SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Section 1: Identification

Product name : Sika Injection-201 CE (B)

Product code : 000000606392

Manufacturer or supplier's details
Company : Sika (NZ) Ltd.
85-91 Patiki Road
Avondale
Auckland AKL 1026
Telephone : +64 9 820 2900
Emergency telephone num- : 0800 734 607
ber
Telefax : +64 9 828 4091
E-mail address : info@nz.sika.com
Recommended use of the chemical and restrictions on use
Product use : Sealing system, For professional users only.

Section 2: Hazard identification

GHS Classification
Acute toxicity (Inhalation) : 6.1D

Skin irritation : 6.3A

Eye irritation : 6.4A

Respiratory sensitisation : 6.5A

Skin sensitisation : 6.5B

Carcinogenicity : 6.7B

Acute toxicity : 6.1E

Specific Target Organ Toxicity : 6.9B

(Inhalation)

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H315 Causes skin irritation.

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or re-
peated exposure if inhaled.

Precautionary statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P321 Specific treatment (see supplemental first aid instructions
on this label).
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ at-
tention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

Section 3: Composition/information on ingredients

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
Diphenylmethanediisocyanate, isomeres and 9016-87-9 >= 90 -<= 100
homologues

Section 4: First-aid measures

General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : irritant effects

and effects, both acute and sensitising effects
delayed Asthmatic appearance
Cough
Respiratory disorder
Allergic reactions
Excessive lachrymation
Headache
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause respiratory irritation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated
exposure if inhaled.

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Notes to physician : Treat symptomatically.

Section 5: Fire-fighting measures

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Standard procedure for chemical fires.

ods

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Section 6: Accidental release measures

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Section 7: Handling and storage

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Avoid formation of aerosol.

Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Follow standard hygiene measures when handling chemical
products

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Conditions for safe storage : Store in original container.

Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.

Section 8: Exposure controls/personal protection

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Diphenylmethanediisocyanate, 9016-87-9 WES-TWA 0.02 mg/m3 NZ OEL
isomeres and homologues (NCO)
Further information: Skin sensitiser, Respiratory sensitiser
WES-STEL 0.07 mg/m3 NZ OEL
(NCO)
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Section 9: Physical and chemical properties

Appearance : liquid

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Colour : brown

Odour : slight

Odour Threshold : No data available

pH : Not applicable

Melting point/range / Freezing : No data available

point
Boiling point/boiling range : No data available

Flash point : > 101 °C (214 °F)

(Method: closed cup)

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : 0.01 hPa

Relative vapour density : No data available

Density : ca. 1.07 g/cm3 (20 °C (68 °F))

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water
Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s ( 40 °C (104 °F))

Explosive properties : No data available

Oxidizing properties : No data available

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Section 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : No hazards to be specially mentioned.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

Section 11: Toxicological information

Acute toxicity
Harmful if inhaled.
Components:
Diphenylmethanediisocyanate, isomeres and homologues:
Acute oral toxicity : LD50 Oral (Rat): > 10,000 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: 1.5 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgement
Assessment: The component/mixture is moderately toxic after
short term inhalation.

Acute dermal toxicity : LD50 Dermal (Rabbit): > 9,400 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation

Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Chronic toxicity

Germ cell mutagenicity

Not classified based on available information.

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
May cause respiratory irritation.
STOT - repeated exposure
May cause damage to organs through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.

Section 12: Ecological information

Ecotoxicity

Components:
Diphenylmethanediisocyanate, isomeres and homologues:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 1,000 mg/l
Exposure time: 96 h

Toxicity to algae/aquatic : EC50 (Desmodesmus subspicatus (green algae)): > 1,640

plants mg/l
Exposure time: 72 h

Persistence and degradability

No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : There is no data available for this product.
mation

Section 13: Disposal considerations

Disposal methods
Waste from residues : Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.

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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

Do not re-use empty containers.

Section 14: Transport information

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

NZS 5433
Not regulated as a dangerous good

Section 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

International Chemical Weapons Convention (CWC) : Not applicable

Schedules of Toxic Chemicals and Precursors

HSNO Approval Number

HSR002679
HSW Controls
Certified handler certificate not required.
Tracking hazardous substance not required.
Refer to the Health and Safety at Work (Hazardous Substances) Regulations 2017, for further infor-
mation.

The components of this product are reported in the following inventories:

NZIoC : On the inventory, or in compliance with the inventory

Section 16: Other information

Full text of other abbreviations

NZ OEL : New Zealand. Workplace Exposure Standards for Atmospher-
ic Contaminants
NZ OEL / WES-TWA : Workplace Exposure Standard - Time Weighted average
NZ OEL / WES-STEL : Workplace Exposure Standard - Short-Term Exposure Limit
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SAFETY DATA SHEET

Sika Injection-201 CE (B)

Version Revision Date: SDS Number: Date of last issue: 2020/08/27

3.0 2020/11/18 000000606392 Date of first issue: 2016/05/31

ADG : Australian Dangerous Goods Code.

ADR : European Agreement concerning the International Carriage of
Dangerous Goods by Road
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978
OEL : Occupational Exposure Limit
PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the
time of publication. All warranties are excluded. Our most current General Sales Conditions shall
apply. Please consult the product data sheet prior to any use and processing.

Changes as compared to previous version !

NZ / EN

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