DPP 2 Optical Isomerism VKP Sir-3707

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ORGANIC CHEMISTRY

TARGET DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP


COURSE NAME : UMANG (UP) DATE : 22.04.2013 to 27.04.2013 DPP NO. 05

DPP No. 05
* Marked Questions are having more than one correct option.
1. Indicate the number of chiral carbon atoms in the following molecule.

(A) 6 (B) 7 (C) 8 (D) 9

2.* Which pair is diastereomer :

(A) and (B) and

(C) and (D) and

3.* Which of the following compound will show diastereomerism.

(A) Ph – CC – Me (B) (C6H5)2N2 (C) (D)

4. Statement-1 : and have identical melting points.

Statement-2 : X and Y are identical compounds.


(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True.

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5. Match the following compounds with their possible isomerism.

6. Indicate whether each of the following structure has the R configuration or the S-configuration.

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k) (l)

(m) (n) (o) (p)

CH2CH3
CH3 H
(q) (r) (s) (t) Br CH3
CH2CH3

(u)

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7. Indicate whether each of the following structure has the R configuration or the S-configuration.

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k) (l)

(m) (n) (o) (p)

(q) (r) (s) (t)

(u) (v) (w) (x)

(y)

Answer Key
DPP # 05
1. (C) 8 2.* (CD) 3.* (BD) 4. (C) 5. (A) q, (B) s, (C) (p), (D) r
6. (a) R (b) R (c) S (d) S (e) R (f) S (g) R (h) S (i) S (j) S (k) S (l) R
(m) S (n) R (o) S (p) S (q) 2R 3R (r) 2R 3R (s) 2S 3R (t) 3S 4R
(u) 2R 3S

7. (a) R, (b) R, (c) S, (d) S, (e) R, (f) S, (g) R, (h) S, (i) S, (j) S, (k) S, (l) R, (m) S, (n) R, (o) S, (p) S
(q) 2R 3R, (r) 3S 4R, (s) 2S 3R, (t) 3S 4R, (u) 1R 2S, (v) 5R 6S, (w) 3S 4R, (x) 4S 5R,
(y) 2R3R4R

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F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303 PAGE NO. # 3

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