11 - Safety Msds English
11 - Safety Msds English
11 - Safety Msds English
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified Uses: Antifreeze/Coolant
Belgium
email : customerservice@arteco-coolants.eu
Symbols:
Xn - Harmful
R22; Harmful if swallowed.
S2; Keep out of the reach of children.
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S46; If swallowed, seek medical advice immediately and show this container or label.
S60; This material and its container must be disposed of as hazardous waste.
3.1 Mixtures
This material is a mixture.
The full text of all R-phrases is shown in Section 16. This product contains a bittering agent.
4.2 Most important symptoms and effects, both acute and delayed
IMMEDIATE SYMPTOMS AND HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to be harmful.
Ingestion: May be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Breathing this material at concentrations above the
recommended exposure limits may cause central nervous system effects. Central nervous system effects
may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision,
drowsiness, confusion, or disorientation. At extreme exposures, central nervous system effects may
include respiratory depression, tremors or convulsions, loss of consciousness, coma or death.
4.3 Indication of any immediate medical attention and special treatment needed
Not applicable.
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SECTION 5 FIRE FIGHTING MEASURES
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities,
and other substances in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, the personal protective equipment listed below is recommended. The
user should read and understand all instructions and limitations supplied with the equipment since
protection is usually provided for a limited time or under certain circumstances. Refer to appropriate CEN
standards.
Attention: the data below are typical values and do not constitute a specification.
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Evaporation Rate: No data available
Flammability (solid, gas): No Data Available
Flammability (Explosive) Limits (% by volume in air):
Lower: No Data Available Upper: No Data Available
Vapor Pressure: 2794 Pa @ 30 °C (30 °F)
Vapor Density (Air = 1): >1 (Typical)
Relative Density: 1 kg/l @ 15°C (59°F)
Solubility: Soluble in water.
Partition coefficient: n-octanol/water: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No Data Available
Viscosity: No data available
Explosive Properties: No Data Available
Oxidising properties: No Data Available
Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.
Carcinogenicity: The hazard evaluation is based on data for components or a similar material.
Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.
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Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.
Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.
2-Ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme levels when repeatedly
administered to rats via the diet. When administered to pregnant rats by gavage or in drinking water,
2-EXA caused teratogenicity (birth defects) and delayed postnatal development of the pups. Additionally,
2-EXA impaired female fertility in rats. Birth defects were seen in the offspring of mice who were
administered sodium 2-ethylhexanoate via intraperitoneal injection during pregnancy.
12.1 Toxicity
This material is not expected to be harmful to aquatic organisms. The product has not been tested. The
statement has been derived from the properties of the individual components.
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13.1 Waste treatment methods
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may
meet the criteria of a hazardous waste as defined by international, country, or local laws and regulations.
In accordance with European Waste Catalogue (E.W.C.) the codification is the following: 16 01 14
The description shown may not apply to all shipping situations. Consult appropriate Dangerous Goods
Regulations for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.
ADR/RID
ICAO
IMO
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REGULATORY LISTS SEARCHED:
01=EU. Directive 76/769/EEC: Restrictions on the marketing and use of certain dangerous substances.
02=EU Directive 90/394/EEC: Carcinogens at work.
03=EU Directive 92/85/EEC: Pregnant or breastfeeding workers.
04=EU Directive 96/82/EC (Seveso II): Article 9.
05=EU Directive 96/82/EC (Seveso II): Articles 6 and 7.
06=EU Directive 98/24/EC: Chemical agents at work.
07=EU Directive 2004/37/EC: On the protection of workers.
08=EU Regulation EC No. 689/2008: Annex 1, Part 1.
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09=EU Regulation EC No. 689/2008: Annex 1, Part 2.
10=EU Regulation EC No. 689/2008: Annex 1, Part 3.
11=EU Regulation EC No. 850/2004: Prohibiting and restricting persistant organic pollutants (POPs).
12=EU REACH, Annex XVII: Restrictions on manufacture, placing on the market and use of certain dangerous
substances, mixture & article.
13=EU REACH, Annex XIV: Candidate List of Substances of Very High Concern for Authorization (SVHC).
The following components of this material are found on the regulatory lists indicated.
Ethylene glycol 06
CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS
(Philippines), TSCA (United States).
REVISION STATEMENT: This revision updates the following sections of this Material Safety Data
Sheet: 1, 15, 16.
Revision Date: SEPTEMBER 12, 2011
Prepared according to the criteria of EU Regulation 1907/2006 by the Chevron Energy Technology
Company, 100 Chevron Way, Richmond, California 94802.
The above information is based on the data of which we are aware and is believed to be correct as of the
date hereof. Since this information may be applied under conditions beyond our control and with which
we may be unfamiliar and since data made available subsequent to the date hereof may suggest
modifications of the information, we do not assume any responsibility for the results of its use. This
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information is furnished upon condition that the person receiving it shall make his own determination of
the suitability of the material for his particular purpose.
No Annex
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