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    The Arrhenius Equation For Reversible Reactions

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    murat
    The document discusses: 1. The Arrhenius equation and how it relates the forward and backward rate constants to temperature. 2. A table showing how the forward rate constant, backward rate constant, and equilibrium constant change with temperature based on different activation energies for the forward and backward reactions. 3. Graphs of the natural log of the forward and backward rate constants versus the inverse of temperature which are used to determine the activation energies from the slopes.

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    The Arrhenius Equation For Reversible Reactions

    Uploaded by

    murat
    52 views4 pages
    The document discusses: 1. The Arrhenius equation and how it relates the forward and backward rate constants to temperature. 2. A table showing how the forward rate constant, backward rate constant, and equilibrium constant change with temperature based on different activation energies for the forward and backward reactions. 3. Graphs of the natural log of the forward and backward rate constants versus the inverse of temperature which are used to determine the activation energies from the slopes.

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    The document discusses: 1. The Arrhenius equation and how it relates the forward and backward rate constants to temperature. 2. A table showing how the forward rate constant, backward rate constant, and equilibrium constant change with temperature based on different activation energies for the forward and backward reactions. 3. Graphs of the natural log of the forward and backward rate constants versus the inverse of temperature which are used to determine the activation energies from the slopes.

    Copyright:

    © All Rights Reserved
    Download as XLS, PDF, TXT or read online from Scribd
    Download as xls, pdf, or txt
    52 views4 pages

    The Arrhenius Equation For Reversible Reactions

    Uploaded by

    murat
    The document discusses: 1. The Arrhenius equation and how it relates the forward and backward rate constants to temperature. 2. A table showing how the forward rate constant, backward rate constant, and equilibrium constant change with temperature based on different activation energies for the forward and backward reactions. 3. Graphs of the natural log of the forward and backward rate constants versus the inverse of temperature which are used to determine the activation energies from the slopes.

    Copyright:

    © All Rights Reserved
    Download as XLS, PDF, TXT or read online from Scribd
    Download as xls, pdf, or txt
    of 4

    The Arrhenius Equation for Reversible Reactions

    1. the forward rate constant as a function of temperature

    2. the backward rate constant as a function of temperature

    3. the equilibrium constant as a function of temperature

    4. an Arrhenius Plot for determining the activation energy

    You can resize the screen by going to View on the menu bar and select Zoom...

    Click on the tabs to navigate!


    Arrhenius Equation k =Ae-Ea/RT Forward A = 100 Backward A = 5000
    take the ln of this equation Reaction Ea = 25 Reaction Ea = 29 DH = -4

    T (K) kf kb K = kf/kb 1/T ln kf ln kb


    Equilibrium Constant
    250 5.86E-04 4.26E-03 1.37E-01 0.00400 -7.44 -5.46 1.21
    260 9.31E-04 7.29E-03 1.28E-01 0.00385 -6.98 -4.92 1.01
    270 1.43E-03 1.20E-02 1.19E-01 0.00370 -6.55 -4.42 1
    0.8
    280 2.13E-03 1.90E-02 1.12E-01 0.00357 -6.15 -3.96 K 1
    290 3.09E-03 2.93E-02 1.05E-01 0.00345 -5.78 -3.53 0.61

    300 4.36E-03 4.37E-02 9.97E-02 0.00333 -5.43 -3.13 0.41


    310 6.03E-03 6.37E-02 9.47E-02 0.00323 -5.11 -2.75 0.21
    320 8.17E-03 9.06E-02 9.02E-02 0.00313 -4.81 -2.40 1
    0.0
    330 1.09E-02 1.26E-01 8.62E-02 0.00303 -4.52 -2.07 1250 270 290 310 330 350
    340 1.42E-02 1.72E-01 8.25E-02 0.00294 -4.25 -1.76 1
    Temperature
    350 1.83E-02 2.31E-01 7.93E-02 0.00286 -4.00 -1.47 1

    Rate constants as a function of temperature 1/T


    2.5E-01 0.002 0.004 0.006
    0.0
    2.0E-01 f(x) = − 3493.97590361446 x + 8.51719319141625
    -1.0
    1.5E-01 -2.0 f(x) = − 3012.04819277109 x + 4.6051701859881 note
    k
    -3.0
    1.0E-01
    ln k
    -4.0
    5.0E-02 -5.0

    0.0E+00 -6.0
    250 270 290 310 330 350 -7.0
    Temperature Arrhenius Plot
    separate plots are given below -8.0
    two temperature version deriving the equation
    Sinex 2006

    Note: different y-axis scales!


    Forward Rate Constant Backward Rate Constant

    2.00E-02 2.50E-01
    1.80E-02
    1.60E-02 2.00E-01
    1.40E-02
    1.20E-02 1.50E-01
    kf kb
    1.00E-02
    8.00E-03 1.00E-01
    6.00E-03
    4.00E-03 5.00E-02
    2.00E-03
    0.00E+00 0.00E+00
    250 260 270 280 290 300 310 320 330 340 350 250 270 290 310 330 350

    Temperature Temperature

    change of rate constant from 250 to 350 K


    (k350/k250) 31.26 54.22

    larger change: backward


    type of reaction: exothermic

    Sinex 2006
    Is this possible? Explain why or why not. Answer

    Can an equilibrium constant, K, ever be temperature independent?


    Answer

    Sinex 2006

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