Mark Scheme (Results) Summer 2019: Pearson Edexcel GCSE in Chemistry (1CH0) Paper 1H
Mark Scheme (Results) Summer 2019: Pearson Edexcel GCSE in Chemistry (1CH0) Paper 1H
Mark Scheme (Results) Summer 2019: Pearson Edexcel GCSE in Chemistry (1CH0) Paper 1H
(Results)
Summer 2019
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Summer 2019
Publications Code 1CH0_1H_1906_MS
All the material in this publication is copyright
© Pearson Education Ltd 2019
General Marking Guidance
• All candidates must receive the same treatment. Examiners must mark the first candidate in exactly the same way as they
mark the last.
• Mark schemes should be applied positively. Candidates must be rewarded for what they have shown they can do rather
than penalised for omissions.
• Examiners should mark according to the mark scheme not according to their perception of where the grade boundaries
may lie.
• There is no ceiling on achievement. All marks on the mark scheme should be used appropriately.
• All the marks on the mark scheme are designed to be awarded. Examiners should always award full marks if deserved, i.e.
if the answer matches the mark scheme. Examiners should also be prepared to award zero marks if the candidate’s
response is not worthy of credit according to the mark scheme.
• Where some judgement is required, mark schemes will provide the principles by which marks will be awarded and
exemplification may be limited.
• When examiners are in doubt regarding the application of the mark scheme to a candidate’s response, the team leader
must be consulted.
• Crossed out work should be marked UNLESS the candidate has replaced it with an alternative response.
Mark schemes have been developed so that the rubrics of each mark scheme reflects the characteristics of the skills within the AO being targeted and
the requirements of the command word. So for example the command word ‘Explain’ requires an identification of a point and then
reasoning/justification of the point.
Explain questions can be asked across all AOs. The distinction comes whether the identification is via a judgment made to reach a conclusion, or, making
a point through application of knowledge to reason/justify the point made through application of understanding. It is the combination and linkage of
the marking points that is needed to gain full marks.
When marking questions with a ‘describe’ or ‘explain’ command word, the detailed marking guidance below should be consulted to ensure
consistency of marking.
Assessment Command Word
Objective
Strand Element Describe Explain
AO1 An answer that combines the marking An explanation that links identification
points to provide a logical description of a point with reasoning/justification(s)
as required
AO2 An answer that combines the marking An explanation that links identification
points to provide a logical description, of a point (by applying knowledge) with
showing application of knowledge and reasoning/justification (application of
understanding understanding)
AO3 1a and An answer that combines points of
1b interpretation/evaluation to provide a
logical description
AO3 2a and An explanation that combines
2b identification via a judgment to reach a
conclusion via justification/reasoning
AO3 3a An answer that combines the marking
points to provide a logical description of
the plan/method/experiment
AO3 3b An explanation that combines
identifying an improvement of the
experimental procedure with a linked
justification/reasoning
Question Answer Additional guidance Mark
number
1(a) 2H2 + O2 → 2H2O (2) Allow =, ⇌ for → (2)
Ignore all words and state symbols
fully correct balanced equation (2) Allow multiples
If not (2), then H2O as product in an equation reject formulae with charges
format, regardless of any other errors (1) Do not penalise small letters e.g allow h2O
if no other mark:
• (atoms with) different allow same atomic number and different mass number (1)
(number of) neutrons (1)
MP2 for deriving ratio from MP1 For MP2: If they go on to calculate a different ratio in addition to 0.5:0.25 or
0.5 : 0.25 2:1 do not award MP2
OR
2 : 1 (1) ecf on step 1: If inverted,
7 : 16 (0)
MP3 for ratio in MP2 to formula 3.5 4.0
empirical formula A2G (1) = 2 : 4
or
1 : 2 (1)
AG2 (1)
• quantitative comparing hydrogen and explicit reference needed to a ratio and not just quoting 2 figures
oxygen:
(volume of) hydrogen double
(volume of) oxygen / ORA / 2:1 ratio allow amount in place of volume throughout
(1)
twice as much hydrogen produced as oxygen (1)
allow ZN, zn
allow multiples
MP2 only for correctly x 100 some figure derived from the data given
= 97.3214….
= 97.3(%) (1)
40 + 12 + 3 x 16 (1) ecf for MP2 if using 12,16 and 40, using addition
=100 (1) and multiplication only
Question Answer Additional guidance Mark
number
4(d)(ii) 56% without working scores 0 56/answer to 4(d)(i) (1) (2)
56 (1) x 100 (1)
100 MP2 only for correctly x 100 some figure derived
from the data given
(x 100) = 56 (%) (1) 100% scores 0
(Total for question 4 = 11 marks)
Question Answer Additional guidance Mark
number
5(a)(i) 14(.2) with or without working scores 3 If the percentage of non nickel compounds is calculated to give (3)
85.8%/86% score 2
1kg = 1000g (1)
142 or 0.142 will score MP1 and MP2
142 (1) 1000
1000
142 x 100 = 14200 scores (1)
x 100% =14(.2) (1) 1
• heat/ boil (1) allow ‘raise temp. to 50oC’ etc. (temp >42 and <90)
REVERSE REACTION
• add water / water rejoins / water reacts with anhydrous
solid (1)
MP4 independent of MP3
• (solid) goes blue (again) / heat is released (1)
• neither rod would rust/ react (in a few days) / Ignore iron corrodes but ALLOW iron corrodes faster than
there would be no {rusting / reaction}/ no stainless steel / iron rusts but stainless steel does not (1)
change would occur / it would take a long time
for any result (1)
• (A) the magnesium has {corroded/ reacted/ MP1 describes reaction that occurs
oxidised} /
(B) {rusting / corrosion / oxidation} has occurred (1)
MP2 reason – ignore ‘sacrificial protection’ etc.
• because magnesium is more reactive than iron /
(magnesium has reacted) instead of the iron (1)
• {less oxygen / no oxygen / oxygen is removed} by For MP1 allow ‘oxygen reacts with hydrazine instead of
the hydrazine (1) the metal’ (1)
• (some) {grey/silver} solid remains allow {grey/silver} solid disappears / reduces / dissolves
(1)
OR
conc = 15.95/159.5 (1) (=0.1 moldm-3)
moles = 50/1000 x 0.1 = (0.005 mol)
= 2.8 g (1)
allow 1 mark for a different calculation using 65 and 0.043 , correctly
evaluated, with working, rounded to 1 decimal place
The indicative content below is not prescriptive and candidates are not required to include all the
material which is indicated as relevant. Additional content included in the response must be
scientific and relevant.
AO3 (6 marks)
• A is copper oxide
• copper oxide is black
• copper oxide reacts with sulfuric acid to make {copper sulfate / blue solution} but no gas
• B is magnesium
• magnesium is silver coloured
• magnesium reacts/ bubbles with water
• magnesium reacts with sulfuric acid to give hydrogen / equation
• C is sodium hydroxide
• sodium hydroxide is white
• sodium hydroxide solution is colourless
• sodium hydroxide reacts with sulfuric acid to form a colourless solution / equation
• sodium hydroxide solution is alkaline
• sodium hydroxide has hydroxide ions
• D is copper carbonate
• copper carbonate is green
• carbonates are insoluble
• copper carbonate reacts with sulfuric acid to form copper sulfate and {gas / carbon
dioxide}
• copper carbonate reacts with sulfuric acid to form carbon dioxide / equation
• copper sulfate (solution) is blue
Level 2 3-4 • Deconstructs scientific information and provides some logical connections between scientific concepts. An imbalanced argument that synthesises
mostly relevant understanding, but not entirely coherently.
• Judgements are supported by evidence occasionally. (AO3)
Level 3 5-6 • Deconstructs scientific information and provide logical connections between scientific concepts throughout. A balanced, well-developed
argument that synthesises relevant understanding coherently.
• Judgements are supported by evidence throughout. (AO3)
Level Mark Descriptor Additional Guidance
0 No rewardable material. Read whole answer and ignore all incorrect material/ discard any
contradictory material then:
No solids are correctly identified/ One solid is identified but no
reason is given
Level 1 1–2 Additional Guidance Possible candidate response
Three solids are correctly identified but only one or
none have valid reasoning (2)
OR
exothermic
OR
2 mol NO = 60 g (1)
60 g NO : 24 dm3 oxygen (1)
1000 g NO reacts with 24 x 1000/60 (1) (=400 dm3)
volume air = volume O2 x 100/20 (1) (=2000 dm3)
3 marks
all working up to
400 x 20/100 = 80
Question Indicative content Mark
number
*10(c) Answers will be credited according to candidate’s deployment of knowledge and understanding of the material in (6)
relation to the qualities and skills outlines in the generic mark scheme.
The indicative content below is not prescriptive and candidates are not required to include all the material which is
indicated as relevant. Additional content included in the response must be scientific and relevant.
AO1 & AO2 (6 marks)
EXCESS AIR
• increases oxygen concentration
• so excess air favours right hand side
• and gives higher yield
PRESSURE
• 9 molecules on left and 10 on right
• so higher pressure favours left hand side
• and gives lower yield
TEMPERATURE
• heat energy given out in forward reaction
• higher temperature favours reaction that takes in heat energy
• so higher temperature favours left hand side
• hence lower yield
0 • No awardable content
Level 1 1-2 • Demonstrates elements of chemical understanding, some of which is inaccurate. Understanding of scientific ideas lacks
detail. (AO1)
• The explanation attempts to link and apply knowledge and understanding of scientific ideas, flawed or simplistic
connections made between elements in the context of the question. (AO2)
Level 2 3-4 • Demonstrates chemical understanding, which is mostly relevant but may include some inaccuracies. Understanding of
scientific ideas is not fully detailed and/or developed. (AO1)
• The explanation is mostly supported through linkage and application of knowledge and understanding of scientific
ideas, some logical connections made between elements in the context of the question. (AO2)
Level 3 5-6 • Demonstrates accurate and relevant chemical understanding throughout. Understanding of the scientific ideas is
detailed and fully developed. (AO1)
• The explanation is supported throughout by linkage and application of knowledge and understanding of scientific ideas,
logical connections made between elements in the context of the question. (AO2)
Level Mark Descriptor Additional guidance
0 No rewardable material. Read whole answer and ignore all incorrect material/ discard any contradictory material
then:
Level 1–2 Additional guidance Possible candidate responses
1 One factor is discussed with a statement of A higher pressure gives a lower yield because there are more gas molecules on the right
effect on yield and/or rate (1) hand side.
Factor and reason – 2 marks
One factor is discussed with explanation of
yield and/or rate (2)