SAFETY DATA SHEET

I. IDENTIFICATION PRODUCT IDENTIFICATION DAVIES ROOFSHIELD BAGUIO GREEN

PRODUCT DESCRIPTION Davies Roofshield - a pure water-based acrylic emulsion gloss paint for beautifying and protecting
galvanized iron and cementitious roofs as well as masonry walls.
PRODUCT CODE DV-50-33
DATE CREATED 10 November 2017
DATE REVISED 5 July 2020
SUPPLIER'S DETAILS
Supplier's name: Davies Paints Philippines, Inc. Telephone Number: (02) 8641-7101
Address: 1387 Mercedes Ave., San Miguel Mobile Numbers: 0917-5721458 / 0922-8886491
Pasig City, Metro Manila Email: customercare@daviespaints.com.ph
1600 Philippines Website: www.daviespaints.com.ph

II. HAZARDOUS A. EMERGENCY OVERVIEW

IDENTIFICATION Non-flammable/Non-corrosive waterbased paint
Harmful if ingested (damaging to mucous membranes).
May cause eye, skin and respiratory system irritation.
B. POTENTIAL HEALTH EFFECTS
EYE CONTACT May cause severe eye irritation.
SKIN CONTACT May cause irritation or allergic reaction by prolonged contact.
INGESTION Harmful or fatal if swallowed.
INHALATION Irritating to mucous membranes. Inhalation of vapor or mist can cause headache, nausea, irritation of nose, throat, and lungs.

III. COMPOSITION / List of hazardous ingredient(s)

INFORMATION ON Chemical Name CASRN % Concentration
INGREDIENTS 2-(2-hydroxyethoxy)ethan-1-ol 111-46-6 1-5
2,2,4-trimethyl-1-[(2-methylpropanoyl)oxy]pentan-3-yl 2-
6846-50-0 1-5
methylpropanoate
2-amino-2-methyl-1-propanol 124-68-5 0.1 - 1.0

List of ingredient(s) with no available hazard classifications

Chemical Name CASRN % Concentration
Limestone 1317-65-3 1-5
Cellulose, hexadecyl 2-hydroxyethyl ether 80455-45-4 0.1 - 1.0
Other ingredients do not present health or environment hazard

IV. FIRST AID EYE CONTACT Immediately flush with water for at least 15 minutes. It is also recommended to have medical personnel check your eyes
MEASURES afterwards.
SKIN CONTACT Remove severely contaminated clothing immediately and flush skin with large amounts of water until irritation subsides. If
irritation persists, get medical attention.
INHALATION Remove to fresh air and if not breathing, give mouth to mouth resuscitation. If breathing is difficult, give oxygen. Call a physician.
INGESTION Do not induce vomiting. Keep rest. Get prompt medical attention. Never give anything by mouth to an unconscious person.

V. FIRE FIGHTING Flash Point and Method Not Applicable

MEASURES Flammable Limits, by volume (LEL - UEL) Not Applicable
Autoignition Point Not Applicable
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers may explode (due to the build-up of pressure when exposed to extreme heat).
During emergency conditions overexposure to decomposition products may cause health hazard.
Symptoms may not be immediately apparent. Obtain medical attention.
FIRE EXTINGUISHING MEDIA:
Water, foam, dry chemical, carbon dioxide or dry sand.

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FIRE FIGHTING EQUIPMENT:

Respiratory and eye protection required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing
apparatus (SCBA) should be used for all indoor fires and significant outdoor fires. For small outdoor fires, which may easily be extinguished with a
portable fire extinguisher, use of a SCBA may not be required.
HAZARDOUS COMBUSTION PRODUCT:
If product is heated to elevated temperatures, irritating vapors can be produced.

VI. ACCIDENTAL Provide maximum ventilation. Personal protection should be used. Remove all sources of ignition. Contain spilled liquid with sand or earth. Avoid
RELEASE runoff into storm sewers and ditches which lead to waterways. Take up spilled material with vermiculite, dry sand. (Don't use organic material to take
MEASURES up or wipe for example: sawdust, cotton cloth or paper which cause fire by spontaneous chemical reaction with air and paint and organic materials)
and place in a disposal container.

VII. HANDLING Handle in sufficiently ventilated areas.

AND STORAGE Keep container closed. Loosen closure cautiously before opening.
Store in a cool, well ventilated place away from incompatible materials.
Keep away from heat, sparks and flame. Protect material from direct sunlight.

VIII. EXPOSURE The face, eyes, head, hands, and all other exposed parts of the bodies of employees handling paints shall be protected. All footwear shall be non-
CONTROLS / sparking, such as rubbers, rubber boots or rubber soled shoes without nails. Coveralls or other outer clothing shall be of cotton. Rubber, rather than
PERSONAL plastic, gloves shall be used because of the danger of static sparks.
PROTECTION No matches, lighted cigarettes, cigars, or pipes, and no cigarette lighters or ferrous articles shall be taken into the area where work is being done. All
employees continuously in a compartment in which painting is being performed shall be protected by air line respirators in accordance with the
requirements of the Occupational Safety & Health Administration (OSHA) and by suitable protective clothing. Employees entering such compartments
for a limited time shall be protected by filter cartridge type respirators in accordance with the requirements of the OSHA. All employees doing exterior
paint spraying shall be protected by suitable filter cartridge type respirators in accordance with the requirements of the OSHA and by suitable
protective clothing.
Do not eat, drink, or smoke while handling it. Thoroughly wash the hands with soap and water before meals and at the end of the work shift.

IX. PHYSICAL AND Appearance Green liquid

CHEMICAL Odour Faint odor
PROPERTIES Odour threshold Not available
pH 8-9
Freezing point 0 ºC (water)
Initial boiling point and boiling range 100 ºC (water)
Flash point Not applicable
Evaporation rate (butyl acetate = 1) Slower than ether
Flammability (solid, gas) Not applicable because product is liquid
Upper/lower flammability or explosive limits, % volume Not applicable
Vapour pressure 23 mbar @ 20 ºC (water)
Vapour density (air = 1) Equal to water
Relative density (water = 1) 1.08
Solubility in water Disperses in water
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature Not applicable
Decomposition temperature Not available
Viscosity 98 - 100 Krebs Unit, KU (Krebs Viscometer)

X. STABILITY AND STABILITY

REACTIVITY This product is considered stable under normal and anticipated storage and handling conditions.
INCOMPATIBILITY (Materials to Avoid)
None known.

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XI. TOXICOLOGICAL 2-(2-hydroxyethoxy)ethan-1-ol

INFORMATION ROUTES OF EXPOSURE: 2-(2-hydroxyethoxy)ethan-1-ol is rapidly and almost completely absorbed via the oral route. It is slowly and
incompletely absorbed via the skin.
SYMPTOMS: Abdominal pain. Nausea. Vomiting. Diarrhoea. Dizziness. Drowsiness. Confusion. Unconsciousness.
INHALATION RISK: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on
spraying or dispersing, however, much faster.
EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the kidneys, resulting in kidney impairment. The substance
may cause effects on the central nervous system and liver by ingestion. Exposure by ingestion may result in death.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Data not available.
ACUTE ORAL TOXICITY: Acute oral LD50 value was 12565 mg/kg body weight in rats which is out of category. Ergo, it is not classified.
ACUTE DERMAL TOXICITY: Acute dermal LD50 was 11890 mg/kg body weight in rabbit which is out of category. Hence, it is not classified.
ACUTE INHALATION TOXICITY: The acute 4-hour inhalation LC50 in rats was 5.08 mg/L based on OECD Guideline 403 and is classified as
Category 3.
SKIN CORROSION / IRRITATION: According to the Draize test performed in rabbits and guinea pigs, 2-(2-hydroxyethoxy)ethan-1-ol is non-
irritating, consequently, it is not classified.
SERIOUS EYE DAMAGE / EYE IRRITATION: No ocular irritation after application of 0.5 ml undiluted 2-(2-hydroxyethoxy)ethan-1-ol was
observed in albino rabbit's eye. Wherefore, it is not classified.
RESPIRATORY / SKIN SENSITIZATION: Classification is not possible due to lack of data.
Skin sensitization: The guinea pig maximization test showed that 2-(2-hydroxyethoxy)ethan-1-ol is not sensitizing, for this reason, it is out of
category.
GERM CELL MUTAGENICITY: 2-(2-hydroxyethoxy)ethan-1-ol does not induce cytogenetic damage in bone marrow cells of NMRI mice in vivo
according to OECD Guideline 474 (Mammalian Erythrocyte Micronucleus Test) and 2-(2-hydroxyethoxy)ethan-1-ol was neither genotoxic nor
cytotoxic to Chinese hamster Ovary (CHO) cells subsequently based on test similar or equivalent to OECD Guideline 473 (In vitro Mammalian
Chromosome Aberration Test), consequently, it is out of category.
CARCINOGENICITY: Based in a two-year bioassay in rats, 2-(2-hydroxyethoxy)ethan-1-ol is negative for carcinogenicity, on that account, it is
not classified.
REPRODUCTIVE TOXICITY: 2-(2-hydroxyethoxy)ethan-1-ol is a reproductive toxicant in Swiss mice affecting fertility and reproductive
performance, although at high doses and developmental toxicity was noted at 8.0 ml/kg/day and included reduced foetal weight and delayed
ossification. There from, 2-(2-hydroxyethoxy)ethan-1-ol is classified as Category 2 reproductive toxicant.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Effects from long-term exposure are seen predominantly in the kidney and
to a lesser degree in the liver. Kidney effects were reported consisting of oxalate crystalluria, increased urine volumes and histopathological
evidence of hydropic degeneration and tubular necrosis. These effects were seen when given at high doses and so it is considered to be out of
category.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

Limestone
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin and/or eye contact.
SYMPTOMS: Irritation of eyes, skin, mucous membrane; cough, sneezing, rhinorrhea (discharge of thin nasal mucus); lacrimation (discharge of
tears)
TARGET ORGANS: Eyes, skin, respiratory system
ACUTE ORAL TOXICITY: Classification is not possible due to lack of data.
ACUTE DERMAL TOXICITY: Classification is not possible due to lack of data.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION / IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE / EYE IRRITATION: Classification is not possible due to lack of data.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: Classification is not possible due to lack of data.
REPRODUCTIVE TOXICITY: Classification is not possible due to lack of data.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.
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2,2,4-trimethyl-1-[(2-methylpropanoyl)oxy]pentan-3-yl 2-methylpropanoate
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin and/or eye contact and by ingestion.
SYMPTOMS: Skin irritation.
ACUTE ORAL TOXICITY: Classification is not possible since the available data were conclusive but not sufficient for classification.
ACUTE DERMAL TOXICITY: Classification is not possible since the available data were conclusive but not sufficient for classification.
ACUTE INHALATION TOXICITY: Classification is not possible since the available data were conclusive but not sufficient for classification.
SKIN CORROSION / IRRITATION: Classification is not possible since the available data were conclusive but not sufficient for classification.
SERIOUS EYE DAMAGE / EYE IRRITATION: Classification is not possible since the available data were conclusive but not sufficient for
classification.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible since the available data were conclusive but not
sufficient for classification.
Skin sensitization: Classification is not possible since the available data were conclusive but not sufficient for classification.
GERM CELL MUTAGENICITY: Classification is not possible since the available data were conclusive but not sufficient for classification.
CARCINOGENICITY: Classification is not possible since the available data were conclusive but not sufficient for classification.
REPRODUCTIVE TOXICITY: Classified as Category 2 based on the following evidences: there was a statistically significant decrease in the total
number of implants, reduced litter weights on postnatal days 0 and 4, and increased mortality in the offspring on postnatal day 4 through oral
exposure.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

2-amino-2-methyl-1-propanol
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion.
INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this
substance at 20°C.
SYMPTOMS: (INHALATION) Cough. Sore throat. (SKIN) Redness. Pain. (EYES) Redness. Pain. Severe deep burns. (INGESTION)
Abdominal pain. Burning sensation.
EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes. The substance is severely irritating to the skin. The aerosol
is irritating to the respiratory tract.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the liver when ingested.
ACUTE ORAL TOXICITY: Classified as Category 5 for the reason that the acute oral LD50 of mouse was calculated as 2,150 mg/kg and the LD50
of rat was calculated as 2,900 mg/kg which is considered to be of low toxicity.
ACUTE DERMAL TOXICITY: There was neither mortality nor toxicity when rabbits were exposed to 2,000 mg of the substance for every
kilogram body weight of the test animals. Consequently, it is assumed that the acute dermal LD50 of rabbits is greater than 2,000 mg/kg body
weight which is set as out of category, thus, it is not classified.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION / IRRITATION: Based on five daily applications of 2-amino-2-methyl-1-propanol to the shaved abdomen of rabbits, it is
considered to be irritating to the skin. Hence, it is classified as Category 2 (Skin irritant).
SERIOUS EYE DAMAGE / EYE IRRITATION: In two studies of the eye irritation potential of 2-amino-2-methyl-1-propanol in rabbits, 2-amino-2-
methyl-1-propanol was applied to the eyes of 6 rabbits. In one study, the eyes were flushed with water 15 to 30 seconds post application, in the
second study the eyes were not flushed with water. 2-amino-2-methyl-1-propanol caused severe damage to the eyes and flushing almost
immediately with water appeared to have little beneficial effect. The damage caused by 2-amino-2-methyl-1-propanol appears likely to be due to
the high pH rather than any other type of chemical damage. It is classified as Category 1 Eye irritant (Irreversible damage on the eyes).
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: 2-Amino-2-methyl-1-propanol was a non-sensitizer in the topical sensitization test in guinea pigs, under the Buehler test
conditions.
GERM CELL MUTAGENICITY: Gene mutation tests according to the following guidelines OECD Guideline 476 (In vitro Mammalian Cell Gene
Mutation Test), OECD Guideline 471 (Bacterial Reverse Mutation Assay), OECD Guideline 474 (Mammalian Erythrocyte Micronucleus Test) were
concluded to be negative for genotoxicity, wherefore, it is not classified.
CARCINOGENICITY: Classification is not possible due to lack of data.
REPRODUCTIVE TOXICITY: According to OECD Guideline 421 (Reproduction / Developmental Toxicity Screening Test), oral exposure of CD-
rats to 2-amino-2-methyl-1-propanol had no effects on mating or conception. Liver effects in females at 100 mg/kg/day and higher, increased post-
implantation loss at 300 mg/kg/day and higher.
Based on OECD Guideline 414 (Prenatal Developmental Toxicity Study), dermal administration of 2-amino-2-methyl-1-propanol no statistically
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 DAVIES ROOFSHIELD BAGUIO GREEN

There were no external foetal alternations observed. Any reported findings were sporadic in nature, and were not considered toxicologically
relevant or treatment related. From these data, 2-amino-2-methyl-1-propanol is considered to be out of category.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

Cellulose, hexadecyl 2-hydroxyethyl ether

ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin/eye contact and by ingestion.
SYMPTOMS: (Eye contact) Dust can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.
(Ingestion) Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may
be harmful.
(Inhalation) This material is a dust or may produce dust. Prolonged or repeated breathing of this material may result in chronic bronchitis
(inflammation of the airways of the lungs). Symptoms include coughing and shortness of breath.
AGGRAVATED MEDICAL CONDITION: Pre-existing disorders of the following organs (or organ systems) may be aggravated by exposure to
this material:, lung (for example, asthma-like conditions).
ACUTE ORAL TOXICITY: Classification is not possible due to lack of data.
ACUTE DERMAL TOXICITY: Classification is not possible due to lack of data.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION / IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE / EYE IRRITATION: Classification is not possible due to lack of data.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: Classification is not possible due to lack of data.
REPRODUCTIVE TOXICITY: Classification not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to insufficient data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to insufficient data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

XII. ECOLOGICAL This has the potential to be toxic in environments. Do not leak or waste in the environments without adequate waste disposal handling.
INFORMATION

XIII. DISPOSAL Empty containers and material (including waste thinner for cleaning and flushing of containers or application equipment) must be disposed in
CONSIDERATION accordance with government and local environmental control regulations.
Do not heat or cut empty container with electric or gas torch because due to residue.

XIV. TRANSPORT UN Number: Not available (Product is not regulated)

INFORMATION UN Proper Shipping Name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards:
Marine pollutant according to IMDG Code: No
Environmentally hazardous according to UN Model Regulations: No
Environmentally hazardous according to ADR: No
Environmentally hazardous according to RID: No
Environmentally hazardous according to ADN: No
Special precautions for user:
EmS Guide: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: No
IATA Dangerous Goods and ICAO Technical Instructions for the Safe
Transport of Dangerous Goods by Air ERG Code: Not applicable
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XV. REGULATORY Philippines Inventory of All components of this product are registered in the Philippines Inventory of Chemicals and Chemical Substances
INFORMATION Chemicals and Chemical (PICCS).
Substances (PICCS)

TSCA Inventory List All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

Montreal Protocol No component of this product is listed on the Montreal Protocol on Substances that Deplete the Ozone Layer.

Stockholm Convention No component of this product is listed on the Stockholm Convention on Persistent Organic Pollutants.

Rotterdam Convention No component of this product is listed on the Rotterdam Convention on the Prior Informed Consent Procedure for
Certain Hazardous Chemicals and Pesticides in International Trade.

XVI. OTHER Legend to abbreviations and acronyms used:

INFORMATION CASRN means Chemical Abstract Service Registry Number
LFL - UFL means lower flammability limit - upper flammability limit
TWA8 means 8-hour time weighted average
LD 50 means the amount of a chemical, given all at once, which causes the death of 50% (one half) of a group of test animals
LC 50 (50% lethal concentration) means the concentration of a chemical in air or of a chemical in water which causes the death of 50% (one
half) of a group of test animals
GHS means the Globally Harmonized System of Classification and Labelling of Chemicals
IUCLID means the International Uniform Chemical Information Database
HSDB means the Hazardous Substance Data Bank
SIDS means the Screening Information Dataset
EHC means the Environmental Health Criteria
OECD means the Organisation for Economic Co-operation and Development
ECHA means the European Chemical Agency
UN means the United Nations
IMDG Code means the International Maritime Dangerous Goods Code
ADR means the European Agreement concerning the International Carriage of Dangerous Goods by Road
RID means the Regulations concerning the International Carriage of Dangerous Goods by Rail
ADN means the European Agreement concerning the International Transport of Dangerous Goods by Inland Waterways
EMS Guide means the Emergency response procedures for Ships Carrying Dangerous Goods
MARPOL 73/78 means the International Convention for the Prevention of pollution from Ships, 1973, as modified by the
Protocol of 1978 relating thereto, as amended
IBC Code means the International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in
Bulk (International Bulk Chemical Code)
IATA means the International Air Transport Association
ICAO means the International Civil Aviation Organization
ERG Code means the Emergency Response Drill Code as found in the International Civil Aviation Organization (ICAO)
document “The Emergency Response Guidance for Aircraft Incidents Involving Dangerous Goods”

The information herein is given in good faith but we cannot guarantee that these are the only hazards which exist. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards
and should be used with caution.

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