Exam 3 Chemistry

Exam IIIB - CHEM 102/014- Solutions
Loyola University Chicago

April 18, 2018
You have 50 minutes to complete the 33 questions on the exam. Choose the best answer
for each question. The double numbered questions count twice and you should mark both
numbers on the answer sheet.
Please use pencil marks for the answer sheet and make sure that it is not too light
and fill in the whole bubble.
Please fill in your name and a 10 digit identification number on your answer sheet.
Good Luck!!
REMOVE THE COVER FROM YOUR CALCULATOR AND PLACE ALL NON-
TEST MATERIALS OUT OF VIEW!!
Supportive material
Please note that both [H+] and [H3O+] are used interchangeably throughout the exam.
[X] means concentration of X in mol/L or M; pressures are measured in atmospheres.
R = 8.314 J/molK
Standard conditions refer to 1M solutions, 1atm gas. When the temperature is not given
assume 298K.
NA = 6.0221 * 1023/mol; Avogadro's Number;
1amu = 1.661* 10-24g
°C = 5/9 (°F -32)
F = 9/5 (°C) +32
273K = 0°C and 298K = 25°C
ACADEMIC HONESTY
By affixing my signature below I acknowledge that I have read and abide by the
demanding standard of personal honesty, drafted by the College of Arts and Sciences at
Loyola University Chicago. I further attest that the work I am submitting with this exam
is solely my own and was developed during the exam. I have used no notes, materials, or
other aids except those permitted by the instructor.
----------------------------------------
1,2) Calculate the pH of a solution prepared by dissolving 0.37mol of formic acid
(HA) and 0.23mol of sodium formate (NaA) in 1L water. Ka(formic acid) = 1.8x10-4.
a) 3.95
b) 2.09
c) 2.30
d) 10.46
e) 3.54
The next six number questions refer to the same equilibrium.
3) 35mL 0.035M benzoic acid are titrated with 0.025M NaOH. Calculate the pH of
the solution before addition of base. Ka Benzoic Acid = 6.28x10-5, pKa = 4.20
a) 2.80
b) 11.18
c) 2.84
d) 9.80
e) 4.20
4) Calculate the pH after addition of 20mL base.
a) 4.20
b) 9.96
c) 7.00
d) 5.78
e) 4.04
5) Calculate the equivalence volume of titrant needed.
a) 25mL
b) 49mL
c) 20mL
d) 50mL
e) 35mL
6,7) Calculate the pH after 49mL of base were added.
a) 5.82
b) 4.20
c) 9.80
d) 8.18
e) 7.00
8) Calculate the pH after addition of 50mL base.
a) 7.00
b) 3.53
c) 4.20
d) 10.47
e) 9.80
9,10) A buffer can be prepared by
a) mixing a weak acid and its conjugated weak base

b) both a) and e) are yielding a buffer.
c) mixing a strong acid and its conjugated strong base
d) mixing a strong acid and a weak acid
e) mixing a weak acid with a strong base
11,12) Calculate the [Ca2+] concentration in a saturated solution of Ca(OH)2 with a pH of

11.35. KspCa(OH)2=3.9x10-11.
a) 3.23x10-3M
b) 2.65M
c) 11.35M
d) 4.97x10-6M
e) 7.85x10-6M
13) __________ is the oxidizing agent in the reaction below.
Cr2O72- + Cl- + 20H+  4Cr3+ + ClO4- + 10H2O
a) Cl-
b) H+
c) ClO4-
d) Cr2O72-
e) Cr3+
14,15) The concentration of iodide ion in a saturated solution of lead(II) iodide

is_____M. Ksp(PbI2)= 1.4x10-8.
a) 1.5x10-3
b) 3.8x10-4
c) 3.0x10-3
d) 1.4x10-8
e) 3.5x10-9
16,17) Given the thermodynamic data in the table at the end, calculate the equilibrium
constant for the reaction:
2 SO2 (g) + O2 (g)  2 SO3 (g)
a) 1.5 x 1020
b) 3 x 1024
c) 1.06
d) 1.95
e) more data are needed.
18,19) The value of ∆G0 at 250C for the decomposition of gaseous sulfur trioxide to solid
elemental sulfur and gaseous oxygen,
2SO3 (g)  2S (s) + 3O2 (g)
is __________ kJ/mol.
a) +370.4
b) -740.8
c) +740.8
d) +185.2
e) -370.4
The next three questions refer to the same equilibrium.
20) A 25mL sample of 0.723M HNO3 is titrated with a 0.273M KOH solution. The
pH after addition of 10.0mL of KOH is______.
a) 7.00
b) 0.44
c) 0.36
d) 3.6x10-4
e) 4.4x10-3
21) A 25mL sample of 0.723M HNO3 is titrated with a 0.273M KOH solution. The
pH after addition of 68mL of KOH is______.
a) 4.92x10-4
b) 2.28
c) 5.28
d) 11.72
e) 7.00
22) A 25mL sample of 0.723M HNO3 is titrated with a 0.273M KOH solution. What
is the equivalence volume of titrant (KOH)?
a) 68mL
b) 25mL
c) 33mL
d) 66.2mL
e) 80mL
23) Based on the table below, which compound has the lowest solubility?
Compound Ksp
CdCO3 5.2x10-12
Cd(OH)2 2.5x10-14
CaF2 3.9x10-11
AgI 8.3x10-17
ZnCO3 1.4x10-11
a) CdCO3
b) Cd(OH)2
c) CaF2
d) ZnCO3
e) AgI
24) ∆S is positive for the reaction __________.
a) 2SO3(g)  2SO2(g) + O2(g)

b) CaO (s) + CO2(g)  CaCO3(s)
c) N2(g) + 3H2(g) 2NH3(g)
d) Ag+(aq) + Cl-(aq)  AgCl(s)
e) H2O(l)  H2O(s)
25) Which one of the following processes produces a decrease in the entropy of the
system?
a) boiling water to form steam
b) dissolution of solid KCl in water
c) freezing water to form ice
d) mixing of two gases into one container
e) melting ice to form water
26,27) Consider the reaction:
Ag+ (aq) + Cl- (aq)  AgCl (s)
determine the temperature (in 0C) above which the reaction is non-spontaneous under
standard conditions (=1M and 1atm).
a) 150.5
b) 1235
c) 1641
d) 432.8
e) 133.0
28,29) What is the balanced equation for the following reaction happening in acidic
solution?
Mn2+(aq) + BiO3-(aq)  MnO4-(aq) + Bi3+(aq)
a) 2Mn2+(aq) + 3BiO3--(aq)  2MnO4-(aq) + 3Bi3+(aq) + O2-(aq)

b) 2Mn (aq) + 5BiO3 (aq) + 14H+
2+ -
 2MnO4-(s) + 5Bi3+(aq) + 7H2O(l)
c) 2Mn2+(aq) + 4OH-(aq) + 3BiO3-(aq)  2MnO4-(s) + 3Bi3+-(aq) +
4H2O(l)
d) Mn2+(aq) + BiO3-(aq) + H2O(l)  MnO4-(s) + Bi3+(aq) + 2H+(aq)
e) Mn2+ + 2H+(aq) + 2BiO3-(aq)  MnO4-(s) + 2HOBi(aq)
30) The equilibrium constant for a reaction is 0.48 at 250C. What is the value of ∆G0
(kJ/mol) at this temperature?
a) 1.8
b) 4.2
c) 1.5x102
d) -4.2
e) more information needed
31) __________ is reduced in the following reaction:
2Cr2O72- + Cl- + 20H+  4Cr3+ + ClO4- + 10H2O
a) Cr2O72-
b) Cl-
c) H+
d) ClO4-
e) Cr3+
32,33) The value of ∆S0 for the decomposition of POCl3 into its constituent elements,
2POCl3 (g)  P2 (g) + O2 (g) + 3Cl2 (g)
is __________ J/K.
a) +321
b) +442
c) +771
d) -321
e) -771
END OF EXAM III
------------------------------------------------------------------------------------------------------------
Thermodynamic data
Species ∆G0f in [kJ/mol] ∆H0f in [kJ/mol] S0 in [J/(molK)]

H2(g) 0 0 130.58
O2(g) 0 0 205.0
CO2(g) -394.4 -393.5 213.6
H2O(l) -237.13 -285.83 69.91
POCl3(g) -502.5 -542.2 325
P2(g) 103.7 144.3 218.1
Cl2(g) 0 0 222.96
S(s) 0 0 31.88
SO2(g) -300.4 -296.9 248.5
SO3(g) -370.4 -395.2 256.2
Ag+(aq) 77.11 105.9 73.93
Cl-(aq) -131.2 -167.2 56.5
AgCl(s) -109.7 -127.0 96.11
http://alpha.chem.umb.edu/chemistry/ch115/Mridula/CHEM
%20116/documents/Chapter19PracticeQuestions.pdf
http://ap.kmacgill.com/wp-
content/uploads/2014/04/ch_16_practice_test_entropy_free_energy.pdf
https://www.unf.edu/~michael.lufaso/chem2046/practice_exam_answers.pdf

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What thermodynamic properties are provided in the table?

Exam IIIB - CHEM 102/014- Solutions

Loyola University Chicago

The next six number questions refer to the same equilibrium.

4) Calculate the pH after addition of 20mL base.

5) Calculate the equivalence volume of titrant needed.

6,7) Calculate the pH after 49mL of base were added.

8) Calculate the pH after addition of 50mL base.

9,10) A buffer can be prepared by

a) mixing a weak acid and its conjugated weak base

11,12) Calculate the [Ca2+] concentration in a saturated solution of Ca(OH)2 with a pH of

13) __________ is the oxidizing agent in the reaction below.

Cr2O72- + Cl- + 20H+  4Cr3+ + ClO4- + 10H2O

14,15) The concentration of iodide ion in a saturated solution of lead(II) iodide

2SO3 (g)  2S (s) + 3O2 (g)

The next three questions refer to the same equilibrium.

24) ∆S is positive for the reaction __________.

a) 2SO3(g)  2SO2(g) + O2(g)

26,27) Consider the reaction:

Ag+ (aq) + Cl- (aq)  AgCl (s)

Mn2+(aq) + BiO3-(aq)  MnO4-(aq) + Bi3+(aq)

a) 2Mn2+(aq) + 3BiO3--(aq)  2MnO4-(aq) + 3Bi3+(aq) + O2-(aq)

2Cr2O72- + Cl- + 20H+  4Cr3+ + ClO4- + 10H2O

2POCl3 (g)  P2 (g) + O2 (g) + 3Cl2 (g)

END OF EXAM III

Species ∆G0f in [kJ/mol] ∆H0f in [kJ/mol] S0 in [J/(molK)]

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