Iron Calibration Curve For PG

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x (Sample Conc.

mg/l) y (Absorbance)
0 0
0.25 0.034
0.5 0.081
0.75 0.121
1 0.154
1.5 0.215
2 0.383
3 0.585
4 0.73

Serial No. Conical Flask No. Concentration (mg/l) Absorbance at 510 nm


1 1 0 0
2 2 0.2 0.034
3 3 0.5 0.081
4 4 0.75 0.121
5 5 1 0.154
6 6 1.5 0.215
7 7 2 0.383
8 8 3 0.585
9 9 4 0.730
10 10 stnd. soln. before aeration 0.711
11 11 stnd. soln. after aeration (4 mg/l) 0.129
12 12 - 0.057
13 13 - 0.007
14 14 - 0.015
15 15 - 0.1047
16 16 - 0.126
17 17 - 0
Calibration cu
0.8

0.7 f(x) = 0.182860377358491 x


R² = 0.994181937339136

0.6

0.5

Absorbance
0.4

0.3

Description Sample Concentration (mg/l) 0.2


50 ml distilled water -
1 ml I.S. + 49 ml d.w. - 0.1
2.5 ml I.S. + 47.5 ml d.w. -
3.75 ml I.S. + 46.25 d.w. -
0
5 ml + 45 d.w. - 0 0.5 1 1.5
7.5 ml I.S. + 42.5 d.w. -
10 ml I.S. + 40 ml d.w. -
15 ml I.S. + 35 ml d.w. -
20 ml I.S. + 30 ml d.w. - Approx. values 2 decimal places
w/o aeration 30 mins. 3.88737014762165 3.89
After aeration 30 mins. 0.705303444505194 0.71
Dipanwita 0.311645708037179 0.31
Poonam 0.0382722799343904 0.04
A. D. 0.0820120284308365 0.08
A. M. 0.572443958447239 0.58
T B. 0.688901038819027 0.69
Aritrya Ghosh (Municipal Tap water) 0 0
Calibration curve for total iron content

0.182860377358491 x
.994181937339136

0.5 1 1.5 2 2.5 3 3.5 4 4.5


Sample concentration (mg/l)
time (hours) Ce Qe 1/ce 1/Qe Qt (mg/g)
0.083 2.663 0.017 0.376 59.287 0.017
0.167 2.433 0.028 0.411 35.275 0.028
0.250 2.247 0.038 0.445 26.565 0.038
0.500 1.832 0.058 0.546 17.117 0.058
1.000 1.208 0.090 0.828 11.163 0.090
1.500 1.247 0.088 0.802 11.406 0.088
2.000 1.268 0.087 0.788 11.550 0.087
2.500 1.318 0.084 0.759 11.888 0.084
3.000 1.340 0.083 0.747 12.045 0.083
3.500 1.356 0.082 0.738 12.165 0.082
4.000 1.372 0.081 0.729 12.288 0.081
6.000 1.372 0.081 0.729 12.288 0.081

V(L) Dose (m) Co


[g] (initial conc.) mg/l
0.05 1 3

Experiment Ci (mg/l) Absorbance Ce (mg/l) Percentage removal


qe (mg/g) 1/Ce 1/qe log Ce
1 10 0.328 3.587 64.133 0.321 0.279 3.118 0.555
2 20 0.31 6.780 66.102 0.661 0.148 1.513 0.831
3 30 0.356 11.679 61.072 0.916 0.086 1.092 1.067
4 40 0.369 16.140 59.650 1.193 0.062 0.838 1.208
5 50 0.412 22.526 54.948 1.374 0.044 0.728 1.353
6 60 0.383 25.128 58.119 1.744 0.040 0.574 1.400

Serial No.Conical FlaskConcentration


No. (mg/l)
DescriptionAbsorbance at 510 nm
1 1 0 50 ml distilled water 0
2 2 0.2 1 ml I.S. + 49 ml d.w. 0.034
3 3 0.5 2.5 ml I.S. + 47.5 ml d.w.0.081
4 4 0.75 3.75 ml I.S. + 46.25 d.w. 0.121
5 5 1 5 ml + 45 d.w. 0.154
6 6 1.5 7.5 ml I.S. + 42.5 d.w. 0.215
7 7 2 10 ml I.S. + 40 ml d.w. 0.383
8 8 3 15 ml I.S. + 35 ml d.w. 0.585
9 9 4 20 ml I.S. + 30 ml d.w. 0.73

y =0.1829 x and R square = 0.9876


Sample description
Initial Concentration
Final
Difference
Concentration
(mg/l)
in Concentration
(mg/l) = (initial
% removal
conc.Adsoprtion
- final
of iron
conc.)
Capacity (mg/g)
Burdwan tap water 0.694368507 0.28977583 0.4045926736 58.267716535 0.010115
Birbhum tap water 1.011481684 0.42099508 0.5904866047 58.378378378 0.014762
Old iiest building tap0.825587753
water 0.34445052 0.4811372335 58.278145695 0.012028
howrah apartment tap0.75997813
water 0.31711318 0.4428649535 58.273381295 0.011072
nt blank solution taken as distilled
0 water 0 0 0 0
average adsorption capacity=
0.011994

CONTACT TIME (minutes)


description
Final Concentration
Difference
(Ce) (mg/l)
in Concentration
% removal of
Adsoprtion
iron Capacity
5 5 min 2.66265719 0.3373428103 11.244760343 0.008434
10 10 min 2.43302351 0.5669764899 18.89921633 0.014174
15 15 min 2.24712958 0.752870421 25.0956807 0.018822
30 30 min 1.83160197 1.1683980317 38.946601057 0.02921
60 60 min 1.20831055 1.7916894478 59.722981593 0.044792
90 90 min 1.24658283 1.7534171679 58.447238928 0.043835
120 equilibrium 1.26845271 1.7315472936 57.71824312 0.043289
150
already reached equilibrium
1.31765992 1.6823400765 56.078002551 0.042059
180
already reached equilibrium
1.3395298 1.6604702023 55.349006743 0.041512
210
already reached equilibrium
1.3559322 1.6440677966 54.802259887 0.041102
240
already reached equilibrium
1.37233461 1.6276653909 54.255513031 0.040692
360
already reached equilibrium
1.37233461 1.6276653909 54.255513031 0.040692
Qe (mg/g)
log (Qe - Qt) 1/Qt 1/t t/Qt Qt/t
0.090 -1.138 59.287 12.000 4.941 0.202
0.090 -1.213 35.275 6.000 5.879 0.170
0.090 -1.284 26.565 4.000 6.641 0.151
0.090 -1.506 17.117 2.000 8.559 0.117
0.090 -4.809 11.163 1.000 11.163 0.090
0.090 -2.715 11.406 0.667 17.109 0.058
0.090 -2.520 11.550 0.500 23.101 0.043
0.090 -2.261 11.888 0.400 29.721 0.034
0.090 -2.182 12.045 0.333 36.134 0.028
0.090 -2.131 12.165 0.286 42.577 0.023
0.090 -2.085 12.288 0.250 49.150 0.020
0.090 -2.085 12.288 0.167 73.725 0.014

log qe ln Ce
-0.494 1.277
-0.180 1.914
-0.038 2.458
0.077 2.781
0.138 3.115
0.241 3.224

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