Silicon Metal ScienceLab

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Material Safety Data Sheet


Silicon MSDS
Section 1: Chemical Product and Company Identification

Product Name: Silicon Contact Information:


Catalog Codes: SLS4102, SLS3313 RODEX
14025 Smith Rd.
CAS#: 7440-21-3 Houston, Texas 77396
RTECS: CW0400000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Silicon
Order Online: sales@rodex.co.in, www.rodex.co.in
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Silicon International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Si For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Silicon 7440-21-3 100

Toxicological Data on Ingredients: Silicon: ORAL (LD50): Acute: 3160 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMEN

Section 4: First Aid Measures


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Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attentio
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, adminis
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clo
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.


Auto-Ignition Temperature: 780°C (1436°F)
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances:
Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence
of static discharge: Not available. Slightly explosive in presence of heat.
Fire Fighting Media and Instructions:
Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing vessels with
water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Interaction of calcium and silicon is violently incndescent above 1050 deg. C after a short delay. Amorphous or crystalline silicon
both react exothermically when heated with alkali-metal carbonates attaining incandescence and evolving carbon monoxide.
Special Remarks on Explosion Hazards:
Material in powder form, capable of creating a dust explosion. Mixture of silicon, aluminum, and lead oxide explodes when heated.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Flammable solid. Stop leak if without risk. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, bas

Section 7: Handling and Storage

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Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear su
Storage:
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (s

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user o
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Sug
Exposure Limits:
TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable. TWA: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation Total

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. (Crystals solid.)
Odor: Not available.
Taste: Not available.
Molecular Weight: 28.09 g/mole
Color: Dark grey. Brown.
pH (1% soln/water): Not applicable. Boiling Point: 2355°C (4271°F) Melting Point: 1410°C (2570°F)
Critical Temperature: 4886°C (8826.8°F)
Specific Gravity: 2.33 (Water = 1) Vapor Pressure: Not applicable. Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. Ionicity (in Water): Not available.

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Dispersion Properties: Not available.
Solubility: Insoluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, incompatible materials
Incompatibility with various substances:
Reactive with oxidizing agents. Slightly reactive to reactive with moisture.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
May react violently or explosively on contact with water. Will react with water or steam to product hydrogen Incompatible (violent reactions) with c
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 3160 mg/kg [Rat].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans:
Nuisance dust. Acute Potential Health Effects: Skin: May cause skin irritation from frictional action. Eyes: May cause eye irritaiton from frictional ac

Section 12: Ecological Information


Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

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Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 4.1: Flammable solid. Identification: : Silicon powder, amorphous UNNA: 1346 PG: III Special Provisions for

Section 15: Other Regulatory Information

Federal and State Regulations:


Illinois toxic substances disclosure to employee act: Silicon Rhode Island RTK hazardous substances: Silicon Pennsylvania RTK:
Silicon Minnesota: Silicon Massachusetts RTK: Silicon New Jersey: Silicon TSCA 8(b) inventory: Silicon
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European
Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS B-4: Flammable solid.
DSCL (EEC):
R11- Highly flammable. S2- Keep out of the reach of children.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 2
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 2
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when
ventilation is inadequate. Safety glasses.

Section 16: Other Information


References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 06:26 PM
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we make n

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no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their pa

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