Designation: E872 − 82 (Reapproved 2013)

Standard Test Method for

Volatile Matter in the Analysis of Particulate Wood Fuels1
This standard is issued under the fixed designation E872; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope 4. Significance and Use

1.1 This test method determines the percentage of gaseous 4.1 The test procedures described in this test method can be
products, exclusive of moisture vapor, in the analysis sample of used to determine the percentage of gaseous products, exclu-
particulate wood fuel that is released under the specific sive of moisture vapor, of any particulate wood fuel meeting
conditions of the test. The particulate wood fuel may be the requirements specified in this test method.
sanderdust, sawdust, pellets, green tree chips, hogged fuel, or
other type particulate wood fuel having a maximum particle 5. Apparatus
volume of 16.39 cm3 (1 in.3). Volatile matter, when determined 5.1 Platinum Crucible, with closely fitting cover, or a
as herein described, may be used to indicate yields on nickel-chromium crucible, with closely fitting cover, pre-fired
processes to provide the basis for purchasing and selling or to to oxidize and stabilize the weight. The crucible shall be of not
establish burning characteristics. less than 10 or more than 20-mL capacity, not less than 25 or
1.2 The values stated in SI units are to be regarded as the more than 35 mm in diameter, and not less than 30 or more
standard. The values given in parentheses are for information than 35 mm in height.
only. 5.2 Vertical Electric Tube Furnace—The furnace may be of
1.3 This standard does not purport to address all of the the form shown in Fig. 1. It shall be regulated to maintain a
safety concerns, if any, associated with its use. It is the temperature of 950 6 20°C in the crucible, as measured by a
responsibility of the user of this standard to establish appro- thermocouple positioned in the furnace.
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use. 6. Procedure
6.1 Sampling:
2. Referenced Documents
6.1.1 Place of Sampling—Take sample where wood is being
2.1 ASTM Standards:2 loaded into or unloaded from means of transportation or when
D346 Practice for Collection and Preparation of Coke discharged from storage bins or conveyors.
Samples for Laboratory Analysis
NOTE 1—Samples collected from the surface of piles are, in general,
D2013 Practice for Preparing Coal Samples for Analysis unreliable because of the exposure to the environment. If necessary,
E871 Test Method for Moisture Analysis of Particulate collect nine increments from a foot or more below the surface at nine
Wood Fuels points covering the pile.

3. Summary of Test Method 6.1.2 Collection of Gross Sample:

6.1.2.1 Collect increments regularly, systematically, and
3.1 Volatile matter is determined by establishing the loss in with such frequency that the entire quantity of wood sampled
weight resulting from heating wood under rigidly controlled will be represented proportionally in the gross sample.
conditions. The measured weight loss, corrected for moisture 6.1.2.2 The quantity of the sample shall be large enough to
as determined in Method E871, establishes the volatile matter be representative but not less than 10 kg (22 lb).
content. 6.1.2.3 Place samples in an airtight container immediately
after collection. Maintain samples in the airtight container
1
This test method is under the jurisdiction of ASTM Committee E48 on whenever possible to prevent gains or losses in moisture from
Bioenergy and Industrial Chemicals from Biomass and is the direct responsibility of the atmosphere.
Subcommittee E48.05 on Biomass Conversion.
Current edition approved Aug. 15, 2013. Published November 2013. Originally 6.1.3 Sample reduction may be done by two methods, a
approved in 1982. Last previous edition approved in 2006 as E872 – 82 (2006). coning and dividing process, or by using a riffle. Mixing,
DOI: 10.1520/E0872-82R13.
2
coning, and quartering are described and illustrated in Practice
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
D346.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on 6.1.3.1 Coning and dividing reduction is accomplished by
the ASTM website. placing the gross sample on a sheet of rubber or oil cloth.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

1
 E872 − 82 (2013)

FIG. 1 Electric Furnace for Determining Volatile Matter

Thoroughly mix it by raising first one corner of the cloth and 6.2 Reduce the sample to a smaller particle size by use of
then the other. After mixing, cone and quarter sample. Con- cutting or shearing type laboratory mill. The final product
tinue the operations until the sample is reduced sufficiently so should pass through a 1-mm or smaller screen. Depending on
that one quarter weighs about 50 g (0.11 lb). This shall the specific product this step may involve more than one stage
constitute a laboratory sample. of reduction, that is, passing the sample through a mill with a
6.1.3.2 Riffle reduction is accomplished by using a standard larger size screen first and then milled to pass the final screen.
coal riffle. The gross sample is riffled repeatedly until one half Minimum atmospheric exposure is recommended and the
of the riffle sample equals about 50 g (0.11 lb) which will milling process should be conducted to avoid significant
constitute a laboratory sample. Riffles and procedures are moisture means to ensure thorough intermix of heavy fines and
described in Practice D2013. milled fluff.

2
 E872 − 82 (2013)
6.3 Weigh the crucible and cover to the nearest 0.01 g and 7. Calculation
record as crucible weight, Wc. Place approximately 1 g of 7.1 Calculate the weight loss percent as follows:
sample in the crucible, cover, weigh the crucible, cover, and
Weight loss, % 5 100 3 ~ W i 2 W f ! / ~ W i 2 W c ! 5 A (1)
sample to the nearest 0.01 g, and record as initial weight, Wi.
where:
6.4 Place the covered crucible with sample on platinum or
nickel-chromium wire supports and insert directly into the Wc = weight of crucible and cover, g,
furnace chamber, which shall be maintained at a temperature of Wi = initial weight, g, and
Wf = final weight, g.
950 6 20°C, and lower immediately to the 950°C zone.
Regulation of the temperature to within the prescribed limits is 7.2 Calculate the volatile matter percent in the analysis
critical. After the more rapid discharge of volatile matter has samples as follows:
subsided as shown by the disappearance of the luminous flame, Volatile matter in analysis sample, % 5 A 2 B (2)
inspect the crucible (Note 2) to verify the lid is still properly
where:
seated. If necessary, reseat the lid to guard against the admis-
sion of air into the crucible. Do this as rapidly as possible by A = weight loss %, and
raising the crucible to the top of the furnace chamber, reposi- B = moisture, %, as determined using Method E871.
tion the lid as described in Practice D2013 to more perfectly 8. Precision and Bias
seal the crucible, then lower immediately back to the 950°C
zone. After heating for a total of exactly 7 min, remove the 8.1 The following criteria should be used for judging the
acceptability of results:
crucible from the furnace and, without disturbing the cover,
8.1.1 Repeatability—Duplicate results by the same labora-
allow it to cool in a desiccator. Weigh the covered crucible with
tory should not be considered suspect unless they differ by
sample as soon as cold to the nearest 0.1 mg and record as final
more than 0.3 %.
weight, Wf.
8.1.2 Reproducibility—The results submitted by two or
NOTE 2—Inspection of the crucible may be aided by the use of a mirror more laboratories should not be considered suspect unless they
held above the furnace well. differ by more than 1.0 %.

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