Safety Data Sheet: Basonat® HI 100 NG
Safety Data Sheet: Basonat® HI 100 NG
Safety Data Sheet: Basonat® HI 100 NG
Page: 1/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Basonat® HI 100 NG
Chemical name: Hexane, 1,6-diisocyanato-, homopolymer
CAS Number: 28182-81-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Intermediate (isolated), Hardener for coating materials or adhesives for
industrial or professional use, Isocyanate used in the manufacturing of polyurethanes
Uses advised against: All consumer uses are strongly advised against., The hazardous properties of
the substance require safety measures which can, in principle, not be sufficiently ensured in the
home worker sector.
For the detailed identified uses of the product see appendix of the safety data sheet.
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Regional Business Unit Dispersions and
Resins Europe
For the classifications not written out in full in this section the full text can be found in section 16.
Pictogram:
Signal Word:
Warning
Hazard Statement:
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
No specific dangers known, if the regulations/notes for storage and handling are considered.
Chemical nature
hexamethylene-di-isocyanate
Content (W/W): < 0.1 % Acute Tox. 4 (oral)
CAS Number: 822-06-0 Acute Tox. 1 (Inhalation - mist)
EC-Number: 212-485-8 Skin Corr./Irrit. 2
INDEX-Number: 615-011-00-1 Eye Dam./Irrit. 2
Resp. Sens. 1
Skin Sens. 1
STOT SE 3 (irr. to respiratory syst.)
H319, H315, H330, H302, H334, H317, H335
For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.
3.2. Mixtures
Not applicable
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water
On ingestion:
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison
control center or doctor.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Inhale corticosteroid dose aerosol. Treat according to symptoms (decontamination, vital
functions), no known specific antidote, administer corticosteroid dose aerosol to prevent pulmonary
odema.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
Storage stability:
If moisture enters isocyanate containers, CO2 forms and pressure builds up.
822-06-0: hexamethylene-di-isocyanate
PNEC
freshwater: 0.127 mg/l
DNEL
Page: 7/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
worker:
Short-term exposure - local effects, Inhalation: 1 mg/m3
worker:
Long-term exposure - local effects, Inhalation: 0.5 mg/m3
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
Form: liquid
Colour: colourless to yellowish
Odour: almost odourless
Odour threshold:
Not determined due to potential
health hazard by inhalation.
pH value:
not applicable
solidification temperature: -70 °C (DSC (DIN 51007))
Boiling range: 300 - 355 °C
Flash point: 237.5 °C (DIN EN 22719; ISO 2719)
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Evaporation rate:
not determined
Flammability: not flammable
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 438 °C (DIN EN 14522)
Vapour pressure: 3 mbar
(20 °C)
Density: 1.168 g/cm3 (ISO 2811-3)
(20 °C)
Relative density: 1.168
(20 °C)
Relative vapour density (air):
not determined
Solubility in water: Reacts with water.
not soluble
Solubility (qualitative) solvent(s): organic solvents
soluble
Partitioning coefficient n-octanol/water (log Kow): 9.81 (calculated)
Self ignition: not self-igniting
Substances to avoid:
water, alcohols, amines
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 2,500 mg/kg (OECD Guideline 423)
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Respiratory/Skin sensitization
Assessment of sensitization:
Caused skin sensitization in animal studies.
Experimental/calculated data:
Guinea pig maximization test guinea pig: skin sensitizing
sensitizing effect in animal tests
Assessment of mutagenicity:
The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell
culture.
Carcinogenicity
Assessment of carcinogenicity:
Study scientifically not justified.
Reproductive toxicity
Developmental toxicity
Assessment of teratogenicity:
Study scientifically not justified.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Specific target organ toxicity (single exposure)
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Aspiration hazard
Toxicity to fish:
LC0 (96 h) >= 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 92/69/EEC, C.1, static)
The product may hydrolyse. The test result maybe partially due to degradation products. The product
has low solubility in the test medium. An eluate has been tested. Nominal concentration.
Aquatic invertebrates:
EL50 (48 h) 127 mg/l, Daphnia magna (Directive 92/69/EEC, C.2, static)
Nominal concentration. The product may hydrolyse. The test result maybe partially due to
degradation products.
Aquatic plants:
EC50 (72 h) > 1,000 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static)
Nominal concentration. The product may hydrolyse. The test result maybe partially due to
degradation products.
Elimination information:
1 % BOD of the ThOD (28 d) (OECD 301D; EEC 92/69, C.4-E) (aerobic, activated sludge, domestic,
non-adapted)
Bioaccumulation potential:
Bioconcentration factor: 367.7, Fish (calculated)
Analogous: Assessment derived from products with similar chemical character.
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification
The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Refer to manufacturer/supplier for information on recovery/recycling.
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Page: 14/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
Directive 2012/18/EU - Control of Major Accident Hazards involving dangerous substances (EU):
Listed in above regulation: no
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
This product is of industrial quality and unless otherwise specified or agreed intended exclusively for
industrial use. This includes the mentioned and recommended usage. Any other intended
applications should be discussed with the manufacturer. In particular this concerns the application for
products that are the object of special standards and regulations.
The product is used mainly as a hardener in coating materials or adhesives. The handling of coating
materials or adhesives containing reactive polyisocyanates and residual monomeric HDI requires
appropriate protective measures referred to in this safety data sheet. These products may therefore
be used only in industrial or trade applications. They are not suitable for use in homeworker (DIY)
applications.
Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Acute Tox. Acute toxicity
Skin Sens. Skin sensitization
STOT SE Specific target organ toxicity — single exposure
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
Resp. Sens. Respiratory sensitization
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H330 Fatal if inhaled.
H302 Harmful if swallowed.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Abbreviations
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road.
ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland
waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract
Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German
national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective
concentration median for 50% of the population. EC = European Community. EN = European Standards.
IARC = International Agency for Research on Cancer. IATA = International Air Transport Association.
IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code.
ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal
concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population.
TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution
from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational
Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent,
Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The
Page: 17/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 17.02.2020 Version: 2.1
Date previous version: 02.08.2019 Previous version: 2.0
Product: Basonat® HI 100 NG
(ID no. 30567108/SDS_GEN_EU/EN)
Date of print 18.02.2020
European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time
Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very
Bioaccumulative.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.