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    Delhi Public School: Nacharam/ Mahendra Hills/ Nadergul

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    eeshwar saagar
    This document contains a question bank with practice questions on the topic of amines for Class XII Chemistry. It includes short answer questions worth 2 marks each testing understanding of concepts like relative basicity of amines and their identification tests. There are also short answer 3 mark questions involving multi-step conversions between aromatic compounds and amines. Long answer 5 mark questions explore reactions like Hoffman bromamide and Gabriel phthalimide synthesis in detail and explain structure-property trends in amines.

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    Delhi Public School: Nacharam/ Mahendra Hills/ Nadergul

    Uploaded by

    eeshwar saagar
    35 views3 pages
    This document contains a question bank with practice questions on the topic of amines for Class XII Chemistry. It includes short answer questions worth 2 marks each testing understanding of concepts like relative basicity of amines and their identification tests. There are also short answer 3 mark questions involving multi-step conversions between aromatic compounds and amines. Long answer 5 mark questions explore reactions like Hoffman bromamide and Gabriel phthalimide synthesis in detail and explain structure-property trends in amines.

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    This document contains a question bank with practice questions on the topic of amines for Class XII Chemistry. It includes short answer questions worth 2 marks each testing understanding of concepts like relative basicity of amines and their identification tests. There are also short answer 3 mark questions involving multi-step conversions between aromatic compounds and amines. Long answer 5 mark questions explore reactions like Hoffman bromamide and Gabriel phthalimide synthesis in detail and explain structure-property trends in amines.

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    Download as docx, pdf, or txt
    35 views3 pages

    Delhi Public School: Nacharam/ Mahendra Hills/ Nadergul

    Uploaded by

    eeshwar saagar
    This document contains a question bank with practice questions on the topic of amines for Class XII Chemistry. It includes short answer questions worth 2 marks each testing understanding of concepts like relative basicity of amines and their identification tests. There are also short answer 3 mark questions involving multi-step conversions between aromatic compounds and amines. Long answer 5 mark questions explore reactions like Hoffman bromamide and Gabriel phthalimide synthesis in detail and explain structure-property trends in amines.

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    DELHI PUBLIC SCHOOL

    NACHARAM/ MAHENDRA HILLS/ NADERGUL

    QUESTION BANK

    CLASS: XII
    SUBJECT: CHEMISTRY
    TOPIC: AMINES

    SHORT ANSWERS TYPE QUESTIONS (2 marks each)


    1) Explain why CH3NH2 is stronger base than CH3OH?
    2) Arrange the following in increasing order of basic strength:
    a. Aniline, p-nitroaniline and p-toluidine
    b. C6H5NH2, C6H5NHCH3, C6H5CH2NH2.
    3) Illustrate the following with one example:
    i) Carbylamine reaction ii) Diazotization
    4) Describe the test for identification of primary, secondary and tertiary amines. Also write
    the chemical equations of the reactions involved.
    5) Arrange the following in the increasing order of given property :
    (i) C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3, (Basic strength in aqueous solution).
    (ii) C2H5NH2, (C2H5)2NH, (C2H5)3N and CH3NH2. (Basic strength ingaseous phase).
    6) Arrange the following in the increasing order of given property :
    (i) Aniline, p-toluidine, p-nitroaniline. (Basic strength).
    (ii) NH4+, C6H5NH3+, p–F–C6H5NH3+. (Acid strength).
    7) Identify the products B, C in the following reaction
    8) Write IUPAC names of following amines

    SHORT ANSWERS TYPE QUESTIONS (3 marks each)


    1) How will you convert
    (i) Benzene into aniline
    (ii) Benzene into N, N-dimethylaniline
    (iii) Cl–(CH2)4–Cl into hexan-1,6-di-amine?
    2) An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms
    compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular
    formula C6H7N. Write the structures and IUPAC names of compounds A, B and C.
    3) Arrange the following in
    i) decreasing order of basic strength in gas phase: C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3
    ii) increasing order of boiling point: C2H5OH, (CH3)2NH, C2H5NH2
    iii) increasing order of solubility in water: C6H5NH2, (C2H5)2NH, C2H5NH2.
    4) Accomplish the following conversions:
    (i) Nitrobenzene to benzoic acid
    (ii) Benzene to m-bromophenol
    (iii) Benzoic acid to aniline

    5) Write the products formed in the following sequence of reactions :


    6) Write the products formed in the following sequence of reactions :

    LONG ANSWERS TYPE QUESTIONS – (5 MARKS Each)


    1) Giving an example of each, describe the following reactions :
    (i) Hoffman bromamide reaction
    (ii) Gabriel phthalimide synthesis
    (iii) Gatterman reaction
    (iv) Coupling reaction
    (v) Hoffman’s ammonolysis
    2) Explain why :
    (i) The C–N–C bond angle in trimethyl amine is 108°
    (ii) The quaternary ammonium salts having four different alkyl groups
    are optically active
    (iii) Alkylamines are more basic than ammonia
    (iv) Aniline can not be prepared by Gabriel phthalimide synthesis
    (v) Garbriel phthalimide synthesis is preferably used for synthesising
    primary amines.
    3) Explain Why:
    i) Amines have lower boiling point than alcohols of comparable molecular masses.
    ii) 1° Amines have higher boiling points than 2° amines which in turn, are higher boiling than
    3° amines.
    iii) The pKb value of benzeneamine is 9.33 while that of ammonia is 4.75.
    iV) Aniline does not undergo Friedel-Crafts reaction.
    V) Aniline readily forms 2, 4, 6-tribromoaniline on reaction with bromine water.

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