E= Eo - RT/nf Ln Q helps evaluating the potential of a cell is called

Select one:
A. Hess equation
B. none of the above
C. Redox equation
D. Nernst Equation

In comparison to acid chlorides what effect will be expected on the central carbonyl of an acid
anhydride

Select one:
A. Resonance
B. High stabilization
C. Less destabilization
D. Conjugation

Which of the following is not used in the detection of radioactivity?

Select one:
A. Scintillation counter
B. Geiger-Muller counter
C. Flame ionization detector
D. Film-badge dosimeter

Ammonia reacts with an aldehyde to give an

Select one:
A. amide
B. Imine
C. Amine
D. Alcohol

If K >>> 1, the equilibrium will lie in favour of ----------.

Select one:
A. Product
 B. Reactant
C. Catalyst
D. a and b only.

Acetone is the common name for:

Select one:
A. 2-propanone
B. 2-butanone
C. 1-propanone
D. 1-butanone

The specific heat of a substance

Select one:
A. is the amount of heat required to raise the temperature of one gram of the substance by
10C
B. is the amount of heat required to raise the temperature of a given quantity of the substance
by 10C
C. None of the above
D. is the amount of heat required to raise the temperature of one gram of the substance by
0C
273

On reduction in the presence of Zn/Hg, amides yields?

Select one:
A. Ketones
B. Alcohols
C. Amines
D. Ethers

What is the oxidation number of Si in H2SiO3 ?

Select one:
A. +4
B. +5
C. +2
 D. +1

Which of the following alkene addition reaction that does not obey markovnikov rule

Select one:
A. Halogenation
B. Halohydrin formation
C. Hydroboration
D. Hydration

Balance the acidic aqueous solutions equations:

Sn(s) + O2(aq) + HCl(aq) → SnCl2(aq) + H2O(l)

Select one:
A. 4Sn(s) + O2(aq) + 3HCl(aq) → 4SnCl2(aq) + 2H2O(l)
B. Sn(s) + 2O2(aq) + 4HCl(aq) → SnCl2(aq) + 2H2O(l)
C. 3Sn(s) + 2O2(aq) + 4HCl(aq) → 3SnCl2(aq) + 6H2O(l)
D. 2Sn(s) + O2(aq) + 4HCl(aq) → 2SnCl2(aq) + 2H2O(l)

Which among these is not a structural isomer of the compound C 4H8

Select one:
A. But-2-ene
B. But-3-ene
C. But-1-ene
D. 2-methylpropene

Which of the following process is not used for synthesizing alcohol?

Select one:
A. Reduction of ketones
B. Hydration of alkenes
C. Ozonolysis
D. Hydrolysis of esters

A 93-L sample of dry air is cooled from 145 oC to -22 oC at a constant pressure of 2.85
atmospheres). What is the final volume?
Select one:
A. 28 L
B. 112 L
C. 93 L
D. 56 L

If a particle collides elastically with the wall, it bounces off the wall with no loss of energy. The
particles velocity was v before the collision and –v after the collision after a time interval Δt.
Therefore the force per collision (Fcollision) is given by

Select one:
A. m(Δt)/v
B. m(v)/Δt
C. m(-v)/Δt
D. m(2v)/Δt

The half-life of 231Pa is 3.25 x 104 years. How much of an initial 10.40 microgram sample
remains after 3.25 x 105 years?

Select one:
A. 0.0240 micrograms
B. 2.18 micrograms
C. 0.240 micrograms
D. 0.0102 micrograms

The cyanide ion −C≡N reacts with a ketone to give

Select one:
A. a cyanohydrins
B. an amine
C. an aldehyde
D. an acid

For the manufacture of H2SO4 in a contact process the catalyst used is ---

Select one:
A. Mn2O5
 B. V3O9
C. V2O5
D. Cr2O5

The unit for rate constant for a second order reaction is given as

Select one:
A. L2mol-2s-2
B. Lmol-1s-2
C. Lmol-1s-1
D. L2mol-1s-1

Select the incorrect statement regarding terminal alkynes

Select one:
A. Methylacetylene is an example of terminal alkynes
B. Are not as acidic as alkanes
C. More acidic when compared with alkenes
D. Have a replaceable acidic hydrogen atom

Consider the following equations (I) v-nb (II) v+nb (III) v2-nb (IV) P + a(n/V)2 (V) P - a(n/V)2 .
The product of which two equals nRT in the van der Waals equation

Select one:
A. (I) * (V)
B. (I) * (IV)
C. (II) * (IV)
D. (II) * (V)

----- is the gas used in Geiger-Muller counter.

Select one:
A. helium
B. uv
C. neon
 D. argon

What is the symbol of lawrencium?

Select one:
A. Lw
B.

La

C. Lr
D. Lm

A voltage that develop as a result of contact of two different phases is known as

Select one:
A. Liquid – solid potential
B.

Full cell potential

C.

Half-cell potential

D. Liquid junction potential

If the standard enthalpy of formation of CO2(g) is – 393 KJmol- how many grams of carbon must
be burned to produce 786 KJ of heat

Select one:
A. 44.0 g
B. 12.0 g
C. 88.0 g
D. 24.0 g

CH3CH2CH2CONH2 reacts with LiAlH4 to give

Select one:
 A.

CH3CH2CH2CH2NH2

B. CH3CH2CH2NH2
C. CH3CH2CH2CH2NHOH
D. CH3CH2CH2CH2NOH

Give the equation that relate concentration to time for a 1 st

Select one:
A. 2.303 log [A]t/[A]0 =kt
B. 2.303 log [A]t/[A]0 =kt2
C. 2.303 log [A]t/[A]0 =k2t
D. 2.303 log [A]t/[A]0 =k2t2

A sample of aluminum absorbed 9.86 J of heat and its temperature increased from 23.2ºC to
30.5ºC. What is the mass of the aluminum?

Select one:
A. 72 g
B. 8.1 g
C. 65 g
D. 1.5 g

How many isomers can you get from C6H14

Select one:
A. 5
B. 4
C. 3
D. 6

In Charles’ law, the only way for pressure to be constant is

Select one:
A. number of particles to be constant
 B. pressure to be varied
C. volume to be altered
D. volume to be increased

The correction for intermolecular forces is given by P = ?

Select one:
A. P * a(n/V)2
B. V + a(n/V)2
C. P - a(n/V)2
D. P + a(n/V)2

Calculate the root mean square velocity (in m/s) of oxygen atom at 25 oC. [O = 16, R = 8.314 J
mol-1 K-1

Select one:
A. 723
B. 515
C. 482
D. 241

Preparation of alkenes from alkylhalide takes place in which medium?

Select one:
A. Zn/H2O
B. Alcoholic (KOH or NaOH)
C. H2O2
D. Ether

What is the mass of molecular oxygen gas in a 438 Litre gas cylinder whose pressure is 1.37
atmosphere at a temperature of 21 oC. [ R = 0.0821 atmL mol-1 K-1

Select one:
A. 797 g
B. 407 g
C. 397 g
D. 753 g
Which is NOT true of the postulates of the kinetic molecular theory of gases

Select one:
A. the collision of one particle with another and with the walls of the container is partially
elastic
B. the average kinetic energy of the particle is proportional to the applied temperature in
kelvins
C. particles are in constant random motion in straight lines until they collide with another
particle.
D. The sizes of gaseous particles are small relative to the size of the container

Which is true for an exothermic reaction?

Select one:
A. The reactants are below the products in the potential energy diagram
B. The reactants have more kinetic energy than the products
C. The ΔH is positive
D. The products have less potential energy than the reactants

Alkanes that contain 5 to 17 atoms are in

Select one:
A. Plasma state
B. Solid state
C. Gaseous state
D. Liquid state

The coalescence of protons in nuclear energy is -------

Select one:
A. Hess’s law
B. radioactivity
C. fission
D. fusion

What happens to the water in a calorimeter when an exothermic reaction occurs in it?

Select one:
 A. It absorbs heat, and a drop in temperature is observed
B. It releases heat, and a drop in temperature is observed
C. It absorbs heat, and a rise in temperature is observed
D. It releases heat, and a rise in temperature is observed

Which of the following material is associated with a scintillation counter?

Select one:
A. BaCl2
B. CaCl2
C. FrBr
D. NaI

For the production of NH3 in Haber process the catalyst used is ------

Select one:
A. Fe
B. Cd
C. Mn
D. Ni

When alkynes is bubbled into a solution of ammonical copper (II) chloride, copper atom displace
hydrogen atom to form ………………

Select one:
A. white precipitate of copper (I) dicarbide
B. reddish-brown precipitate of silver chloride
C. reddish-brown precipitate of copper (I) dicarbide
D. white precipitate of silver chloride

What are Lactams?

Select one:
A. Cyclic Ketones
B. Cyclic amines
C. Cyclic Carboxylic acids
 D. Cyclic Amides

The "magic numbers" for atoms are

Select one:
A. atomic masses that confer nuclear stability
B. numbers of protons and/or neutrons that confer nuclear stability.
C. numbers of electrons that confer atomic stability
D. n/p ratios that confer nuclear stability

Reaction of halogens (Group-VII) and alkane (saturated hydrocarbons) in presence of sunlight is

Select one:
A. Substitution
B. hydrogenation
C. Carbation
D. Halogenation

Primary and secondary alcohol can be distinguish from tertiary alcohol using

Select one:
A. all of the above
B. Jones test
C. Iodo from test
D. Lucas test

Calculate the volume of a sample of carbon monoxide that is at -14 oC and 367 torrs if it
occupies 3.65 L at 298 K and 745 torrs

Select one:
A. 6.44
B. 3.28
C. 4.64
D. 12.35

CH3CH2MgBr + CO2 + H3O+ will react to give

ethanol

B. propanoic acid
C. Butanol
D. Propanol

Which among the following is not an alkane isomer with 6 carbon atoms

Select one:
A. Neopentane
B. 2,2-dimethylbutane
C. Hexane
D. 2,3-dimethylbutane

When NH4Cl(s) is added to water, the resulting solution feels cool to the touch. Which best
describes this observation?

Select one:
A. NH4Cl(s) → NH4+(aq) + Cl–(aq) + 33.6 Kj
B. NH4Cl(s) + 33.6 kJ → NH4+(aq) + Cl–(aq)
C. NH4Cl(s) → NH4+(aq) + Cl–(aq) ΔH = -33.6 kJ
D. Heat is released as NH4Cl(s) dissolves

Factors to be considered for chemical reactions to occur

Select one:
A. the reacting molecule must collide
B. the reacting molecule must jump
C. the reacting molecule must start
D. none of the above

Calculate the nuclear binding energy of 16O in J per atom, given that the observed atomic mass is
15.99491 u. Electron rest mass=9.10939 x 10-31 kg; Proton rest mass=1.67262 x 10-27 kg;
Neutron rest mass=1.67493 x 10-27 kg; c= 2.998 x 108 ms-1; atomic number of O=8:
Select one:
A. 2.94 x 10-11 J per atom
B. 2.05 x 10-11 J per atom
C.

3.01 x 10-12 J per atom

D. 3.42 x 10-11 J per atom

The sole difference between diffusion and effusion is

Select one:
A. Vacuum
B. room temperature and pressure
C. molecular diameter
D. concentration gradient

What is the effect of doubling the temperature and pressure on the volume of 1 mole of an ideal
gas

Select one:
A. V remains unchanged
B. V decreases by a factor of 2
C. V decreases by a factor of 4
D. V increases by a factor of 4

If emphasis was on a 2-dimensional derivation of the root mean square velocity (μ rms), then the
final equation is the positive square root of

Select one:
A. RT/2M
B. 2RT/M
C. 3RT/M
D. RT/M

Those catalyst that speed up the rate of chemical reaction are called

Select one:
 A. positive catalyst
B. micro catalyst
C. hydro catalyst
D. negative catalyst

A spontaneous cell that convert chemical energy to electrical energy is termed.

Select one:
A. Voltaic cell
B. Chemolytic cell
C. Electrolytic cell
D. Photolytic cell

Calculate the rate constant in min-1 for the concentration of a drug in a body expressed in unit
milligram/kg with initial does of 30.00mg/kg in the body of the animal. After 2 hrs the
concentration of the drug administer to the animal dropped to 10.00mg/kg which is eliminated by
the first order.

Select one:
A. 9.16x10-6min-1
B. 9.16x10-3min-1
C. 9.16x10-7min-1
D. 8.16x10-3min-1

Which of the following alcohols would be oxidised to propan-2-one?

Select one:
A. 2-methylpropan-2-ol
B. Ethanol
C. butan-1-ol.
D. propan-2-ol

For the Ideal gas equation PV = nRT, the pressure P is measured in -----------

Select one:
A. MmHg
B. Tons
 C. Nm-2
D. Atmospheres

Which of these is the general molecular formula of alkenes

Select one:
A. CnH2n
B. CnH2n -2
C. CnH2n + 2
D. CnH2n +1

A sample of chlorine gas is confined in a 5.0 L container at 328 torr and 37 oC. How many moles
of gas are in the sample?

Select one:
A. 1.2 mole
B. 0.01 mole
C. 0.085 mole
D. 0.6 mole

Identify the one which shows E-Z mechanism

Select one:
A. 2-methylpent-2-ene
B. 3-methylpent-2-ene
C. 2,3-methylpentene
D. 2,4-dimethyl-pent-2-ene

The following methods are use to test for alcohol except

Select one:
A. Iodoform Test
B. Lucas Test
C. Jones Test
D. Bromine water Test

The product of reaction CH3CH2CH2CH2CH=CH2 + O3/H2O/Zn is

CH3CH2CH2CHO and CH3CHO

C. CH3CH2CH2COOH and CH3CH2CH2=CH2

Benzoic acid, propanal, methybutanoate and Butan-2-one are reduce to their respective alcohol
using which of the reagents

Select one:
A. all of the above
B. KMnO4
C. Pt/H2
D. LiAlH4

Which of the following energy source does not require a turbine?

Select one:
A. nuclear
B. wind
C. solar
D. geo-thermal

If 41.2 kJ of energy is needed to raise the temperature of 170.0 g of a liquid from 18.8ºC to
65.2ºC, what is the specific heat capacity of the solution?

Select one:
A. 5.22 J/g•ºC
B. 11.2 J/g•ºC
C. D. 12.0 J/g•ºC
D. 4.19 J/g•ºC

The total work done when a cell is in equilibrium condition is_________ joule.

Select one:
 A. 100 J
B. 25 J
C. 50 J
D. 0 J

How much heat is released when 100 g of butane is burned with formation of water vapour (ΔH O
of water vapour is – 2878 KJmol-1 )

Select one:
A. -2878 KJ
B. -2658 KJ
C. +2304 KJ
D. - 4962.1 KJ