Answer: Step 1
Answer: Step 1
Answer: Step 1
eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlh…
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Question
Answer
Step 1
a)
Step 2
Calculate the number of moles in the binary mixture .
Step 3
Calculate the mole fraction of species 1 .
Step 4
Express the reported molar enthalpy of liquid mixture.
…… (1)
Here, temperature is T.
Step 5
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Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream a .
Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream b .
Step 6
Express the energy balance equation for adiabatic process.
Here, flow rate of moles of stream a is , flow rate of moles of stream b is , flow rate of moles of output mixture
is , and enthalpy of output mixture is .
Step 7
b)
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…… (2)
Step 8
Differentiate Equation (2) partially with respect to and calculate the partial molar enthalpy of species 1 .
…… (3)
Step 9
Substitute for T, and 0.5 for both and .
Step 10
Hence, the partial molar enthalpy of species 1 is .
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Step 11
c)
Step 12
In Equation (2), substitute 1 for , 0 for and calculate the partial molar volume of species 1 at infinite dilution
.
Substitute for T.
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