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    Recitation - Analytical Chemistry 1

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    LORRAINE ABIGAIL KHOZA
    This document contains information for an analytical chemistry recitation including: 1) A sample analysis to determine the percentage of P2O5 in a sample which resulted in 0.2922 g of PbMoO4 being formed. 2) An analysis of a 1.59-g sample to determine the percentage of potassium iodide, which resulted in 0.0538 g of barium iodate being recovered. 3) Calculations involving solubility products, activities, and concentrations for various compounds in different solutions.

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    Recitation - Analytical Chemistry 1

    Uploaded by

    LORRAINE ABIGAIL KHOZA
    275 views23 pages
    This document contains information for an analytical chemistry recitation including: 1) A sample analysis to determine the percentage of P2O5 in a sample which resulted in 0.2922 g of PbMoO4 being formed. 2) An analysis of a 1.59-g sample to determine the percentage of potassium iodide, which resulted in 0.0538 g of barium iodate being recovered. 3) Calculations involving solubility products, activities, and concentrations for various compounds in different solutions.

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    Recitation_Analytical Chemistry 1

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    This document contains information for an analytical chemistry recitation including: 1) A sample analysis to determine the percentage of P2O5 in a sample which resulted in 0.2922 g of PbMoO4 being formed. 2) An analysis of a 1.59-g sample to determine the percentage of potassium iodide, which resulted in 0.0538 g of barium iodate being recovered. 3) Calculations involving solubility products, activities, and concentrations for various compounds in different solutions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    275 views23 pages

    Recitation - Analytical Chemistry 1

    Uploaded by

    LORRAINE ABIGAIL KHOZA
    This document contains information for an analytical chemistry recitation including: 1) A sample analysis to determine the percentage of P2O5 in a sample which resulted in 0.2922 g of PbMoO4 being formed. 2) An analysis of a 1.59-g sample to determine the percentage of potassium iodide, which resulted in 0.0538 g of barium iodate being recovered. 3) Calculations involving solubility products, activities, and concentrations for various compounds in different solutions.

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    © All Rights Reserved
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    of 23

    2020-2021 Fall Semester

    ANALYTICAL CHEMISTRY 1

    RECITATION 2
    12-29. The phosphorus in a 0.2091-g sample was precipitated as the
    slightly soluble (NH4)3PO4.12MoO3. This precipitate was filtered,
    washed, and then redissolved in acid. Treatment of the resulting
    solution with an excess of Pb2+ resulted in the formation of 0.2922 g of
    PbMoO4. Express the results of this analysis in terms of percent P2O5.
    12-21. The iodide in a sample that also contained chloride was converted to
    iodate by treatment with an excess of bromine:

    The unused bromine was removed by boiling; an excess of barium ion was
    then added to precipitate the iodate:

    In the analysis of a 1.59-g sample, 0.0538 g of barium iodate was recovered.


    Express the results of this analysis as percent potassium iodide.
    10-12. For a solution in which µ= 8.0 x 10-2 calculate
    K’sp for
    (a)AgSCN.
    (b)PbI2.
    (c)La(IO3)3
    10-14. Calculate the solubilities of the following compounds in
    a 0.0333 M solution of Mg(ClO4)2 using (1) activities and (2)
    molar concentrations:
    (a) AgSCN.
    (b) PbI2.
    (c) BaSO4.
    (d) Cd2Fe(CN)6.
    11-12. Calculate the molar solubility of ZnCO3 in a
    solution buffered to a pH of 7.00.
    The following solutions were added to the 250 mL of solution including

    0.04M CH3COOH and 0.06M CH3COONa;

    a) 50.00 mL 0.010 M of HCl

    b) 50.00 mL 0.010 M of NaOH

    Calculate the ph change in the buffer solution? (Ka: 1.75x10-5)


    Calculate the solubility of Ag2CrO4 (Ksp: 1.2x10-12, α for Ag+: 0.25, α for
    CrO4 2-: 0.40 nm)
    a) in water
    b) in 0.050 M NaNO3
    • A solution contains 1 x 10-4 M of both Fe2+ and Cd2+. Sulfide ions are
    slowly added to this solution to precipitate either FeS or CdS.
    Determine which ion precipitates first and the range of S2-
    concentration that will allow a clean separation of the two ions.
    • The analytical concentration of H2S in a solution saturated with H2S(g)
    is 0.10 M. What pH range is necessary for the clean separation
    described in part (b)?

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