Lecture Notes-Mole
Lecture Notes-Mole
Lecture Notes-Mole
- n .
Physical chemical
Glassine classification
F'Tm
*÷÷Ei'÷
- -
o
high Pat
&
loot
E high T
-| Yl¥TATEOFMATTE#
b-
PLASMA STATE
{ me;÷I- }
Ionized gas containing
Inane
gas
ey , lightning
stars
SOLID LIOUID Temp point
.
=
Melting
6100113 TI GAS ( VAPOUR ) Tent Boiling
or =
.
-
°
T O
PIBstANES Mixture
be separated be
# can 't # can
separated
by physical methods
by physical methods
TO 0
ftp.YENT/C0MP0UNDTf
0 contain more Than
contain only one
O
/\ s
0¥
I
inorganic
0
confounds A
compounds Ac Chiefs, effing
'
Y
-
Tm feMPN) &
( DCNsiT
way
⇐ faucet )
solugtim
f.no#/
tho =
Nat g- H2O
single phase
-
a
-
Eat
⇐ aasmixture →
Single phase .
's
c
of Feo I 17203 → 2
phases
( Fett) ( Fetz
IMIX-URC.SI
-0 0
/±*÷÷÷÷±%
Homogeneous MIX .
Heterogeneous
-
Mix .
1-
mo.etiuanaephasetx.si:
single-phase Fusing
"
'
: on
→ H2o (g)
{3 phases }
=
#I thomas)
-
→
lawcfconseruaticnof.mu# :
4h chemical reaction :
@assofpood_uctDfIHUcqytNa0Hcqy-2Naclcqjt h0fe136.s
Ecesis of reactant) - I
-
40 585 18
gm gm gm gm
{ MR = 36.5-140 =
Emp = 58.5+18
-
lawtfdefinikproportions-r.cn
→
compound
a same elements
always
combine in a
fixed proportion by mass .
④ H2O
→ 16g O
18g few
→ 2-
GIM
Mo :
mm
= 16 : 2 = 8 :/ ( constant)
#
.
-9N
no.gs#o-- F
H2O : no .
of atoms
of H
Show that
on reduction produced O -
92 gm of copper .
resultsjustifylawofdef-n.to/nstxpt.I
these
# : copper = 216
gm Copper oxide = 2.7 gm
mass
of 0 = 2.7 -
2-16 =
0.54 gm
mass ratio :
Mcu/mo
=
2oq = -
①
# copper =
O -
92
gm Copper oxide =
" 15
gin
0 1-15
man
of =
0.92 0.23
=
gm
-
I÷=o÷3 , =⑤ -
②
.
.
.
① e ② are
equal .
I
.
Law
of definite proper .
justified
lawofmultipupoopostions-n.at
→
' ?
' '
combines with two elements B
element A
' '
to different then
& c form '
two
'
'
compounds
'
manses
of B e C which combine with fixed man
of A'
'
with
are in
simple ratio each other .
② NO
14g 16g
③ Nz 03 28g 48
g
with 28
g of Nitrogen man
of oxygen combined
is in ratio =
16g :
32g
:
48g 04g 80g
: :
=
→
#
I :3 4=5 simple
: 2 :
ratio
=
⑤ Two oxides
of lead were reduced to metallic lead
by
heating with hz in two experiments :
⑦ Man
of yellow oxide used =
3.45pm
mo ← loss
of mass due to reduction = 0.24 gm .
④ Mass
of Brown oxide used =
1.195 gm
due to reduction = 0.156
gm
loss
of man .
? o- of Pb
' man
M 6
BIN oxide :
mPb/mo = =
with Igm 0
Man of Pb
reacting with fgm O
) is in ratio = 1216.24 =
ratio
Snafu
--
I
→ MOLE CONCEPT :
-_ #
# i more =
{Ygjfotpe
C- atoms in '
Lgn of c- 12
}
=
NA = 6.023 X 1023
Number
(
Avogadro
's
,
atom I mde of atoms
# I =
grain
-
molecules
I
grain
-
molecule = I note
of
1 grain
-
ion =
I rude of lens
Resat Atenas ( R A M)
:#
→ . -
Iy
Yz (
Dimensionless
/RrArM=MassA1atanm#
of C- 12 atom) mass
If ( )
I AMN =
fz mass
of C- 12 atom
= I t Mess unit
*
/RHM=MassA,lagtn7Aekma#
-
EI R Arm
.
of O =
④ @ AM)
t ←
←
P
lughole
t
f
( ) )
luck
of
of
(
mass one man
Eaton o - atom
# { I AMU =
¥ ( mass
of C- 12 atom )
iz Cia's) ¥ }
-
-
an
,
°h③
ftp.imgur
-
of atoms of
element .
④ ( Sulphur) S ( RAM 2)
-
o/\o
{Lff gm= 32 AMU
} {328/6}
to to
atoms
mS-atf-
# Relative Mdeculax Mass CRM - M )
= Mass
-
of l molecule dfeleueitiompomd
l AMV ( or
# Cma 9- Fan)
's
all
= Sum
of RAM of atoms in
a molecule
# Arain
- -
Molecular Mass ( arm M) -
⑨
f → Camm )
98 AMU 98
glmde
= Mass
of one
= Man
of Inde
pyzgoy molecule
fyzfoy molecules
(9*1)
=
gm ' '
= Man
4- NA
= 98×1-6715024 gun thfoy
molecules
-
-
Immaterial
µousAmdewks=Maa;g!Ie=noA¥Y£#
-
→ LID # equation :
fPV=n/ n - moles
'
R=a¥tT =
Absolute ,§np .
I latmzl.co/3Bar.=lro13XI0JPaCN/m2
tf
760 760
Hg Torr
= = mm
,=76anHg#
|=1O3mL=1o3cm3fr#
153 m3 I def
# IL =
=
#
1-144=-141-12737
→
*ag
fr.osIIImoiv#
can ' '
(aeD -
YII÷oIzzarin
casein P → Bao
i
/P=1Barg-=0C=273rI5 I
#
# INTI ,
Normal
Temp .
& Pressure Condemn
/p=1atm,-=o°c=273K#
-
→
µ0T
① At NTP
/RT=22ML-matm_#
1-
€0821 X 273
)
② At S Trp
/RT=227L##
-
1-
③ At 1 atm
-
E -
300k ( or (07083×273)-7
RT
(
27°C
=
)
take RT -_
0.0821×3=-24-63
24-63
⑨ At S -
Trp for ideal gas
/Vm=22#n#/
#
Um = Molar volume =
%
proof
→
PV - NRT
Vm =
In =
Rt =
0.08311×2732=22.7
⑤ At NTP for ideal
gas JVmt-22.tl/n#
Proof
vm=nI 2
→
Rpt
= =
⑥ At 1 atm e 3W K
-
fvmr-24.io#4nMI
INofmdesAmdecuks=a?,g=No7jf#
#
= =
Find atoms
no .
of wider
of molecules & in
④ 196 gm of Mady (H -
I
, 5--32,0=10)
rude of molecule j
L
of molecules 2nA
= no .
-_
11 11 atoms =
14 5
'
i n atoms = 14 NA
⑤ "9
kg of Hzpoy ( P -
3D
molecule 50
more
of =
11 11 at ours =
400
④ HAM
of 42Wh 98 =
of molecules =
toggle
mole = 2
⑧ me 4900
gm
98 g and
Hzpoy
=
UMM
of
499,1
end
of molecules = = 50
no
of 6.023×1023
JONA 50 X
.
11 =
=
④ Find no
of .
protons ,
neutrons & electrons in
32
gm Cny 4 ) ( )
-
N
e
*
12 12 NA
I maacn
l molecule 10 6 10
Clay has
=P , =
N
, -
e
lie)
Cfc ,
⑤ Calculate I
arrange
in
decreasing
order of
volume at STP for following gas samples :
4)
(2)
88g
1.6g
wzcg )
02cg )
yt
{- 2731
(3) 1.2046×1020 molecules of Nz Cg)
(4) 6.023×1024 atoms
of the
(g)
-
S⑤ C) may
=
=
2
Vaz = 2×22.7
=
45.4 L
(2) 1%2
0,05×22-7
0.05
Moz = =
Voz
-
135 L
I -2046×1020 XTOY
③ N
Nz
= = 2 my
¥5023
Vnz =
2×704×227 L
(4) n
me
= 6.023×1024 = to end
¥523
=22#
④ Find no .
3
of protons ,
neutrons & electrons in
N' ( Nitride )
(a) 42g ion
→ 7N
I. 21
NA LI
NA 22nA
S④ Ca )
N→
I has
f lo 7h
]
-
ion
p g
e
g
4,2yd
and of N' car = =3 not
@m4igpbomae.Y4.n;D
(b) I NJO has
[ 21
p ,
22 e-
g
21 n
)
md
of Nj =
Uffe = Imd
⑤ Arrange in
decreasing order
of no .
of atoms :
CI ) L -
24L Oz at NTP
3D
(E) 2.12
gm Narcos ( Na -
- 23
,
CI 2,0=167 .
[Ans -
: III > I > I > I
]
S④ Moz
=
zj?Y = or ' md
Md -
of atoms =
0.2inch
CI) nw< = 2.27×-106 L
=
187 and
Ma .
of atoms =
3xmd
CI ) nhzpoy = 9-
Egg = Orl
Md .
of atoms =
0.8inch
CI) n
Nazcoz
=
2%2 = 0.02
Md .
of atoms =
0.12Mt
④ Hzsoy
y
TF 32g Sg 64 go
98 has 2g H
l more =
gm Hz soy g
←
2nd H
b 4 and O
l nd s
b b b
2g 32g 69g
Intend
Fg ytq
:
Mtl = constant = =
MHz y
321
M÷ constant I
= = =
1
2g
6%-4=37
MO
=
Boy
⑤ Find man
of 172804 which contains 6. y
gm
Aur :
Grieg
#
Ms =
=
Boy mtzsoy
19 6
mnzgoy gm
= -
⑤ Find man
of oxygen
in 4.24 gm of Naz coz
[ Molar man of Naz cog glued]
→ 48g O
MO
Toft y?÷
=
lrazgm
=
mo -
w
,
④ Find vd .
of 02cg) at STP
if it contains
as
many
O atoms as in 196
gm Hzsoy ?
-
/Am=-#
-
o
s④ and of nary =
tfgd = 2nd
÷¥÷÷÷:
-
# Do
yourself :
( ¥3,6]
{ }
Ex S -
l : I to 10
exo -
l : I -66,8