MG(S) - M (0.1M) - C (1 × M - Cu(s) ) G U 10 Given, +0.34V, E 2.37V) E

Prasanna sajee
TERM 2 MOCK TEST

Class 12 - Chemistry
Time Allowed: 1 hour and 30 minutes Maximum Marks: 35
Section A
1. Calculate the emf of the cell [2]
+2 +2 −3
Mg(s)|Mg (0.1M)||C u (1 × 10 M|Cu(s))
⊖ ⊖
Given, E = +0.34V, E = −2.37V)
C u2+ /C u M g +2 /M g
2. i. Describe the mechanism of the addition of Grignard's reagent to the carbonyl group of a [2]
compound to form an adduct which on hydrolysis yield an alcohol.
ii. Draw the structure of the following compounds:
a. 3-methylbutanal
b. p-nitropropiophenone
3. How will you convert ethanal into the following compounds? (i) Butane-1,3-diol (ii) But-2-enal [2]
(iii) But-2-enoic acid.
Section B
4. Write reactions for the conversion of: [3]
i. Aniline to benzene
ii. Methyl amine to methyl cyanide
iii. Propanenitrile to ethylamine.
5. Complete the following equations and mention the name of the reactions: [3]
a. RNH2 + CHCl3 +3KOH →
b. RCONH2 + Br2 +4NaOH →
OR
How will you convert:
i. Benzene into aniline
ii. Benzene into N, N-dimethylaniline
iii. Cl-(CH2)4-Cl into hexan-1, 6-diamine?
6. What is meant by crystal field splitting energy? On the basis of crystal field theory, write the [3]
electronic configuration of d4 in terms of t2g and eg in an octahedral field when
i. Δ0 > P
ii. Δ0 <P
7. Zinc, Cadmium and Mercury are not considered as transition metals. Why? [3]
OR
Name the members of the lanthanoid series which exhibit +2 oxidation states and those which
exhibit +4 oxidation states. Try to correlate this type of behaviour with the electronic configuration
of these elements?
1/2
8. Calculate the number of unpaired electrons in the following gaseous ions: Mn3+, Cr3+, V3+ and [3]
Ti3+. Which one of these is most stable in aqueous solution.

9. Explain what is observed when: [3]
i. A beam of light is passed through a colloidal sol.
ii. An electrolyte, NaCl is added to hydrated ferric oxide sol.
iii. Electric current is passed through the colloidal sol?
10. Calculate the emf of the following cell at 25°C. [3]
2+ +
Fe |Fe (0.001M)∥ H (0.01M) |H2 (g)(1 bar )|Pt(s)
Given that, EF e = -0.44 V; EH = 0.00 V

o o
2+ +
/F e /H2
OR
Silver is deposited on a metallic vessel by passing a current of 0.2 amps. for 3 hrs. Calculate the
weight of silver deposited. (At mass of silver = 108 amu,1 F = 96500 C)?
11. Two moles of compound (A) on treatment with a strong base gives two compounds (B) and (C). [3]
The compound (B) on dehydrogenation with Cu gives (A) while acidification of (C) gives
carboxylic acid (D) having molecular formula CH2O2. Identify (A) to (D).
Section C
12. Read the given passage and answer the questions that follow: [5]
The order of the reaction is the sum of the powers of the concentration of the reactants in the
rate law. It can either be a whole number or a fraction the order of the reaction is determined
by the experimental methods based on this value, reactions may be classified as first-order,
second-order, third-order, etc. A reaction whose order is different from the actual due to large
excess concentration of one of the reactants is called pseudo order reaction. Another property
of a reaction called molecularity helps in understanding its mechanism. The number of
reacting species (atoms, ions, or molecules) taking part in an elementary reaction, which must
collide simultaneously in order to bring about a chemical reaction is called the molecularity of
a reaction. The reaction can be unimolecular when one reacting species is involved,
bimolecular reactions involve a simultaneous collision between two species & trimolecular or
termolecular reactions involve a simultaneous collision between three reacting species.
a. For the reaction, A+B → Products, the rate is given as, rate =k[A][B]2. How will the rate
change if the volume of the reaction mixture is reduced to 1/3 of its original volume?
b. The hydrolysis of ethyl acetate in the presence of acid is a reaction of first order whereas,
in the presence of alkali, it is a reaction of second order. Give reason.
c. The graph between time (t) and the substance consumed at any time is found to be a
straight line passing through the origin. Predict the order of the reaction.
d. For which type of reactions, order, and molecularity have the same value?
OR
e. Why is the probability of reaction with molecularity higher than three very rare?
2/2

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Prasanna sajee

TERM 2 MOCK TEST

Ti3+. Which one of these is most stable in aqueous solution.

Given that, EF e = -0.44 V; EH = 0.00 V

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