SAFETY DATA SHEET

This SDS adheres to the standards and regulatory requirements of the United States and may not meet
the regulatory requirements in other countries.

1. Identification
Product identifier Sodium Chlorate Process Liquor De-chromed SN
Other means of identification De-chromed blend of Crystallizer Feed Liquor and Mother Liquor,
NaClO3
Recommended use For internal transfer between ERCO Worldwide sodium chlorate
manufacturing facilities for process purposes
Recommended restrictions None known
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ERCO Worldwide
Address 335 Carlingview Drive
Unit 1
Etobicoke, M9W 5G8
Canada
Telephone Information #: (416) 239-7111 (M- F: 8:00 am – 5:00pm EST)
Website http://www.ercoworldwide.com
E-mail productinfo@ercoworldwide.com
Emergency phone number Canada & USA: 1-800-424-9300 (CHEMTREC)
Supplier Refer to Manufacturer

2. Hazard(s) Identification
Physical hazards Oxidizing liquids Category 2

Health hazards Acute toxicity, oral Category 4

Environmental hazards Not currently regulated by OSHA, refer to Section 12 for additional
information.

OSHA defined hazards This mixture does not meet the classification criteria according to OSHA
HazCom 2012.

Label elements

Signal word Danger

Hazard statement May intensify fire; oxidizer.

Harmful if swallowed.

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Precautionary statement
Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Keep away from clothing and other combustible
materials. Wear protective gloves, protective clothing, eye protection, face
protection.

Response IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and
wash it before reuse.

In case of fire: Use water to extinguish.

Call a POISON CENTER or doctor/physician if you feel unwell.

Storage Does not apply.

Disposal Dispose of contents and containers in accordance with

local/regional/national/international regulations.

Hazard(s) not otherwise No OSHA defined hazard classes.

classified (HNOC) Other hazards which do not result in classification:
May cause mild skin and eye irritation.

Supplemental Not applicable

information

3. Composition/Information on Ingredients
Chemical name Common name and synonyms CAS number Conc. % By Weight
Sodium Chlorate De-chromed blend of 7775-09-9 30-50 w/w%
Crystallizer; Feed Liquor and
Mother Liquor
Dihydrogen oxide Water 7732-18-5 Balance

Chemical name of impurities, stabilizing solvents and/or additives: None

4. First-Aid Measures
Inhalation Remove person to fresh air and keep comfortable for breathing. If not
breathing, give artificial respiration. If breathing is difficult, trained
personnel should give oxygen. Call a POISON CENTER or doctor/physician if
you feel unwell.

Skin Contact Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Call a POISON
CENTER or doctor/physician if you feel unwell.

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Eye Contact Immediately flush eyes with plenty of water for at least 20 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.

Ingestion Rinse mouth. Do not induce vomiting. Never give anything by mouth to a
victim who is unconscious or is having convulsions.
If the patient is conscious, give one or two glasses of water to dilute stomach
contents. Call a POISON CENTER or doctor/physician if you feel unwell.

Most important May cause mild eye irritation. Symptoms may include redness and itching.
symptoms/effects, May cause irritation to the nose, throat and upper respiratory tract.
acute and delayed Symptoms may include coughing, choking and wheezing. May be harmful or
fatal if swallowed. Symptoms may include cyanosis (bluish discoloration of
the skin), nervous system damage, lung inflammation and pulmonary edema
(fluid accumulation). Symptoms may include pain, headache, nausea,
vomiting, dizziness, drowsiness and other central nervous system effects.
Prolonged or repeated exposure may cause blood system effects. Prolonged
or repeated overexposure may cause kidney effects.

Indication of immediate Provide general supportive measures and treat symptomatically.

medical attention and
special treatment
needed

General information In the case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible). Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves.

5. Fire-Fighting Measures
Suitable extinguishing Water spray, fog (flooding amounts).
media

Unsuitable DO NOT use dry chemical fire extinguishing agents containing ammonium
extinguishing media compounds (such as some A:B:C agents), since an explosive compound can
be formed. DO NOT use carbon dioxide, dry chemical powder or other
extinguishing agents that smother flames, since they are not effective in
extinguishing fires involving oxidizers.

Specific hazards arising Strong oxidizer - contact with other material may cause fire. May cause fire
from the chemical or explosion; strong oxidizer.

Special protective Firefighters must use standard protective equipment including flame
equipment and retardant coat, helmet with face shield, gloves, rubber boots, and in
precautions for enclosed spaces, SCBA.
firefighters

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Firefighting Firefighters must use standard protective equipment including flame

equipment/instructions retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. In case of fire: Evacuate area. Fight fire remotely due
to the risk of explosion. In the event of fire, cool tanks with water spray.
Move containers from fire area if you can do so without risk. Containers
should be cooled with water to prevent vapor pressure build up. Do not
allow run-off from firefighting to enter drains or water courses. Dike for
water control.

Specific methods Cool containers exposed to flames with water until well after the fire is out.

General fire hazards May intensify fire; oxidizer.

Hazardous combustion Pure sodium chlorate decomposes explosively under intense fire conditions.
products It initially decomposes to sodium perchlorate and begins to liberate oxygen
at about 265°C. Besides oxygen, other compounds formed in a fire include
chlorine, hydrogen chloride and sodium oxide.

6. Accidental Release Measures

Personal precautions, Eliminate all ignition sources (no smoking, flares, sparks, or flames in
protective equipment immediate area). Immediately evacuate personnel to safe areas. Ensure
and emergency clean-up is conducted by trained personnel only. Wear appropriate
procedures protective equipment and clothing during clean-up. Ventilate the
contaminated area. Do not breathe mist or vapor.

Methods and materials Eliminate all ignition sources (no smoking, flares, sparks, or flames in
for containment and immediate area). Ventilate the contaminated area. Wear appropriate
cleaning up protective equipment and clothing during clean-up. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. Stop leak if you can do it
without risk. Dike far ahead of spill for later disposal. Absorb in vermiculite,
dry sand or earth and place into containers. Prevent entry into waterways,
sewer, basements or confined areas. Following product recovery, flush area
with water. For waste disposal, see section 13 of the SDS.

Environmental Avoid release to the environment. Avoid discharge into drains, water courses
precautions or onto the ground.

7. Handling and Storage

Precautions for safe Do not handle or store near an open flame, heat or other sources of
handling ignition. No smoking in the area. Avoid contamination with organic
materials. Avoid breathing mist or vapor. Avoid contact with eyes, skin and
clothing. Keep away from acids and other incompatibles. Keep containers
closed when not in use. Label containers appropriately. Wash hands after
handling and before eating. Wear protective gloves and eye/face
protection.

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Conditions for safe Storage area should be clearly identified, clear of obstruction and accessible
storage, including any only to trained and authorized personnel. Storage areas should not be
incompatibilities constructed of wood or other organic materials. Do not store wood or other
organic materials in areas that could come in contact with this material.
Keep away from combustible or readily oxidizable materials and acids.

Store in a closed container away from incompatible materials. Keep

quantity stored as small as possible. Post "NO SMOKING" signs in area.
Stored containers should be periodically checked for general condition and
leakage. Protect against physical damage. Keep empty containers in
separate storage area. Empty containers may contain hazardous residues.
Keep closed. Have appropriate fire extinguishers and spill clean-up
equipment in storage area.

8. Exposure Controls/Personal Protection

Occupational Exposure Limits No exposure limits noted for ingredient(s).

Biological limit values No biological exposure limits noted for the ingredient(s).

Appropriate engineering Good general ventilation (typically 10 air changes per hour) should
controls be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or
other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. In case
of insufficient ventilation, wear suitable respiratory equipment.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles). Eye wash fountain
and emergency showers are recommended.

Skin protection
Hand protection Wear appropriate chemical-resistant gloves. Advice should be
sought from glove suppliers.

Other Wear suitable protective clothing. Wear fire/flame

resistant/retardant clothing. For exposures with a high potential of
contact, wear PVC or rubber rain suit, hard hat, rubber or plastic
gloves, rubber boots, and safety glasses or goggles. Do Not Wear
Leather Boots or Gloves.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory

equipment. Use a NIOSH/MSHA approved respirator if there is a risk
of exposure to fume/mists at levels exceeding the exposure limits.
Seek advice from respiratory protection specialists.

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General hygiene considerations When using, do not eat, drink or smoke. Always observe good
personal hygiene measures, such as washing after handling the
material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove
contaminants.

9. Physical and Chemical Properties

Appearance Clear to pale yellow mobile liquid.
Physical state Liquid.
Form Liquid.
Colour Clear to light yellow.
Odor None.
Odor threshold Not available.
pH 6-9
Melting point/Freezing Point -8 °C (17.6 °F) (20% solution)
-18 °C (-0.4 °F) (40% solution)
Initial boiling point and boiling range 102 °C - 108 °C (215.6 °F - 226.4 °F)
Flash point Not applicable.
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit – lower (%) Not applicable.
Flammability limit – upper (%) Not applicable.
Explosive limit – lower (%) Not available.
Explosive limit – upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility (ies)
Solubility (water) Soluble.
Partition coefficient (n-octanol/water) Not available.
Auto-ignition temperature Not applicable.
Decomposition temperature > 265 °C (> 500 °F)
Viscosity Not available.
Other information
Density 1.15 - 1.45 g/cm3
Explosive properties Oxidizer, may have explosive properties
Molecular formula Cl-Na-O3
Molecular weight 106.45 g/mol
Oxidizing properties Strong oxidizer - contact with other material may cause fire.
Percent volatile Not available.
Specific gravity 1.38 – 1.46 (varies according to solution composition)

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10.Stability and Reactivity

Reactivity The product is stable and non-reactive under normal conditions of use,
storage and transport. Can form shock-, heat- or friction-sensitive mixtures
with finely divided metals, metal salts, ammonium salts, non-metals, strong
reducing agents and sulfides. Low pH (acidic) solutions can decompose to
form corrosive and dangerously reactive chlorine dioxide. Decomposes
above 265°C releasing oxygen.

Chemical stability Stable at normal temperatures and pressure. At low pH, solutions
decompose forming corrosive and dangerously reactive chlorine dioxide. In
intense fire situations there have been several cases of violent explosions
attributed to sodium chlorate by itself.

Possibility of hazardous Hazardous polymerization does not occur.

reactions

Conditions to Avoid Heat, sparks, friction, shock, impact, open flames, contact with combustible
materials and acidic pH.

Incompatible materials Combustible material. Organic compounds. Organic lubricants. Strong

acids. Ammonium salts. Reducing agents. Powdered metals.

Hazardous No hazardous decomposition products are known.

decomposition products

11.Toxicological Information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.

Skin contact Causes mild skin irritation.

Eye contact May cause mild eye irritation.

Ingestion Harmful if swallowed.

Delayed and immediate effects and chronic effects from short-term and long-term exposure
Effects of short-term Symptoms may include cyanosis (bluish discoloration of the skin),
(acute) exposure nervous system damage, lung inflammation and pulmonary edema (fluid
accumulation). Symptoms may include pain, headache, nausea, vomiting,
dizziness, drowsiness and other central nervous system effects.
May cause mild eye irritation. Symptoms may include redness and
itching. May cause mild skin irritation. Symptoms may include redness
and itching. May cause irritation to the nose, throat and upper
respiratory tract. Symptoms may include coughing, choking and
wheezing.

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Effects of long-term Prolonged or repeated exposure may cause blood system effects.
(chronic) exposure Prolonged or repeated overexposure may cause kidney effects.

Information on toxicological effects

Acute toxicity See data for individual ingredient acute toxicity data.

Product Species Test Results

Sodium Chlorate Solution 50%
Acute
Other
LD50 Rat 2400 mg/kg (Calculated ATE)

Sodium Chlorate (CAS 7775-09-9)

Acute
Dermal No information available.
Inhalation
LC50 Rat > 7 mg/l (4 hour)
Oral
LD50 Rat 1200 mg/kg
LD50 Mouse 8350 mg/kg
LD50 Rabbit 7200 mg/kg

Skin corrosion/irritation Direct contact can cause mild irritation.

Serious eye damage/eye irritation May cause mild eye irritation. Symptoms may include redness and
itching.

Respiratory or skin sensitization

Respiratory Not expected to be a respiratory sensitizer.
sensitization
Skin sensitizer Not expected to be a respiratory sensitizer.

Germ cell mutagenicity Not expected to be mutagenic.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH,

NTP, or OSHA.
OSHA Specifically Not listed.
Regulated
Substances (29 CFR
1910.1001-1050)

Reproductive toxicity Not classifiable as a reproductive toxin.

Specific target organ toxicity - Hazardous by OSHA criteria.

single exposure Specific Target Organ Toxicity (STOT), Single Exposure Category 3
May cause respiratory irritation.

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Specific target organ toxicity - Not classified as a specific target organ toxicity - repeated
repeated exposure exposure.

Aspiration toxicity Not expected to be an aspiration hazard.

Chronic effects Repeated and prolonged exposure of the skin can cause
dermatitis and blood system effects. Repeated exposure by
inhalation or ingestion may result in toxic effects, which appear
gradually over weeks. Initially there may be abdominal pain,
followed by internal bleeding, destruction of red blood cells, lung
damage, liver damage, and kidney damage. The skin may be
bluish.

12. Ecological Information

Ecotoxicity Not expected to be harmful to aquatic organisms.

Product Species Test Results

Sodium Chlorate (CAS 7775-09-9)
Aquatic
Acute
Crustacea EC50 Water flea (Daphnia magna) > 1000 mg/l, 48 hours
Fish LC50 Rainbow trout, Donaldson trout > 1000 mg/l, 96 hours
(Oncorhynchus mykiss)
Chronic
Algae NOEC Green algae (Selenastrum capricornutum) > 500 mg/l, 72 hours
Crustacea EC50 Water flea (Daphnia magna) > 500 mg/l, 21 days
Fish NOEC Zebra danio (Danio rerio) > 500 mg/l, 35 days

Persistence and Readily biodegradable. Sodium chlorate degrades very slowly in soil
degradability under aerobic conditions. May decompose by microbial degradation
more rapidly under anaerobic conditions.

Bioaccumulative No data available.

potential

Mobility in soil High water solubility indicates a high mobility in soil. Sodium chlorate
can be leached out of soil. Chlorate accumulates in plant cells until toxic
concentrations are reached and the plant dies.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion,
photochemical ozone creation potential, endocrine disruption, global
warming potential) are expected from this component.

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13. Disposal Considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste
disposal site. This material and its container must be disposed of as
hazardous waste. Do not allow this material to drain into sewers/water
supplies. Do not contaminate ponds, waterways or ditches with chemical
or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.

Local disposal Dispose in accordance with all applicable regulations.

regulations

Hazardous waste code The waste code should be assigned in discussion between the user, the
producer and the waste disposal company.

Waste from residues / Dispose of in accordance with local regulations. Empty containers or liners
unused products may retain some product residues. This material and its container must be
disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for
recycling or disposal.
Since emptied containers may retain product residue, follow label
warnings even after container is emptied.

14. Transport Information

DOT
UN number UN2428
UN proper shipping name Sodium chlorate, aqueous solution
Transport hazard class(es)
Class 5.1
Subsidiary risk -
Label(s) 5.1
Packing group II
Special precautions for user Read safety instructions, SDS and emergency
procedures before handing.
Special provisions A2, IB2, T4, TP1
Packaging exceptions 152
Packaging non bulk 203
Packaging bulk 241

IATA
UN number UN 2428
UN proper shipping name Sodium Chlorate, Aqueous Solution
Transport hazard class(es)
Class 5.1
Subsidiary risk -
Packing group II

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Environmental hazards No
ERG Code 5L
Special precautions for user Read safety instructions, SDS and emergency
procedures before handling.
Other information
Passenger and cargo aircraft Allowed
Cargo aircraft only Allowed

IMDG
UN number UN 2428
UN proper shipping name Sodium Chlorate, Aqueous Solution (Sodium
Chlorate)
Transport hazard class(es)
Class 5.1
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant No
EmS F-H, S-Q
Special precautions for user Read safety instructions, SDS and emergency
procedures before handling.
Transport in bulk according to Annex II of Not available.
MARPOL 73/78 and the IBC Code

DOT

IATA; IMDG

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15. Regulatory Information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Not regulated.

Export Notification
(40 CFR 707, Subpt.
D)
CERCLA Hazardous Not listed.
Substance List (40
CFR 302.4)
SARA 304 Not regulated.
Emergency release
notification
OSHA Specifically Not listed.
Regulated
Substances (29 CFR
1910.1001-1050)

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard – No
SARA 302 Extremely Not listed.
Hazardous
Substance 311/312
Hazardous Chemical
SARA 313 (TRI Not regulated.
reporting)

Other federal regulations

Clean Air Act (CAA) Not regulated.
Section 112
Hazardous Air
Pollutants (HAPs)
List
Clean Air Act (CAA) Not regulated.
Section 112(r)
Accidental Release
Prevention (40 CFR
68.130)
Safe Drinking Water Contaminate candidate list.
Act (SDWA)

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US state regulations
US. California Not listed.
Controlled
Substances. CA
Department of
Justice (California
Health and Safety
Code Section 11100)
US. Massachusetts Sodium Chlorate (CAS 7775-09-9)
RTK - Substance List
US. New Jersey Sodium Chlorate (CAS 7775-09-9)
Worker and
Community Right-
to-Know Act
US. Pennsylvania Sodium Chlorate (CAS 7775-09-9)
Worker and
Community Right-
to-Know Law
US. Rhode Island Not regulated.
RTK
US. California California Safe Drinking Water and Toxic Enforcement Act of 1986
Proposition 65 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.

International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Yes
Substances (AICS)
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List No
(NDSL)
China Inventory of Existing Chemical Yes
Substances in China (IECSC)
Europe European Inventory of Existing Yes
Commercial Chemical Substances
(EINECS)
Europe European List of Notified Chemical No
Substances (ELINCS)
Japan Inventory of Existing and New Yes
Chemical Substances (ENCS)
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals Yes
and Chemical Substances (PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Yes
Inventory

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*A "Yes" indicates that all components of this product comply with the inventory requirements
administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from
listing on the inventory administered by the governing country(s).

16.Other Information
Issue date 11/18/2020
Revision # 3
Revision Indicator Updated address in Section 1.
List of abbreviations ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstract Services
CERCLA: Comprehensive Environmental Response, Compensation and
Liability Act of 1980
CFR: Code of Federal Regulations
DOT: Department of Transportation
EPA: Environmental Protection Agency
EPCRA: Emergency Planning and Community Right-to-Know Act
ERG: Emergency Response Guidebook
HSDB® - Hazardous Substances Data Bank
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
IBC: Intermediate Bulk Container
IDLH: immediately dangerous to life or health
IMDG: International Maritime Dangerous Goods
LC: Lethal Concentration
LD: Lethal Dose
NIOSH: National Institute of Occupational Safety and Health
NOEC: No observable effect concentration
NTP: National Toxicology Program
OECD: Organization for Economic Cooperation and Development
OEL: National occupational exposure limits
OSHA: Occupational Safety and Health Administration
PEL: Permissible exposure limit
RCRA: Resource Conservation and Recovery Act
RQ: Reportable Quantity
RTECS: Registry of Toxic Effects of Chemical Substances
SAR: supplied-air respirator
SCBA: self-contained breathing apparatus
SDS: Safety Data Sheet
STEL: Short Term Exposure Limit
TWA: Time Weighted Average
UN: United Nations

References None.

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Disclaimer

Information presented in this SDS is furnished in accordance with OSHA’s Hazard Communication
Standard (HCS) 2012.

This information provided was developed and is provided for educational purposes and is not intended to
be, nor should it be construed as, legal advice or as ensuring compliance with any laws or regulations of
any jurisdiction. ERCO Worldwide, A division of Superior Plus LP (“ERCO”) assumes no responsibility and
shall have no liability for any inaccuracies, errors or omissions in, nor for any damages (including
consequential, or indirect damages), losses, costs, fees, resulting from the use of, or reliance on, any part
of this information. Likewise, ERCO assumes no responsibility for injury to, or the death of, recipient(s) or
users of this information, or for any loss or damage to any property, arising from the use or consideration
of this information. The recipient(s) and users, and each of their respective employees and agents, assume
all responsibility and liability for all such risks, costs, losses, damages, fees, or otherwise, even if caused
by the negligence, omission, default, or error in judgement of ERCO, its agents, subsidiaries, affiliates, or
representatives.

Recipients or users of this information should ensure, and are responsible for, its compliance with the
current state of the law and legislation applicable thereto, and the content of the laws and regulations of
any other jurisdictions, as applicable. Any person receiving or using this SDS is responsible for and must
exercise their own judgment and due diligence in ensuring safe and lawful use and handling of any product
or information, as they assume the risk of using or relying on any information contained herein.

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