STEM1-06 FinalPaper
STEM1-06 FinalPaper
STEM1-06 FinalPaper
Gatchalian, Dannie M.
Lundag, Sofia Z.
Grade 12 – STEM 1
May 2022
ABSTRACT
This study aimed to know the potential of rice husk ash and eggshell powder as biocomposite
tiles. Its purpose was to produce biocomposite tiles as an alternative to commercially used tiles to lessen
adverse effects on the environment. The descriptive-comparative research design was utilized in order to
compare the biocomposite and commercially used tiles in terms of thickness, breaking load, and flexural
strength. Mean and independent t-test were used to know the significant difference between the two tile
groups. It was found that the rice husk ash decreased the strength of the tiles but statistics shown there
was no significant difference between the two tile groups which implies that the biocomposites tile could
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INTRODUCTION
Tile Industry
One of the most widely used tiles today are ceramic tiles. Back then, these were made from clay
then baked or fired in a kiln at low temperatures. There are glazed ceramic tiles, wall tiles, and floor tiles
(Flooring America, 2020). Tiles may be made with naturally occurring materials, such as clay, rocks and
sand, but these have been quarried and used for construction work for years. Their biggest impact to the
environment is the energy spent for the collection of these raw materials. These also produce adverse
environmental effects as the quarries emit air and water pollutants which make these environmentally
As a solution for the harmful effects on the environment, people came up with biocomposites.
According to Abdulkhani et. al. (2020), biocomposites are materials composed of natural and renewable
sources and these have been found feasible as raw materials used in construction. These consist of a large
variety of materials, ranging from natural polymers, proteins, and sugars to nanocarbons that are
presented in various forms such as films, coatings, particles, fibers, and foams (Haraguchi, 2021).
Biocomposites are natural fiber-reinforced biopolymers and are being developed as alternatives to
(Christian, 2016). These biocomposites have recently found their way into the building and construction
industry.
Concepts of green buildings to live and work require an ecologically healthy place, hence
biocomposites serve as potential eco-friendly materials for eco-friendly buildings (Alam et. al., 2021). A
study conducted by Gebremedhin & Rotich (2020) produced biocomposite tiles from pineapple leaf fibers
reinforced with low-density polyethylene, and determined the feasibility for prospective industrial use.
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Another study also produced biocomposite tiles from four different granulometries of rubber waste
powders combined with polyurethane resin using a hot-press machine. It has been said that making
biocomposite tiles is very important to save the environment, and to reduce waste and pollution. These
not only help to prevent pollution caused by rubber wastes, but they also provide new business options for
In making biocomposites, natural materials are needed and one of these are waste materials. One
of the most common agricultural wastes generated by the country is rice husk that came from the staple
food of the Philippines which is rice. The estimated production of rice hull in the Philippines is more than
2 million tons per annum which is equivalent to approximately 5 million BOE (barrels of oil equivalent)
in terms of energy (Zafar, 2021). Rice husk is the hard protective coverings of rice grains which are
separated from the grains during the milling process. It contains about 30% - 50% of organic carbon, and
when turned to ash as a product of incineration, the primary residues are the silicates (Singh, 2018).
Because of its high silica content, it has been found that rice husk ash could be beneficially added to
cement deep mixing to enhance the strength of materials. The utilization of rice husk ash into construction
Another most common waste generated are eggshells. According to Waheed et. al (2020), the
global egg production was around 78 million metric tons back in 2018, approximately 8.58 million metric
tons of these are discarded mostly as waste. Eggshells are calcium-rich commodities that are being
dumped into landfills and contribute to various environmental issues. According to Hamada et. al. (2020),
eggshells have cementitious properties due to the presence of calcium oxide. Commercial cement and
eggshells are similar, having calcium carbonate (CaCO3) as the main constituent. Further, eggshells have
been found to improve the durability of concrete by reducing water absorption which provides higher
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Usage of Epoxy Resin
In making composites, epoxy resins are used primarily for fabricating composites with high
mechanical properties and good adhesion (Composites Lab, 2022). Resins are liquid with two
components. When mixed with a hardener, a chemical reaction will take place making the resin form into
solid. Resin possesses excellent insulation and electrical capabilities, has a lengthy shelf life, and is
resistant to impact. It is also extensively used in molding parts due to its varied property range, offering
numerous reinforcements and combinations (Acrylgiessen, 2021). Based on the article of Conserve
Energy Future (2022), resin is only biodegradable if it is produced from organic materials and it can be
broken down into smaller pieces. Unlike plastic that can take years to decompose, biodegradable resins
can be broken down by bacteria and microorganisms. According to the Resin Expert (2020), epoxy resins
is considered the best option due to its strong properties, finish, and good adhesion qualities. Ideal for
many applications. It can be used in sealants, varnishes, casting and caulking compounds, paints, and all
sorts of other industrial applications. According to Roxy Epoxy (2021), the average time it takes for the
resin to cure can take 24-72 hours. During this time, the resin shouldn’t be touched or moved as it can
According to Xie et. al. (2018), epoxy resin has been used as adhesive, vital in concrete adhesive
and repair, structural design, runway repair, road repair and concrete fracture strengthening. With these,
epoxy resin materials are usually utilized in concrete member bonding and repair. It has high strength,
good durability, fast growth strength, good toughness, forming time is short, and the advantages of easy
construction. Lee et. al. (2020) used epoxy resin adhesive injected into the cement mortar and was then
applied to tiles. Because of the injected epoxy resin, the mechanical adhesion at each surface was
enhanced, and it minimized the moisture evaporation and shrinkage of the mortar. Combined with a
cement matrix to achieve enhanced strength, specimens that used epoxy resin adhesive exhibited the
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Evaluation of Properties of Composites
Due to its main advantage, which is recycling waste materials, biocomposites became a subject of
different research. According to the study of Singh & Singh (2019), an evaluation on the properties of
biocomposite materials using sawdust and rice husk found that rice husks reduced the mechanical strength
of the epoxy resin and decreased the tensile (flexural) strength of the material. But the tensile strength
varies directly with the (breaking) load when used with rice husks. Supporting this was the study
conducted by Gebremedhin & Rotich (2020), the flexural strength of the recycled low-density
polyethylene reinforced with pineapple leaf fiber tile composite was evaluated and was also found that
there was a reduction in the flexural strength when the weight of the proponents were heavier but if the
amount was controlled and lowered, the optimum flexural strength was obtained. A similar study by
Kondu et. al. (2021), proved that in making biocomposite roofing shingles, adding more rice husk ash
resulted in a decline in flexural strength, suggesting that the ash saturated the matrix therefore producing a
weaker composite. However, in order to strengthen the composites, Lazrak et. al. (2018) stated that the
strength properties of the composites could further be improved by increasing the polymer content. It was
study conducted by Azman et. al. (2012), proved that hydrothermally treated biocomposite kenaf fibers
presented good strength but biocomposite kenaf fibers that were left untreated projected a higher modulus
of rupture or strength.
Based on multiple literature and studies, the production of most commercially available tiles
presents adverse effects on the environment. Biocomposites, being made of renewable resources, have the
potential to help in having eco-friendly construction. However, past studies only focused on utilizing rice
husk ash, eggshells, and resin individually in improving cement and other composite materials, there are
no existing studies about making rice husk ash and eggshell powder into biocomposite tiles. Hence the
researchers figured to make biocomposite tiles out of rice husk ash and eggshell powder mixed with
epoxy resin instead. It could be an alternative as it is beneficial for the environment because it reduces
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waste through recycling and repurposing instead. This study only focused on the thickness, breaking load,
and the flexural strength of the made biocomposite tiles, any other tests weren’t included. Only the data
gathered from the results of the trials and tests from the testing facility were used. Any materials and data
The main purpose of this study was to produce biocomposite tiles that would be an alternative to
commercially used tiles to lessen adverse effects on the environment from its production. This may also
lessen wastes by repurposing rice husk ash and eggshell powder which are conventionally treated as
waste products.
Specifically, this study intended to provide answers and solutions to the following questions:
1. What are the resulting physical properties of the rice husk ash and eggshell powder biocomposite
1.1. thickness;
2. What are the resulting physical properties of the commercially used tiles in terms of:
2.1. thickness;
3. Is there significant difference between the rice husk ash and eggshell powder biocomposite tiles
3.1. thickness;
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Hypothesis
LaMorte (2019) stated that p-value ≤ 0.05 is an arbitrary but widely used threshold for assessing
whether or not a change is statistically significant therefore, the following null hypothesis tested using this
level of significance: There is no significant difference between the rice husk ash and eggshells
1. thickness;
3. flexural strength.
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METHODS
Research Design
This study utilized a descriptive-comparative research design. A descriptive design aims on obtaining
information to systematically describe a phenomenon and the variables are only identified, observed and
measured. A descriptive-comparative design was used as it compares two or more groups, people, or
conditions based on a specific aspect (Voxco, 2021). In this study, two groups that were subjected to
different tests were the rice husk ash and eggshell powder biocomposite tiles and the commercially used
tiles. No manipulation between the two groups was made. The tests involved measured the physical
properties of the two tile groups namely, thickness, breaking load, and flexural strength. The results from
both groups were compared and used to prove or disprove on whether there is a significant difference
between the rice husk ash and eggshell powder biocomposite tiles and the commercially used tiles in
The research was conducted at the residence of the researcher during the School Year 2021-2022.
The researchers as students of Siena College of Taytay, were unable to conduct the study at the school
with having laboratories and equipment, due to the COVID-19 pandemic restrictions. The researchers
then conducted the testing of the final product at the University of the Philippines Diliman Institute of
Civil Engineering Construction Materials and Structures Laboratory, as it is one of the qualified
institutions that provided the necessary means to measure the results of the study.
Sampling Technique
This study did not employ any sampling technique since no respondents were needed in order to
gather data for the needed physical properties and significant difference of the tiles. The study only relied
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Participants of the Study
The study didn’t gather any participants since a sampling technique wasn’t utilized. The physical
properties and significant difference between rice husk ash and eggshell powder biocomposite tiles and
commercially used tiles were gathered through experimentation only, hence respondents were not needed.
Research Instrument
The instrument used to obtain relevant data required to gather the outcomes of the tests were
experiment and testing. It was used to provide information about the thickness, breaking load and flexural
strength of biocomposite tile and the commercially used tiles. To reinforce the accuracy and validity of
the research instrument to this study, the testing was sought with the help of a qualified engineer from
University of the Philippines Diliman Institute of Civil Engineering Construction Materials and Structures
Laboratory.
Before doing the testing, the researchers made the biocomposite tiles and purchased the
commercially used tiles to compare the physical characteristics and differences of each tile. Every tile was
subjected to a standardized test then the results based on the trial were listed.
The following steps and procedures were done to make rice husk ash and eggshell powder
biocomposite tiles, and the testing of the biocomposite tiles and the commercially used tiles:
1. Gathered all the data in related studies and literature as a data basis.
1.1. The researchers determined the components and properties of rice husk ash and eggshell
powder
1.1.1. Rice husk ash has high silica content that can enhance construction materials
(Jongpradist, 2018)
1.1.2. Eggshell powder has cementitious properties because of the calcium oxide
content that increases the durability of construction materials (Hamada et. al.,
2020).
1.2. The researchers researched the ratio of the ingredients and mixtures in making the
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1.2.1. 1200g of particles should be casted then 120g for the resin for adhesion (Revelo
1.2.2. Average time it takes for the resin to cure can take 24-72 hours (Roxy Epoxy,
2021).
2.1. Prepared the materials and equipments used in making the biocomposite tiles
2.1.1. For fast gathering of materials, the researchers ordered rice husk ash and eggshell
powder online. The resin was also ordered online. Then all the materials were
gathered.
2.1.2. Contacted the testing lab and asked for schedule reservations.
2.1.4. The commercially used tiles were bought to have a comparison to the rice husk
2.2.1. From the study conducted by Revelo et. al. (2021), the ratio was 1200g of
particles to be casted then 120g for the resin but it didn’t work for the
2.2.2. The researchers made changes in the ratio in which the first trial was 400g rice
husk ash and 200g of eggshell powder with 450g of epoxy and 150g of hardener
3.1.1. First, the researchers wore protective equipment such as gloves, goggles and
masks.
3.1.2. Prepared the rice husk ash, eggshell powder, epoxy together with its hardener and
3.1.3. In a container, the researchers mixed 400g of rice husk ash and 200g of eggshell
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3.1.4. The epoxy resin that the researchers bought had instructions to mix in 3:1 ratio.
In making the epoxy resin mix, 450g of epoxy resin and 150g of hardener was
used per batch. Then it was added into the rice husk ash and eggshell powder mix
3.1.5. Using a leveler tool, the researchers made sure the mold was on a leveled place.
3.1.6. The researchers used candle wax as mold release and was applied in every mold
to make sure that none of the resin would stick to the mold.
3.2. Based on Roxy Epoxy (2021), the average curing time for resin should be at least 24-72
3.3. Since the researchers learned the correct portions and mixture, the researchers made a
Laboratory for the testing, and delivered the prototypes and the commercially
used tiles.
4.1.2. For every test, both the rice husk ash and eggshell powder biocomposite tiles and
4.1.3. The researchers were informed by the engineer from the testing laboratory that in
one trial, two results can be gathered. Both the breaking load which is the same
4.1.4. The researchers waited for the results from the laboratory technician.
5.1. After collecting the data in each test, the researchers compared the test results of the
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5.2. In order to know the significant difference of the two tiles, t-test was used as a statistical
test.
6. Interpretation of Data
6.1. All data were listed and analyzed, then interpretations were made.
Statistical Treatment
To analyze and interpret the data gathered, descriptive statistics as mean was used in which it
summarizes all the datas with a single number to represent the datas’ center point or typical value (Frost,
2022). It describes and presents the results of the physical properties of both the biocomposite and
commercially used tiles. Then inferential statistics as independent sample t-test was utilized for it is a
parametric test that compares the means of two independent groups in order to know whether there is
statistical evidence that would prove the groups are significantly different (Kent State University, 2022).
Hence it was used for numerical analysis and for comparing magnitude of rice husk ash and eggshell
powder biocomposite tiles as the first group and commercially used tiles as the second group. The
physical properties, thickness, breaking load and flexural strength were the magnitudes gathered.
Ethical Considerations
This study considered the following ethics: (1) Honesty and Integrity. All the data gathered and
used will not extrapolate to mislead anyone that will utilize this study for future reference, (2) Objectivity.
This study avoids bias in any aspect, such as design, data analysis, interpretation, and peer review. (3)
Respect for Intellectual Property. This study did not plagiarize. Proper citation of all literature and studies
was observed by the researchers, and (4) Carefulness and openness. This study attentively avoided
careless errors and negligence. Kept good records of research activities, such as data collection,
experiment, and results of the tests. Open for sharing of data, results, ideas, resources to other researchers
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RESULTS
Table 1. Physical Properties of of Rice Husk Ash and Eggshell Powder Biocomposite Tiles and
Commercially Used Tiles
Physical Tiles Sample Sample Sample Sample Sample Mean
Properties 1 2 3 4 5
Table 1 indicates the descriptives of the rice husk ash and eggshell powder biocomposite tiles and
commercial tiles in terms of thickness, breaking load and flexural strength. It consisted of 5 samples for
the rice husk ash and eggshell powder biocomposite tiles and 5 samples for the commercially used tiles.
Respectively, when it comes to thickness, the biocomposite tiles have a mean of 6.826 from a fluctuating
raw data while the commercially used tiles have 6.5 mean. All commercially used tiles were found to be
consistent. The biocomposite tiles have a higher mean than the commercially used tiles in thickness.
When it comes to breaking load, the biocomposite tiles have a mean of 672.958 from a diverse
raw data while the commercially used tiles have a mean of 760.77 from also a diverse set of data. The
commercially used tiles have a higher mean compared to the biocomposite tiles in breaking load.
Lastly, when it comes to flexural strength, the biocomposite tiles have a mean of 14.486 from a
shifting raw data while the commercially used tiles have a mean of 18.008 from also a shifting set of data.
The commercially used tiles have a higher mean compared to the biocomposite tiles in flexural strength.
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Table 2. Independent Samples T-Test of Rice Husk Ash and Eggshell Powder Biocomposite Tiles and
Commercially Used Tiles
Physical Tile Mean Statistic p-value Decision Remarks
Properties
Table 2 shows the difference in the physical properties between the rice husk ash and eggshell
powder biocomposite tiles and the commercially used tiles using the independent sample t-test via SPSS
23. Even if the biocomposite tiles are thicker with a mean of 6.826 than the commercially used tiles with a
mean of 6.5, the resulting mean of the breaking load and flexural strength of the commercially used tiles
are higher than the biocomposite tiles. The mean of the commercially used tiles in the breaking load is
760.796 while the biocomposite has 672.958. Also, the mean of the commercially used tiles in flexural
strength is higher with a 18.008 mean while the biocomposite tiles has 14.486 mean only.
On a side note, significance of difference is then interpreted as follows: having a p-value less than
0.05 (p<0.05) is statistically significant. On the other hand, the p-value that is higher than 0.05 (p>0.05) is
not statistically significant. As shown on the tabular data, the thickness has a p-value of 0.134
(0.134>0.05), the breaking load has a p-value of 0.541 (0.541>0.05), and the flexural strength has a
p-value of 0.257 (0.257>0.05) indicating that all of the p-values of the physical properties were greater
than 0.05 therefore they failed to reject the null hypothesis, which indicates that there is not enough
evidence to support the claim that there is a significant difference between the rice husk ash and eggshell
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DISCUSSION
Interpretation
The 5 biocomposite tile samples have a mean of 6.826 in thickness, mean of 672.958 in breaking
load and mean of 14.486 in flexural strength. The 5 commercially used tile samples have a mean of 6.500
in thickness, mean of 760.796 in breaking load and mean of 18.008 in flexural strength. The resulting
mean of the breaking load and flexural strength of the commercially used tiles are higher than the
biocomposite tiles, while the biocomposite tiles are thicker than the commercially used tiles. With the
data, it can be inferred that even if the biocomposite tiles are thicker, the durability and physical
properties of the commercially used tiles are better, supporting the study of Singh & Singh (2019),
because of the rice husk ash, it reduced the strength of the resin and decreased the flexural strength of the
tile and because it also varies directly with the breaking load, it also decreased. Also, a study conducted
by Gebremedhin & Rotich (2020) supported that the flexural strength of the material was reduced because
there was a high amount of rice husk ash, the weight of the rice husk ash affected the optimum strength of
the tile, this was also supported by Kondu et. al. (2021), suggesting that the ash saturated the matrix that
produced a weaker composite. Lazrak et. al. (2018), stated that in order to improve the strength of the
material, more polymer content should be added, this proves that the rice husk ash content should be
lessened in order to get the optimal breaking load and flexural strength of the tiles.
According to the data gathered, the biocomposite tiles don't have a consistent thickness unlike the
commercially used tiles. Both tile groups have inconsistent outcomes. Although the results were different
from each other, it has been found that there is no significant difference in the thickness, breaking load
and flexural strength between the biocomposite tiles and the commercially used tiles. Because of its
materials, it was found to be on the same level of strength as the commercially used tiles. The rice husk
has high silica content that can enhance construction materials (Jongpradist, 2018) and eggshell powder
has cementitious properties because of the calcium oxide content that increases the durability of
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construction materials (Hamada et. al., 2020). Meanwhile, the resin was utilized as a binder for its high
strength and durability that can enhance the adhesion strength of a tile (Lee et. al., 2020). Moreover, rice
husk ash, eggshell powder and resin are eco-friendly materials that were made into tiles, supporting the
study of Gebremedhin & Rotich (2020), that biocomposites have the potential to be used in industrial
applications such as a tile. Unlike previous studies that focused on using the said materials in cement, the
focal point of the study is to make an eco-friendly tile that can be an alternative for commercially used
tiles. Furthermore, this would be beneficial to the environment by reducing waste and recycling it into
biocomposite tiles.
Implication
It can be inferred that due to the matrix of the rice husk ash and eggshell powder, the breaking
load and the flexural strength of the biocomposite tiles suffered. This proved the studies of Singh & Singh
(2019), Gebredmedhin & Rotich (2020), and Kondu et. al. (2021), stating that the high content of the rice
husk ash in the mixture of the tiles, have saturated the matrix that resulted in a weaker breaking load and
flexural strength. Also, Lazrak et. al. (2018) stated that in order to improve the strength of the tiles, more
epoxy resin should be added. This proved that the ratio used by the researchers resulted in weaker
biocomposite tiles and needs to be further improved. The thickness only makes up for the weak strength
of the biocomposite tiles. Even though there were observed differences between the two tile groups when
it comes to thickness, breaking load, and flexural strength, these were not statistically significant. It can
be inferred that biocomposite tiles could be on par with the commercially available tiles, making it a
Limitations
This research has several notable limitations such as the use of inconsistent tile molds and the
lack of evaluation of other tile properties due to lack of resources. Various properties of tiles such as
impact resistance, moisture expansion, thermal shock resistance, and other required characteristics by the
Department of Trade and Industry’s Bureau of Philippine Standards (DTI-BPS) were not measured in the
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study. Only the breaking load and flexural strength were tested since these were the only ones practical to
measure during the time of the pandemic. Also, it lacked an in depth study because of the time
restrictions. However, measuring only the thickness, breaking load, and flexural strength still provided an
insight to the structural capacity of the rice husk ash and eggshell powder biocomposite tiles, an extensive
study would validate the data gathered and strengthen the possibility of using the biocomposites tiles as
an alternative.
Recommendations
Based on the results of the study, the researchers would like to recommend improving the ratio of
the rice husk ash, eggshell powder and epoxy resin mixture in order to reach the optimum strength of the
biocomposite tiles. Taking the conclusions of the study, the breaking load and flexural strength could be
further improved if the rice husk ash content could be reduced to avoid saturating the matrix. Also, adding
more epoxy resin could be a potential solution on the matter. Therefore, the future researchers should try
using different concentrations in order to know the best mixture when making the rice husk ash and
eggshell powder biocomposite tiles. When it comes to thickness, the researchers recommend to get a
uniformed mold or a professional mold in order to get the consistent thickness of the commercially used
tiles. The researchers also recommend studying other physical properties to gain more insight to the
structural capacity of the tiles. Take in consideration the required characteristics of the tiles from the
Department of Trade and Industry’s Bureau of Philippine Standards (DTI-BPS). With this study further
improved, the rice husk ash and eggshell powder biocomposite tiles could be commercially manufactured
in the market as eco-friendly tiles that can potentially be used as alternatives for the commercially used
tiles. These could be used in households, buildings, public spaces, and other walkways, lessening the
environmental impact of the adverse effects of the production of commercially used tiles.
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THE PROPONENTS
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