Mass and Energy Balance of Palm Oil

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Utilization of Palm Oil Mills Wastes as Source of Energy and Water in the
Production Process of Crude Palm Oil

Article · January 2014

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Chemistry and Materials Research www.iiste.org
ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online)
Vol.6 No.8, 2014

Utilizations of Palm Oil Mills Wastes as Source of Energy and


Water in the Production
1*
Process
2
of Crude
3
Palm Oil 4
Ridzky Kramanandita , Tajuddin Bantacut , Muhammad Romli , Mustofa Makmoen
1,4
School of Industrial Management, Ministry of Industry, Indonesia
2,3
Department of Agroindustrial Technology, Bogor Agricultural University, Indonesia
* E-mail of the corresponding author: ridzky@kemenperin.go.id
Abstract
Palm oil mills in their production process require a large amount of energy and water. Scarcity and enormous
costs of energy and water become factors that may limit the future production of crude palm oil (CPO). On the
other hand, demands for palm oil and its derivatives are increasing. Therefore, a number of research on energy
and water by utilizing biomass produced by fresh fruit bunches (FFB) are necessary to develop. Analysis on the
energy and mass balance of palm oil mills was carried out to obtain accurate information on the needs and the
potential of energy and water from the wastes generated. Analysis on the energy and mass balance of palm oil
mills was carried out to obtain accurate information on the needs and the potential of energy and water from the
wastes generated. The results of the analysis of the energy and mass balance show that the potential of the total
solid wastes generated by the palm oil mills with a capacity of 30 tons/hr are equal to 16,090.09 kg/hr or
equivalent to 53.63% of the fresh fruit bunches with the composition of empty fruit bunches (26.97%), fibers
(17.67%) and shells (6.46%), while the liquid wastes generated are equal to 18,113.15 Kg/hr (%) with the
composition of mud (18.38%) and water (42.05%). The palm oil mills required To supply energy for palm oil
mills, the solid wastes can be converted into biohydrogen, biogas and bioethanol, while the liquid wastes can be
converted into biogas and biohydrogen as well as water sources.
Keywords: oil palm, energy, water, equilibrium

1. Introduction
The conversion processes of fresh fruit bunch (FFB) into crude palm oil (CPO) require sufficiently enormous
energy and water supply. To produce CPO, Palm oil mills with the capacity of 30-60 ton/hr require 14-25 kWh of
energy (Yusoff, 2006; Chalvaparit et al., 2006; Mahlia, 2001; Yoshizaki et al., 2013) and 300,000-350,000
tons/year of water (Ahmad et al., 2003). In addition, the use of energy and water in a large quantity also
generates a sufficiently sizeable waste. Ohimain et al. (2013) states that the conversion process of FFB will
produce 10-30% CPO with by-product of 30-70% solid waste and 60-70% palm oil mill effluents (POME).
According to Nasution et al. (2014), the composition of solid wastes generated by the palm oil mills in Indonesia
consists of fibers (12-15%), shells (5-7%) and empty fruit bunches (20-23%), depending on the technology
process applied.
The potential of wastes from palm oil mills as an energy source for those palm oil mills has also been widely
studied. However, these studies remains incomplete, because the wastes converted into energy for palm oil mill
is still confined either only to solid wastes (Husain et al., 2003; Nasution et al., 2014; Ohimain, 2014) or liquid
waste (Gobi et al., 2013). This issue leads to the analysis of waste potential use which cannot predict the exact
amount of energy necessary for those palm oil mills. Therefore, this study will examine the details of mass
balance and energy balance in order to determine the potential of by-products in the form of either solid waste or
liquid waste and thus palm oil mills will have alternatives to meet its energy requirements.

2. Methodology
2.1 The Analysis of Mass and Energy Balance
The mass and energy balance calculation was made based on the law of conservation of mass and energy which
states that mass and energy cannot be created or destroyed, but they can be transformed into another form. The
completion stage of mass and energy balance did not involve a chemical reaction because the crude palm oil was
generated through the processes of pressing and physical purification.
To make the calculation, the basic mass balance employed was 30 ton of FFB/hr, based on the results of the
proximate analysis of FFB processed in palm oil mills, FFB composition was dominated by empty fruit bunches
(23%), oil (21%) and silt (22%), while the rest was water (12%), endoscarp (6%), kernel (5%) and fibers (11%).
The mass balance was calculated based on the law of mass balance by Perry et al. (1997) with the formula as
follows:

Where:
minput = mass input (kg)
moutput = mass output (kg)

In some production processes, production costs can be estimated based on the amount of energy required for the

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Chemistry and Materials Research www.iiste.org
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Vol.6 No.8, 2014

production process. The basic concept of energy balance is defined as follows:

Where:
Ei = Energy input (kJ)
E0 = Energy output (kJ)
Q = Heat (kJ)

The assumptions used in the calculation of the energy balance are:


 stationary and material flows are in a state of a thermodynamic equilibrium level at both the entrance
station and the exit station
 one-dimensional flows at both the entrance station and the exit station
 kinetic energy and potential energy are ignored

1.1.1 The determination of the steam requirement


The calculation of the steam requirement of palm oil mills with a capacity of 30 ton of FFB/hr was performed
using the following formula:

Where:
M = flow mass of FFB (kg)
Dt = temperature difference (oC)
Cp = the average specific heat of EFB (kcal/kg°C )

1.1.2 The determination of the average Cp of FFB


The approach taken to determine the Cp average of FFB is:

Where:
M = mass of FFB components (kg)
Cp of FFB components = water; shell; kernel; EFB; fiber (kg)
M = Mass of FFB (kg)

The mass and energy balance analysis was performed in all stations (sterilization, Stripper, Digester, Pressing,
Continous Settling Tank, Sludge Tanks, Sludge Separator, Oil Purifier, Vacuum Dryer, CPO Storage,
Depericarper, Silo Dryer, Nut Crackers, Hidrocyclone, Kernel Dryer and Kernel Storage).

2. Data
The primary data consisting of CPO production process were retrieved from a palm oil mill in Southern Borneo,
which had a production capacity of 30 ton of FFB/hr. The secondary data including the waste-to-energy
conversion process were based on the results of the literature study related to the research topic.

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FFB

Sterilizer

Hopper Stripping

Digester

Pressing Depericarper

CST

Silo Dryer
Oil purifier
Sludge tank
Nut
Crackers
Vacuum
dryer
Sludge
separator
Hidrocyclone
Storage
Tank

Kernel Dryer

Storage Boiler
Waste Plan
Kernel

Figure 1. The stages of CPO production processes at palm oil mills

3. Result and Discussion


3.1 CPO Production Process
Fresh fruit bunch (FFB) processing into crude palm oil (CPO) has several stages including raw materials input,
boiling, digesting, fruit compression, waste and nut disseverance, palm oil clarification, sludge processing and
nut cracking (Pardamean, 2008). While according to Pahan (2006), palm oil mills basically can be divided into
two stations – the main station and the supporting station. The main station, which covers the entire series of the
primary process to convert palm oil into crude palm oil, comprises units of fruit acceptance, sterilizer, stripper,
digester, press, purification as well as nut and kernel separation (Figure 1).
3.1.1 Sterilizer Station
The sterilization process was performed by inserting fresh fruit bunches (FFB) at a temperature of 125oC–135oC
for 82-90 minutes. The amount of the steam required was 3,345 kg/hr (11%), whereas the steam loss that
occurred was 3.65% (1,095 kg/hr). This process generated 85% of cooked FFB (25.041 kg/hr) and a condensate
by 6,905 kg/ hr (22.5%). Based on the results of the calculation, it is suggested that the efficiency of the
sterilization process was 85%. The energy need in this process was 19,954.05 MJ/ hr.
3.1.2 Stripper Station
In this station, the cooked fresh fruit bunches produced in the sterilizer station were fed into a 33.95 rpm stripper
drum to dislodge fruits from their stems. The total number of cooked FFB generated in this station reached
25,041 kg/hr with a by-product in the form of empty fruit bunches (EFB) that reached 8,093.27 kg/hr. In this
process, the estimated heat loss reached 85,645.02 MJ /hr, with a total energy contained in this station by
308,921.4 MJ/hr.
3.1.3 Digester Station
Palm oil fruits generated in the stripping station by 17,079.9 kg/hr were fed into the digester. In this stage, the
digester separated flesh fruit and nut using agitator blades at a temperature of 90 – 95oC. Furthermore, the
estimated steam demand was 6.67% of the amount of the feed and therefore the amount of the heat required was
7,494.01 MJ/ hr.
3.1.4 Pressing Station
Palm oil fruits generated from the digester station were then circulated into the pressing machine with addition of

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hot water as much as 3,710.76 kg/hr of the amount of the mass of the material to be pressed. This stage produced
crude oil by 12,245.50 kg/hr (consisting of oil by 5,632.93 kg/ hr; dirt by 857.19 kg/ hr, and free fatty acids by
514.31 kg/ hr) and silt by 41, 9%.
3.1.5 Continous Settling Tank (CST) Station
The crude oil generated by the pressing station was flowed into the continous settling tank (CST), where sewage
sludge was separated from the oil by gravity. This stage is divided into two, namely crude oil flowing to the
sludge tanks station and crude oil flowing to the oil purifier station. On the other hand, the sludge flowing to the
sludge tank amounted to 8,449.40 kg/ hr (4.90% of oil, 7.5% of water and 87.6% of impurities), whereas the
amount of crude oil leading to the oil purifier station was as much as 6,245.21 kg/ hr. In this process, the
estimated heat loss was at 857.24 MJ/ hr.
3.1.6 Sludge Tank Station
Sludge which still contains oil from CST was flowed into the sludge tank to separate the oil from the impurities.
The sedimentation process generated crude oil by 8,381.80 kg/ hr, which will be streamed to the sludge separator
station. This stage will generate sludge as a by-product by 67.59 kg/ hr. The heat required in the tank sludge
station was 11,587.21 MJ/ hr.
3.1.7 Sludge Separator Station
In sludge separator station, oil and impurities that the crude oil produced in the sludge tank station were
separated using a precleaner and a stainer. The amount of the crude oil separated, while the results obtained from
this process were 2,449.10 and a by-product in the form of sludge by 5,867.26 kg/ hr. The amount of the energy
required in this station was 258.83 MJ/ hr.
3.1.8 Oil Purifier Station
The total amount of crude oil generated in CST station amounted to 6,245.21 kg/hr. Crude palm oil was then
purified to be separated from its impurities. This process generated a total of 6,231.46 kg/hr of crude palm oil
which consisted of 96% of oil, 0.45% of water, 0.13% of impurities and 2.92% of free fatty acids. The by-
product generated from this process was 13.74 kg/hr of sludge. In this process the heat lost reached 658.67 MJ/ h
with a total energy involved in the system as much as 23,606.3 MJ/hr.
3.1.9 Vacuum Dryer Station
Crude oil generated in the oil purifier station was then dried to remove the water, to make the FFA value do not
increase. The crude oil produced in this process was equal to 6,170.40 kg/hr with a water content that reached
0.002% (0.123 kg/hr) and was then stored in the storage tank, while the by-product was in the form of 61.07
kg/hr of water. On the other hand, this process also produced heat steam as a by-product by 163,419.04 MJ/hr
and the heat needs reached 778.51 MJ /hr.
3.1.10 Depericarper Station
The by-product generated in the pressing station was nuts 4,408.38 kg/hr, fibers 5,460.38 kg/hr and water 150.29
kg/hr. This process was intended to separate the nut from the fiber. The solids produced in the depericarper
station was 4,608.76 kg/ hr, while the by-product that consisted of fibers reached 5,410.29 kg/hr. The heat energy
involved in this process was 38,606.16 MJ/hr while the estimated heat loss was 1,347.87 MJ/hr.
3.1.11 Silo Dryer Station
This station serves to remove water contained in the nuts, therefore the heat required in this process was 139.81
MJ/hr. This process produced nuts by 4,332.24 kg/hr and a byproduct in the form of water vapor as much as
276.53 kg/hr (6% of the input).
3.1.12 Nut Cracker Station
Palm nuts that had been dried in the silo dryer station were fed to this station to encounter a breakdown process.
Palm nuts that had encountered the breakdown process would generate 3,444.13 kg/hr of kernels and 888.11
kg/hr of shells. The heat missing in this process reached 14,198.3 MJ/hr.
3.1.13 Hidrocyclone Station
A mixture of fractions generated in the nut crackers station was put into a hidrocyclone. In the hidrocyclone,
separation of kernels from their shells occurred based on the specific gravity. The core of the kernels would
move upwards the hidrocyclone, while the shells would fall under the hidrocyclone. The by-product generated in
this stage consisted of 1,949.50 kg/hr of shells, while the heat loss was equal to 13,016.18 MJ /hr.
3.1.14 Kernel Dryer Station
Kernels from the hydrocyclone were fed into a kernel dryer. In this process, the water content as much as 357.41
kg/hr contained in the kernels was evaporated. Furthermore, the kernels (2,025.32 kg/hr) was stored in a kernel
shelter. The by-product generated was in the form of steam by 956.42 MJ/hr, while the heat required was equal
to 233.50 MJ/hr.
3.2 The Mass and Energy Balance of CPO Production Processes
Based on these data, the calculation of the mass balance is described in Figure 2, and the energy balance for each
station is described in Figure 3.

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FFB Water Fiber


Steam Out
1.095 kg 5.302,08 kg
FFB Steam In IX.
30.000 kg 3.345 kg Depericarper
Water (condensate)
6.646,25 kg Nuts
Water 108,21 kg
Oil
I. Sterilizer 150,29 kg
47,25 kg Condensate
Fiber
Solids 5.460,38 kg
256,5 kg Coocked FFB 25.041 kg Nuts Nuts 4.484,33 kg
Water 459 kg 4.408,38 kg Water 78,35 kg
Fiber 46,09 kg
Oil
2,45 kg II. Stripping
EFB
8.092,27 kg Water
Fruits 17.079,9 kg X. Silo Dryer
276,53 kg
Fruits Water 260,1 kg
65,28 kg Steam In
1.213,8 kg Nuts 4.310,58 kg
III. Digister Fiber 21,66 kg

Flesh Fruits 17.079,9 kg Steam In XI. Nut


Water 1.473,9 kg 3.710,76 kg Cracker

Water IV. Pressing Shell Kernel


50,7 kg 888,11 kg 3.444,13 kg
Va. Sludge Water
Tank Oil 5.632, 93 kg, Water 5.241,08 kg 4.115,63 kg
Solids
Solids 857,19 kg, FFA 514,31 kg Water
16,6 kg
Oil 414,02 kg 4.115,63 kg XII. Shell
Oil 2.305 kg Water 633,71 kg Hidrocyclone 1.939,76 kg
Water 5909,17 kg Solids 7.401,67 kg V. Continous
Settling Tank Kernel
Solids 167,64 kg
9,75 kg
Water Kernel 2.102,52 kg
5.515,23 kg Oil 2.069,49 kg Oil 5.964,17 kg Water 280,21 kg
Water 324,51 kg Water 28,1 kg, FFA 218,58 kg
Vb. Sludge Solids 55,1 kg Solids 34,35 kg
Separator
Solids XIII. Kernel Water
299,23 kg Dryer 357,41 kg
VI. Oil Purifier

Oil
52,81 kg Oil 6013,37 kg, Solids 8,1 kg Kernel 2.023,3 kg
Water 28,04 kg, FFA 181,96 kg Water 2,03 kg

Solids
0,41 kg VII. Vacuum
Dryer XIV.Kernel
Tank
Water
13,33 kg Oil 5.972,95 kg, FFA 189,31 kg
Water 0,12 kg, Solids 8,02 kg
Water
61,07 kg VIII. Oil
Tank

Figure 2. Detail Mass Balance of Palm Oil Mill

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FFB Water Fiber


Steam Out
1.329,86 MJ 110oC IX. 1.858,83 MJ
FFB Steam In Depericarper
o
Water (condensate) 362.921 MJ 30oC 2132,71 MJ 130 C (1347,87 MJ) Nut
8.967,21 MJ 863,32 MJ
Water
Oil I. Sterilizer 40oC
196,50 MJ
218,51 MJ Condensate 90oC 19.954,05 MJ
Fiber
Solids 1.914,33 MJ Nut 35.778,48 MJ
75,33 MJ Cooked FFB 373.759 MJ Nut Water 89,35 MJ
Water 657,67 MJ 100oC 35.172,56 MJ Fiber 16,15 MJ
50oC 50oC
Oil
9,62 MJ II. Stripping
90oC (85.645,0 MJ)
EFB Water
11.817,15 MJ X. Silo Dryer
Palm Fruits 210.338,19 MJ 338,46 MJ
139,81 MJ
Palm Fruits Water 307,49 MJ 90oC Steam In 70oC
803,92 MJ 1.434,95 MJ
100oC Nut 35.651,99 MJ
III. Digister Fiber 7,87 MJ 60oC
7.494,01 MJ
Water XI. Nut
Flesh Fuits 217.770,63 MJ 4851,91 MJ Cracker
Water 1.804,02 MJ 100oC 50oC (14.198,3 MJ)

IV. Pressing
Water Kernel
(151.828,62 Shell
59,93 MJ 17669,6 MJ
Va. Sludge MJ) 2.529,52 MJ
90oC 60oC Water
Tank Oil 21.356,89 MJ, Water 5.977,08 MJ
Solids 11587,2 MJ Water 5524,84 MJ
Solids 206,39 MJ, FFA 280,16 MJ 90oC
4,21 MJ 4693,58 MJ XII.
Oil 1569,73 MJ Shell
Water 722,69 MJ 90oC V. Continous 30oC Hidrocyclone 2.529,52 MJ
Oil 9.059,36 MJ Solids 1782,21 MJ (13016,18 MJ)
Settling Tank Kernel
Water 6.985,84 MJ 80oC
(857,24 MJ) 50 MJ
Solids 41,84 MJ Kernel 10.786,67 MJ 30oC
Water Water 319,55 MJ
Oil 7846,3 MJ Oil 22.612,77 MJ
6520,12 MJ
Water 370,07 MJ Water 32,05 MJ, FFA 119,06 MJ 30oC
Vb. Sludge Solids 206,3 MJ Water
Separator Solids 8,27 MJ 90oC 407,6 MJ
90oC XIII. Kernel
Solids 258,83 MJ Evaporation
Dryer
74,68 MJ VI. Oil Purifier Heat
233,5 MJ
956,42 MJ
(658,67 MJ)
Oil 60oC
207,54 MJ Oil 22.799,28 MJ, Solids 1,95 MJ Kernel 10380,22 MJ
90oC Water 31,97 MJ, FFA 99,11 MJ 80oC Water 2,3 MJ 60oC

Solids VII. Vacuum


0,09 MJ Dryer XIV. Kernel
778,51 MJ Tank
Water
15,19 MJ Oil 23.475,56 MJ, FFA 110,67 MJ
80oC Water Water 0,15 MJ, Solids 2,07 MJ 80oC
69,64 MJ
80oC
Evaporation Heat VIII. Oil
163,41 MJ Tank

Figure 3. Detail Energy Balance of Palm Oil Mill

4. The Potency Of By Product Generated Palm Oil Industry


Based on the analysis of the mass balance and the energy balance that had been performed, it is revealed that the
by-product of the palm oil mills with a capacity of 30 ton/hr can be categorized into three: solid waste, liquid
wastes and gases. Table 2 shows that the most dominating solid waste is empty fruit bunch with a total number
of 8,092.27 kg/hr, followed by fiber wastes (5,348.17 kg/hr) and shell wastes (1,939.76 kg/hr). Compared to the
obtained fresh fruit bunches, the total solid wastes generated reached 51.27% with a composition that consisted
of empty fruit bunches (26.27%), fibers (17.83%) and shells (6.47%). This is in line with the study conducted by
Ohimain et al. (2013) suggesting that the solid wastes generated by palm oil mills reach 30 to 70%, depending on
the technology and the type of the plant used. The empty bunches were converted into biohydrogen (Abdul et al.,
2013; Kalinci et al., 2011; Chiew et al., 2013; Chong et al. 2013), biogas (O-Thong et al. 2012) and bioethanol
(Sudiyani et al. 2013).

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Table 2. The potential of solid wastes generated by palm oil mills with a capacity 30 ton/hr
Station Types of Solid Waste Composition Quantity (kg/hr)
Stripper Empty Fruit Bunches 99,17% EFB, 0,8% Fruits and 0,03% oil, at 90oC 8.092,27
Depericarper Fiber 98% Fiber and 2% kernel at 40oC 5.348,17
Hidrocyclone Shell 99,5% Shell dan 0,5% kernel at 28.5oC 1.939,76
The total amount of solid wastes 15.380,20

The liquid wastes produced by palm oil mills originate from several processing stations, among others are
sterilization, sludge tank, sludge separator, oil purifier and hidrocyclone stations. Each station has different
characteristics of wastes. The characteristics depend on the processes conducted, but in palm oil mills, liquid
wastes generally can be categorized into two: water (10,865.63 kg/hr) and sludge (5,948.60 kg/hr). The amount
of the liquid waste that reached 58% (16,814.23) is one of the potential to be developed into other forms of
energy sources such as (Choi et al., 2013; Poh et al., 2010; Gobi et al., 2013), biohidrogen (Singh et al., 2013a;
Singh et al., 2013b; Singh et al., 2013c; Badiei et al., 2011; Badiei et al., 2012; Ismail et al., 2010) and water
(Ahmad et al., 2003).

Table 3. Palm Oil Mill Effluents with a capacity of 30 ton/hr


Station Types of liquid waste Composition Quantity
(kg/hr)
Sterilisasi Water 0.70% oil, 3.8% Impurities and 95.5% water at 90 oC 6.750

Sludge Tank Sludge 75% water and 25% water at 90oC 67,60
Sludge Separator Sludge 0.95 oil, 94% water and 5.10%impurities, at 90oC 5.867,26
Oil Purifier Sludge 97% water and 3% impurities 13,74
Hidrocyclone Water Pure water (100%) at 30oC 4.115,63
The total amount of liquid wastes 16.814,23

5. Conclusion
Based on the analysis of the mass balance and the energy balance, palm oil mills with a capacity of 30 ton of
FFB/hr require 12.38 ton of water sources (41% of TBS). The amount of water input by 12.38 ton eventually
generated 18.11 ton of water, where the water surplus originated from FFB containing 5.73 ton of water (19.1%
FFB).
The amount of the output produced by CPO was 6.07 ton, while the yield generated by palm oil mills was 5.97
ton (19.9% of FFB). In the processing of oil palm into CPO, there was unprocessed oil which amounted to 0.102
ton (1.68% of CPO output).
Furthermore, the potential of solid waste generated by palm oil mills with a capacity of 30 ton/hr is equal to
15,380.20 kg/hr or 51.27% of fresh fruit bunches (FFB) consisting of empthy fruit bunches (26.27%), fibers
(17.83%) and shells (6.47%). On the other hand, the amount of the liquid wastes generated are equal to
16,814.23 kg/hr or 58% with the composition of the wastes that consisted of sludge (64.62%) and water
(35.38%). To meet the energy requirements of the palm oil mills, the solid wastes can be converted into
biohydrogen, biogas and bioethanol, while the the liquid wastes can be converted into biogas and biohydrogen
and water sources.
The station with the highest value of energy input/ output is the Sterilizer Station by 385,008 MJ/hr. The total
energy produced by the by-product of palm oil mills was equal to 42,865 MJ/hr consisting of the three largest
components, namely condensate water (16,063 MJ/hr), fibers (2,722 MJ/hr) and shells (8,104 MJ/hr). The
potential of untapped energy produced by palm oil mills using the appropriate technology can be used as a
source of energy.

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