Product Name: ESCOREZ™ 1000 SERIES

Revision Date: 05 Aug 2016

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SAFETY DATA SHEET

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE
COMPANY / UNDERTAKING

As of the revision date above, this SDS meets the regulations in the United Kingdom & Ireland.

1.1. PRODUCT IDENTIFIER

Product Name: ESCOREZ™ 1000 SERIES
Product Description: Hydrocarbon Resin, see Section 16 for applicable grades.

1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
Intended Use: Road marking, Tackifier resin/Adhesive component, Tapes and labels

Uses advised against: None unless specified elsewhere in this SDS.

1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Supplier: ExxonMobil Petroleum & Chemical BVBA
Polderdijkweg
B-2030 Antwerpen
Belgium
Phone: 32 3 543 31 11

Local Contact: ExxonMobil Chemical Ltd.

MAILPOINT 14
MARSH LANE
FAWLEY, SOUTHAMPTON
SO45 1TX HAMPSHIRE
Great Britain
Supplier General Contact: +44 (0)23-8089-3822
E-Mail: sds.uk@exxonmobil.com

1.4. EMERGENCY TELEPHONE NUMBER

24 Hour Environmental / Health Emergency +(44)-8708200418 (CHEMTREC)
Telephone:

This material is not subject to Safety Data Sheet provision according to Article 31 of REACH.

SECTION 2 HAZARDS IDENTIFICATION

2.1. CLASSIFICATION OF SUBSTANCE OR MIXTURE

Classification according to Regulation (EC) No 1272/2008

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Not Classified

2.2. LABEL ELEMENTS

No Label elements according to Regulation (EC) No 1272/2008

2.3. OTHER HAZARDS

Physical / Chemical Hazards:

Contact with hot material can cause thermal burns which may result in permanent damage. WARNING: May
form combustible dust concentrations in air (during processing/handling). Material can accumulate static
charges which may cause an ignition. Spilled pellets present a slipping hazard on hard surfaces.

Health Hazards:
If dust is generated, it could scratch the eyes and cause minor irritation to the respiratory tract. When heated,
the vapour/fumes given off may cause respiratory tract irritation.

Environmental Hazards:
No significant hazards. Material does not meet the criteria for PBT or vPvB in accordance with REACH Annex
XIII.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

3.1. SUBSTANCES

This material is defined as a substance.

No Hazardous Substance(s) required for disclosure.

NOTE: The product may contain varying levels of additives such as slip and anti-blocking agents, antioxidants and
stabilisers.

3.2. MIXTURES Not Applicable. This product is regulated as a substance.

SECTION 4 FIRST AID MEASURES

4.1. DESCRIPTION OF FIRST AID MEASURES

INHALATION
At ambient/normal handling temperatures, no adverse effects due to inhalation of dust are expected. In case of
adverse exposure to vapours and / or aerosols formed at elevated temperatures, immediately remove the
affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.
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SKIN CONTACT
Wash contact areas with soap and water. For hot product: Immediately immerse in or flush affected area with
large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt
medical attention.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
No adverse effects due to ingestion are expected.

4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
No important symptoms or effects.

4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
The need to have special means for providing specific and immediate medical treatment available in the
workplace is not expected.

SECTION 5 FIRE FIGHTING MEASURES

5.1. EXTINGUISHING MEDIA

Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Unsuitable Extinguishing Media: Straight streams of water

5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Hazardous Combustion Products: Flammable hydrocarbons, Incomplete combustion products, Oxides of
carbon, Smoke, Fume

5.3. ADVICE FOR FIRE FIGHTERS

Fire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area.
Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters
should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).
Use water spray to cool fire exposed surfaces and to protect personnel.

Unusual Fire Hazards: Explosion: Avoid generating dust; fine dust dispersed in air in sufficient concentration
and in the presence of an ignition source is a potential dust explosion hazard.

FLAMMABILITY PROPERTIES
Flash Point [Method]: Not technically feasible
Upper/Lower Flammable Limits (Approximate volume % in air): UEL: No data available LEL: No data
available
Autoignition Temperature: No data available

SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

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NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material. Dust Deposits should not be allowed to accumulate on surfaces, as
these may form an explosive mixture if they are released into the atmosphere in sufficient concentration.
Avoid dispersal of dust in the air (for example, clearing dust surfaces with compressed air). Prevent dust
exposure to ignition sources. For example, use non-sparking tools and prohibit smoking, flares, sparks or
flames in immediate area. See Section 5 for fire fighting information. See the Hazard Identification Section
for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary,
depending on the specific circumstances and/or the expert judgment of the emergency responders.

6.2. ENVIRONMENTAL PRECAUTIONS

Prevent entry into waterways, sewers, basements or confined areas.

6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

Land Spill: Spilled pellets present a slipping hazard on hard surfaces. Prevent dust cloud. Small Dry Spills:
With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.

Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

6.4. REFERENCES TO OTHER SECTIONS

See Sections 8 and 13.

SECTION 7 HANDLING AND STORAGE

7.1. PRECAUTIONS FOR SAFE HANDLING

Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dusts do
not accumulate on surfaces. Dust from material can accumulate electrostatic charges due to friction from
transfer and mixing operations and cause an electrical spark (ignition source). Provide adequate precautions to
ignition sources, such as electrical grounding and bonding, inert atmosphere or non-sparking tools. However,
bonding and grounds may not eliminate the hazard for static accumulation. Consult local applicable standards
for guidance. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids and EN 61241, Electrical Apparatus
for Use in the Presence of Combustible Dust for safe handling. Avoid elevated temperatures for prolonged
periods of time. Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Prevent
small spills and leakage to avoid slip hazard. DO NOT handle, store or open near an open flame, sources of
heat or sources of ignition. Protect material from direct sunlight. Care should be taken when storing and
handling this product. Apart from the specific nature of the polymer product, conditions such as humidity,
sunlight and temperature have an influence on the way the product behaves during storage and handling.
Special attention should be paid to avoid inappropriate stacking of palletised bags or other package units.
Indeed, polymer products may be dimensionally unstable under certain conditions. Avoid conditions generating
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heat during transfer operations.

Loading/Unloading Temperature: [Ambient]

Transport Temperature: [Ambient]

Static Accumulator: This material is a static accumulator.

7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

The type of container used to store the material may affect static accumulation and dissipation. Store in a cool,
dry place.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]

Suitable Containers/Packing: Bags (20/25kg); Big Bags

Suitable Materials and Coatings (Chemical Compatibility): Polyethylene; Polypropylene; Paper; Steel

7.3. SPECIFIC END USES

Section 1 informs about identified end-uses. No industrial or sector specific guidance available.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. CONTROL PARAMETERS

Exposure limits/standards for materials that can be formed when handling this product: For dusty conditions,
ACGIH recommends for insoluble and poorly soluble particles not otherwise specified an 8-hour TWA of 10 mg/m3
(inhalable particles), 3 mg/m3 (respirable particles).

Note: Information about recommended monitoring procedures can be obtained from the relevant
agency(ies)/institute(s):
UK Health and Safety Executive (HSE)

8.2. EXPOSURE CONTROLS

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
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Adequate ventilation should be provided so that exposure limits are not exceeded. SPECIAL
PRECAUTIONS: Should significant vapours/fumes be generated during thermal processing of this
product, it is recommended that work stations be monitored for the presence of thermal degradation by-
products which may evolve at elevated temperatures (for example, oxygenated components).
Processors of this product should assure that adequate ventilation or other controls are used to control
exposure. It is recommended that the current ACGIH-TLVs for thermal degradation by-products be
observed. Contact your local sales representative for further information. It is recommended that all
dust control equipment such as local exhaust ventilation and material transport systems involved in
handling of this product are designed and maintained to minimize dust generation and accumulation.
Ensure that dust-handling systems (such as exhaust ducts, dusts collectors, vessels, and processing
equipment) are designed to minimize the potential for dust ignition and prevent explosion propagation.
For example, use explosion relief vents, an explosion suppression system or inert equipment internals.
Additional examples of proper equipment include using only appropriately classified electrical
equipment and powered industrial trucks.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Particulate air-purifying respirator approved for dust or oil mist is recommended. European Committee
for Standardization (CEN) standards EN 136, 140 and 405 provide respirator masks and EN 149 and
143 provide filter recommendations.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves. CEN standards EN 420 and EN 374 provide general
requirements and lists of glove types.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
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ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.

9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Form: Powder, Flake, Prills
Colour: Pale Yellow
Odour: None to Mild
Odour Threshold: No data available
pH: Not technically feasible
Melting Point: 90°C (194°F) - 123°C (253°F) [test method unavailable]
Freezing Point: No data available
Initial Boiling Point / and Boiling Range: Not technically feasible
Flash Point [Method]: Not technically feasible
Evaporation Rate (n-butyl acetate = 1): Not technically feasible
Flammability (Solid, Gas): Not technically feasible
Upper/Lower Flammable Limits (Approximate volume % in air): UEL: No data available LEL: No data
available
Vapour Pressure: Not technically feasible
Vapour Density (Air = 1): Not technically feasible
Relative Density (at 18 °C): 0.97 [test method unavailable]
Solubility(ies): water Negligible
Partition coefficient (n-Octanol/Water Partition Coefficient): Not technically feasible
Autoignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: Not technically feasible
Explosive Properties: None
Oxidizing Properties: None

9.2. OTHER INFORMATION

Density (at 18 ºC): 970 kg/m3 (8.09 lbs/gal, 0.97 kg/dm3) [test method unavailable]
Molecular Weight: 800 - 2000
Hygroscopic: No
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SECTION 10 STABILITY AND REACTIVITY

10.1. REACTIVITY: See sub-sections below.

10.2. CHEMICAL STABILITY: Material is stable under normal conditions.

10.3. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.

10.4. CONDITIONS TO AVOID: Avoid elevated temperatures for prolonged periods of time.

10.5. INCOMPATIBLE MATERIALS: Strong oxidisers

10.6. HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

SECTION 11 TOXICOLOGICAL INFORMATION

11.1. INFORMATION ON TOXICOLOGICAL EFFECTS

Hazard Class Conclusion / Remarks

Inhalation
Acute Toxicity: No end point data for Minimally Toxic. Based on chemical structure (polymers).
material.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Ingestion
Acute Toxicity: No end point data for Minimally Toxic. Based on chemical structure (polymers).
material.
Skin
Acute Toxicity: No end point data for Minimally Toxic. Based on chemical structure (polymers).
material.
Skin Corrosion/Irritation: No end point data Negligible irritation to skin at ambient temperatures. Based on
for material. chemical structure (polymers).
Eye
Serious Eye Damage/Irritation: No end point May cause mild, short-lasting discomfort to eyes. Based on
data for material. chemical structure (polymers).
Sensitisation
Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.
for material.
Skin Sensitization: No end point data for Not expected to be a skin sensitizer. Based on chemical structure
material. (polymers).
Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-
chemical properties of the material.
Germ Cell Mutagenicity: No end point data Not expected to be a germ cell mutagen. Based on chemical
for material. structure (polymers).
Carcinogenicity: No end point data for Not expected to cause cancer. Based on chemical structure
material. (polymers).
Reproductive Toxicity: No end point data Not expected to be a reproductive toxicant. Based on chemical
for material. structure (polymers).
Lactation: No end point data for material. Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for Not expected to cause organ damage from a single exposure.
material.
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Repeated Exposure: No end point data for Not expected to cause organ damage from prolonged or repeated
material. exposure. Based on chemical structure (polymers).

OTHER INFORMATION
For the product itself:

Dust may be irritating to the eyes and respiratory tract.

Elevated temperatures or mechanical action may form vapours, mists or fumes which may be irritating to the eyes and
respiratory tract.
Contains:
Additives that are encapsulated in the polymer. Under the normal conditions for processing and use of this polymer the
encapsulated additives are not expected to pose any health hazard. However, grinding of the polymer is not
recommended without the use of appropriate measures to control exposure (see Section 8 - Engineering Controls).

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

12.1. TOXICITY
Material -- Not expected to be harmful to aquatic organisms.
Material -- Not expected to demonstrate chronic toxicity to aquatic organisms

12.2. PERSISTENCE AND DEGRADABILITY

Biodegradation:
Material -- Expected to be persistent.

12.3. BIOACCUMULATIVE POTENTIAL

Material -- Potential to bioaccumulate is low.

12.4. MOBILITY IN SOIL

Material -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to
sediment and wastewater solids.

12.5. PERSISTENCE, BIOACCUMULATION AND TOXICITY FOR SUBSTANCE(S)

This product is not, or does not contain, a substance that is a PBT or a vPvB.

12.6. OTHER ADVERSE EFFECTS

No adverse effects are expected.
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SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

13.1. WASTE TREATMENT METHODS

Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.

REGULATORY DISPOSAL INFORMATION

European Waste Code: 08 04 10

NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).

SECTION 14 TRANSPORT INFORMATION

LAND (ADR/RID): 14.1-14.6 Not Regulated for Land Transport

INLAND WATERWAYS (ADNR/ADN): 14.1-14.6 Not Regulated for Inland Waterways Transport

SEA (IMDG): 14.1-14.6 Not Regulated for Sea Transport according to IMDG-Code

SEA (MARPOL 73/78 Convention - Annex II):

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not classified according to Annex II

AIR (IATA): 14.1-14.6 Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS

Listed or exempt from listing/notification on the following chemical inventories: TSCA

15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE

SUBSTANCE OR MIXTURE
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Applicable EU Directives and Regulations:

1907/2006 [... on the Registration, Evaluation, Authorisation and Restriction of Chemicals ... and
amendments thereto]
1272/2008 [on classification, labelling and packaging of substances and mixtures.. and amendments
thereto]

15.2. CHEMICAL SAFETY ASSESSMENT

REACH Information: A Chemical Safety Assessment has not been carried out for any of the substances present in the
material.

SECTION 16 OTHER INFORMATION

REFERENCES: Sources of information used in preparing this SDS included one or more of the following: results from
in house or supplier toxicology studies, CONCAWE Product Dossiers, publications from other trade associations, such
as the EU Hydrocarbon Solvents REACH Consortium, U.S. HPV Program Robust Summaries, the EU IUCLID Data
Base, U.S. NTP publications, and other sources, as appropriate.

List of abbreviations and acronyms that could be (but not necessarily are) used in this safety data sheet:
Acronym Full text
N/A Not applicable
N/D Not determined
NE Not established
VOC Volatile Organic Compound
AICS Australian Inventory of Chemical Substances
AIHA WEEL American Industrial Hygiene Association Workplace Environmental Exposure Limits
ASTM ASTM International, originally known as the American Society for Testing and Materials (ASTM)
DSL Domestic Substance List (Canada)
EINECS European Inventory of Existing Commercial Substances
ELINCS European List of Notified Chemical Substances
ENCS Existing and new Chemical Substances (Japanese inventory)
IECSC Inventory of Existing Chemical Substances in China
KECI Korean Existing Chemicals Inventory
NDSL Non-Domestic Substances List (Canada)
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances
TLV Threshold Limit Value (American Conference of Governmental Industrial Hygienists)
TSCA Toxic Substances Control Act (U.S. inventory)
UVCB Substances of Unknown or Variable composition, Complex reaction products or Biological materials
LC Lethal Concentration
LD Lethal Dose
LL Lethal Loading
EC Effective Concentration
EL Effective Loading
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NOEC No Observable Effect Concentration
NOELR No Observable Effect Loading Rate

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Section 07: Materials/Coatings - Suitable information was modified.

Section 07: Suitable Containers information was modified.
Section 09: Physical State information was modified.
Section 16: Materials Covered information was modified.

THIS SDS COVERS THE FOLLOWING MATERIALS: Aliphatic Hydrocarbon Resins. Names of individual grades
consist of the base polymer name or the base polymer name plus a suffix as an additional identifier. | Base polymers :
| ECR 288 | ESCOREZ 1000 | ESCOREZ 1102 | ESCOREZ 1202 | ESCOREZ 1204 | ESCOREZ 1304 |
ESCOREZ 1306 | ESCOREZ 1310 | ESCOREZ 1315 | ESCOREZ 1401 | Suffixes: | C | LC | LS | OFF-SPEC
| P | POWDER | PP | RECOVERED | RESIN DUST | RESIN SWEEPINGS | RM | S | TRANSITION
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

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Internal Use Only

MHC: 0, 0, 0, 0, 0, 0

DGN: 4408967MGB (1007644)

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ANNEX
Annex not required for this material.