FULL TEST-2 - PCM - Question Paper

FIITJEE- NJEETS
(JEE MAIN TEST SERIES - 2022)

CLASS - XII
FULL TEST - 2
TEST ID : T-59000
CONDUCTION DATE: 27-01-2022
Time Allotted: 3 Hours Maximum Marks: 300
 Do not open this Test Booklet until you are asked to do so.
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
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attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
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rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks will be awarded for every correct answer and -1 mark will be
deducted for every incorrect answer.
(i) Part-C (01-05) contains Five (05) Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +4 marks will be awarded for every correct answer and NO MARKS will be
deducted for every incorrect answer.
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NJEETS-2022 - FT - 2 -PCM -2
Useful Data Chemistry:

Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
-27
= 6.25 x 10 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
-27
1 amu = 1.66 x 10 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
NJEETS-2022 - FT - 2 -PCM -3
Section – I (Physics)
PART – A
Single Correct Choice Type
1. In an experiment the angles are required to be measured using an instrument. 29 divisions of the main scale
exactly coincide with the 30 divisions of the vernier scale. If the smallest division of the main scale is half-a-
degree(=0.5o), then the least count of the instrument is
(A) one minute (B) half minute

(C) one degree (D) half degree
2. A fish looking up through the water sees the outside world contained in a circular horizon. If the refractive
index of water is 4/3 and the fish is 12 cm below the surface, the radius of this circle in cm is
(A) 36 7 (B) 36 / 7 (C) 36 5 (D) 4 5
3. Two fixed frictionless inclined plane making an angle

o o
30 and 60 with the vertical are shown in the figure.
Two block A and B are placed on the two planes.
What is the relative vertical acceleration of A with
respect to B ?
(A) 4.9 ms–2 in horizontal direction

(B) 9.8 ms–2 in vertical direction
(C) zero
(D) 4.9 ms–2 in vertical direction
4. The potential energy function for the force between two atoms in a diatomic molecule is approximately given
a b
by U(x)  12  6 , where a and b are constants and x is the distance between the atoms. If the dissociation
x x
energy of the molecule is D = [U(x = ) – Uat equilibrium], D is
b2 b2 b2 b2
(A) (B) (C) (D)
2a 12a 4a 6a
5. Two coherent point sources S1 and S2 are separated by a small d

distance ‘d’ as shown. The fringes obtained on the screen will be: S1 S2 Screen
D
(A) straight lines (B) semi-circles
(C) concentric circles (D) points
6. The two bodies of masses m1 and m2 (m1 > m2) respectively are tied to the ends of a string, which passes
over a light frictionless pulley. The masses are initially at rest and released. The acceleration of the centre of
mass is
2
 m  m2   m  m2 
(A)  1  g (B)  1 g
 m1  m2   m1  m2 
(C) g (D) zero
space for rough work
NJEETS-2022 - FT - 2 -PCM -4
7. A ‘T’ shaped object with dimensions shown in the figure, is lying

on a smooth floor. A force F is applied at the point P parallel to
AB, such that
the object has only the translational motion without rotation.
Find the location of P with respect to C
2 3
(A) l (B) l
3 2
4
(C) l (D) l
3
8. A jar filled with two non mixing liquids 1 and 2 having densities 1 and 2
respectively. A solid ball, made of a material of density 3, is dropped in the
jar. It comes to equilibrium in the position shown in the figure.
Which of the following is true for 1, 2 and 3? Liquid 1 1
3
Liquid 2 2
(A) 3 < 1 < 2 (B) 1 < 3 < 2

(C) 1 < 2 < 3 (D) 1 < 3 < 2
9. The figure shows a system of two concentric spheres of radii r1 and r2

and kept at temperatures T1 and T2 respectively. The radial rate of flow
of heat in a substance between the two concentric sphere is
proportional to
r2  r1  r2 
(A) (B) ln  
r1r2  r1 
rr
(C) 1 2 (D) ln  r2  r1 
r2  r1
10. The above p-v diagram represents the thermodynamic cycle of

A B
an engine, operating with an ideal monoatomic gas. The amount 2p0
of heat extracted from the source in a single cycle is p
p0 C
D
O v0 2v0
v
 13   11 
(A)   p0 v0 (B)   p0 v0
 2 2
(C) 4p0v 0 (D) p0v 0
NJEETS-2022 - FT - 2 -PCM -5
11. A fully charged capacitor has a capacitance ‘C’ it is discharged through a small coil of resistance wire
embedded in a thermally insulated block of specific heat capacity ‘s’ and mass ‘m’. If the temperature of the
block is raised by ' T '. The potential difference V across the capacitance is
2mC T mC T msT 2msT

(A) (B) (C) (D)
s s C C
12. Two charges, each equal to q, are kept at x = a and x = a on the x-axis. A particle of mass m and charge
q
q0  is placed at the origin. If charge q0 is given a small displacement (y  a) along the y-axis, the net
2
force acting on the particle is proportional to:
1
(A) y (B)
y
1
(C)  (D) y
y
13. If a ball of steel (density  = 7.8 cm-3) attains a terminal velocity of 10 cm s-1 when falling in a tank of water
(coefficient of viscosity water = 8.5  10-4 Pa.s) then its terminal velocity in glycerin ( = 1.2 g cm -3  = 13.2
Pa.s) would be, nearly :
(A) 1.5  10-5 cm s-1 (B) 1.6  10-5 cm s-1

(C) 6.25  10-4 cm s-1 (D) 6.45  10-4 cm s-1
14. A current I flows along the length of an infinitely long, straight, thin walled pipe. Then
(A) the magnetic field is zero only on the axis of the pipe
(B) the magnetic field is different at different points inside the pipe
(C) the magnetic field at any point inside the pipe is zero
(D) the magnetic field at all points inside the pipe is the same, but not zero
15. Two long parallel wires are at a distance 2d apart. They carry steady equal current flowing out of the plane of
the paper as shown. The variation of the magnetic field along the line XX ' is given by
(A) (B)
(C) (D)
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16. A metallic rod of length ‘’ is tied to a string of length 2 and made
to rotate with angular speed  on a horizontal table with one end
of the string fixed. If there is a vertical magnetic field ‘B’ in the
region, the e.m.f. induced across the ends of the rod is:
3B 2 4B 2
(A) (B)
2 2
5B 2 2B 2
(C) (D)
2 2
17. The maximum possible mutual induction between the two coil of inductance L1 and L2 can be
(A) L21  L22 (B) L1L 2

L1L 2
(C) (D) L1 + L2
L1  L2
18. The bob of a simple pendulum is a spherical hollow ball filled with water. A plugged hole near the bottom of
the oscillation bob gets suddenly unplugged. During observation, till water is coming out, the time period of
oscillation would
(A) first increase and then decrease to the original value.
(B) first decreased then increase to the original value.
(C) remain unchanged.
(D) increase towards a saturation value.
19. A mass M, attached to a horizontal spring, executes S.H.M. with amplitude A1. When the mass M passes
through its mean position then a smaller mass m is placed over it and both of them move together with
 A1 
amplitude A2. The ratio of   is:
 A2 
1/ 2 1/ 2
Mm  M  Mm M
(A) (B)   (C)   (D)
M Mm  M  Mm
20. A string is stretched between fixed points separated by 75 cm. It is observed to have resonant frequencies of
420 Hz and 315 Hz. There are no other resonant frequencies between these two. Then, the lowest resonant
frequency for this string is
(A) 10.5 Hz (B) 105 Hz (C) 1.05 Hz (D) 1050 Hz
NJEETS-2022 - FT - 2 -PCM -7
PART – C
Integer Type
1. A particle located at x  0 at time t = 0, starts moving along the positive x –direction with a velocity ‘v’ that
varies as v   x. The displacement of the particle varies with time as t n . Find n.
2. A bomb of mass 16 kg at rest explodes into pieces of masses of 4 kg and 12 kg. The velocity of the 12 kg
1
mass is 4ms . The kinetic energy of the other mass is 32n Joules. Find n.
3. A hoop of radius r and mass m rotating with an angular velocity 0 is placed on a rough horizontal surface.
The initial velocity of the centre of the hoop is zero. The velocity of the centre of the hoop when it ceases to
r0
slip is . Find n.
n
4. In the circuit, the galvanometer G shows zero deflection. If

the batteries A and B have negligible internal resistance, the
value of the resistor R is 100 n  . Find n .
5. The minimum force required to start pushing a body up a rough (frictional coefficient ) inclined plane is F1
while the minimum force needed to prevent it from sliding down is F2. If the inclined plane makes an angle 
from the horizontal such that tan  = 2 then the ratio F1/F2 is:
NJEETS-2022 - FT - 2 -PCM -8
Section – II (Chemistry)
PART – A
Single Correct Choice Type
1. The equilibrium constants KP1 and K P2 for the reactions X  2Y and Z  P  Q, respectively are in the
ratio of 1 : 9. If the degree of dissociation of X and Z be equal then the ratio of total pressure at these
equilibria is
(A) 1 : 36 (B) 1 : 1 (C) 1 : 3 (D) 1 : 9
2. In aqueous solution the ionization constants for carbonic acid are

K1 = 4.2 x 10–7 and K2 = 4.8 x 10–11
Select the correct statement for a saturated 0.034 M solution of the carbonic acid.
(A) The concentration of CO32  is 0.034 M.
(B) The concentration of CO32  is greater than that of HCO 3 .
(C) The concentration of H+ and HCO 3 are approximately equal.
(D) The concentration of H+ is double that of CO32  .
3. In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
3
CH3 OH( )  O2 (g)  CO 2 (g)  2H2 O( ) At 298K standard Gibb’s energies of formation for
2
CH3 OH(), H2 O() and CO2 (g) are -166.2, -237.2 and -394.4 kJ mol1 respectively. If standard enthalpy of
combustion of methanol is -726kJ mol1 , efficiency of the fuel cell will be
(A) 80 % (B) 87% (C) 90% (D) 97%
4. A 5.25 % solution of a substance is isotonic with a 1.5% solution of urea (molar mass = 60 g mol1) in the
same solvent. If the densities of both the solutions are assumed to be equal to 1.0 g cm 3, molar mass of the
substance will be
(A) 90.0 g mol1 (B) 115.0 g mol1 (C) 105.0 g mol1 (D) 210.0 g mol1
5. CsCl crystallises in body centred cubic lattice. If ‘a’ is its edge length then which of the following expressions
is correct?
3 3a
(A) rCs  rCl  a (B) rCs  rCl  3a (C) rCs   rCl   3a (D) rCs  rCl 
2 2
6. Assuming that water vapour is an ideal gas, the internal energy (U) when 1 mol of water is vapourised at 1
bar pressure and 100C, (Given: Molar enthalpy of vapourization of water at 1 bar and 373 K = 41 kJ mol1
and R = 8.3 J mol1K1) will be
(A) 4.100 kJ mol1 (B) 3.7904 kJ mol1

(C) 37.904 kJ mol1 (D) 41. 00 kJ mol1
NJEETS-2022 - FT - 2 -PCM -9
7. A solution containing 2.675 g of CoCl3. 6 NH3 (molar mass = 267.5 g mol–1) is passed through a cation
exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give 4.78 g of AgCl
(molar mass = 143.5 g mol–1). The formula of the complex is (At. Mass of Ag = 108 u)
(A) [Co(NH3)6]Cl3 (B) [CoCl2(NH3)4]Cl (C) [CoCl3(NH3)3] (D) [CoCl(NH3)5]Cl2
8. In a multi – electron atom, which of the following orbitals described by the three quantum numbers will have
the same energy in the absence of magnetic acid and electric fields?
(a) n = 1, l = 0, m = 0 (b) n = 2, l = 0, m = 0 (c) n = 2, l = 1, m = 1 (d) n = 3, l = 2, m = 1
(e) n = 3, l = 2, m = 0
(A) (a) and (b) (B) (b) and (c) (C) (c) and (d) (D) (d) and (e)
9. If Z is a compressibility factor, van der Waals equation at low pressure can be written as:
Pb Pb RT a
(A) Z  1 (B) Z  1 (C) Z  1 (D) Z  1
RT RT Pb VRT
10. Which one of the following conformation of cyclohexane is chiral?
(A) Twist boat (B) Rigid (C) Chair (D) Boat
11. The organic chloro compound, which shows complete stereochemical inversion during a SN2 reaction, is
(A) (C2H5)2CHCl (B) (CH3)3CCl (C) (CH3)2CHCl (D) CH3Cl
12. The number of stereoisomers possible for a compound of the molecular formula
CH3  CH  CH  CH  OH  Me is :
(A) 3 (B) 2 (C) 4 (D) 6
13. Out of the following, the alkene that exhibits optical isomerism is
(A) 3–methyl–2–pentene (B) 4–methyl–1–pentene
(C) 3–methyl–1–pentene (D) 2–methyl–2–pentene
14. Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives
(A) 2,4,6-trinitrobenzene (B) o-nitrophenol (C) p-nitrophenol (D) nitrobenzene
15. Consider the following reaction:

C2 H 5 OH  H 2SO 4 
 Product
Among the following, which one cannot be formed as a product under any conditions?
(A) Diethyl ether (B) Ethyl-hydrogen sulphate

(C) Ethylene (D) Acetylene
16. A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass
390. The number of amino groups present per molecule of the former compound is:
(A) 5 (B) 4 (C) 6 (D) 2
17. Considering the basic strength of amines in aqueous solution, which one has the smallest pKb value?
(A)  CH 3 3 N (B) C6 H5 NH 2 (C)  CH 3 2 NH (D) CH3 NH 2
NJEETS-2022 - FT - 2 -PCM -10
18. The secondary structure of a protein refers to

(A) α-helical backbone (B) hydrophobic interactions
(C) sequence of -amino acids (D) fixed configuration of the polypeptide backbone
19. The polymer containing strong intermolecular forces e.g. hydrogen bonding, is
(A) teflon (B) nylon-6,6 (C) polystyrene (D) natural rubber
20. Identify the incorrect statement among the following

(A) d-Block elements show irregular and erratic chemical properties among themselves
(B) La and Lu have partially filled d orbitals and no other partially filled orbitals
(C) The chemistry of various lanthanoids is very similar
(D) 4f and 5f orbitals are equally shielded
PART – C
Integer Type
1. In how many of the following ionization processes, the bond order has increased and the magnetic behaviour
has changed?
C2  C2 ; NO   NO ; O2  O2 ; N2  N2
2. How many of the following species exhibits the diamagnetic behaviour?

O22 ; O 2 ; O 2 ; NO
3. If the coordination number and the oxidation state of the element ‘E’ in the complex [E(en)2(C2O4)]NO2 are x
and y respectively (where (en) is ethylene diamine). Report x  y
4. Heating mixture of Cu2 O and Cu 2 S will give a gas S a Ob . Report the sum of a  b.
5. The rate of a reaction doubles when its temperature changes from 300K to 310K. If the activation energy of
such a reaction is 2 18  y  kJ mol –1 . Find the value of y.
(R = 8.314 JK–1 mol–1 and log 2 = 0.301)
pace for rough work
NJEETS-2022 - FT - 2 -PCM -11
Section – III (Mathematics)

1. A circle touches the x-axis and also touches the circle with centre at (0, 3) and radius 2. The locus of the
centre of the circle is
(A) an ellipse (B) a circle (C) a hyperbola (D) a parabola
a3 x 2 a 2 x
2. The locus of the vertices of the family of parabolas y    2a is
3 2
105 3 35 64
(A) xy  (B) xy  (C) xy  (D) xy 
64 4 16 105
3. Statement-1: The point A(3, 1, 6) is the mirror image of the point B(1, 3, 4) in the plane x – y + z = 5.
Statement-2: The plane x – y + z = 5 bisects the line segment joining A(3, 1, 6) and B(1, 3, 4).
(A) Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is false
(C) Statement-1 is false, Statement-2 is true
(D) Statement-1 is true, Statement-2 is true; Statement-2 is the correct explanation for Statement-1
3x 2  9 x  17
4. If x is real, the maximum value of is
3x 2  9 x  7
(A) ¼ (B) 41 (C) 1 (D) 17/77
5. From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and
arranged in a row on the shelf so that the dictionary is always in the middle. Then the number of such
arrangements is
(A) less than 500 (B) at least 500 but less than 750
(C) at least 750 but less than 1000 (D) at least 1000
1 1 1
6. 
Let A and B be two event such that P A  B   6
, P  A  B   and P  A   . where A stands for
4 4
complement of event A. Then events A and B are
(A) equally likely and mutually exclusive (B) equally likely but not independent
(C) independent but not equally likely (D) mutually exclusive and independent
2 2
7. The intercept on the line y  x by the circle x  y  2x  0 is AB. Equation of the circle on AB as a
diameter is
2 2 2 2
(A) x  y  x  y  0 (B) x  y  x  y  0
2 2 2 2
(C) x  y  x  y  0 (D) x  y  x  y  0
NJEETS-2022 - FT - 2 -PCM -12
 1 z 
8. If z is a complex number of unit modulus and argument , then arg   equals
 1 z 

(A)  (B)  (C)    (D)  
2

9.  xf  sin x  dx
0
is equal to
   /2  /2

(A)   f  cos x  dx (B)   f  sin x  dx (C)  f  sin x  dx (D)   f  cos x  dx
0 0 2 0 0
 1
10. In a binomial distribution B  n, p   , if the probability of at least one success is greater than or equal to
 4
9
, then n is greater than
10
1 1
(A) (B)
log10 4  log10 3 log10 4  log10 3
9 4
(C) (D)
log10 4  log10 3 log10 4  log10 3

11. Solution of the differential equation cos x dy = y(sin x – y) dx, 0 < x < is
2
(A) y sec x = tan x + c (B) y tan x = sec x + c (C) tan x = (sec x + c)y (D) sec x = (tan x + c)y
12. Given P  x   x 4  ax3  bx 2  cx  d such that x = 0 is the only real root of P'  x   0 . If P  1  P 1 , then in
the interval  1, 1
(A) P(– 1) is the minimum and P(1) is the maximum of P

(B) P(– 1) is not minimum but P(1) is the maximum of P
(C) P(– 1) is the minimum and P(1) is not the maximum of P
(D) neither P(– 1) is the minimum nor P(1) is the maximum of P
13. An ellipse has OB as semi minor axis, F and F’ its foci and the angle FBF’ is a right angle. Then the
eccentricity of the ellipse is
1 1 1 1
(A) (B) (C) (D)
2 2 4 3
NJEETS-2022 - FT - 2 -PCM -13
  i
n
14. If x  a , y   b n , z   c n where a, b, c are in A.P. and a  1, b  1, c  1. then x, y, z are in
n 0 n 0 n 0
(A) G.P. (B) A.P.

(C) Arithmetic –Geometric progression (D) H.P.
2
1  cos  ax 2  bx  c 
15. Let  and  be the distinct roots of ax  bx  c  0, then lim 2
is equal to
x 
 x  
a2 2 a2 1 2 2
(A)     (B) 0 (C)     
    (D)
2 2 2
16. The locus of a point P  ,   moving under the condition that the line y   x   is a tangent to the
x2 y2
hyperbola 2  2  1 is
a b
(A) an ellipse (B) a circle (C) a parabola (C) a hyperbola
4 5 
17. Let cos( + ) = and let sin( – ) = , where 0  ,   , then tan 2 =
5 13 4
56 19 20 25
(A) (B) (C) (D)
33 12 7 16
1 y
18. If cos x  cos 1   , then 4 x 2  4 xy cos   y 2 is equal to
2
2 2
(A) 2sin 2 (B) 4 (C) 4sin  (D) 4 sin 
19. The statement ~(p  ~q) is
(A) equivalent to p  q (B) equivalent to ~p  q
(C) a tautology (D) a fallacy

9 1 8 2 7 9 9
20. If (10) + 2(11) (10) + 3(11) (10) + ….. + 10(11) = k(10) , then k is equal to
121 441
(A) (B) (C) 100 (D) 110
10 100
NJEETS-2022 - FT - 2 -PCM -14
PART – C
Integer Type
k
1. The area of the plane region bounded by the curves x + 2y2 = 0 and x + 3y2 = 1 is , then k equal to
3
11 11
7 2  1  7   1 
2. If the coefficient of x in  ax     equals the coefficient of x in  ax   2   , then ab equal
  bx     bx  
to
3. If a1 , a2 , a3 ,...., a n ...... are in G.P., then the determinant

log an log an 1 log an  2
  log an 3 log an  4 log an 5 is equal to
log an 6 log an  7 log an 8
5 tan x
4. If the integral  tan x  2 dx  x  a ln sin x  2 cos x  k, then a is equal to

5. The angle between the lines 2 x  3 y   z and 6 x   y  4 z is , then k
k
NJEETS-2022 - FT - 2 -PCM -15
FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2022)
CLASS - XII
FULL TEST - 2
CONDUCTION DATE: 03/01/2022
TEST ID : T-59000
ANSWERS
PART – A
1. A 2. B 3. D 4. C
5. C 6. A 7. C 8. D
9. C 10. B 11. D 12. D
13. C 14. C 15. A 16. C
17. B 18. A 19. C 20. B
PART – C
1. 2 2. 9 3. 2 4. 1
5. 3
PART – A
1. A 2. C 3. D 4. D
5. A 6. C 7. A 8. D
9. D 10. A 11. D 12. C
13. C 14. B 15. D 16. A
17. C 18. A 19. B 20. D
PART – C
1. 1 2. 1 3. 3 4. 3
5. 9
PART – A
1. D 2. A 3. A 4. B
5 D 6. C 7. A 8. B
9. D 10. A 11. D 12 B
13. A 14. D 15. A 16. D
17. A 18. C 19. A 20. C
PART – C
1. 4 2. 1 3. 0 4. 2
5. 2
NJEETS-2022 - FT - 2 -PCM -16
HINTS & SOLUTIONS

PART - A
1. A
o o
value of main scale division 1 1 1 1
Sol. Least count = = MSD =   = 1 minute
No of divisions on vernier scale 30 30 2 60
2. B
3 r
Sol. sin r 
4 12 r
9 7 r
cos r  1  
16 4
3 r
tan r  
7 12
36
r
7
3. D
Sol. mg sin  = ma
 a = g sin 
where a is along the inclined plane
 vertical component of acceleration is g sin2 
 relative vertical acceleration of A with respect to B is
g
g[sin2 60  sin2 30]   4.9 m / s 2 in vertical direction.
2
4. C
a b
Sol. U(x)  12
 6
x x
U(x = ) = 0
dU 12a 6b 
as, F    13  7 
dx x x 
at equilibrium, F = 0
2a
 x6 
b
a b b2
 Uat equilibrium  2
 
 2a   2a  4a
   
 b   b 
b2
 D  U(x  )  Uat equilibrium  
4a
5. C
Sol. Concept Based.
NJEETS-2022 - FT - 2 -PCM -17
6. A
 m  m2 
Sol. a1   a2   4 g  a
 m1  m2 
m a  m2 a2  m1  m2 
acm  1 1  a
m1  m2  m1  m2 
2
 m  m2 
 1  g
 m1  m2 
7. C
Sol. P will be the centre of mass of system
l  2 l    2 l  l  4 l 2 4 l
 
 3l 3l 3
8. D
Sol. As liquid 1 floats above liquid 2,
The ball is unable to sink into liquid 2,
3 < 2
The ball is unable to rise over liquid 1,
1 < 3
Thus, 1 < 3 < 2
9. C
dr
Sol. R dr
4 r 2
dQ
dT  R r r1
dt
T2
dQ r dr
2
r2
 dT  
T1
dt r 4 r 2
1
r2
dQ   1 
T2  T1  
dt 4   r  r1
dQ   1 1 
T2  T1    
dt 4  r1 r2 
dQ rr
 12
dt r2  r1
10. B
Sol. Heat is extracted from the source in path DA and AB is
3  P0 V0  5  2P0 V0  13
Q  R
2  R  2R R  = 2 P0 V0
  
NJEETS-2022 - FT - 2 -PCM -18
11. D
Sol. Q  msT
2
 i Rdt
 2t

2
 i0 e  Rdt
0

  2t 
 i 2 e R 
 0 2 
  0
i02 R
2
2 2
i0 R C
 msT
2
V 2C
 msT
2
2 msT
V
C
12. D
Sol. Fnet  2Fcos  F   F
k q q / 2 y q/2
2 2
 y
 a 2  y2  a  y2
2
q a a q
kq 2 y
 (y  a)
a3
13. C
2 r 2 (  )g
Sol. t 
9 
Vt' (  gly ) / gly


v t (   water ) / water
v't  6.25 104 cm/s
14. C
Sol. Use Ampere’s law
15. A
Sol. The magnetic field in between because of each will be in opposite direction
0 i ˆ 0i
Bin between = j ( ˆj)
2x 2(2d  x)
 i 1 1  ˆ
 0   ( j)
2  x 2d  x 
at x = d, Bin between = 0
for x < d, Bin between = ( ˆj)
for x > d, Bin between = ( ˆj)
towards x net magnetic field will add up and direction will be ( ˆj)
towards x ' net magnetic field will add up and direction will be ( ˆj)
NJEETS-2022 - FT - 2 -PCM -19
16. C
Sol. de  B(x)  dx

3L 2L L
e  B  xdx x
2L
2
5BL

2
17. B
Sol. Concept Based.
18. A
Sol. First CM goes down and then comes to its initial position.
19. C
Mv1
Sol. v1  1 A2 v2 
mM
v2  2 A2
k k
1  ; 2 
M M m
A1 v1 2 m M M
 
A2 v2 1 M M m
M m

M
20. B
Sol. HCF of 420 and 315 = 105 Hz
PART - C
1. 2
dx
Sol.  x
dt
x
dx t
   dt
0 x 0
2 x  t
4 x  2t 2
2. 9
Sol. 12  4  4 x
x  12 m / s
1
 KE   4  12  12  288 J
2
3. 2
Sol. From conservation of angular momentum about any fix point on the surface
mr 20  2mr 2

  0
2
r
 VCM  0
2
NJEETS-2022 - FT - 2 -PCM -20
4. 1
Sol. iR  2
500i  10
1
i
50
R  100 
5. 3
Sol. F1 = mg cos   mg sin  , F2 = mg sin   mg cos 
F1 mg cos   mg sin    tan 

 = =3
F2 mg sin   mg cos  tan   
PART - A
1. A
Sol.
X 
2Y


1 0
1  x  2x
2
 2x   P1 1
kp 1
1  x   1  x 


Z 
 PQ
1 0 0
1  x  x x
1
x 2  P2 
k p2 
1  x   1  x 
4  P1 1 P 1
  1 
P2 9 P2 36
2. C
+
Sol. A 

H2CO3  
 H + HCO 3 K1 = 4.2 x 10–7
+
B HCO 3  H + CO3
2
K2 = 4.8 x 10–11
As K2 << K1
All major H   H  
total A
and from I equilibrium, H    HCO 3   H  

A total
 CO 32  is negligible compared to HCO 3  or H  

total
NJEETS-2022 - FT - 2 -PCM -21
3. D
3
Sol. CH3 OH( ) + O2 (g)  CO2 (g)  2H2 O() H  726kJ mol1
2
Also Gof CH3 OH(  ) = -166.2 kJ mol-1
-1
Gof H2 O( ) = -237.2 kJ mol
-1
Gof CO 2 (  ) = -394.4 kJ mol
 G = Gof products Gof reactants.
= -394.4 -2 (237.2) + 166.2
-1
= 702.6 kJ mol
G
now Efficiency of fuel cell =  100
H
702.6
=  100
726
= 97%
4. D
Sol. Solutions with the same osmotic pressure are isotonic
Let the molar mass of the substance be M
1  C1RT  C2 RT  2
So, C1 = C2
As density of the solutions are same
5.25 15
So 
M 60
5.25  60
M  210
1.5
5. A
a
Sol. In CsCl structure, Cs+ ion is in contact with Cl– ion at the nearest distance which is equal to 3
2
Cl

Cs+

Cl

6. C
Sol. H2 O    
vaporisation
 H2 O  g 
ng  1  0  1
H   U   ng RT
U   H  n g RT
= 41 – 8.3 × 10-3 × 373
= 37.9 kJ mol-1
NJEETS-2022 - FT - 2 -PCM -22
7. A
– AgNO3
Sol : CoCl3. 6NH3  xCl   x AgCl 
n(AgCl) = x n(CoCl3. 6NH3)
4.78 2.675
x x=3
143.5 267.5
 The complex is  Co NH3 6  Cl3
8. D
Sol. n = same
9. D
 n 2a 
Sol.  P  2   V  nb   nRT
 V 
 a 
For 1 mole,  P  2   V  b   RT
 V 
a ab
PV  RT  Pb   2
V V
ab
at low pressure, terms Pb & 2 will be negligible as compared to RT.
V
a
So, PV  RT 
V
a
Z 1
RTV
10. A
Sol. Twisted boat is chiral as it does not have plane of symmetry.
11. D
Sol. For SN2 reaction, the C atom is least hindered towards the attack of nucleophile in the case of (CH3Cl).
12. C
Sol. About the double bond, two geometrical isomers are possible and the compound is having one chiral
carbon.
13. C
Sol.
H
H2C=HC C2 H5 only 3–methyl–1–pentene has a chiral carbon
CH3
14. B
OH
OH OH
NO 2
Conc.H2 SO4
  Conc.HNO3
 
SO 3H
NJEETS-2022 - FT - 2 -PCM -23
15. D
Sol. 110o C
C2 H5 OSO3 H
140o C
C2 H5 OH  H 2SO4 C2 H5OC2 H5
170o C
C2 H 4
16. A
O O
|| ||
Sol. R  NH 2  CH 3  C Cl 
 R  NH  C CH 3  HCl
O
||
Each CH 3  C addition increases the molecular wt. by 42.
Total increase in m.wt. = 390 – 180 = 210
210
Then number of NH2 groups = 5
42
17. C
Sol. Aliphatic amines are more basic than aromatic amines.
(CH3)2NH > CH3NH2 > (CH3)3N (among aliphatic amines in water).
18. A
Sol. Secondary structure of proteins involves   helical back bond and   sheet structures. These structures
are formed as a result of H-bonding between different peptide groups.
19. B
Sol. nylon 6,6 is a polymer of adipic acid and hexamethylene diamine

O O
C (CH2)4 C NH (CH2)6 NH
n
20. D
Sol. 4f and 5f belongs to different energy levels, hence the shielding effect is on them is not the same.
Shielding of 4f is more than 5f.
PART – C
1. 1
Sol. In C2 – C2+ electron is removed from bonding molecular orbital so bond order decreases. In NO  NO+,
electron is removed from anti bonding molecular orbital so bond order increases and nature changes from
paramagnetic to diamagnetic.
2. 1
Sol. The correct option is O22

This species has 18 e-, which are filled in such a way that all molecular orbitals are fully filled, so
diamagnetic.
1s2  * 1s2 , 2s2  * 2s2 , 2p 2z , 2p 2x  2p 2y , * 2p 2x  * 2p2y
NJEETS-2022 - FT - 2 -PCM -24
3. 3
en
E ox
NO 2
en
Coordination no. = 6 and Oxidation no. = 3
4. 3
Sol. 2Cu2O  Cu2 S 

 6Cu  SO2
5. 9
Sol. As per Arrhenius equation:

E 1 1
ln 2   a   
k
k1 R  T2 T1 
E a  1 1 
2.303 log 2     
8.314  310 300 
 Ea = 53.6 kJ/mole
PART - A
1. D
Sol. Let P  h, k  be the centre of the circle

2 2
equation of circle is  x  h    y  k   k 2
2 2
then,  h  0   k  3  2  k
2  1
Simplify to get x  10  y  
 2
2. A
2 b D
Sol. Let the vertex be  h, k  . For y  ax  bx  c h ,k
2a 4a
 h
 a / 2    3 ; k    a
2 2 2
/ 2   4  a 3 / 3   2 a     35a
2  a / 3 4a3
4 a / 3
3
16
105
 hk  is the locus.
64
NJEETS-2022 - FT - 2 -PCM -25
3. A
Sol. A(3, 1, 6); B = (1, 3, 4)

Mid-point of AB = (2, 2, 5) lies on the plane.
and d.r’s of AB = (2, –2, 2)
d.r’s Of normal to plane = (1, –1, 1).
AB is perpendicular bisector
 A is image of B
Statement-2 is correct but it is not correct explanation.
4. B
3 x 2  9 x  17 10
Sol. f  x  1 2 is maximum when 3 x 2  9 x  7 is minimum
3 x2  9 x  7 3x  9 x  7
D 1
 
4a 4
10
 max f  x   1   41
1 / 4
5. D
Sol. 4 novels can be selected from 6 novels in 6 C4 ways. 1 dictionary can be selected from 3 dictionaries in 3 C1
ways. As the dictionary selected is fixed in the middle, the remaining 4 novels can be arranged in 4! ways.
 The required number of ways of arrangement = 6 C 4 x 3 C1 x 4! = 1080
6. C
3 5 5 1 3 1
Sol. P  A   ; P  A  B   ; P  B   P  A  B   P  A  B   P  A    
4 6 6 4 4 3
 P  A  P  B   P  A  B   A & B are independent events.
P  A  P  B   A & B are not equally likely
P  A  B   0  A & B are not mutually exclusive.
7. A
2 2
Sol. Points of intersection of line y = x with x  y  2x  0 are (0, 0) and (1, 1) hence equation of circle having
2 2
end points of diameter (0, 0) and (1, 1) is x  y  x  y  0
8. B
Sol. |z| = 1  zz  1
1  z 1 z
 z.
1 z 1
1
z
9. D

Sol. I      x  f  sin x  dx
0
 / 2 
2 I     2  f  sin x  dx 
 0 
 f sin x   f sin    x  
/2
I    f  cos x  dx
0
NJEETS-2022 - FT - 2 -PCM -26
10. A
n
n 9 3 1 1
Sol. 1 q      n   log 3 10  n 
10 4 10 4 log10  log10 3
4
11. D
Sol. cos x dy = y(sin x – y) dx

dy
 y tan x  y 2 sec x
dx
1 dy 1
 tan x   sec x
y 2 dx y
1
Let t
y
1 dy dt
 
y 2 dx dx
dt dt
 – t tan x = –sec x  + (tan x) t = sec x.
dx dx
I.F. = e tan x dx = sec x
Solution is t(I.F) =  (I.F) sec x dx
1
sec x = tan x + c
y
12 B
Sol. P  x   x 4  ax3  bx 2  cx  d
P'  x   4x 3  3ax 2  2bx  c
 x = 0 is a solution for P'  x   0 ,  c = 0
 P  x   x 4  ax3  bx 2  d …(A)
Also, we have P  1  P 1
 1 a  b  d  1 a  b  d  a  0
 P'  x   0 , only when x = 0 and P(x) is differentiable in ( - 1, 1), we should have the maximum and
minimum at the points x = - 1, 0 and 1 only
Also, we have P  1  P 1
 Max. of P(x) = Max. { P(0), P(1) } & Min. of P(x) = Min. { P(-1), P(0) }
In the interval [ 0 , 1 ],
P '  x   4x 3  3ax 2  2bx  x  4x 2  3ax  2b 
 P'  x  has only one root x = 0, 4x 2  3ax  2b  0 has no real roots.
2 3a2
  3a   32b  0  b
32
b>0
Thus, we have a > 0 and b > 0
 P'  x   4x 3  3ax 2  2bx  0, x   0, 1
Hence P(x) is increasing in [ 0, 1 ]
 Max. of P(x) = P(1)
Similarly, P(x) is decreasing in [-1 , 0]
Therefore Min. P(x) does not occur at x = - 1
NJEETS-2022 - FT - 2 -PCM -27
13. A
Sol. Let F  ae, 0  , F '  ae, 0  , B  0, b 

b b
mFB  mF ' B 
ae ae
b2
mFB  mF ' B  1    a 2 e2  b2
a 2 e2
b2 1
e2  1  2  e2  1  e2  e 
a 2
14. D

1 1
Sol. x   an  a  1
n 0 1 a x

1 1
y   bn  b  1
n 0 1 b y
i
1 1
z   cn  c  1
n0 1 c z
a, b, c are in A.P.
2b  a  c
 1 1 1
2 1    1   1 
 y x y
2 1 1
 
y x z
 x, y, z are in H.P.
15. A
Sol. We can write

ax 2  bx  c  a  x    x   
 a  x    x    
2 sin 2  
 2  0 
 lim 2  0 form 
x 
 x    
2
  a  x    x     
2  sin  
2 a2  x     2 
 lim
x  4  a  x    x    
 
 2 
 
2
a2   
 Limit =
2
16. D
Sol.    a 22  b2  c   a 2 m 2  b 2 
 
 y 2  a2 x 2  b2
x2 y2
 2
  1 is a hyperbola.
b / a  b2
NJEETS-2022 - FT - 2 -PCM -28
17. A
4 3
Sol. cos ( + ) =  tan( + ) =
5 4
5 5
sin( – ) =  tan( – ) =
13 12
3 5

56
tan 2 = tan( +  +  – ) = 4 12 
3 5 33
1
4 12
18. C
y y2 y 2 x2 y 2 x2 y 2
Sol. x  1  x2 1   cos  1  x 2    cos 2    xy cos 
2 4 4 4 4
y2
x 2  xy cos    sin 2 
4
19. A
Sol.
P q q pq  (p   q) pq
T T F F T T
T F T T F F
F T F T F F
F F T F T T
20. C
Sol. S = 109 + 2  111  108 + … + 10  119

11
S  111  108 + … + 9  119 + 1110
10
1
 S  109  111  108  112 10 7  ...  119  1110
10
  11 10 
   1 
1  10    1110   1 S  1110  1010  1110
 S  109 
10  11  10
 1 
10 
 
S = 1011
 S = 100  109
 k = 100.
NJEETS-2022 - FT - 2 -PCM -29
PART – C
1. 4
Sol. Solving the equations we get the points of y

intersection (–2, 1) and (–2, –1)
The bounded region is shown as shaded region.
1 (–2, 1)
 1  3y    2y 
2 2
The required area = 2 d y 
0
1 1
 y3  2 4
= 2 1  y  dy  2  y    2  

2
(1, 0) x
 3 0 3 3
0
2
x + 2y = 0 (–2, –1)
2
x + 3y = 1
2. 1
a 11  r 2  11  r   r
Sol. Tr  1  11 Cr x
br
22  3r  7  r  5
a 11 k
x
11 k   2 k
Tk' 1  11Ck k
 b 
11  3k  7  k  6
11 a 6 11 a 5
C5  C6 5  ab  1
b5 b
3. 0
Sol. Let r be the common ratio of the G.P.

C3  C3  C2 and C2  C2  C1
an1 an 2
log an log log
an an 1
log an log r log r
a an5
  log an 3 log n 4 log  log an 3 log r log r  0 (two identical columns)
an3 an 4
log an6 log r log r
an 7 an8
log an6 log log
an 6 an  7
4. 2
5 tan x  2  cos x  2sin x    sin x  2 cos x  

Sol.  tan x  2 dx    sin x  2cos x
 dx

 cos x  2 sin x 
 2   dx   dx  k  2 log sin x  2 cos x  x  k a  2
 sin x  2 cos x 
NJEETS-2022 - FT - 2 -PCM -30
5. 2
x y z x y z
Sol.    
 1 / 2   1 / 3   1   1 / 6   1  1 / 4 
a1 a2  b1b2  c1 c2  1 / 12    1 / 3    1 / 4 
cos    0
2
a b c
1
2
1
2
1
2
a b c
2
2
2
2
2  1 / 4    1 / 9   1  1 / 36   1   1 / 16 
   90

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FIITJEE- NJEETS

(JEE MAIN TEST SERIES - 2022)

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

(A) one minute (B) half minute

(A) 36 7 (B) 36 / 7 (C) 36 5 (D) 4 5

3. Two fixed frictionless inclined plane making an angle

(A) 4.9 ms–2 in horizontal direction

5. Two coherent point sources S1 and S2 are separated by a small d

space for rough work

7. A ‘T’ shaped object with dimensions shown in the figure, is lying

(A) 3 < 1 < 2 (B) 1 < 3 < 2

9. The figure shows a system of two concentric spheres of radii r1 and r2

10. The above p-v diagram represents the thermodynamic cycle of

space for rough work

2mC T mC T msT 2msT

(A) 1.5  10-5 cm s-1 (B) 1.6  10-5 cm s-1

space for rough work

(A) L21  L22 (B) L1L 2

(A) 10.5 Hz (B) 105 Hz (C) 1.05 Hz (D) 1050 Hz

space for rough work

4. In the circuit, the galvanometer G shows zero deflection. If

space for rough work

(A) 1 : 36 (B) 1 : 1 (C) 1 : 3 (D) 1 : 9

2. In aqueous solution the ionization constants for carbonic acid are

(A) The concentration of CO32  is 0.034 M.

(B) The concentration of CO32  is greater than that of HCO 3 .

(C) The concentration of H+ and HCO 3 are approximately equal.

(D) The concentration of H+ is double that of CO32  .

(A) 80 % (B) 87% (C) 90% (D) 97%

(A) 4.100 kJ mol1 (B) 3.7904 kJ mol1

space for rough work

(A) [Co(NH3)6]Cl3 (B) [CoCl2(NH3)4]Cl (C) [CoCl3(NH3)3] (D) [CoCl(NH3)5]Cl2

(A) Twist boat (B) Rigid (C) Chair (D) Boat

(A) (C2H5)2CHCl (B) (CH3)3CCl (C) (CH3)2CHCl (D) CH3Cl

(A) 3 (B) 2 (C) 4 (D) 6

15. Consider the following reaction:

(A) Diethyl ether (B) Ethyl-hydrogen sulphate

space for rough work

18. The secondary structure of a protein refers to

20. Identify the incorrect statement among the following

2. How many of the following species exhibits the diamagnetic behaviour?

pace for rough work

Section – III (Mathematics)

space for rough work

(A) P(– 1) is the minimum and P(1) is the maximum of P

(A) G.P. (B) A.P.

(A) equivalent to p  q (B) equivalent to ~p  q

(C) a tautology (D) a fallacy

space for rough work

3. If a1 , a2 , a3 ,...., a n ...... are in G.P., then the determinant

space for rough work

HINTS & SOLUTIONS

Vt' (  gly ) / gly

Batch :___ Date of Examination :