Date Printed: 17/07/2015 Product: 0229B1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0229B1NL

Product Name: ZINC FILLER TYPE II (fka Revision Date: 07/17/2015

SPECIAL ZINC FILLER)
Supercedes Date: 05/30/2015
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - ehs@stoncor.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Hazardous to the aquatic environment, Acute, category 1

Hazardous to the aquatic environment, Chronic, category 1

2.2 Label elements

Symbol(s) of Product

Signal Word
Warning

Named Chemicals on Label

Page 1 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

GHS HAZARD STATEMENTS

Hazardous to the aquatic environment, H400 Very toxic to aquatic life.

Acute, category 1
Hazardous to the aquatic environment, H410 Very toxic to aquatic life with long lasting effects.
Chronic, category 1
GHS PRECAUTION PHRASES
P273 Avoid release to the environment.
P391 Collect spillage.
2.3 Other hazards
Not applicable

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
7440-66-6 ZINC (DUST OR FUME) 75-100
1314-13-2 ZINC OXIDE 1.0-2.5

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

7440-66-6 GHS09 H400-410 0
1314-13-2 GHS09 H400-410 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: Wash off with warm water and soap.
AFTER EYE CONTACT: Flush eyes with water as a precaution. Rinse thoroughly with plenty of water for at least 15
minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Obtain medical attention. Do not induce vomiting. If conscious, give 2
glasses of water. Get immediate medical attention.

4.2 Most important symptoms and effects, both acute and delayed
This product has been tested and shown to fall well below the level of gas emission when exposed to water (49CFR Part 173
E, 4) and is, therefore, not a regulated product and is not defined as dangerous when wet. Product is packaged in steel or
plastic water tight containers.
4.3 Indication of any immediate medical attention and special treatment needed

No Information

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information

5.2 Special hazards arising from the substance or mixture

No Information

Page 2 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
In the case of dust or aerosol formation use respirator with an approved filter.
6.2 Environmental precautions
No Information
6.3 Methods and material for containment and cleaning up
No Information
6.4 Reference to other sections

No Information

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Do not smoke. Avoid dust formation. Protect from moisture. Avoid breathing vapors, mist or gas.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Do not
breathe dust. Avoid contact with the skin and the eyes.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Keep from any possible contact with water.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No Information

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- OEL Note
TWA STEL TWA CEILING
ZINC (DUST OR FUME) 75-100 N/E N/E 5.0 MG/M3 N/E
ZINC OXIDE 1.0-2.5 2 MGM3 10 MGM3 5 MGM3 N/E

FURTHER INFORMATION: No Information

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: Dust safety masks are recommended when the dust concentration is more than 10 mg/m3.
Respirator must be worn if exposed to dust. Use the indicated respiratory protection if the occupational exposure limit is
exceeded and/or in case of product release (dust).
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious glovesRequest information on glove permeation properties from the glove supplier.
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
Lightweight protective clothing
ENGINEERING CONTROLS: Maintain air concentrations below occupational exposure standards.

Page 3 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Blue - Grey Powder

Physical State Solid

Odor Odorless

Odor threshold N/D

pH N/A
Melting point / freezing point (°C) N/A
Boiling point/range (°C) N/D - .
Flash Point, (°C) 999
Evaporation rate N/A

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive N/D - N/D

limits
Vapour Pressure, mmHg N/A
Vapour density N/A
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l:

Specific Gravity (g/cm3) 7.109

10. Stability and Reactivity

10.1 Reactivity
No Information

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Keep from any possible contact with water.

10.5 Incompatible materials

Keep away from oxidising agents and strongly acid or alkaline materials. Strong oxidizing agents.

Page 4 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

10.6 Hazardous decomposition products

Preparation reacts slowly with water resulting in evolution of hydrogen.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
7440-66-6 ZINC (DUST OR FUME) >2000 mg/kg, oral, rat >5.4 mg/L, / 4Hr ,rat, inh

1314-13-2 ZINC OXIDE 15000 mg/kg, oral, rat Not Available

Additional Information:
This product has been tested and shown to fall well below the level of gas emission when exposed to water (49CFR Part 173 E, 4)
and is, therefore, not a regulated product and is not defined as dangerous when wet. Product is packaged in steel or plastic water
tight containers.

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

Page 5 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

7440-66-6 ZINC (DUST OR FUME) No information No information No information

1314-13-2 ZINC OXIDE No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Dispose of in accordance with local regulations.

14. Transport Information

14.1 UN number None
14.2 UN proper shipping name Not Regualted
Technical name N/A
14.3 Transport hazard class(es) None
Subsidiary shipping hazard N/A
14.4 Packing group N/A
14.5 Environmental hazards
14.6 Special precautions for user Unknown
EmS-No.: N/A

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
ZINC (DUST OR FUME) 7440-66-6
ZINC OXIDE 1314-13-2
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

Page 6 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

U.S. State Regulations: As follows -

New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

No NJ Right-To-Know components exist in this

product.
Pennsylvania Right-To-Know
The following non-hazardous ingredients are present in the product at greater than 3%.

No PA Right-To-Know components exist in this product.

California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.

CADMIUM 7440-43-9
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
Chemical Name CAS-No.
CADMIUM 7440-43-9

International Regulations: As follows -

* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Reasons for revision

No Information

No Information

Page 7 / 8
Date Printed: 17/07/2015 Product: 0229B1NL

Page 8 / 8