Safety Data Sheet: Basonat® HI 100 NG

Download as pdf or txt
Download as pdf or txt
You are on page 1of 17

Safety data sheet

Page: 1/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1. Product identifier

Basonat® HI 100 NG
Chemical name: Hexane, 1,6-diisocyanato-, homopolymer
CAS Number: 28182-81-2

REACH registration number: 01-2119485796-17-0004

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Intermediate (isolated), Hardener for coating materials or adhesives for
industrial or professional use, Isocyanate used in the manufacturing of polyurethanes
Uses advised against: All consumer uses are strongly advised against., The hazardous properties of
the substance require safety measures which can, in principle, not be sufficiently ensured in the
home worker sector.

For the detailed identified uses of the product see appendix of the safety data sheet.

1.3. Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Regional Business Unit Dispersions and
Resins Europe

Telephone: +49 621 60-72509


E-mail address: ed-psr@basf.com

1.4. Emergency telephone number


Page: 2/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
International emergency number:
Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Acute Tox. 4 (Inhalation - mist)


Skin Sens. 1
STOT SE 3 (irritating to respiratory system)

H332, H317, H335

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

Globally Harmonized System, EU (GHS)

Pictogram:

Signal Word:
Warning

Hazard Statement:
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

Precautionary Statements (Prevention):


P280 Wear protective gloves.
P271 Use only outdoors or in a well-ventilated area.
P260 Do not breathe dust/gas/mist/vapours.
P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary Statements (Response):


Page: 3/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or
doctor/physician.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P362 + P364 Take off contaminated clothing and wash it before reuse.

Precautionary Statements (Storage):


P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

Precautionary Statements (Disposal):


P501 Dispose of contents and container to hazardous or special waste
collection point.

Labeling of special preparations (GHS):


EUH204: Contains isocyanates. May produce an allergic reaction. EUH208: May produce an allergic
reaction. Contains: hexamethylene-di-isocyanate

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: (OLIGOMER) Hexamethylene diisocyanate


isocyanurate-type oligomers

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

No specific dangers known, if the regulations/notes for storage and handling are considered.

SECTION 3: Composition/Information on Ingredients


3.1. Substances

Chemical nature

(OLIGOMER) Hexamethylene diisocyanate isocyanurate-type oligomers


CAS Number: 28182-81-2

Hazardous ingredients (GHS)


according to Regulation (EC) No. 1272/2008

(OLIGOMER) Hexamethylene diisocyanate isocyanurate-type oligomers


Page: 4/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Content (W/W): >= 95 % - <= 100 Acute Tox. 4 (Inhalation - mist)
% Skin Sens. 1
CAS Number: 28182-81-2 STOT SE 3 (irr. to respiratory syst.)
H332, H317, H335

hexamethylene-di-isocyanate
Content (W/W): < 0.1 % Acute Tox. 4 (oral)
CAS Number: 822-06-0 Acute Tox. 1 (Inhalation - mist)
EC-Number: 212-485-8 Skin Corr./Irrit. 2
INDEX-Number: 615-011-00-1 Eye Dam./Irrit. 2
Resp. Sens. 1
Skin Sens. 1
STOT SE 3 (irr. to respiratory syst.)
H319, H315, H330, H302, H334, H317, H335

Specific concentration limit:


Skin Sens. 1: >= 0.5 %
Resp. Sens. 1: >= 0.5 %

For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.

3.2. Mixtures

Not applicable

SECTION 4: First-Aid Measures


4.1. Description of first aid measures
Immediately remove contaminated clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.

On skin contact:
Wash thoroughly with soap and water

On contact with eyes:


Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.

On ingestion:
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison
control center or doctor.
Page: 5/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Inhale corticosteroid dose aerosol. Treat according to symptoms (decontamination, vital
functions), no known specific antidote, administer corticosteroid dose aerosol to prevent pulmonary
odema.

SECTION 5: Fire-Fighting Measures


5.1. Extinguishing media
Suitable extinguishing media:
dry powder, foam

5.2. Special hazards arising from the substance or mixture


harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

5.3. Advice for fire-fighters


Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

SECTION 6: Accidental Release Measures


6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective clothing.

6.2. Environmental precautions


Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

6.3. Methods and material for containment and cleaning up


For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.

6.4. Reference to other sections


Page: 6/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage


7.1. Precautions for safe handling
No special measures necessary provided product is used correctly.

Protection against fire and explosion:


Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.

7.2. Conditions for safe storage, including any incompatibilities


Further information on storage conditions: Keep container tightly closed and in a cool place.

Storage stability:
If moisture enters isocyanate containers, CO2 forms and pressure builds up.

7.3. Specific end use(s)


See exposure scenario(s) in the attachment to this safety data sheet.

SECTION 8: Exposure Controls/Personal Protection


8.1. Control parameters

Components with occupational exposure limits

822-06-0: hexamethylene-di-isocyanate

PNEC
freshwater: 0.127 mg/l

marine water: 0.0127 mg/l

intermittent release: 1.27 mg/l

sediment (freshwater): 266700 mg/kg

marine water: 26670 mg/kg

soil: 53182 mg/kg

STP: 38.28 mg/l

DNEL
Page: 7/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
worker:
Short-term exposure - local effects, Inhalation: 1 mg/m3

worker:
Long-term exposure - local effects, Inhalation: 0.5 mg/m3

8.2. Exposure controls


Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of
organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures


Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment.

SECTION 9: Physical and Chemical Properties


9.1. Information on basic physical and chemical properties

Form: liquid
Colour: colourless to yellowish
Odour: almost odourless
Odour threshold:
Not determined due to potential
health hazard by inhalation.
pH value:
not applicable
solidification temperature: -70 °C (DSC (DIN 51007))
Boiling range: 300 - 355 °C
Flash point: 237.5 °C (DIN EN 22719; ISO 2719)
Page: 8/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Evaporation rate:
not determined
Flammability: not flammable
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 438 °C (DIN EN 14522)
Vapour pressure: 3 mbar
(20 °C)
Density: 1.168 g/cm3 (ISO 2811-3)
(20 °C)
Relative density: 1.168
(20 °C)
Relative vapour density (air):
not determined
Solubility in water: Reacts with water.
not soluble
Solubility (qualitative) solvent(s): organic solvents
soluble
Partitioning coefficient n-octanol/water (log Kow): 9.81 (calculated)
Self ignition: not self-igniting

Thermal decomposition: 140 °C, 10 kJ/kg, (DSC (DIN 51007))


The indicated value is for inert gas atmosphere.
290 °C, 280 kJ/kg, (DSC (DIN 51007))
The indicated value is for inert gas atmosphere.
425 °C, > 70 kJ/kg, (DSC (DIN 51007))
The indicated value is for inert gas atmosphere.
20 - 145 °C, 0 kJ/kg, (Warm storage test)
No exothermic decomposition within the mentioned temperature range.
125 °C, 550 J/g, (DSC (DIN 51007))
Oxidization on contact with air above the mentioned temperature.
Viscosity, dynamic: 3,000 mPa.s
(23 °C)
Viscosity, kinematic: 4,760 mm2/s
(20 °C)
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating

9.2. Other information

Miscibility with water:


Reacts with water.
Hygroscopy: hygroscopic
Adsorption/water - soil: log KOC: 7.3 - 7.8 (calculated)
Page: 9/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Surface tension:
Based on chemical structure, surface
activity is not to be expected.
Grain size distribution: The substance / product is marketed or used in a non solid or
granular form.

SECTION 10: Stability and Reactivity


10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability


The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions


Reacts with alcohols. Reacts with amines. Reacts with substances which contain active hydrogen.
Reacts with water, with formation of carbon dioxide. The formation of gaseous decomposition
products builds up pressure in tightly closed containers.

10.4. Conditions to avoid


Avoid moisture. See SDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:
water, alcohols, amines

10.6. Hazardous decomposition products

Hazardous decomposition products:


No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information


11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:


Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Of moderate
toxicity after short-term inhalation.

Experimental/calculated data:
LD50 rat (oral): > 2,500 mg/kg (OECD Guideline 423)

LC50 rat (by inhalation): 0.467 mg/l 4 h (OECD Guideline 403)


Page: 10/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
The test result applies only to the substance transferred into respirable aerosol (particles < 20 µm).
The substance from the isocyanate substance class has been tested in a form (respirable aerosol)
that is different from the forms in which the product is placed on the market and used. Therefore, the
test result is not adequate for the purpose of classification and labelling of the product. Based on
expert judgement and available data, a modified classification and labeling for acute inhalation
toxicity is justified. The generation of a respirable aerosol must be prevented!

LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:


May cause slight irritation to the skin. May cause slight irritation to the eyes.

Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)

Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:
Caused skin sensitization in animal studies.

Experimental/calculated data:
Guinea pig maximization test guinea pig: skin sensitizing
sensitizing effect in animal tests

Germ cell mutagenicity

Assessment of mutagenicity:
The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell
culture.

Carcinogenicity

Assessment of carcinogenicity:
Study scientifically not justified.

Reproductive toxicity

Assessment of reproduction toxicity:


Study scientifically not justified.

Developmental toxicity

Assessment of teratogenicity:
Study scientifically not justified.
Page: 11/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Specific target organ toxicity (single exposure)

Assessment of STOT single:


Causes temporary irritation of the respiratory tract.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:


After repeated exposure the prominent effect is local irritation.

Aspiration hazard

No aspiration hazard expected.

SECTION 12: Ecological Information


12.1. Toxicity

Assessment of aquatic toxicity:


The inhibition of the degradation activity of activated sludge is not anticipated when introduced to
biological treatment plants in appropriate low concentrations. There is a high probability that the
product is not acutely harmful to aquatic organisms.
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations. The product may hydrolyse. The test result
maybe partially due to degradation products.

Toxicity to fish:
LC0 (96 h) >= 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 92/69/EEC, C.1, static)
The product may hydrolyse. The test result maybe partially due to degradation products. The product
has low solubility in the test medium. An eluate has been tested. Nominal concentration.

Aquatic invertebrates:
EL50 (48 h) 127 mg/l, Daphnia magna (Directive 92/69/EEC, C.2, static)
Nominal concentration. The product may hydrolyse. The test result maybe partially due to
degradation products.

Aquatic plants:
EC50 (72 h) > 1,000 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static)
Nominal concentration. The product may hydrolyse. The test result maybe partially due to
degradation products.

Microorganisms/Effect on activated sludge:


EC20 (3 h) 880 mg/l, (OECD Guideline 209, static)
Nominal concentration. The product may hydrolyse. The test result maybe partially due to
degradation products.
Page: 12/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Chronic toxicity to fish:
Study not necessary due to exposure considerations.

Chronic toxicity to aquatic invertebrates:


Study not necessary due to exposure considerations.

Assessment of terrestrial toxicity:


No data available concerning terrestrial toxicity.
Study not necessary due to exposure considerations.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):


Poorly biodegradable. The product is unstable in water. The elimination data also refer to products of
hydrolysis.

Elimination information:
1 % BOD of the ThOD (28 d) (OECD 301D; EEC 92/69, C.4-E) (aerobic, activated sludge, domestic,
non-adapted)

Assessment of stability in water:


In contact with water the substance will hydrolyse rapidly.
Information on Stability in Water (Hydrolysis):
t1/2 < 1 h, (OECD Guideline 111, pH 4)

t1/2 < 1 h, (OECD Guideline 111, pH 7)

t1/2 < 1 h, (OECD Guideline 111, pH 9)

12.3. Bioaccumulative potential

Assessment bioaccumulation potential:


Significant accumulation in organisms is not to be expected.
The product has not been tested. The statement has been derived from the structure of the product.

Bioaccumulation potential:
Bioconcentration factor: 367.7, Fish (calculated)
Analogous: Assessment derived from products with similar chemical character.

12.4. Mobility in soil

Assessment transport between environmental compartments:


Volatility: The substance will not evaporate into the atmosphere from the water surface.
Adsorption in soil: No data available.

12.5. Results of PBT and vPvB assessment

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT
Page: 13/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification

12.6. Other adverse effects

The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.

12.7. Additional information

Other ecotoxicological advice:


Do not release untreated into natural waters. The local regulations on waste-water treatment must be
followed.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Refer to manufacturer/supplier for information on recovery/recycling.

SECTION 14: Transport Information

Land transport

ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Page: 14/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Inland waterway transport


ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user:

Transport in inland waterway vessel


Not evaluated

Sea transport

IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport

IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Page: 15/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020

14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name


See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)


See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group


See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards


See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

14.6. Special precautions for user


See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

SECTION 15: Regulatory Information


15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

Prohibitions, Restrictions and Authorizations

Annex XVII of Regulation (EC) No 1907/2006: Number on List: 3

Directive 2012/18/EU - Control of Major Accident Hazards involving dangerous substances (EU):
Listed in above regulation: no

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

15.2. Chemical Safety Assessment


Page: 16/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020

Chemical Safety Assessment performed

SECTION 16: Other Information

This product is of industrial quality and unless otherwise specified or agreed intended exclusively for
industrial use. This includes the mentioned and recommended usage. Any other intended
applications should be discussed with the manufacturer. In particular this concerns the application for
products that are the object of special standards and regulations.

The product is used mainly as a hardener in coating materials or adhesives. The handling of coating
materials or adhesives containing reactive polyisocyanates and residual monomeric HDI requires
appropriate protective measures referred to in this safety data sheet. These products may therefore
be used only in industrial or trade applications. They are not suitable for use in homeworker (DIY)
applications.

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Acute Tox. Acute toxicity
Skin Sens. Skin sensitization
STOT SE Specific target organ toxicity — single exposure
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
Resp. Sens. Respiratory sensitization
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H330 Fatal if inhaled.
H302 Harmful if swallowed.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Abbreviations
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland
waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract
Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German
national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective
concentration median for 50% of the population. EC = European Community. EN = European Standards.
IARC = International Agency for Research on Cancer. IATA = International Air Transport Association.
IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code.
ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal
concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population.
TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution
from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational
Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent,
Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The
Page: 17/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time
Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very
Bioaccumulative.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.

You might also like