Use of Extended Cover Factor Theory in UV Protecti
Use of Extended Cover Factor Theory in UV Protecti
Use of Extended Cover Factor Theory in UV Protecti
Article
Use of Extended Cover Factor Theory in UV Protection of
Woven Fabric
Klara Kostajnšek * and Krste Dimitrovski
Department of Textiles, Graphics Art and Design, Faculty for Natural Sciences and Engineering,
University of Ljubljana, Snežniška 5, 1000 Ljubljana, Slovenia; krste.dimitrovski@gmail.com
* Correspondence: klara.kostajnsek@ntf.uni-lj.si; Tel.: +386-1-200-32-14
Abstract: The paper presents an extension of existed cover factor theory more suitable for the
evaluation of light penetration through a net woven fabrics structure. It also introduces a new
simplified model of predicting the ultraviolet (UV) protective properties of woven fabrics assuming
that the coefficient of reflection (KR ), transmission (KT ), and absorption (KA ) of constitutive yarns
are known. Since usually they are not, the procedure of preparation of simulation of proper woven
fabric samples without interlacing and with known constructional parameters is also presented. The
procedure finishes with a fast and cheap detection of missed coefficient for any type of yarns. There
are differences between theoretical and measured results, which are not particularly significant in
regard to the purpose and demands of investigation.
Keywords: cover factor; simplified model of UV penetration; woven fabrics simulation; coefficient
KR ; KT and KA determination
Water content, water vapor, sweat, the presence of various additives [7,13,15,16] (absorbers,
repellents), etc. and changes that occur during wear [2,17], all this affects the changes in
the protection of textiles from UV radiation.
Many studies [1,4,11,12,18–21] have shown that the aforementioned textile parameters
have different effects on the protective properties of textiles, with some parameters having
a greater influence on protection and others having less. For the development of a method
to predict the protection against UV rays at the stage of the design and construction of
fabrics (before production), it is necessary to know all the parameters that affect the UV
protection of the fabric. Roughly speaking, adequate protection against UV radiation
is most easily and quickly achieved by an appropriate textile construction, which must
therefore have a sufficient cover factor, and/or using protective agents that allow a high
reflection (R) or absorption (A) of UV radiation.
The aim of the research was to develop a fast, universal, and efficient method for
predicting the UV protective properties of fabrics at the planning and design stage. The
method is based on the determination of the parameters of UV radiation transition (trans-
mission, reflection, and absorption) through textiles, more precisely through thread/yarn
systems. For this purpose, it was necessary to extend the existing cover factor theory by
considering that the transition through parts of the surface covered by one and two yarns
is different. The method is based on the extended cover factor theory and the basic prepara-
tion of fabric samples or threads systems with previously known construction parameters
of samples.
The specific problem and main result of this work is the determination of the KR ,
KT , and KA for different row materials and types of yarns. That allows us to establish
a simplified mathematical model for predicting the UV protective properties of woven
fabrics based on the set of special fabrics with the possibility of predicting parameters of
protection from UV radiation in advance. In this case, we have introduced the method of
preparing the simulation of fabrics of any yarns and in this way simple, quick, and cheap
determination of KR , KT , and KA .
The theoretical calculations give us the relations between almost all parameters of UV
penetration through fabrics, but in practice, we do not get unified results from all invented
relations. They are all very close to each other, but we want to find the best procedure to
obtain the results in the simplest and most accurate way, also in regard to the number of
samples and the time for their preparation.
2. Theoretical Part
2.1. Extended Woven Fabric Cover Factor Theory
Cover factor (i.e., the degree of fabric fullness (Cf)) is a proportion of the fabric area
covered by warp and weft yarns. Classical woven fabric cover factor theory is defined as
the ratio between the projected area of the two elementary yarn systems in the fabric area
unit [22,23]. It means that in practice, cover factor is calculated independently for warp and
weft yarn by the proportion of fabric area covered by those yarn [22]. Theoretically, it can
be calculated from the known yarn density and the theoretical yarn diameter. Due to the
insufficient description of the yarn-covered area by the classical existing cover factor theory,
the need for an extension of the cover factor theory became apparent. This considers
the penetration of UV radiation and/or light through the mesh structure of the fabric
as equivalent, although the surface/area coverage of biaxial fabrics (single-layer woven
fabrics) with one system of warp and weft yarns consists of surface units covered by
only one yarn (warp or weft) and the corresponding number of surface units covered by
two yarns (warp and weft) simultaneously (Figure 1) [24].
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Polymers 2021,13,
13,1188
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13
Figure1.1.Scheme
Figure Schemeof
ofwoven
wovenfabric
fabricininplane
planeweave,
weave,where
wherethere
thereare
areshown
shownareas
areaswithout
without yarns
yarns (open
(open area (OA) = ∑ OA ), units/areas of fabric surface covered by only one (Cf1 = ∑ Cf ) and two
area (OA) = ∑ OAi ), units/areas of fabric surface covered by only one (Cf1 = ∑ Cfi1 ) and two yarn
yarn (Cf2 = ∑ Cf ) where i is the number of individual areas in a unit area of fabric.
(Cf2 = ∑ Cfi2 ) where i is the number of individual areas in a unit area of fabric.
Generally, the
Generally, thetheory
theoryofofwoven
wovenfabrics
fabricsconstruction
construction isis defining
defining aacover
coverfactor
factoras
asaa
fraction of
fraction ofsurface
surface covered
covered by
byyarns
yarnswhich
whichisisequal
equaltotoquotient
quotientof ofarea
areacovered
coveredbybyyarns
yarns
and total area of web [22] expressed by Equation (1). That way, it takes the values from 0 to0
and total area of web [22] expressed by Equation (1). That way, it takes the values from
1,toand
1, and
if itifisitmultiplied
is multiplied by 100,
by 100, it isitexpressed
is expressed in %.
in %.
Cf = area covered by yarns⁄total area of web (1)
Cf = area covered by yarns/total area of web (1)
Calculation of the cover factor consists of the calculation of warp and weft cover fac-
Calculation
tor as Cfwa = Dwaof× the
dwacover
and Cf factor consists
we = D we × dweofwhere
the calculation
Dwa and Dofwewarp and weft of
are densities cover
warpfactor
and
as Cfwa
weft =D
and dwa × dwa
wa and dweand
are Cf = Dwe ×of
thewediameter dwe where
warp andDweft
wa and Dwe are densities of warp and
yarns.
weft and
The dcover
wa and dwe of
factor areathe diameter fabric
single-layer of warp and weft yarns.
is expressed by the cover factor of warp and
weftThe cover
yarns. factor of a Equation
It transforms single-layer(1)fabric
to the is expressed
form by the(2):
of Equation cover factor of warp and
weft yarns. It transforms Equation (1) to the form of Equation (2):
Cf = Cf + Cf − Cf × Cf . (2)
Cf = Cfwa +
For the purpose of investigation, we −
weCfhad wa × Cfand
toCfmodify we . expend woven fabric cover(2)
factor theory to the next form. The fabric cover factor is the sum of areas covered by one
For the purpose of investigation, we had to modify and expend woven fabric cover
yarn—Cf1 and two yarns—Cf2 expressed with Equation (3):
factor theory to the next form. The fabric cover factor is the sum of areas covered by one
yarn—Cf1 and two yarns—Cf2 expressed = CfEquation
Cf with + Cf (3): (3)
The portion of fabric covered by
Cftwo
= yarns
Cf1 + is
Cfcalculated
2
as shown in Equation (4):(3)
Cf = Cf × Cf (4)
The portion of fabric covered by two yarns is calculated as shown in Equation (4):
The portion of yarns covered by one yarn as shown in Equation (5):
Cf2 = Cfwa × Cfwe (4)
Cf = Cf − Cf (5)
The portion of yarns covered by one yarn as shown in Equation (5):
This extended cover factor theory allows for a completely new theoretical approach
to the treatment of the individual portions Cf1 = of Cf the cover factor in the fabric structure for
− Cf (5)a
2
certain group of fabrics—e.g., square fabrics or fabrics made of equal warp and weft
yarns/threads
This extendedand cover
densities,
factorwhich
theoryare usedfor
allows inapractice
completely for new
fine theoretical
filtration orapproach
printing
screens.
to For that,ofEquation
the treatment (2) transforms
the individual portionsinofEquation
the cover (6):factor in the fabric structure for
a certain group of fabrics—e.g., square Cf = 2 fabrics
× Cf , or − fabrics
Cf , made of equal warp and weft (6)
yarns/threads and densities, which are used in practice for fine filtration or printing screens.
To explain
For that, Equation it (2)
graphically,
transformswe in chose fabrics
Equation (6): with an ideal theoretical diameter up to
(200 µm) and different densities of warp and weft (10, 15, 20, 25, 30, 35, and 40 yarns/cm).
2
Their theoretically calculatedCfvalues = 2 ×ofCfthe − Cffactors—warp
cover
wa,we wa,we and weft cover factor(6)
(Cfwa,we), fabric cover factor (Cf), and cover factor, which refers to the proportion of the
areaTo explain
of the it covered
fabric graphically, we chose
by only one (Cffabrics with an ideal theoretical diameter up to
1) and two (Cf2) yarns and the open area (OA) of
(200 µm) and different densities of warp
fabric—are given in Table 1, and the graph of theand weft (10,curves
15, 20,as25,a30, 35, andof40the
function yarns/cm).
different
Their
densitytheoretically
is shown incalculated
Figure 2. values of the cover factors—warp and weft cover factor
Polymers 2021, 13, 1188 4 of 13
(Cfwa ,we ), fabric cover factor (Cf), and cover factor, which refers to the proportion of the
area of the fabric covered by only one (Cf1 ) and two (Cf2 ) yarns and the open area4(OA)
Polymers 2021, 13, x FOR PEER REVIEW of 13
of fabric—are given in Table 1, and the graph of the curves as a function of the different
density is shown in Figure 2.
Table 1. Calculated Cfwa,we, Cf, Cf1, Cf2, and open area (OA) depending on the given ideal yarn
Table 1. Calculated Cfwa,we, Cf, Cf1 , Cf2 , and open area (OA) depending on the given ideal yarn
diameter (d) and different densities of warp and weft (D).
diameter (d) and different densities of warp and weft (D).
d [µm] D [yarns/cm] Cfwa,we Cf Cf1 Cf2 OA
d [µm] D [yarns/cm] Cfwa,we Cf Cf1 Cf2 OA
10 0.20 0.36 0.32 0.04 0.64
10 0.20 0.36 0.32 0.04 0.64
15 0.30 0.51 0.42 0.09 0.49
15 0.30 0.51 0.42 0.09 0.49
20
20 0.40
0.40 0.64
0.64 0.48
0.48 0.16
0.16 0.30
0.30
200
200 25
25 0.50
0.50 0.75
0.75 0.50
0.50 0.25
0.25 0.25
0.25
30
30 0.60
0.60 0.84
0.84 0.48
0.48 0.30
0.30 0.16
35
35 0.70
0.70 0.91
0.91 0.42
0.42 0.49
0.49 0.09
0.09
40 0.80 0.96 0.32 0.64 0.25
40 0.80 0.96 0.32 0.64 0.25
Figure 2.
Figure 2. Cf
Cfwa,we
wa,we, ,Cf,
Cf,Cf
Cf1,1 ,Cf
Cf2 2and
andOA,
OA,depending
dependingon onDD with
with aa linear
linear line of Cf
line of Cfwa,we
wa,we and
andother
othercurves
curves
(second-order polynomial
(second-order polynomial functions)
functions) and
and the
the corresponding
correspondingcoefficient
coefficientofofdetermination.
determination.
2.2. Introduction of Simplified Mathematical Model for Predicting UV Properties of Woven Fabrics
In a previous work [11,24], we evaluated a penetration of UV rays through single
layer monofilament PET fabrics trying to find out how much is reflected, absorbed, and
transmitted by one yarn and how much from the two yarns in the fabric structure. We
calculated quotient as shown in Equations (7)–(9) for every sample.
R R= Cf Cf
2 = × K× KR (17) (17)
Table 2. Transmission
Table (Tme—measured,
2. Transmission Tm—material),
(Tme —measured, absorption
Tm —material), and reflection
absorption values
and reflection for simulated
values single-
for simulated and double-
single- and double-
layerlayer
samples calculated
samples by the
calculated bysimplified model
the simplified for the
model forprediction of woven
the prediction fabrics
of woven UV properties.
fabrics UV properties.
Dwa,weD[yarns/cm]
wa,we [yarns/cm]
T1me T1me T2me T2me T1m T1mT2m T2m A1 A1 A2 A2 R1 R1 R2 R2
20 20 0.72 0.72 0.5184 0.51840.12 0.1584
0.12 0.15840.2 0.2 0.3531 0.3531 0.08 0.08 0.1280.128
25 25 0.65 0.65 0.4225 0.42250.15 0.1725
0.15 0.17250.25 0.25 0.4268 0.4268 0.1 0.1 0.15 0.15
30 30 0.58 0.58 0.3364 0.33640.18 0.1764
0.18 0.17640.3 0.3 0.4946 0.4946 0.12 0.12 0.1680.168
35 35 0.51 0.51 0.2601 0.26010.21 0.21
0.1701 0.17010.35 0.35 0.5565 0.5565 0.14 0.14 0.1820.182
40 0.44 0.1936 0.24 0.1536 0.4 0.6126 0.16 0.192
40 0.44 0.1936 0.24 0.1536 0.4 0.6126 0.16 0.192
45 0.37 0.1369 0.27 0.1269 0.45 0.6628 0.18 0.198
45 50 0.37 0.30 0.1369 0.09 0.27 0.1269
0.30 0.09 0.45 0.50 0.6628 0.7071 0.18 0.20 0.1980.200
50 0.30 0.09 0.30 0.09 0.50 0.7071 0.20 0.200
Figure 3. Curves
Figure of reflection
3. Curves fromfrom
of reflection one-layer (R1), (R
one-layer double-layer (R2) samples,
1 ), double-layer T1m, TT1me
(R2 ) samples, 1m,,and
T1meOA of OA of
, and
double-layer samples.
double-layer samples.
FromFromTable 2, it 2,
Table is it
evident
is evidentthatthat
the summa
the summa of Tof
1, RT11, ,AR11, ,and
A1 , open area area
and open for single-layer
for single-layer
samples
samples − )Cis
(1 − C(1wa,we always
wa,we equal toequal
) is always 1, andtofor
1, double-layer
and for double-layer samples,samples,
it is moreitthan 0.99.than
is more
In the0.99.
lastInrow,
the it
last
is row,
seen it is seen
that that the
the values forvalues for one-layer
one-layer samples are samples are identical
identical as were
as were sup-
posed supposed
and thatand thethat the transmission
transmission troughtrough double-layer
double-layer samples samples correspond
correspond to thetosquared
the squared
function
function of K1Tofand
K1T square
and square root root function
function of K1Aof. K1A .
Usually,
Usually, in thein real
the real samples,
samples, we can
we can easilyeasily determine
determine onlyonly the density
the density of yarns
of yarns and and
not real
not the the real deformed
deformed diameterdiameter of yarns
of yarns as well
as well as Kas R, K KRT, K T , and
and KA. K A . What
What is measured
is measured is is
openopen area—optically,
area—optically, and and transmission
transmission and and reflection
reflection spectrophotometrically.
spectrophotometrically. The The curves
curves
presented
presented in Figure
in Figure 3 gave 3 gave
us the us possibility
the possibility of easily
of easily detecting
detecting the missing
the missing parameters
parameters
necessary for calculating the cover factor elements and predicting
necessary for calculating the cover factor elements and predicting UV protective proper- UV protective properties.
ties. Figure 3 shows that there are several possibilities to identify the diameter of yarns and
also to verify it by double or triple checking. We will list
Figure 3 shows that there are several possibilities to identify the diameter of yarns some of them:
and also
- to verify it by
Optically: from double or triple checking.
the single-layer samples, We we willcanlist getsome of curve
linear them: of Cwa,we . At the
- Optically: from the single-layer samples, we can get linear curve ofdensity
point where the linear curve becomes 1, we can get the maximum Cwa,we.and
At also
the the
proper diameter of yarn (Equation (18)). This is
point where the linear curve becomes 1, we can get the maximum density and also also possible following the double-
layer curve
the proper diameter (Equation
of yarn (19)) [25]: (18)). This is also possible following the dou-
(Equation
1
ble-layer curve (Equation (19)) [25]: d = (18)
Dmax
1
𝑑 = (18)
Polymers 2021, 13, 1188 𝐷 7 of 13
(1 − p O )
d , = 1D− Op (19)
dwa, we = , (19)
Dwa, we
- Determining the maximum of reflection curve from the double-layer systems of
- Determining the maximum of reflection curve from the double-layer systems of
yarns—R2, that way, calculating the maximal density, diameter of yarns, and value
yarns—R2 , that way, calculating the maximal density, diameter of yarns, and value of
of KR. (R2 = −0.00008x 2 + 0.008x, from the first derivation of the equation of the func-
KR . (R2 = −0.00008x2 + 0.008x, from the first derivation of the equation of the function
tion curve R2′ = −0.00016x + 0.008 = 0, we calculate x (maximal density of yarns) x = 50
curve R2 0 = −0.00016x + 0.008 = 0, we calculate x (maximal density of yarns) x = 50
and KR = 0.2).
and KR = 0.2).
- Supposing the reflection from single-layer and double-layer fabrics at cover factor 1
- Supposing the reflection from single-layer and double-layer fabrics at cover factor 1
will be
will be equal,
equal, wewe can
can verify
verify the
the previous
previous mentioned
mentioned findings
findings using
using the
the same
same values
values
when curves for R 1 and R2 cross each other (−0.00008x22 + 0.008x = 0.004x, where we
when curves for R1 and R2 cross each other (−0.00008x + 0.008x = 0.004x, where we
get xx =
get = 50
50 in
in K
KRR ==0.2).
0.2).
-- If we determine
If we determine T1m T 1m by subtraction T1me for OA of single-layer samples, we can see
by subtraction T1me for OA of single-layer samples, we can see
that the linear curves
that the linear curves for forTT1me and T1m cross each other in the point that corresponds
1me and T1m cross each other in the point that corresponds
to maximal density and to the value of K at the
ofR K same time (−0.14x + 1 = 0.006x, follows
to maximal density and to the value R at the same time (−0.14x + 1 = 0.006x,
x = 50 and K T1 = 0.3).
follows x = 50 and K = 0.3).
T1
Of course,
Of course, all
all statements
statements above
above are
are valid
valid for
for square
square fabrics
fabrics (fabrics
(fabrics from
from the
the same
same
yarns and same densities in warp and weft construction). The pallet of such
yarns and same densities in warp and weft construction). The pallet of such structured structured
fabrics practically
fabrics practically does
doesnot
notexist,
exist,soso
wewe
developed
developed a method for creating
a method suchsuch
for creating typetype
of sam-
of
ples allowing
samples presented
allowing findings
presented andand
findings calculations.
calculations.
Figure 4.
Figure 4. Preparation of thread system samples for measurements: (a)
(a) woven
woven fabrics
fabrics with
withfloating
floating
warp and weft yarns; (b) Removing the warp and display measuring surface of thread distribu-
warp and weft yarns; (b) Removing the warp and display measuring surface of thread distribution—
tion—thread
thread systemsystem
sample.sample.
We measured
We measured thethe UV
UV radiation
radiation parameters
parameters on
on single-and double-layer yarn systems.
For
For double-layer samples,
samples, we laid two single layerscrosswise
we laid two single layers (at(at
crosswise ananangle of 90°)
angle ◦ ) with
of 90with the
approximation
the approximation of fabric simulation
of fabric fromfrom
simulation the same yarns
the same and and
yarns withwith
the same density
the same (Fig-
density
ure 5). The
(Figure thread
5). The in in
thread thethe
vertical and
vertical andhorizontal
horizontaldirections
directionswas
wasthethe same.
same. We wanted to
We wanted to
simulate the fabric without interlacing and thus avoid the conditional deformation that is
realistically reflected in the fabric.
Polymers 2021, 13, x FOR PEER REVIEW 8 of 13
simulate the fabric without interlacing and thus avoid the conditional deformation that is
realistically reflected in the fabric.
Polymers 2021, 13, 1188 simulate the fabric without interlacing and thus avoid the conditional deformation 8that
of 13is
realistically reflected in the fabric.
Figure5.5.Schematic
Figure Schematicrepresentation
representationofofthe
thepreparation
preparationofofdouble-layer
double-layersamples.
samples.
3. Materials and Methods
To support
3.3.Materials
Materials andthe
and model presented and confirm the theory, we used two different series
Methods
Methods
of samples
To and material. The first setand of samplesthe was madewe from red-colored CO yarns
Tosupport
supportthe themodel
modelpresented
presented andconfirm confirm thetheory,theory, weused usedtwotwodifferent
differentseries
series
and was
ofofsamples deliberately chosen to check how high can be the effect of UV protection. Cotton
samplesand andmaterial.
material. The
Thefirst setset
first of samples
of samples waswas made fromfrom
made red-colored CO yarns
red-colored and
CO yarns
is thedeliberately
was ideal material for summer
chosen to check cloths
how but
highallows
can be high
the transmission
effect of UV of UV radiation
protection. Cottonwhen is
and was deliberately chosen to check how high can be the effect of UV protection. Cotton
undyed.
the ideal Dyed yarns
material for extensively
summer clothsincrease
but the absorption
allows high of UV radiation
transmission of UV on account
radiation when of
is the ideal material for summer cloths but allows high transmission of UV radiation when
diminishing
undyed. Dyed its yarns
transmission [12]. increase the absorption of UV radiation on account of
extensively
undyed. Dyed yarns extensively increase the absorption of UV radiation on account of
The secondtransmission
diminishing set of samples from the PET rotor yarn was also chosen deliberately to
diminishingits its transmission[12]. [12].
checkThe thesecond
KR, KT, set and KAsamples
determined frompreviously in one of our
wasresearch studies for mono-
The second set of of samples from the PET rotor
the PET rotor yarn yarn
was also chosen
also deliberately
chosen deliberately to
filament PET fabrics [11,24]. The necessary data for chosen
to check the KR , KT , and KA determined previously in one of our research studies for materials and methods are
check the KR, KT, and KA determined previously in one of our research studies for mono-
presented below.
monofilament PET fabrics [11,24]. The necessary data for chosen materials and methods
filament PET fabrics [11,24]. The necessary data for chosen materials and methods are
are presented below.
presented below.
3.1. Materials
3.1. Materials
For the experimental work, we prepared samples with the same construction param-
3.1. Materials
etersFor the experimental
in both (warp and weft) work,directions,
we prepared samples
so-called with the
square sameWe
fabrics. construction param-
used a Minifaber
eters For the
in both experimental
(warp and weft) work, we
directions,prepared samples
so-called with the same construction
square fabrics. We used a Minifaber param-
laboratory loom (Minifaber, Italy) to produce the samples.
eters
laboratoryin both
loom (warp and weft) directions, so-called square fabrics. We used a Minifaber
For the first(Minifaber, Italy) tosamples,
series of weaved producewe theused
samples.dyed CO ring yarns, fineness 2 × 8
laboratory loom (Minifaber, Italy) to produce the samples. 2×
tex in four densities (20, 25, 30, and 35 yarns/cm) as single-CO
For the first series of weaved samples, we used dyed ring yarns,
(Figure 6a) andfineness
double- 8 tex
(Figure
in fourFor the first
densities series
(20, 25, of and
30, weaved35 samples, as
yarns/cm) wesingle-
used dyed(Figure CO 6a)ring
and yarns,
double- fineness
(Figure 26b)
×8
6b) layer yarn systems. For the second series of weaved samples, we used raw, undyed
tex
layer in four densities
yarn systems. (20, 25, 30,
For the34second and 35 yarns/cm) as single- (Figure 6a) and double- (Figure
PET rotor yarn, fineness tex, inseries
threeofdensities
weaved (6, samples,
10, 14,we and used
18 raw, undyed
yarns/cm) asPET ro-
single-
6b)yarn,
tor layerfineness
yarn systems.
34 tex, inFor thedensities
three second series(6, 10, of
14, weaved
and 18 samples, we
yarns/cm) as used raw,
single- undyed
(Figure 6c)
(Figure 6c) and double- (Figure 6d) layer yarn systems. A method for the preparation of
PETdouble-
and rotor yarn,
(Figurefineness 34 tex,
6d)samples
layer yarn in systems.
three densities (6, 10,for14,the
and 18 yarns/cm) as single-
single- or double-layer with uniformAdensity
method preparation
was developed of single-
and used or
(Section
(Figure
double-layer 6c) and double- (Figure 6d) layer yarn systems. A method for the preparation of
2.3) [26,27]. samples with uniform density was developed and used (Section 2.3) [26,27].
single- or double-layer samples with uniform density was developed and used (Section
2.3) [26,27].
Figure 6.
Figure 6. Single-layered
Single-layered(a,c)
(a,c)double-layered
double-layeredyarn
yarnsystems
systems(b,d)
(b,d)from
fromcolored
coloredcotton
cotton (CO)
(CO) yarns
yarns (a,b)
(a,b)undyed
and and undyed polyester
polyester (PET)(PET)
yarnsyarns (c,d)
(c,d) in 10×inmagnification.
10× magnification.
Figure 6. Single-layered (a,c) double-layered yarn systems (b,d) from colored cotton (CO) yarns
(a,b) and undyed polyester (PET) yarns (c,d) in 10× magnification.
3.2. Methods
3.2. Methods
The
The transmission
transmission and
and reflection
reflection of
of the
the selected
selected samples
samples was
was measured
measured with
with Lambda
Lambda
3.2. Methods
800,
800, UV/VIS
UV/VIS Spectrophotometer,
Spectrophotometer,PELA-1000
PELA-1000 (PerkinElmer
(PerkinElmer Inc.,Inc.,
Waltham, MA, USA).
Waltham, Mea-
MA, USA).
The transmission
surements werewere
mademade
anand reflection
“inanvitro” of the in
method selected samples
accordance was
with themeasured
SIST with Lambda
Measurements “in vitro” method in accordance with theEN 13758-1:2002
SIST EN 13758-
800, UV/VIS
standard, Spectrophotometer,
in 2-nm PELA-1000
steps and in the range (PerkinElmer
of 700–200 nm. We made Inc., five
Waltham, MA, USA).
measurements on
Measurements were made an “in vitro” method in accordance
each sample (vertically, horizontally, and at an angle of 45 ). ◦ with the SIST EN 13758-
Table3.3.DDddand
Table andD Dme values of
me values of the
the transmission
transmission TT (%)
(%) and
andreflection
reflectionRR(%),
(%),for
forsingle-
single-(T
(T1,1 R
,R ) and
1)1and
double- (T , R ) layered CO samples.
double- (T22, R22) layered CO samples.
D
Ddd[yarns/cm]
[yarns/cm] D me[yarns/cm]
Dme [yarns/cm] TT11[%]
[%] T22 [%]
T [%] R11 [%]
[%] R22 [%]
R [%]
20
20 21.67
21.67 47.06
47.06 20.8
20.8 9.67
9.67 10.46
10.46
25 25.67
25.67 35.87
35.87 13.08
13.08 9.74
9.74 11.00
11.00
30
30 30.00
30.00 28.52
28.52 9.16
9.16 10.06
10.06 10.99
10.99
35 36.33 19.06 2.89 10.53 11.03
35 36.33 19.06 2.89 10.53 11.03
From
Fromthethemeasured
measuredvaluesvalues ofof
T1T, T , 2and
1, 2T R1Rpresented
, and 1 presentedin in
Table 3, we
Table 3, wecreated a graphical
created a graph-
representation (Figure
ical representation 7) and
(Figure 7) got
andthegotequation
the equationdescribing themthem
describing in dependence
in dependence of density.
of den-
The
sity.maximum
The maximum density (Dmax(D
density ) was calculated
max) was fromfrom
calculated derivation of the
derivation of T 2 curve,
the because
T2 curve, at
because
that point,
at that the the
point, OAOA through samples
through supposed
samples supposed to betoabe
zero, andand
a zero, the the
transmission
transmissionshould be
should
minimal.
be minimal.At At
thethe
same
sametime, thethe
time, obtained
obtained results
resultsare based on the original measurement.
2 2and K √are based on the original measurement.
Table 4 presents values for K
Table 4 presents values for2TK2T ≈ 1T≈ K K1T and 2A ≈ K
K2A ≈ √K1A following the
1Afollowing the theory
theory presented
presentedinin
Section 2.2. These values,
Section 2.2. These values, D D and d
max and dmin
max min, were taken for the further calculationof
, were taken for the further calculation ofthe
thecover
cover
factor
factorparameters
parameterspresented
presentedininTable
Table5.5.FromFromthethelinear
linearequation
equationT1T1andandRR1 ,1,we
wecalculated
calculated
KK1T and K1Ratatthe
1T and K1R
thepoint
pointofofdetermined
determinedmaximum maximum density
density andand
K1AKas as different
1A different fromfrom 1
1 (Ta-
(Table
ble 6).6).
Table 5. Dmax and dmin , calculated values of Cf, Cfwa , Cfwe , Cf1 , Cf2 , and OA for CO samples.
Table 6. Calculated values (c ) of UV parameters double- (T2 , R2 , A2 ) layered CO samples and the absolute values of their
differences compared with measurement (me ) values and the conformation of their connections with the coefficient of
correlation.
Dd T2 R2 A2
∆|T2c − T2me | ∆|R2c − R2me | ∆|A2c − A2me |
[yarns/cm] (Equation (11)) (Equation (17)) (Equation (15))
Table 7. Dd and Dme , values of the T (%) and R (%), for single- (T1 , R1 ) and double- (T2 , R2 ) layered
PET samples.
Tables 5 and 6 show the calculation values of T2, R2, and A2 (Equations (11), (15) and
Table 10. Calculated values (17))
(c ) of according
UV parameters to thedouble-
theory.(TTable 6 presents calculated values compared with measured
2 , R2 , A2 ) layered PET samples and the absolute values of
values. It also presents the absolute
their differences compared with measurement (me ) values and the conformation differencesofamong calculatedwith
their connections andthe
measured
coefficientvalues
of as
correlation. well as correlation among them. It is obvious that the level of mistakes does not exceed
6.7% at the lowest used density.
Dd T 2 The R2obtained results A2clearly confirm the known fact that colored cotton yarns can be
∆|T2c − T2me | ∆|R2c − R2me | ∆|A2c − A2me |
[yarns/cm] (Equation (11)) used for permanent
(Equation (17)) and successful
(Equation (15)) protection against UV radiation if the woven fabric
6.67 0.70367 construction
0.12488 is carefully planned. For example,
0.12472 0.01573 if the weave is sateen, fabric
0.03632 construction
0.05205
11.25 0.53027 can have a maximum 0.25014
0.19133 weft density and0.00727 because of the high coefficient of absorption
0.03437 0.02710 can
13.33 0.45960 offer 0.21632
practically excellent 0.31779
protection against 0.00690
UV radiation 0.02838
[12]. 0.03527
18.33 0.31040 0.26313
For the second set0.50776
of samples from0.01580 PET yarns, we used 0.02087 0.03667 as for
the same methodology
r (c:me ) 0.998 0.999 0.980
the first set of samples from CO yarns. The results are presented in Tables 7–10 and in
Figure 8.
Figure 8. T and R of UV radiation of single-layer and double-layer PET samples, depending on the
yarn density, with the corresponding linear, polynomial equations, and the coefficient of determina-
tion.
The presented research shows very high correlations of 0.98 and differences not higher
than 5% between the calculated and measured values, which confirms the theoretical
assumption and confirms the established mathematical model for the prediction of the UV
protective properties of fabrics.
The identified coefficient of transmission for rotor PET yarn was 0.315, which was very
close to the monofilament PET yarn (0.3–0.35) [11,24], confirming that the row material has
a crucial role in the parameters of UV protection.
5. Conclusions
In the paper, an extension of the cover factor woven fabric theory was presented, which
is necessary for understanding the mechanism of penetration of UV light through the yarn
covered part of the mesh structure of fabrics. Regarding the penetration of UV light, the
previous cover factor theory did not distinguish between the fabric areas covered by one
and two yarns, which is why there was no existing model for predicting the transmission
and thus the ultraviolet protection factor (UPF). The extension of the theory provides the
Polymers 2021, 13, 1188 12 of 13
theoretical relationships between the existing and newly introduced parameters of the
cover factor (Cf, OA, Cf1 , Cf2 ) and fabrics constructional parameters (d and D)). The theory
was applied to the woven fabrics made from the same yarns and with the same warp and
weft densities but can be easily extended to other types of woven fabrics.
A simplified theoretical model for the prediction of UV protection properties was
presented, which offers the possibility to plan for the phase of fabric design stage. The
model was called simplified because not all elements were exact; however, the calculations
were very simple, and the results were good enough to serve the purpose. In addition to the
elements of the extended cover factor theory, the data for the UV reflection, transmission,
and absorption of the yarns (KR , KT , KA ) were included in the model. Such data do usually
not exist in the literature. The paper also presents the procedure of preparation of proper
single- and double-layer samples. The samples represent a simulation of woven fabrics
without interlacing of yarns (thus avoiding the deformation of yarns), which are suitable
for fast and cheap determination of the missing data from a very low quantity of any row
material and yarn type.
The experimental part performed on red dyed CO yarns confirmed the fact that
intensely dyed yarns absorb most of the UV light (coefficient K1A = 0.84), have small
reflection (K1R = 0.12) and very low transmission (K1T = 0.04), which makes them almost
perfect for constructing woven fabrics that can provide at least good, very good, and
permanent UV protection. The results of the experiment on the second set of samples
confirmed the assumption that coefficient of transmission of PET yarns is about 0.3 to 0.35,
which was found in one of our previous research for the PET monofilament.
The obtained results of the experimental part justify both theories (cover factor and
simplified model). It must be said that the obtained results practically give the maximal
transmission (minimal UPF). Due to the interlacing in the real fabrics, the deformation
of the yarns at the interlacing points and the resulting reduction of the open area, the
transmission should be lower and the UPF should be higher.
Author Contributions: Conceptualization, K.D.; methodology, K.D., K.K.; formal analysis, K.D.,
K.K.; investigation, K.D., K.K.; data curation, K.D., K.K.; writing—original draft preparation, K.D.
and K.K.; writing—review and editing, K.D., K.K.; funding acquisition, K.D. All authors have read
and agreed to the published version of the manuscript.
Funding: This research received no external funding.
Institutional Review Board Statement: Not applicable.
Informed Consent Statement: Not applicable.
Data Availability Statement: The data presented in this study are available on request from the
corresponding author.
Conflicts of Interest: The authors declare no conflict of interest.
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