CC 13

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CHEM (CC-13)

2021

1. If ionic product is greater than solubility product, the nature of the solution is-
(A)Saturated solution
(B) Unsaturated solution
(C)Super saturated solution
(D) None of these
2. The solubility of Ag2CrO4 at 850Cis 8.0C x10-5moles/litre, the solubility product of
Ag2CrO4 is.
(A)2.048x10-12
(B)1.071x10-10
(C)5.612x10-23
(D)3.870x10-5
3. Hydroformylation is process of:
(A)Addition of formyl group and H-atom to C=C double bond
(B)Addition of ketone to C=C double bond
(C)Addition of H2 to C=C double bond
(D)Insertion of alkyl to acetyl Ligand
4. The Catalyst used in Exxon Process is.
(A)Ni Catalyst
(B)Co catalyst
(C)Pd catalyst
(D)Rh catalyst
5. The catalyst used for oxidation of ethylene to acetaldehyde by Wacker Process.
(A)Ru(PPh3)3Cl2)
(B)[Cu2(CO)8] and H2
(C)PdCl2 andCuCl2
(D)TiCl4 andAlCl3
6. Water gas is the mixture of:
(A) 1:1 CO and H2
(B)1:2 CO and H2
(C) 2:1 CO and H2
(D)None of these
7. syn gas is mixture of following gases.
(A) CO, H2 and H2S
(B) CO, H2and CO2
(C) CO,O2 and CO2
(D)None of these
8. Recovery of NaCl from sea water due to:
(A)Common Ion effect
(B)Solubility product
(C)Solubility
(D)Degree of dissociation
9. The solubility of solute in solution:
(A)Increases with increase in temperature
(B)Decreases with increase in temperature
(C)increases with decrease in temperature
(D) None of these
10. Asphalt or Pitch black is used for.
(A) Dry cleaning
(B)Paint and vanishes
(C) Candle
(D)Manufacture of Oil gases

11. The chemical formula of Zeise salt is:


(A)CH3-CH2-Mg-CH2-CH3
(B)Pb(CH3CH2)4
(C)Fe(C5H5)2
(D)K[PtCl3(C2H4)]
12. The organometallic compound Mn(C5H5)2 is.
(A)Diamagnetic
(B)Paramagnetic
(C)Ferromagnetic
(D) Anti-ferromagnetic
13. In Co(C5H5)2 the hapticity of two Cp moieties.
(A) η5 and η5

(B) η5 and η3

(C) η3and η3

(D) η3 and η1
14. The EAN rule of the compound(C6H6)Cr(CO)4 is.
(A)37
(B)36
(C)78
(D)38
15. The no. of Metal-Metal bond present in the compoundCo4(CO)12 is:
(A) 6
(B) 5
(C) 3
(D) 4
16. The no. of bridge carbonyl present inFe3(CO)12 is.
(A) 2
(B)3
(C) 4
(D) 6

17. The bond order of CO is.


(A) 2
(B) 3
(C) 2.5
(D) 1.5
18. Hybridisation of iron metal in compound Fe(CO)5 is.
(A) sp3
(B) dsp3
(C) d2sp3
(D) sp3d
19. In IR region, frequency of absorption CO group of different metal carbonyl are in the
order:
(A)Fe(CO)5 >Ni(CO)4 >Cr(CO)6
(B)Ni(CO)4 > Fe(CO)5 > Cr(CO)6
(C) Cr(CO)6> Fe(CO)5> Ni(CO)4
(D) Fe(CO)5> Cr(CO)6>Ni(CO)4
20. The reactivity of different metal towards carbon monoxide are in order:

(A)Fe >Ni >Co

(B)Ni >Fe >Co


(C)Ni > Co >Fe
(D)Co >Ni >Fe
21. The EAN of the compound (Me3Si) W(CO)3(π-C5H5) (At.no W=74).
(A)80
(B)82
(C)85
(D)86
22. The chemical formula of Ziegler Natta Catalyst is:
(A)(C2H5)3Al+TiCl4
(B)K[AlCl3(C2H4)]
(C)(PPh3)3RhCl
(D)Pd/BaSO4
23. Ferrocene react with formaldehyde/(CH3)2NH, the reaction is known as.
(A)Mannich reaction
(B)Friedel craft acylation
(C)Friedel craft alkylation
(D)Michael addition
24. Schlenk equilibrium is arises in the preparation of compound:
(A)Grignard reagent
(B)Tollens’s reagent
(C)Schiff’s reagent
(D)Collin’s reagent
25. The chemical formula of Hauser bases is.
(A)Mg(NH2)2
(B)Mg(OH)2
(C)Ca(OH)2
(D)NaOH
26. Which of the following is a example of primary active transport.
(A)Cl- and HCO3-
(B)Na+ K+ ATPase
(C)Na+ H+ exchange
(D)Na+-Ca2+ Exchange.
27. The EAN of Ferrocene is.
(A)32
(B)35
(C)36
(D)38
28. The Sodium pump.
(A)Exchange extracellular Na+ and Intracellular K+
(B) Is an ion Channel
(C) Is important for maintaining a constant cell volume
(D) Can only be inhibited by metabolic process

29. The oxygenated form of haemoglobin is together by which type of bonding:

(A)H2 bonding

(B)Covent bond

(C)Metallic bond

(D)Salt bridges

30. Haemoglobin has which structure of protein.


(A)Primary structure
(B)Secondary structure
(C) Tertiary structure
(D) Quaternary structure

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