Overall CHP 7 and 12

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OBJECTIVE

Q.No.1 (1×8=8)
1. The carbon atom of carbonyl group is
(A) sp hybridized (B) sp2 hybridized
(C) sp3 hybridized (D) dsp2 hybridized
2. Which of the following has highest boiling point?
(A) methanal (B) ethanal (C) propanal (D) 2-hexanone
3. The characteristic reaction of aldehydes and ketones is
(A) nucleophilic addition (B) electrophilic addition
(C) nucleophilic substitution (D) electrophilic substitution
4. Which of the following compound will react with Tollen’s reagent?
(A) CH3CHO (B) CH3COCH3
(C) CH3COOH (D) CH3COCH2CH3
5. The general formula of aldehydes is:
(A) CnH2nO (B) CnH2n (C) CnH2nOH (D) CnH2n+2O
6. Hydroxyl amine on reaction with carbonyl compounds in the presence of acid
catalyst gives
(A) imine (B) oxime (C) hyrdazone (D) nitriles
7. The compound used in the processing of anti-polio vaccine is:
(A) Acetaldehyde (B) Formaldehyde (C) Acetone (D) Ethyl bromide
8. Which is most difficult to oxidize?
(A) C2H5CHO (B) CH3CHO (C) HCHO (D) CH3COCH3

1. The carbon atom in carbonyl group is:


(a) Sp hybridized (b) Sp2 hybridized
(c) Sp3 hybridized (d) None of these
2. Which of the following has highest boiling point:
(a) Methanal (b) Ethanal
(c) 2-hexanone (d) propanal
3. Ketones are prepared by the oxidation of:
(a) Primary alcohols (b) Secondary alcohols
(c) Tertiary alcohols (d) None of these
4. Cannizzao’s reaction is not given by:
(a) formaldehyde (b) Acetaldehyde
(c) Benz aldehyde (d) trymethylacetaldehyde
SUBJECTIVE
SECTION-I
Q.No.2. Write short answers to the following questions. (7×2=14)
i) Write down industrial preparation of methanal.
ii) Write down mechanism of addition of HCN to carbonyl compounds.
iii) Differentiate between 2-pentanone and 3-pentanone?
iv) What is Tollen’s reagent? Where is it used?
v) Differentiate between acetone and acetaldehyde.
vi) Convert acetone into tertiary butyl alcohol.
vii) Write down reaction of hydrazine with ethanal.
viii) How iodoform is prepared from ethanol and acetaldehyde?
ix) How would acetone be changed in to propane and t-butyle alcohol?
x) Give the general mechanism of base catalyzed nucleophilic addition reaction?
xi) How will you distinguish between methanal and ethanal?
xii) What is aldol condensation?
xiii) Discuss chemistry of iodoform test?
xiv) Give mechanism of addition of HCN to carbonyl compounds?
xv) Give one industrial method to acetaldehyde?
xvi) Give industrial method to prepare acetone?
Q.No.3
(a) Explain with mechanism the aldol condensation. (4)
(b) Convert ethanal into (4)
Ethanol, ethanoic acid, 1,1-diethoxyethane, lactic acid
OBJECTIVE

Q.No.1 (1×10=10)

1. Which one of the following is alcohol?


(A) CH3COOH (B) CH3OCH3

(C) CH3CH2OH (D) CH3CH2Br

2. Type of hybridization of carbon in ethene is


(A) sp (B) sp2

(C) sp3 (D) dsp2

3. In tertiary butyl alcohol, tertiary carbon is attached to


(A) three hydrogen atoms (B) one hydrogen atom

(C) two hydrogen atoms (D) Hydroxyl group

4. Which one of the following is not heterocyclic compound?


(A) furan (B) phenanthrene (C) pyridine (D) thiophene

1. The state of hybridization of carbon atom in methane is:


(a) Sp3 (b) Sp2
(c) sp (d) Dsp2
2. Ethers show the phenomenon of:
(a) Position isomerism (b) Functional group isomerism
(c) metamerism (d) Cis-trans isomerism
3. A double bond consist of:
(a) Two sigma bonds (b) One sigma and one pi
(c) Two pi bonds (d) None of these
4. In t-butyl alcohol, the tertiary carbon is bonded to:
(a) Two hydrogen atoms (b) Three hydrogen atoms
(c) One hydrogen atom (d) No hydrogen atom
SUBJECTIVE

SECTION-I

Q.No.2. Write short answers to the following questions. (5×2=10)

i) Define heterocyclic compounds.


ii) What is the importance of Wohler’s work in chemistry?
iii) Define reforming with example.
iv) Write down isomers of C2H6O.
v) Define octane number.
vi) What is meant by functional group?
vii) What is catalytic cracking?
viii) Define tautomerism with an example?
ix) What is meant by fractional distillation?
x) What are heterocyclic aromatic compounds give an example?
xi) What is meant by knocking?
xii) What is meant by metamerism?
xiii) What is catenation?
i) Branched chain hydrocarbons are better fuel as compare to straight chain. Why?
SECTION-II

Note: Attempt the following Question. (6×1=6)


Q.No.3
What is cracking of petroleum? Give its purpose? Explain it in detail?
What is atomic orbital hybridization? How can you explain structure of ehtene and ethyne?

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