Safety Data Sheet: 1. Identification

SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: GREAT STUFF™ Window and Door Insulating Issue Date: 01/04/2016
Foam Sealant STW 16oz HC ES 24ct
Print Date: 01/13/2016
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct
Recommended use of the chemical and restrictions on use

Identified uses: Polyurethane foam.
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number: 800-258-2436

SDSQuestion@dow.com
EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: CHEMTREC +1 703-527-3887
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Flammable aerosols - Category 2
Gases under pressure - Liquefied gas
Acute toxicity - Category 4 - Inhalation
Skin irritation - Category 2
Eye irritation - Category 2B
Respiratory sensitisation - Category 1
Skin sensitisation - Category 1
Specific target organ toxicity - single exposure - Category 3
Specific target organ toxicity - repeated exposure - Category 2 - Inhalation
Label elements
Hazard pictograms
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 18

company of Dow
Signal word: DANGER!
Hazards
Flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Precautionary statements
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves.
In case of inadequate ventilation wear respiratory protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor/ physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If skin irritation or rash occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician.
Take off contaminated clothing and wash before reuse.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
Water Reactive
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3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.

Component CASRN Concentration
Polymethylenepolyphenyl polyisocyanate, 53862-89-8 >= 30.0 - <= 60.0 %

polypropyleneglycol copolymer
Polymethylenepolyphenylisocyanate, 57029-46-6 >= 10.0 - <= 30.0 %

propoxylated glycerin polymer
Diphenylmethane Diisocyanate, isomers and 9016-87-9 >= 10.0 - <= 30.0 %

homologues
4,4’ -Methylenediphenyl diisocyanate 101-68-8 >= 7.0 - <= 13.0 %
Isobutane 75-28-5 >= 5.0 - <= 10.0 %
Methyl ether 115-10-6 >= 1.0 - <= 5.0 %
Propane 74-98-6 >= 1.0 - <= 5.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 5.0 - <= 10.0 %
Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
4. FIRST AID MEASURES

Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.
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Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed

Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives
may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase
“myocardial irritability”. Do not administer sympathomimetic drugs such as epinephrine unless
absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working
with other respiratory irritants or sensitizers. Treatment of exposure should be directed at the control
of symptoms and the clinical condition of the patient. Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams
may not be effective to extinguish fire.
Special hazards arising from the substance or mixture

Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride.
Carbon monoxide. Carbon dioxide. Hydrogen cyanide.
Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire
can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are
heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash
back may occur. Dense smoke is produced when product burns.
Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in
extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location
or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition
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sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire-
exposed containers and fire-affected zone until fire is out.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing

apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Evacuate area. Only
trained and properly protected personnel must be involved in clean-up operations. Keep personnel
out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill.
Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion
hazard. Check area with combustible gas detector before reentering area. Ground and bond all
containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released
vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for
more specific information. Use appropriate safety equipment. For additional information, refer to
Section 8, Exposure Controls and Personal Protection. Refer to section 7, Handling, for additional
precautionary measures.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use
non-sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released
vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area.
Ground and bond all containers and handling equipment. Collect in suitable and properly labeled
containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See
Section 10 for more specific information. See Section 13, Disposal Considerations, for additional
information.
7. HANDLING AND STORAGE

Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes.
Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing
vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation.
Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage
area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas.
Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate
container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind,
weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless
adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or
explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
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Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Store in a dry place. See Section 10 for more specific information.
Storage stability
Storage temperature: Shelf life: Use within
49 °C (120 °F) 12 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
4,4’ -Methylenediphenyl ACGIH TWA 0.005 ppm
diisocyanate
OSHA Z-1 C 0.2 mg/m3 0.02 ppm
NIOSH REL TWA 0.05 mg/m3 0.005 ppm
NIOSH REL C 0.2 mg/m3 0.02 ppm
Isobutane ACGIH STEL 1,000 ppm
Methyl ether US WEEL TWA 1,000 ppm
Propane ACGIH Asphyxiant
OSHA Z-1 TWA 1,800 mg/m3 1,000
ppm
This material contains a simple asphyxiant which may displace oxygen. Insure adequate ventilation to
prevent an oxygen deficient atmosphere.
The minimum requirement of 19.5% oxygen at sea level (148 torr O2, dry air) provides an adequate
amount of oxygen for most work assignments.
Exposure controls
Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in
areas with poor ventilation.
Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene.
Polyethylene. Ethyl vinyl alcohol laminate (“EVAL”). Examples of acceptable glove
barrier materials include: Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”).
Viton. Polyvinyl chloride (“PVC” or “vinyl”). NOTICE: The selection of a specific glove
for a particular application and duration of use in a workplace should also take into
account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
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Other protection: Use protective clothing chemically resistant to this material.

Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure
guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-
purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations
where the atmospheric levels may exceed the level for which an air-purifying respirator is
effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing
apparatus). For emergency response or for situations where the atmospheric level is
unknown, use an approved positive-pressure self-contained breathing apparatus or positive-
pressure air line with auxiliary self-contained air supply. In confined or poorly ventilated areas,
use an approved self-contained breathing apparatus or positive pressure air line with auxiliary
self-contained air supply.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.
9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state Foam
Color Yellow
Odor Mild
Odor Threshold No test data available
pH Not applicable
Melting point/range No test data available
Freezing point No test data available
Boiling point (760 mmHg) Not applicable
Flash point closed cup -104 °C ( -155 °F) Estimated.
Evaporation Rate (Butyl Acetate No test data available
= 1)
Flammability (solid, gas) No data available
Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure 1,151 kPa at 55 °C (131 °F) Estimated.
Relative Vapor Density (air = 1) No test data available
Relative Density (water = 1) 1.06 Estimated.
Water solubility Insoluble
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No test data available
Decomposition temperature No test data available
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties No
Molecular weight No data available
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NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY

Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Unstable at elevated temperatures.
Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause
product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed
containers. Acids.
Conditions to avoid: Avoid temperatures above 50 °C

Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated
temperatures can cause product to decompose.
Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal
compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many
materials to release heat. The reaction rate increases with temperature as well as with increased
contact; these reactions can become violent. Contact is increased by stirring or if the other material
acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and
will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a
layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Toxic gases are released during decomposition.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. Observations in animals include: Gastrointestinal irritation.
As product: Single dose oral LD50 has not been determined.
LD50, Rat, > 2,000 mg/kg Estimated.
Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
LD50, Rabbit, > 2,000 mg/kg Estimated.
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Acute inhalation toxicity

In confined or poorly ventilated areas, vapor can easily accumulate and can cause
unconsciousness and death due to displacement of oxygen. Excessive exposure may cause
irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema
(fluid in the lungs.) Effects may be delayed. May cause central nervous system depression.
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and
drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine
and increase myocardial irritability (irregular heartbeats). Decreased lung function has been
associated with overexposure to isocyanates.
As product: The LC50 has not been determined.
Skin corrosion/irritation
Prolonged contact may cause moderate skin irritation with local redness.
Material may stick to skin causing irritation upon removal.
May stain skin.
Serious eye damage/eye irritation

May cause moderate eye irritation.
May cause slight temporary corneal injury.
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.

MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)

May cause respiratory irritation.
Route of Exposure: Inhalation
Specific Target Organ Systemic Toxicity (Repeated Exposure)

Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Teratogenicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother.
Reproductive toxicity
Based on information for component(s): May cause harm to breastfed babies.
Page 9 of 18
Mutagenicity
In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI
are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative.
Animal mutagenicity studies were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
COMPONENTS INFLUENCING TOXICOLOGY:
Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

The LC50 has not been determined.
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

The LC50 has not been determined.
Diphenylmethane Diisocyanate, isomers and homologues

LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l
For similar material(s): 2,4’-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4

Hour, Aerosol, 0.31 mg/l
For similar material(s): 4,4’-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1

Hour, Aerosol, 2.24 mg/l
4,4’ -Methylenediphenyl diisocyanate

LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l
Isobutane
LC50, Mouse, 1 Hour, 52 mg/l
Methyl ether
LC50, Rat, 4 Hour, gas, 164000 ppm
Propane
LC50, Rat, male and female, 4 Hour, vapour, > 425000 ppm
Tris(1-chloro-2-propyl) phosphate
LC50, Rat, 4 Hour, dust/mist, > 7 mg/l
12. ECOLOGICAL INFORMATION
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Ecotoxicological information appears in this section when such data is available.
Toxicity

Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.

For this family of materials:
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates

EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants

NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms

EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants

EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l

The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Page 11 of 18
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent

EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent

NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms

EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants

EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
Isobutane
No relevant data found.
Methyl ether
LC50, Poecilia reticulata (guppy), semi-static test, 96 Hour, > 4,000 mg/l

LC50, Daphnia magna (Water flea), 48 Hour, > 4,000 mg/l, OECD Test Guideline 202 or
Equivalent
Propane
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/l, OECD Test
Guideline 203 or Equivalent

EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Page 12 of 18

ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test
Chronic toxicity to aquatic invertebrates

NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l
LOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, > 32 mg/l
Persistence and degradability

Biodegradability: Expected to degrade slowly in the environment.

Biodegradability: For this family of materials: Material is readily biodegradable. Passes
OECD test(s) for ready biodegradability.

Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent

Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Isobutane
Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of
oxygen).
Theoretical Oxygen Demand: 3.58 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 4.4 d
Method: Estimated.
Page 13 of 18
Methyl ether
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 5 %
Exposure time: 28 d
Method: OECD Test Guideline 301A or Equivalent
Photodegradation
Method: Estimated.
Propane
Biodegradability: No relevant data found.
Photodegradation
Method: Estimated.
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 302A or Equivalent
Photodegradation
Method: Estimated.
Bioaccumulative potential

Bioaccumulation: In the aquatic and terrestrial environment, movement is expected to be
limited by its reaction with water forming predominantly insoluble polyureas.
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Bioaccumulation: No relevant data found.

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
Isobutane
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 2.76 Measured
Methyl ether
Propane
Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured
Mobility in soil

In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.



Isobutane
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient(Koc): 35 Estimated.
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Methyl ether
Partition coefficient(Koc): 1.29 - 14 Estimated.
Propane
Partition coefficient(Koc): 24 - 460 Estimated.
Potential for mobility in soil is slight (Koc between 2000 and 5000).
Partition coefficient(Koc): 1300 Estimated.
13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device.
14. TRANSPORT INFORMATION

DOT
Proper shipping name Aerosols
UN number UN 1950
Class 2.1
Packing group
Classification for SEA transport (IMO-IMDG):

Proper shipping name AEROSOLS
UN number UN 1950
Class 2.1
Packing group
Marine pollutant No
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):

Proper shipping name Aerosols, flammable
UN number UN 1950
Class 2.1
Page 16 of 18
Packing group
This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION

OSHA Hazard Communication Standard
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Components CASRN
Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9
4,4’ -Methylenediphenyl diisocyanate 101-68-8
Pennsylvania Worker and Community Right-To-Know Act:

The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Isobutane 75-28-5
Methyl ether 115-10-6
Propane 74-98-6
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
United States TSCA Inventory (TSCA)

All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Page 17 of 18
16. OTHER INFORMATION
Revision
Identification Number: 101187825 / A001 / Issue Date: 01/04/2016 / Version: 7.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
Asphyxiant Asphyxiant
C Ceiling
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
STEL Short-term exposure limit
TWA 8-hour, time-weighted average
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Information Source and References

This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
Page 18 of 18

Safety Data Sheet: 1. Identification

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SAFETY DATA SHEET

THE DOW CHEMICAL COMPANY

Recommended use of the chemical and restrictions on use

Customer Information Number: 800-258-2436

EMERGENCY TELEPHONE NUMBER

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 18

Signal word: DANGER!

This product is a mixture.

Polymethylenepolyphenyl polyisocyanate, 53862-89-8 >= 30.0 - <= 60.0 %

Polymethylenepolyphenylisocyanate, 57029-46-6 >= 10.0 - <= 30.0 %

Diphenylmethane Diisocyanate, isomers and 9016-87-9 >= 10.0 - <= 30.0 %

4,4’ -Methylenediphenyl diisocyanate 101-68-8 >= 7.0 - <= 13.0 %

Isobutane 75-28-5 >= 5.0 - <= 10.0 %

Methyl ether 115-10-6 >= 1.0 - <= 5.0 %

Propane 74-98-6 >= 1.0 - <= 5.0 %

Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 5.0 - <= 10.0 %

4. FIRST AID MEASURES

Indication of any immediate medical attention and special treatment needed

Special hazards arising from the substance or mixture

Advice for firefighters

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Individual protection measures

Other protection: Use protective clothing chemically resistant to this material.

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

Conditions to avoid: Avoid temperatures above 50 °C

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

As product: Single dose oral LD50 has not been determined.

LD50, Rat, > 2,000 mg/kg Estimated.

Acute dermal toxicity

As product: The dermal LD50 has not been determined.

LD50, Rabbit, > 2,000 mg/kg Estimated.

Acute inhalation toxicity

Serious eye damage/eye irritation

May cause allergic respiratory reaction.

Specific Target Organ Systemic Toxicity (Single Exposure)

Specific Target Organ Systemic Toxicity (Repeated Exposure)

COMPONENTS INFLUENCING TOXICOLOGY:

Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

Diphenylmethane Diisocyanate, isomers and homologues

For similar material(s): 2,4’-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4

For similar material(s): 4,4’-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1

4,4’ -Methylenediphenyl diisocyanate

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

Diphenylmethane Diisocyanate, isomers and homologues

Acute toxicity to aquatic invertebrates

Acute toxicity to algae/aquatic plants

Toxicity to soil-dwelling organisms

Toxicity to terrestrial plants

4,4’ -Methylenediphenyl diisocyanate

Acute toxicity to aquatic invertebrates