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    Organic Name Reactions

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    Pratham Zala
    1. The Finkelstein reaction converts an alkyl halide to the corresponding alkyl iodide using sodium iodide. 2. The Friedel-Crafts alkylation and acylation reactions introduce alkyl and acyl groups onto aromatic rings using Lewis acids like anhydrous aluminum chloride. 3. The Wurtz and Wurtz-Fittig reactions involve the dimerization of alkyl halides to form alkanes using sodium metal in dry ether.

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    Organic Name Reactions

    Uploaded by

    Pratham Zala
    161 views2 pages
    1. The Finkelstein reaction converts an alkyl halide to the corresponding alkyl iodide using sodium iodide. 2. The Friedel-Crafts alkylation and acylation reactions introduce alkyl and acyl groups onto aromatic rings using Lewis acids like anhydrous aluminum chloride. 3. The Wurtz and Wurtz-Fittig reactions involve the dimerization of alkyl halides to form alkanes using sodium metal in dry ether.

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    ORGANIC NAME REACTIONS

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    1. The Finkelstein reaction converts an alkyl halide to the corresponding alkyl iodide using sodium iodide. 2. The Friedel-Crafts alkylation and acylation reactions introduce alkyl and acyl groups onto aromatic rings using Lewis acids like anhydrous aluminum chloride. 3. The Wurtz and Wurtz-Fittig reactions involve the dimerization of alkyl halides to form alkanes using sodium metal in dry ether.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    161 views2 pages

    Organic Name Reactions

    Uploaded by

    Pratham Zala
    1. The Finkelstein reaction converts an alkyl halide to the corresponding alkyl iodide using sodium iodide. 2. The Friedel-Crafts alkylation and acylation reactions introduce alkyl and acyl groups onto aromatic rings using Lewis acids like anhydrous aluminum chloride. 3. The Wurtz and Wurtz-Fittig reactions involve the dimerization of alkyl halides to form alkanes using sodium metal in dry ether.

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    ORGANIC NAME REACTION

    1. Finkelstein
    CH3Br + NaI CH3-I + NaBr

    Swarts CH3Br + AgF CH3F + AgBr


    2.
    CH3
    Friedel-
    Anhydrous AlCl3
    Crafts
    + H 3C Cl
    Alkylation
    3.
    COCH 3
    Friedel-
    CH 3COCl
    Crafts
    4. Acylation
    Anhydrous AlCl3

    2Na
    Wurtz H 3C Cl + Cl CH3 H 3C CH3 + Na Cl
    5.
    Cl Cl

    Fittig +
    2Na
    + Na Cl
    6. Dry ether
    Cl

    Wurtz-Fittig 2Na
    + Cl CH3 CH3 + Na Cl
    Dry ether
    7.
    OH OH
    ON a

    Na OH i) CO2 COOH
    Kolbe
    ii) H+
    8.

    Reimer-
    Tiemann
    9.
    10. Williamson CH3-Br + CH3-ONa CH3-O- CH3 + NaBr

    H3O+
    Stephen H 3C CN + SnCl2 + HCl H 3C CH NH H 3C CHO
    11.
    CH3 CHO

    CrO2Cl2
    Etard
    H3O+
    12.
    CHO

    Gatterman – CO / HCl
    Koch
    Anhydrous AlCl3
    13.

    Lokesh Suredia K V ONGC MEHSANA Page 1


    ORGANIC NAME REACTION
    O H2 O
    Rosenmund
    C C
    reduction H 3C Cl H 3C H
    Pd / BaSO 4
    14.
    O
    Clemmensen Zn - Hg
    C H 3C CH2 CH3
    reduction Conc. HCl
    15. H 3C CH3
    O
    Wolff-Kishner i) NH2-NH2
    reduction C H 3C CH2 CH3
    16. H3C CH3 ii) KOH / Ethylene glycol / 
    17. Tollens’ test R-CHO + 2 [Ag(NH3)2]+ + 3 OH- R-COO- + 2Ag + 2H2O + 4 NH3
    18. Fehling’s test R-CHO + 2 Cu 2+
    + 5 OH -
    R-COO + Cu2O-
    + 3H2O
    O
    I2 / NaOH
    Iodoform C CHI3 + CH3COONa
    19. H 3C CH3 OR, NaOI
    OH
    dil NaOH 
    Aldol H3C CH CH2 CHO H3C CH CH
    2 H 3C CHO
    condensation
    20.
    Conc. NaOH
    21.
    Cannizzaro HCHO
    + HCHO HCOON a + H 3C OH

    i) Cl2 / Red Phosphorus


    Hell-Volhard- H 3C COOH H 2C COOH
    Zelinsky (HVZ)
    ii) H2O
    22. Cl
    O
    Hoffmann Br2
    bromamide H 3C C NH2 H3C NH2
    23. degradation NaOH

    Carbylamine 
    24. R-NH2 + CHCl3 + 3 KOH R-NC + 3 KCl + 3 H2O
    NH2 + -
    N 2 Cl

    NaNO 2 + dil HCl


    Diazotisation
    273 - 278 K
    25.
    + -
    N 2 Cl Cl

    Sandmeyer. CuCl / HCl


    N2
    +
    26.
    + -
    N 2 Cl Cl

    Gatterman Cu / HCl
    N2
    +
    27.

    + -
    OH-
    Coupling N 2 Cl + H OH N N OH
    28.

    Lokesh Suredia K V ONGC MEHSANA Page 2

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