Safety Data Sheet: Rubia Fleet HD 200 Sae 10W

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SAFETY DATA SHEET

according to SS 586

SDS # : 084307 RUBIA FLEET HD 200 SAE 10W


Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name RUBIA FLEET HD 200 SAE 10W


Number BTH
Substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Motor oil.


1.3. Details of the supplier of the safety data sheet
Supplier TOTAL OIL ASIA PACIFIC PTE LTD
331 North Bridge Road
#23-01 Odeon Towers
Singapore 188720
Tel: +65 6879 2200
Fax: +65 6879 2203

Importer OIL INTEL LIMITED


56 Whakatu Road, Whakatu, Hastings 4172
NEW ZEALAND
Phone: +64 (06) 871 53 25
Fax: +64 (06) 870 48 90
For further information, please contact:

Contact Point HSE


E-mail Address ms.ap-sds@total.com

1.4. Emergency telephone number

New Zealand Poisons Information Centre: 0800 764 766


New Zealand: +64 9801 0034.

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture


This product is not classified as hazardous according to Singapore Standard SS 586 on the Hazard Communication for Hazardous
Chemicals and Dangerous Goods

Label elements

This product is not classified as hazardous according to Singapore Standard SS 586 on the Hazard Communication for Hazardous
Chemicals and Dangerous Goods

Version SGPE

Quick-FDS [17944-07173-14138-014378] - 2017-02-15 - 01:59:33


SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Other hazards which do not result in classification


Physical-Chemical Properties Contaminated surfaces will be extremely slippery.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No EC-No Weight %


Branched alkylphenol and calcium ^ - 0.1-<0.25
branched alkylphenol

Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346

4. FIRST AID MEASURES

4.1. Description of first-aid measures


General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR
EMERGENCY MEDICAL CARE.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes.

Inhalation Move to fresh air.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or Poison Control Center immediately.

4.2. Most important symptoms and effects, both acute and delayed
Skin contact Not classified.

Eye contact Not classified.

Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of respiratory
system.

Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

4.3. Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically.

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special Hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon
monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly
dangerous if inhaled in confined spaces or at high concentration.

5.3. Advice for fire-fighters

Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters

Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local regulations.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely slippery.
Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition.

6.2. Environmental precautions

General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to local /
national regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4. Reference to other sections

Personal Protective Equipment See Section 8 for more detail.

Waste treatment See section 13.

7. HANDLING AND STORAGE

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

7.1. Precautions for safe handling

Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in well-
ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyes and
clothing.

Prevention of fire and explosion Take precautionary measures against static discharges: Ground/bond containers, tanks and
transfer/receiving equipment.

Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of contact
with the product. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and at the end of workday. Do not use abrasives, solvents or fuels.
Do not dry hands with rags that have been contaminated with product. Do not put product
contaminated rags into workwear pockets.

7.2. Conditions for safe storange

Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep container
conditions tightly closed. Keep preferably in the original container. Otherwise reproduce all indication of the
regulation label on the new container. Do not remove the hazard labels of the containers (even
if they are empty). Design the installations in order to avoid accidental emissions of product (due
to seal breakage, for example) onto hot casings or electrical contacts. Protect from frost, heat
and sunlight. Protect from moisture.

Materials to Avoid Strong oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1. Control parameters
Exposure limits Mineral oil mist:
USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3, STEL 10 mg/m3, ACGIH
(TLV) TWA 5 mg/m3 (highly refined).

Legend See section 16

8.2. Exposure controls

Occupational Exposure Controls

Engineering Measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.

Personal Protective Equipment

General Information If the product is used in mixtures, it is recommended that you contact the appropriate protective
equipment suppliers. These recommendations apply to the product as supplied.

Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN
14387). The use of breathing apparatus must comply strictly with the manufacturer's instructions
and the regulations governing their choices and uses.

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.

Hand Protection Hydrocarbon-proof gloves: Fluorinated rubber, Nitrile rubber. Please observe the instructions
regarding permeability and breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which the product is used, such
as the danger of cuts, abrasion, and the contact time. If used in solution, or mixed with other
substances, and under conditions which differ from EN 374, contact the supplier of the EC
approved gloves.

Environmental exposure controls

General Information The product should not be allowed to enter drains, water courses or the soil.

9. PHYSICAL AND CHEMICAL PROPERTIES

General Information
Color yellow To orange
Physical State @20°C liquid
Odor Characteristic
Odor Threshold No information available

Important health safety and environmental information

Property Values Remarks Method

pH Not applicable
Melting point/range Not applicable

Boiling No information
point/boiling available
range
ASTM
D92
Flash point
232 °C ASTM
450 °F D92.
Evaporation rate No information
Flammability available No
Limits in Air information
available
No information
Vapor Pressure 0.8639 available
Vapor density No information ASTM
Relative density available @ 15 °C D0452
Density 863.9 kg/m3 @ 15 °C ASTM
Water solubility Insoluble D4052
Solubility in other No information
solvents logPow available
No information
available

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Autoignition
temperature 35.8 mm2/s
Decomposition No information
temperature available
Viscosity, No information ASTM
kinematic available @ 40 °C D445
6.1 mm2/s @ 100 °C ASTM
D445
Explosive Not explosive
properties
Oxidizing Properties No information available
Possibility of hazardous reactions None under normal processing
Other information
Freezing Point No information available

Pour point -39 °C ASTM


D97

10. STABILITY AND REACTIVITY

10.1. Reactivity

General Information No dangerous reaction known under conditions of normal use.

10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous Reactions None under normal processing.

10.4. Conditions to Avoid

Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.

10.5. Incompatible Materials

Materials to Avoid Strong oxidizing agents.

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon
monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Information on likely routes of exposure


Germ Cell Mutagenicity This product is not classified as mutagenic.

Carcinogenicity This product is not classified carcinogenic. During use in engines, contamination of oil with low
levels of combustion products occurs. Used motor oils have been shown to cause skin cancer in
mice following repeated application and continuous exposure. Brief or intermittent skin contact
with used motor oil is not expected to have serious effects in humans if the oil is thoroughly
removed by washing with soap and water.

Reproductive toxicity Not classified. Contains a presumed human reproductive toxicant substance.
Principle Routes of Exposure Skin contact, Eye contact, Inhalation, Ingestion.

Skin contact Not classified.

Eye contact Not classified.

Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of respiratory
system.

Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity - Product Information

Oral Not classified.

Dermal Not classified.

Inhalation Not classified.

Acute toxicity - Component Information

No information available

Skin corrosion/irritation Not classified.

Serious eye damage/eye irritation Not classified.

Sensitization Not classified as a sensitizer.

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Chemical Name European Union


Branched alkylphenol and calcium branched alkylphenol Repr. 1B (H360)
^

STOT-single exposure Not classified.


STOT - repeated exposure Not classified.

Aspiration Hazard Not classified.

Other adverse effects Characteristic skin lesions (pimples) may develop following prolonged and repeated exposures
(contact with contaminated clothing).

ECOLOGICAL INFORMATION
12.1. Toxicity

Not Classified.

Acute aquatic toxicity - Product Information

No information available.

Acute aquatic toxicity - Component Information

No information available.

Chronic aquatic toxicity - Product Information No


information available.

Chronic aquatic toxicity - Component Information No


information available.

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.04

Effects on terrestrial organisms No


information available.

12.2. Persistence and degradability

General Information No information available.

12.3. Bioaccumulative potential

Product Information No information available.

logPow No information available


Component Information No information available.

12.4. Mobility in soil

Soil Given its physical and chemical characteristics, the product generally shows low soil mobility.

Air Loss by evaporation is limited.

Water The product is insoluble and floats on water.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment No information available.

12.6. Other adverse effects

General Information No information available.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste Disposal Methods Should not be released into the environment. Where possible recycling is preferred to disposal
or incineration. If recycling is not practicable, dispose of in compliance with local regulations.
After use, this oil must be sent to a licensed waste oil facility. Incorrect disposal of used oil
poses a risk to the environment. Mixture with other waste types such as solvents, brake- and
cooling liquids is forbidden.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.03

Disposal Precautions Refer to section 8 for safety and protective measures for disposal personnel.

14. TRANSPORT INFORMATION

ADR/RID Not regulated

IMDG/IMO Not regulated

ICAO/IATA Not regulated

15. REGULATORY INFORMATION

National regulatory information

Singapore
Applicable National Regulation:
Workplace Safety and Health (General Provision) Regulations

New Zealand Regulatory Information:

HSNO Approval Number HSR002605


HSNO Group Standard Lubricants (Low Hazard) Group Standard 2006

HSNO Classification 6.3 - SKIN IRRITATION - Category B


6.4 - EYE IRRITATION - Category A (Irritant)
9.1 - AQUATIC ECOTOXICITY - Category D

Regulation according to other foreign laws:


AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations

16. OTHER INFORMATION


Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists bw
= body weight bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one half) of
a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals LL =
Lethal Loading
NIOSH = National Institute of Occupational Safety and Health
NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
/ 11

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SDS # : 084307 RUBIA FLEET HD 200 SAE 10W
Issuing date: 2015-06-30 Revision Date: 2018-07-16 Version 1.03

OECD = Organization for Economic Co-operation and Development OSHA =


Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material

Legend Section 8
TWA: Time Weight Average
STEL: Short Time Exposure Limit
PEL: Permissible exposure limit
REL: Recommended exposure limit
TLV: Threshold Limit Values

+ Sensitizer * Skin designation


** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction

Revision Date: 2018-07-18


Revision Note *** Indicates updated section.

This safety data sheet serves to complete but not to replace the technical product sheets. The information contained herein is
given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the user that any use
of the product for purposes other than those for which it was designed entails potential risk.The information given herein in no
way dispenses the user from knowing and applying all provisions regulating his activity.The user bears sole liability for the
precautions required when using the product.The regulatory texts indicated herein are intended to aid the user to fulfil his
obligations. This list is not to be considered complete and exhaustive.It is the user's responsibility to ensure that he is subject to
no other obligations than those mentioned.

End of the Safety Data Sheet

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