A, B, D
a b
Sol. A ; ad – bc 0
c d
a + b + c + d = 5, aij {0, 1, 2, 3, 4, 5}
(A) (i) Exactly one zero
4! 4!
Number of matrices = 24
2! 2!
(ii) Exactly 2 zeros
Number of matrices = 2 5 1C2 1 8
Total matrices = 32
2
(B) Number of symmetric matrices = 6 2b 12
b0
(C) Det A = ad – bc is odd
a b
A if A = A then b = c
T
c d
Det A = ad – b2, a + d = 5 – 2b
(i) b = 0, a + d = 5 not possible
(ii) b = 1, a + d = 3 4 cases
(iii) b = 2, a + d = 1 not possible
44. A, B, D
1
Sol.
P n 1 P n 1 4
P(2) = 0
P 3 1 P 2 41 41
1 1 3
P 4 1
4 4 16
3 1 13
P 5 1
16 4 64
13 1 51
P 6 1 4 256
64
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13 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
45. B, C, D
Sol. Foot of perpendicular P (–6, –9)
Q 12, 36 (0, 8)
S(48, 72)
and R 24, 18
R
S1 y 2 108x 0
(27, 0)
S2 x 2 32y 0
P
46. A, B, C
Sol. z z 1 z 1
1
(2x + 1)2 = (x – 1)2 ; x
2
x 1
2
y2
3x2 + 6x – y2 = 0
1
1 3
branch of
hyperbola
(–1, 0) (–1, 0)
y = –2
x 1
2
y2
|z – 1| + |z + 3| = 6 z lies on an ellipse 1
9 5
Re z > 0, Im (z) –2
Let ax + by = 1 be a chord of curve S1 = 0
3(x)2 – y2 + 6x(ax + by) = 0
If angle subtended is 90, then
1 x
3(1 + 2a) – 1 = 0 a . Chord is by 1 0 which passes through (–3, 0)
3 3
47. C, D
Sol. Let f(x) = x3 – x4 – x2 + 2020
f(x) = 3x2 – 4x3 – 2x = –x(4x2 – 3x + 2)
f(x) is decreasing x > 0
n 1
1 r
Sn lim
n
n f n T
k 0
n
48. B, D
cos x x cos x x
= 0 x = , 0,
cos2 x 1 x tan x
2
2
g(x) > 0 0 < x < ; g(x) < 0 < x <
2
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AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021 14
SECTION – C
49. 00300.00
n
Sol. Sn
k 0
nk
Ck k = 1 n 1Cn 2 n 2
Cn ..... n 2n
Cn
50. 00025.00
C
100 x 2 5 B
Sol. cos
10 –
x 5
50 x 2 100 x 2 x 2 50
cos
50 10 50 D 10 A
25(100 – – x 2) =
= + 2500 – (x2 50)2 x4 100x2
2
x 5 3 and ABC
3 3
51. 00004.00
/3 2
2
Sol. I
0
log
2
1 3 tan 3
x
3
x
3 3
x dx
/3
x 3x
2
2 4
= log2 dx
0 1 3 tan x
/3
x 3x
2
2 5
I dx =
810
0
52. 00082.00
k 2
Sol. S1(n) = –64n2, S2 k k 3k 1
3
53. 00009.00
R
Sol. In radius of DEF = 2R cos A cos B cos C =
4
1
cos A cos B cos C = ABC is equilateral
8
a3
R 3 a=3
3 2
4 a
4
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15 AITS-OT (Paper-1)-PCM(Sol.)-JEE (Advanced)/2021
54. 00192.00
C(0, c, 0)
Sol. OP a ˆi bkˆ R(a, c, 0)
PC a ˆi cjˆ bkˆ
E(0, c, b)
OA a ˆi Q
Equation of PC, r a ˆi bkˆ a ˆi cjˆ bkˆ
O A(a, 0, b)
Equation of OA, r aiˆ
ac kˆ bjˆ B(0, 0, b) P(a, 0, b)
Shortest distance = a ˆi bkˆ ackˆ abjˆ
a b2 c 2
abc bc ac ab
1 Similarly 2 , 3
2 2 2 2
a b c b c a c2
2
a b2
2
1 1 1 1 1 1 1 1 1
2 2 2 2 2
12 22 23 a b c ab bc ca
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