Answer: Step 1

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Question

Answer
Step 1
a)

Step 2
Calculate the number of moles in the binary mixture .

Here, number of moles of species 1 is , and number of moles of species 2 is .

Substitute for , and for .

Step 3
Calculate the mole fraction of species 1 .

Substitute for and for .

Calculate the mole fraction of species 2 .

Substitute for and for .

Step 4
Express the reported molar enthalpy of liquid mixture.

…… (1)

Here, temperature is T.

Step 5
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Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream a .

Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream b .

Step 6
Express the energy balance equation for adiabatic process.

Here, flow rate of moles of stream a is , flow rate of moles of stream b is , flow rate of moles of output mixture
is , and enthalpy of output mixture is .

Substitute for , for , for , for , for ,


for , 0.8 for , and 0.2 for .

Hence, the temperature of the outlet stream is .

Step 7
b)

Express the enthalpy of the binary mixture .

Substitute for h, for , for , for .

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…… (2)

Step 8
Differentiate Equation (2) partially with respect to and calculate the partial molar enthalpy of species 1 .

…… (3)

Step 9
Substitute for T, and 0.5 for both and .

Step 10
Hence, the partial molar enthalpy of species 1 is .

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Step 11
c)

Step 12
In Equation (2), substitute 1 for , 0 for and calculate the partial molar volume of species 1 at infinite dilution
.

Substitute for T.

Hence, the partial molar volume of species 1 at infinite dilution is .

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